Engineering Commons^™

Oxygen Charge Transfer Reaction At The Pt/Ysz Interface, Yi Jiang, Wenzhao Li, Jingwang Yan, Shizhong Wang

Journal of Electrochemistry

Oxygen Charge transfer reaction has been investigated by various degrees of potential polarization at the Pt/YSZ interface. Anodic and cathodic charge transfer coefficients were found to be unity over the wide range of oxygen partial pressures and temperatures. While the exchange current density of the interface was found dependent on the partial pressure of oxygen in accordance with the relation: i₀=2FKr(K_O2P_O2)^1/4(1+K_O2P_O2)^1/2. Several important parameters, such as electrochemical rate constant, equilibrium constant of oxygen adsorption on Pt surface had also been extracted.

Study On Electrode Constructure And Electrical Performance Of Na/S Cell, Jianhua Yang, Jiadi Cao

Journal of Electrochemistry

A sodium wick for sodium electrode and trough shaped performs for sulfur electrode in Na/S cell were designed and investigated. The experiments suggested that the sodium wick for sodium electrode not only improved the discharge performance of cell but also reduced the quantity of sodium utilization, and increased the specific energy of Na/S cell. The trough shaped preform with alumina fibres for sulfur electrode decreased the polarization, improved the charge acceptance and prolonged the life of cell.

The Reduction Of Oxygen To Hydrogen Peroxide In An Acidic Trickle Bed Cell Using Graphite Chip Cathode, Zhaoe Lu, Guanyong Zhang, Tiangeng Zhong, Guonu Fang

Journal of Electrochemistry

The authors investigated the electrochemical reduction of oxygen to hydrogen peroxide in 0.05 mol/L H₂SO₄ solution by the trickle bed electrode using graphite chip. The bed dimension was 14×5×0.6 cm. The current efficiency and the concentration of H₂O₂ in the catholyte were determined at various current strengths and various rates of adding the electrolyte. The proper current was 0.15 A. i.e. the current density was 2.1 mA/cm² vertical cross section area of the bed. The concentration of H₂O₂ reached 7×10^-3 mol/L with the current efficiency of 0.2. If the …

Corosion Potential Imagingat The Interface Of Coating/Metal By A New Electrochemical Technique, Changjian Lin, Xiangdong Zhuo, Jidong Chen, Hui Wang, Rong-Zong Hu, Yi Song, Jian-Guang Tan

Journal of Electrochemistry

/

Surface Raman Spectra Of Pyridine And 2 Mercaptopyrimidine Adsorbed On Rough Nickel Electrode, Qunjian Huang, Jinsong Gao, Xiongwei Cai, Bingwei Mao, Mingsen Zheng, Zhongqun Tian

Journal of Electrochemistry

The Raman spectra of pyridine and 2-mercaptopyrimidine (2-MP) adsorbed on bare nickel electrodes roughened by a HNO₃ etching procedure have been obtained for the first time by utilizing a highly sensitive confocal Raman microscope. Their adsorption behaviours are discussed briefly. This primary result illustrates a great potential for in-situ Raman spectroscopy in the study of chemical and electrochemical processes of transition metal surfaces.

Studies Of Surface Treatment Methods And Their Operating Mechanisms For Activation Of Hydrogen Storage Electrode, Ronghui Hu, Hanxi Yang, Shigang Lu, Shengxian Li, Jingcheng Liu, Chongzhi Yang

Journal of Electrochemistry

Surface treatment methods by use of charge discharge cycling, KBH₄ reduction and KOH etching were parallely investigated for the rapid activation of Mn(NiCoMnAl)₅ electrode. It is found that the MH electrode treated with hot and concentrated KOH solution exhibits rapid and full activation, and also gives lower discharge overvoltage, higher stable capacity and improved cycleability. It is also revealed from SEM, EDAX and ICP analysis that the KOH activation of the electrode proceeds mainly through the enrichment of mischmetal and nickel in surface to form electrocatalytically active surface for hydrogen absorption reaction, but the surface modification with KBH …

Electrocatalytic Reduction Of Nitrite In The Presence Of Complex Of Cobalt(Ⅱ) And 1,10 Phenanthroline, Jian Tong, Xiaojun Dang, Hulin Li

Journal of Electrochemistry

The electrochemistry of cobalt(Ⅱ)-1,10-phenanthroline Co(Phen)₂²⁺ complex and its ability to electrocatalyze the reduction of nitrite were studied, we found that this complex could act as a catalyst in alkaline or neutral solution for nitrite reduction. We have investigated the effect of the complex composition on electrocatalytic ability. The effects of pH value, complex concentration, regeneration and activation of electrocatalyst on the catalytic current have been studied and discussed.

Multi-Component Perfusion Chromatography In Fixed Bed And Periodic Counter Current Column Operation, G. A. Heeter, Athanasios I. Liapis

Chemical and Biochemical Engineering Faculty Research & Creative Works

A mathematical model of multi-component dynamic adsorption in columns with spherical perfusive and spherical purely diffusive adsorbent particles with a bidisperse porous structure is constructed, solved, and used to study the performance of a binary adsorption system in a single-column fixed-bed process and in a two-column periodic countercurrent process in which the adsorbent is equally distributed over two beds. The total length of the two-column periodic counter-current system is equal to the length of the single-column fixed-bed system. The performance of fixed-bed and periodic counter-current systems with both perfusive and purely diffusive adsorbent particles is examined for different values of …

Method For Reducing The Generation Of Wear Particulates From An Implant, David A. Pienkowski

Biomedical Engineering Faculty Patents

A method is provided for reducing the amount of wear particulates generated by a total joint orthopaedic implant. The implant consists of two matched articulating components. The method includes the steps of placing the total joint orthopaedic implant in a fluid bath and articulating the implant in the fluid bath for at least 1,000 cycles. The articulation may be performed in three stages. In the first, the implant is articulated under a load of substantially 0.1-500 Newtons with sliding speeds of substantially 0.01-0.5 meters per second. During a second stage the articulation takes place under a load of substantially 200-2,500 …

Circuit Implementation Of A High-Speed Continuous-Time Current-Mode Field Programmable Analog Array (Fpaa), Osama K. Shana'a

Dissertations and Theses

The growing interest in programmable analog circuits has led to the development of Field Programmable Analog Arrays (FPAAs). An FPAA consists of: 1) a programmable cell that can be reconfigured to perform several analog functions. 2) an architecture that interconnects a number of copies of the programmable cell.

In this thesis, the full monolithic circuit implementation of the analog part of the programmable cell is presented. Chapter I gives an introduction to the idea of FPAA and introduces the FPAA architecture and the cell block diagram. Chapter II deals with the design and verification of a differential current-mode four-quadrant multiplier. …

Monitored Energy Use Patterns In Low-Income Housing In A Hot And Humid Climate, Florida Solar Energy Center, Danny Parker

FSEC Energy Research Center®

The Florida Solar Energy Center (FSEC) is metering energy use in two Habitat for Humanity developments. The objective is to understand how energy is used in low income housing and how it can be effectively reduced. The ten "control homes" come from a conventional housing project built by in 1993 Habitat for Humanity in Homestead, Florida. Another ten "experimental homes" have been recruited from the 190 home Jordan Commons development in the same vicinity. These houses, which are soon to be metered, are designed to be energy efficient with high SEER air conditioners, reflective roofing, solar water heaters and energy …

Remote Sensing Of Volcanic Ash Clouds Using Special Sensor Microwave Imager Data, David J. Delene, William I. Rose, Norman C. Grody

Department of Geological and Mining Engineering and Sciences Publications

Measurements from the satellite-based special sensor microwave imager (SSM/I) were used to collect passive microwave radiation (19–85 GHz) for the August 19, 1992 (UT date), Crater Peak/Spurr volcanic cloud. This eruption was also imaged by a ground-based C-band radar system at Kenai, Alaska, 80 km away, and by the thermal infrared channels of the polar-orbiting advanced very high resolution radiometer (AVHRR). The SSM/I sensor detects scattering of Earth-emitted radiation by millimeter size volcanic ash particles. The size of ash particles in a volcanic ash cloud can be estimated by comparing the scattering at different microwave frequencies. The mass of particles …

Side-By-Side Testing Of Commercial Office Lighting Systems: Two-Lamp Fluorescent Fixtures, Florida Solar Energy Center, Danny Parker

FSEC Energy Research Center®

Lighting systems in commercial office buildings are primary determinants of building energy use. In warmer climates, lighting energy use has important implications for building cooling loads as well as those directly associated with illumination tasks. To research the comparative performance of conventional and advanced office lighting systems, Florida Solar Energy Center (FSEC) set up the Lighting Flexible Test Facility (LFTF) which allows side-by-side comparison of lighting options in two otherwise identical 2.7 m x 3.7 m (9' x 12') south facing offices.

The ceiling of the LFTF contains 0.61 m x 1.2 m (2' x 4') recessed fluorescent fixtures designed …

Low-Frequency Noise In 4h-Silicon Carbide Junction Field Effect Transistors, J. W. Palmour, M. E. Levinshtein, S. L. Rumyantsev, Grigory Simin

Faculty Publications

Low frequency noise in 4H‐silicon carbide junction field effect transistors (JFETs) has been investigated. JFETs with a buried p ⁺ n junction gate were manufactured by CREE Research Inc. Very low noise level has been observed in the JFETs. At 300 K the value of Hooge constant α is as small as α∼10⁻⁵ and the α value can be decreased by an appropriate annealing to α∼2×10⁻⁶. It has been shown that even these extremely low noise values are determined not by the volume noise sources but by the noise at the SiC–SiO₂ interface.

Experimental And Theoretical Study Of Vibrations Of A Cantilevered Beam Using A Zno Piezoelectric Sensor, B. R. Jooste, Hendrik J. Viljoen, S. L. Rohde, N. F. J. Van Rensburg

Hendrik J. Viljoen Publications

Piezoelectric sensors can measure vibrations of solid structures very accurately. A model of a cantilevered beam, with a ZnO film on one side is presented. Both viscous and internal damping are considered. The output of the sensor is modeled and matched with experimental results by adjusting the damping parameters. A theoretical formulation for damage is introduced. Experimental results for a damaged beam confirm the shift in frequencies to lower values. The model is used to identify the extent of the damage.

Shear Wall Design Guide, Steel In Residential Construction Advisory Group

American Iron and Steel Institute (AISI) Specifications, Standards, Manuals and Research Reports (1946 - present)

No abstract provided.

Acuta Enews May 1996, Vol. 25, No. 5

ACUTA Newsletters

In This Issue

From the President

DC at a Glance

Letter to FCC

High-Tech Crime

From ACUTA Headquarters

Sizing Of Header And Flushing Manifolds For Row Crop Drip, Charles M. Burt, Stuart W. Styles

BioResource and Agricultural Engineering

No abstract provided.

Optimization Of Torquer Coil Design For Use With The Small Satellite Attitude Control Simulator, David Deloyd Anderson

Undergraduate Honors Capstone Projects

This paper presents a procedure used to optimize the performance of a ferromagnetic core magnetic torquer coil design for use on the Space Dynamics Laboratory (Logan, UT) Small Satellite Attitude Control Simulator. The items of optimization include the primary goal of maximizing the coil 's magnetic moment while reducing power consumption and system mass within given power, mass, and dimensional constraints. The optimization process makes use of several simple equations to determine a few starting points for design, after which an iterative approach based on experimentation is used to produce the final design. It is found that optimal magnetic moment …

Measured Performance Of Energy-Efficient Computer Systems, Florida Solar Energy Center, David Floyd

FSEC Energy Research Center®

The intent of this study is to explore the potential performance of both Energy Star computers/printers and add-on control devices individually, and their expected savings if collectively applied in a typical office building in a hot and humid climate. Recent surveys have shown that the use of personal computer systems in commercial office buildings is expanding rapidly. The energy consumption of such a growing end-use also has a significant impact on the total building power demand. In warmer climates, office equipment energy use has important implications for building cooling loads as well as those directly associated with computing tasks. Recently, …

Behavior And Performance Of Adsorptive Natural Gas Storage Cylinders During Discharge, K. J. Chang, Orhan Talu

Chemical & Biomedical Engineering Faculty Publications

Adsorbed natural gas (ANG) has the potential to replace compressed natural gas in mobile storage applications, such as in vehicles. Although a substantial research effort has been devoted to ANG, very few studies evaluate the impact of heat of adsorption on system performance. This paper concentrates on the impact of heat of adsorption on ANG performance during discharge, while the gas outflow rate is dictated by the energy demand of the application. The temperature drop and performance loss was measured with commercially available ANG cylinders under realistic conditions. Data show as high as a 37°C temperature drop at …

A Computer Model For Analysis Of Alternative Burley Tobacco Harvesting Practice, Thomas C. Bridges, Larry G. Wells, George A. Duncan, Larry D. Swetnam

Agricultural Engineering Extension Publications

Agricultural operations and practices have been the subject of many computer models and simulations. Holtman et al. (1970) developed a corn harvesting simulator, and Morey et al. (1971) used simulation techniques to analyze net profit of a corn harvesting and handling system during a particular weather year. Further, Loewer et al. (1977) advanced a model that assessed alternative beef production strategies for the individual farm with land, energy and capital as constraints. Bridges et al., (1979) developed a design simulation oriented toward the individual producer that examines corn harvesting systems and compares them regarding investment and annual cost. The CATCH …

Genetic Algorithms Vs. Simulated Annealing: A Comparison Of Approaches For Solving The Circuit Partitioning Problem, Theodore W. Manikas, James T. Cain

Computer Science and Engineering Research

An important stage in circuit design is placement, where components are assigned to physical locations on a chip. A popular contemporary approach for placement is the use of simulated annealing. While this approach has been shown to produce good placement solutions, recent work in genetic algorithms has produced promising results. The purpose of this study is to determine which approach will result in better placement solutions.

A simplified model of the placement problem, circuit partitioning, was tested on three circuits with both a genetic algorithm and a simulated annealing algorithm. When compared with simulated annealing, the genetic algorithm was found …

Wright State University College Of Engineering And Computer Science Bits And Pcs Newsletter, Volume 12, Number 5, May 1996, College Of Engineering And Computer Science, Wright State University

BITs and PCs Newsletter

An eight page newsletter created by the Wright State University College of Engineering and Computer Science that addresses the current affairs of the college.

A New Grouping Measure For Evaluation Of Machine-Component Matrices, Hamid Seifoddini, Manocher Djassemi

Industrial Technology and Packaging

The machine-component matrix is the main input to most machine-component grouping models used in cellular manufacturing. A number of measures have been developed for performance evaluation of machine-component grouping algorithms. In this paper, the relationship between these measures and the performance of the corresponding cellular manufacturing system is evaluated and a new grouping measure is developed which is more consistent in predicting the suitability of a manufacturing system for cellular manufacturing.

Nucleation Initiated Spinodal Decomposition In A Polymerizing System, Thein Kyu, Jae Hyung Lee

College of Polymer Science and Polymer Engineering

Dynamics of phase separation in a polymerizing system, consisting of carboxyl terminated polybutadiene acrylonitrile/epoxy/methylene dianiline, was investigated by means of time-resolved light scattering. The initial length scale was found to decrease for some early periods of the reaction which has been explained in the context of nucleation initiated spinodal decomposition We have combined the Cahn-Hilliard kinetic equation and polymerization kinetics, and predicted the initial reduction of the length scale triggered by nucleation.

Macrosegregation During Dendritic Arrayed Growth Of Hypoeutectic Pb-Sn Alloys: Influence Of Primary Arm Spacing And Mushy Zone Length, Surendra N. Tewari, Rajesh Shah

Chemical & Biomedical Engineering Faculty Publications

Thermosolutal convection in the dendritic mushy zone occurs during directional solidification of hypoeutectic lead tin alloys in a positive thermal gradient, with the melt on the top and the solid below. This results in macrosegregation along the length of the solidified samples. The extent of macrosegregation increases with increasing primary dendrite spacings for constant mushy zone length. For constant primary spacings, the macrosegregation increases with decreasing mushy zone length. Presence of convection reduces the primary dendrite spacings. However, convection in the interdendritic melt has significantly more influence on the spacings as compared with that in the overlying melt, which is …

Nonlinear Analysis Of Airfoil Flutter At Transonic Speeds, Scott A. Morton

Theses and Dissertations

Hopf-bifurcation analysis is used to determine flutter boundaries of a pitch and plunge airfoil (PAPA) at transonic Mach number conditions. The PAPA model is a coupling of the Euler equations and a two-degree-of-freedom structural model composed of linear and torsional springs. The Euler equations are discretized using an upwind total variation diminishing scheme (TVD) of Harten and Yee. Equilibrium solutions of the PAPA model are computed using Newton's method and dynamic solutions are explicitly integrated in time with first-order accuracy. The Hopf-bifurcation point, which models the flutter condition, is computed directly by solving an extended system of equilibrium equations following …

Mathematics: Meeting The Needs Of High Education, Industry, And The Students Of Electronics Engineering Technology At Hawkeye Community College, Stanley J. Niedermann

Graduate Research Papers

This study pertained to a problem faced by officials of Hawkeye Community College (HCC). With the Tech-Prep educational reform now taking place in the United States and with the ever increasing diversity of electronics, those officials had to make a decision about the status of the courses entitled Applied Algebra and Electronics Math, both of which are included in the electronics engineering technology program at HCC.

The purpose of this study was to determine which mathematics courses were most appropriate for electronics technicians now and in the near future. Three research questions required answers: Question 1 -- should Applied Algebra …

A Comparative Analysis Of Viable Solar Thermal Technologies For Solar Field Development And Commercialization, Sean M. Crawford

UNLV Theses, Dissertations, Professional Papers, and Capstones

Diminishing fossil fuels and concerns about the quality of the environment has lead the recent drive to establish a commercialized solar field in Southern Nevada. The competing solar thermal technologies for the Solar Enterprise Zone (SEZ) are Parabolic Dish-Stirling, Central Receiver Power Towers, and Parabolic Trough Systems. It is important to compare the technologies based on the guidelines set by the Corporation for Solar Technology and Renewable Resources. The variables weighted are solar conversion performances, initial capital investment, operation and maintenance costs, water and land use, and electricity production costs. All technologies have been proven to viable power sources and …