Engineering Commons^™

Effect Of Adding Silver Element And Zirconia Ceramic On Corrosion Behavior And Mechanical Properties Of Pure Titanium, Wehad Al-Rawy, Emad Al-Hassani

Engineering and Technology Journal

In this research, all the samples are prepared using the powder metallurgy technique by adding silver element and Zirconia ceramic material to the commercially pure titanium at a different weight percent of (10, 20 and 30) to investigate the effect of adding these materials to the CP-Ti on corrosion behavior and mechanical properties. There are two sets of each type of alloys Ti-Ag and Ti ZrO2. The Preparation process was by Weighing, Mixing and Homogenizing Powders by Ball Mill, compacting at 4 tons for 1 min. and Sintering at 700 and 900 °C for 2 hrs. under a controlled atmosphere. …

Investigating The Corrosion Behavior Of Stainless Steel 316 In Static Lead Lithium Eutectic Under Applied Stressed Conditions, Daniel E. Levario

Nuclear Engineering ETDs

As fusion power moves closer to feasibility, identifying structural materials compatible with breeding blanket environments remains a critical challenge. Lead-lithium eutectic (LLE) is a leading candidate breeder and coolant material due to its low melting point and combined tritium breeding and neutron multiplication capability. However, the corrosive nature of LLE toward structural steels at elevated temperatures must be characterized before these systems can be reliably deployed. This study investigates the corrosion behavior of Type 316 stainless steel in static LLE under applied stress conditions at 550°C using C-ring stress corrosion specimens. Post exposure analysis via optical microscopy, SEM, EDS, and …

Characterization Of Various Corrosion-Resistant Rebars Embedded In Concrete After 20 Years Of Exposure, Samantha Mavrak

Electronic Theses and Dissertations

In aggressive marine environments, the deterioration of reinforced concrete structures is primarily caused by chloride-induced corrosion of embedded carbon steel reinforcement, resulting in concrete cracking, spalling, and costly maintenance or premature replacement. Corrosion-resistant reinforcement has been developed to mitigate these effects; however, long-term field performance data remain limited. This study evaluates the long-term corrosion performance of several corrosion-resistant rebars embedded in simulated deck slab concrete specimens following approximately 20 years of chloride exposure.

Concrete specimens containing 304SS, 316SS, and 2304 duplex SS, two types of clad reinforcement (316SS with carbon steel core), and an intermediate alloy with 12% Cr were …

Improvement Of Mechanical And Corrosion Properties Of Weld In Stainless Steel In Crude Oil Tank By Using Nano-Fillers, Ali Abdulzahra Shanshoon

Al-Esraa University College Journal for Engineering Sciences

The aim of this study is to investigate the corrosion behavior and mechanical properties of welded steel exposed to gases emitted from crude oil reservoirs. In this study, two types of nanoparticles were used as fillers during welding to improve corrosion and mechanical properties. TiO₂ and SiO₂ nanoparticles were mixed with soldering oil in four mass concentrations of 0, 1, 2.5 and 5% by ultrasonic bath method and used as filler during the welding process. In order to prepare the samples, plain carbon steel with a thickness of 3 mm was used and they were welded together by …

Effect Of Heat Treatments On The Corrosion Resistance Of A Trip Steel And Its Evaluation By Non-Destructive Testing, Karla Ivette Vega-Nava, Ariosto Medina-Flores, Marco Antonio Espinosa-Medina, José Sergio Pacheco-Cedeño, Héctor Guillermo Carreón-Garcidueñas, Francisco Fernando Curiel-López, Jose Jaime Taha-Tijerina

Mechanical Engineering Faculty Publications

The development of advanced high-strength steels (AHSS) for the automotive industry requires optimizing the balance between mechanical properties and durability in aggressive environments. This study investigates the effects of two heat treatment routes on the microstructure and corrosion resistance of a transformation-induced plasticity (TRIP) steel (Fe-0.2C-1.75Mn-0.5Si-1Al). Route A includes a full austenitizing step at 1000 °C prior to intercritical annealing, whereas Route B omits this step and begins directly with intercritical annealing at 800 °C. Microstructural characterization (SEM/XRD), electrochemical assays, and eddy current tests were employed. The results revealed that Route A yields a homogeneous microstructure with 12.7% retained austenite, …

Development Of A Lead-Lithium Eutectic Magnetohydrodynamic Loop For Corrosion Studies, Xavier S. Angus

Nuclear Engineering ETDs

Lead–lithium eutectic (LLE) is a leading candidate coolant and tritium breeder for fusion reactor blankets due to its favorable heat transfer properties and high tritium breeding ratio. However, LLE is highly corrosive and, in the strong magnetic fields present in fusion reactors, experiences magnetohydrodynamic (MHD) effects that can produce significant pressure drops and flow instabilities. Understanding corrosion behavior in these extreme environments is essential for assessing the viability of LLE blanket systems. This work presents the design and construction of a forced-convection LLE corrosion loop to study corrosion behavior at temperatures up to 425 °C and flow velocities up to …

Steel Corrosion In Underground Transportation Infrastructure, Amr M. Morsy, Islam A. Ebo, Shiv K. Janardhanan

Mineta Transportation Institute

Corrosion of buried steel, a critical component of American transportation infrastructure, remains one of the most insidious challenges due to the uncertainty associated with its estimates. Predicting when and how this corrosion happens is very difficult. This uncertainty grows exponentially with time, making corrosion estimation in the long term even more challenging, especially with buried steel and steel structures, which cannot even be monitored visually. While significant advancement has been made to understand the effect of the various corrosion parameters on soil corrosivity, there is a lack of a comprehensive understanding of how these factors collectively contribute to corrosion as …

Evaluation Of Polyester Polymer Concrete Overlays On Bridge Decks In Utah, Landon Moore

Theses and Dissertations

The objective of this research was to evaluate the condition of polyester polymer concrete (PPC) overlays placed on both new and in-service concrete bridge decks in Utah. The procedures for this research included a desktop review of 80 bridges with PPC deck overlays; scanning of nine decks using rapid automated sounding and advanced deck imaging technologies to document delamination, cracking, spalling, and patching; and additional testing of two decks. This research involved evaluations of PPC overlays that were 2 to 8 years old and bridges that were 4 to 40 years old at the time of testing. The primary distresses …

Data-Driven Prediction Of Concrete Bridge Deck Corrosion Using Ground Penetrating Radar (Gpr), Nafisa Shafiullah

Civil Engineering Theses

Corrosion detection remains a crucial factor in the proper maintenance of Reinforced Concrete (RC) structures. While several studies have used Ground Penetrating Radar (GPR) for corrosion detection, quantitative models for prediction are still limited. This study presents an approach for the quantitative prediction of rebar corrosion in concrete using GPR data obtained from a prior experimental program involving accelerated corrosion. A total of 36 RC samples were cast, varying in cover depth, rebar diameter, and concrete porosity. The samples were subjected to an impressed current of 0.65 A in a 5% NaCl solution over three phases: 10, 20, and 30 …

Effect Of Niobium Addition On Corrosion Behavior, Mechanical Properties, And Microstructures Of U6zr Alloys In An Aerated Environment, Masrukan Masrukan, Djati Handoko, Dede Djuhana, Rohmad Sigit, M. Husna Al Hasa, Wisnu Ari Adi, Siti Mardiah

Makara Journal of Science

The effect of Nb addition on the corrosion behavior of U–6Zr alloys within an aerated, demineralized water (DW) environment (pH 5.61) and its correlation of this addition with the mechanical and microstructural properties of the alloys were investigated. The U–6Zr–xNb alloys (x = 1, 4, and 7 wt.%) were synthesized by arc-melting U, Zr, and Nb. Additionally, the samples were mounted and polished, after which they were subjected to electrochemical corrosion analysis using a potentiostat. This evaluation was conducted in a DW medium (pH 5.6), representing an aerated atmosphere, at room temperature (27°C) and a potentiodynamic scan rate of 1 …

Rehabilitation Of Reinforced Concrete Columns Pre-Damaged By Corrosion Using Advanced Composite Materials, Feras Farid Abu Obaida

Thesis/ Dissertation Defenses

Reinforced concrete (RC) columns exposed to aggressive environments are highly susceptible to corrosion-induced deterioration, resulting in significant reductions in load-carrying capacity. This research investigates the structural performance of RC circular short columns with varying levels of corrosion damage and evaluates the effectiveness of two composite-based repair techniques, namely carbon fabric-reinforced cementitious matrix (C-FRCM) and carbon fiber-reinforced polymer (C-FRP) composites, combined with concrete cover replacement. The study aims to establish these methods as practical solutions for rehabilitating corrosion-damaged columns under concentric and eccentric loading conditions. The experimental program included 30 RC column specimens tested in two phases. Phase I involved thirteen …

Investigation Of Electrochemical Corrosion Fatigue Mitigation Strategies For Mild Carbon Steel, Joel Andrew Hudson

Doctoral Dissertations

Corrosion fatigue remains a critical durability challenge for steels used in boiler tubes and other safety-critical components, where the interaction of cyclic stresses and corrosive environments accelerates material degradation. This dissertation comprises three experimental studies aimed at advancing mitigation strategies and test methodologies: (1) enhancing corrosion resistance through electrodeposited Fe-Ni anodic coatings, (2) inducing synthetic crack closure to suppress fatigue crack growth, and (3) developing an accessible, low-cost, automated testing system to investigate environmentally assisted cracking (EAC) under controlled laboratory conditions. The first study examined the corrosion behavior of Fe and Fe-Ni electrodeposits synthesized from sulfate-based baths and applied to …

A Magnesium Alloy With High Corrosion Resistance, Hardness And Elastic Modulus Enabled By Elemental Synergy, Alexander Helmer, Manoj V. Mugale, Tushar Borkar, Rajeev K. Gupta

Mechanical Engineering Faculty Publications

A magnesium alloy containing Ca, Ti, Zn, and In was synthesized via high-energy ball milling of elemental powders followed by spark plasma sintering. X-ray diffraction and scanning electron microscopy revealed a homogeneous matrix with dispersed Mg-rich phases and intermetallics. Potentiodynamic polarization tests revealed low corrosion current density (9.6 f 2.1 mu A/cm2), a noble corrosion potential (-1197 f 4 mVSCE), and a clear passive region, indicating excellent corrosion resistance. Nanoindentation tests showed high hardness (2.61 f 0.21 GPa) and elastic modulus (55.35 f 5.47 GPa), exceeding those of commercial Mg alloys.

Rehabilitation Of Reinforced Concrete Columns Pre-Damaged By Corrosion Using Advanced Composite Materials, Feras Farid Abu Obaida

Dissertations

Reinforced concrete (RC) columns exposed to aggressive environments are highly susceptible to corrosion-induced deterioration, resulting in significant reductions in load-carrying capacity. This research investigates the structural performance of RC circular short columns with varying levels of corrosion damage and evaluates the effectiveness of two composite-based repair techniques, namely carbon fabric-reinforced cementitious matrix (C-FRCM) and carbon fiber-reinforced polymer (C-FRP) composites, combined with concrete cover replacement. The study aims to establish these methods as practical solutions for rehabilitating corrosion-damaged columns under concentric and eccentric loading conditions. The experimental program included 30 RC column specimens tested in two phases. Phase I involved thirteen …

Improving Fatigue Strength And Life Of Single Crystal Cmsx-4, Jochen Peter Fuhr, Lloyd Hackel, Nicolau I. Morar, Noah Holtham, Keivan Davami, Montu Sharma, Rajkumar Roy

15th International Conference on Shot Peening

The deep penetration of laser peening (LP) and retention of residual stress at high temperature by LP is significant in improving fatigue life and strength of superalloys exposed to high temperature and corrosion. Single crystal CMSX-4, was evaluated for stress relaxation and both fatigue life and fatigue strength of material that was LP-treated compared to non-LP and shot-peened (SP) specimens. LP was done with multiple layers using a 20 J/pulse laser where the laser high energy enabled using a 5 mm spot size on the metal surface. Stress measurements by the slitting technique showed the plastic penetration depth exceeded SP …

Corrosion Behavior Of Mgtizn And Mg4tizn Alloys After Ball Milling And Subsequent Spark Plasma Sintering, Alexander Helmer, Rahul Agrawal, Manoj Mugale, Tushar Borkar, Rajeev Gupta

Mechanical Engineering Faculty Publications

Magnesium-containing multi-principal element alloys (MPEAs) are promising for lightweight applications due to their low density, high specific strength, and biocompatibility. This study examines two Mg-Ti-Zn alloy compositions, equal molar MgTiZn (TZ) and Mg4TiZn (4TZ), synthesized via ball milling followed by spark plasma sintering, focusing on their microstructures and corrosion behaviors. X-ray diffraction and transmission electron microscopy revealed the formation of intermetallic phases, including Ti2Zn and Mg21Zn25 in TZ, while 4TZ exhibited a predominantly Mg-rich phase. Potentiodynamic polarization and immersion tests in 0.1 M NaCl solution showed that both alloys had good corrosion resistance, with values of 3.65 +/- 0.65 mu …

Experimental Characterisation Of Laser Cladding Of Crniw And Crnifealzr Powders On H13 Tool Steel And Optimisation Of Process Parameters, Martin Vinoth S

Theses and Dissertations

In this work, laser cladding on H13 steel substrate with two different powder compositions CrNiW and CrNiFeAlZr has been carried out. The laser power, powder feed rate, and scanning speed were varied and the clad dimensions, aspect ratio, and dilution percentage were measured. The microhardness found in the CrNiW clad is 834 ± 20 HV0.5, which is higher than that of the CrNiFeAlZr clad (780 ± 20 HV0.5) as well as the substrate (548 ± 20 HV0.5).

The X-ray Diffraction (XRD) patterns identified the common phase creation of Ni3C and Fe3C for CrNiFeAlZr and CrNiW coatings, while the oxide formation …

Analysis Of The Mechanical, Microstructural, And Biocompatibility Properties Of Novel Magnesium-Based Hybrid Nanocomposite Materials For Orthopedic Applications, Thomas H. Mcgehee

Biomedical Engineering Undergraduate Honors Theses

Bone fractures and complete joint replacements are becoming more common, primarily because of accidents and age-related issues. Conventional solutions to treat these orthopedic injuries involve inert metal alloys to correct bone fractures until the healing process is complete, where a secondary revision surgery is then required to remove the implant. Issues regularly associated with these solutions include stress shielding, bone resorption, infection, inflammation, and implant loosening. Magnesium (Mg)-based nanocomposites offer promising potential as an alternative to commonly used metal alloys because of their favorable mechanical properties and biocompatibility. A particularly advantageous property of Mg is its natural biodegradation in vivo, …

Experimental Study Of Novel Bcsa Scc Repair Materials And Implications On Corrosion In Bcsa Concrete Structures, Elizabeth S.M. Poblete

Graduate Theses and Dissertations

Some current building codes for structural concrete allow the use of alternative cement concrete if their structural, durability, and fire performance can be shown to be comparable to portland cement (PC) concrete. One such alternative cement, belitic calcium sulfoaluminate (BCSA) cement, is a promising standalone replacement for portland cement given its lower global warming potential (GWP), fast setting time, and high early age compressive strength. These properties also make it an ideal repair material. But repair materials often need to be highly flowable and easy to consolidate and their performance when used to repair PC concrete structures must be understood. …

Fabrication And In Vitro Biocompatibility Assessment Of Composite-Coated Magnesium Materials, Bryce Williams

Biomedical Engineering Undergraduate Honors Theses

This study provides a comparative assessment of the corrosion, morphology, and biological properties of four of the most promising coating methods for magnesium in biomedical applications, namely micro-arc oxidation (MAO), graphene oxide (GO)-containing MAO coating, MAO/sol-gel composite coating, and MAO/polycaprolactone (PCL) polymer dip coating approaches. Despite the abundance of research focused on these promising approaches, there is a notable lack of comparative studies evaluating their properties. To this end, the investigated composite coatings are ZK60+MAO, ZK60+MAO/GO, ZK60+MAO/Sol-gel, and ZK60+MAO/PCL composite coating. Several tests were used to assess various properties of the prepared groups such as in vitro corrosion characteristics, surface …

Development Of A Probabilistic Interaction Rule And Failure Pressure Model For Pipelines With A Colony Of Corrosion Defects, Kiswendsida J. Kere

Civil and Environmental Engineering Faculty Research and Publications

The interaction effect originating from a defect colony can pose a higher pipeline failure risk than the case when such possible interaction is not considered. Recognizing the limitations in existing models that can lead to inaccurate pipeline integrity assessment, the goal of this study is to develop a probabilistic interaction rule and predictive burst failure pressure model for pipelines with a colony of corrosion defects. First, a comprehensive database of burst failure pressure for pipes with a colony of corrosion is established that encompasses a wide range of influencing factors (e.g., spacing, defect sizes, and material properties) on the defect …

Behavior Of Buried Sliplined Corrugated Metal Pipes Subjected To Footing Loading, S. Mustapha Rahmaninezhad, Saif Jawad, Jie Han, Mahdi Al-Naddaf, Robert L. Parsons

Civil Engineering Faculty Publications

Buried structures (e.g., culverts and pipes under roadways) installed several decades ago are reaching the end of their service life. Excavation and replacement of these structures will cause disturbances to the transportation network and require significant funding. Trenchless techniques (e.g., sliplining) have been increasingly employed to rehabilitate deteriorated buried structures (e.g., corroded corrugated steel pipes). Sliplining includes inserting a new pipe (liner) into an existing deteriorated pipe and filling the gap between them with grout. The objective of this study was to evaluate the effect of sliplining on the behavior of buried corrugated steel pipes with different degrees of corrosion …

Feasibility Of Hyperspectral Sensing For Detection Of Early Stages Of Corrosion In Structural Steel, Amrita Das, Sattar Dorafshan

Civil Engineering Faculty Publications

The estimated global cost of steel atmospheric corrosion is 3-4% of the Gross Domestic Product, despite decades of corrosion mitigation practice. Steel, widely used for infrastructure construction, is composed primarily of iron and therefore is extremely vulnerable to atmospheric corrosion. The free iron atoms are highly reactive with water and oxygen molecules abundantly found in the atmosphere. Common non-contact in-field corrosion detection methods such as visual imaging and passive infrared thermography (IRT) use characteristics of visible corrosion compounds as the main features for corrosion detection. In this study, diffuse spectroscopy is investigated for the feasibility of corrosion detection before visual …

Quantifying The Impact Of Highly Corrosive Environments On Fsrm Budgets And Infrastructure Condition At Air Force Bases, Justin M. Weber

Theses and Dissertations

The Department of Defense (DoD) faces significant challenges in maintaining mission-critical infrastructure within highly corrosive environments, with annual costs exceeding $22.5 billion to combat corrosion. This thesis investigated the interplay between environmental severity, sustainment funding, and infrastructure performance. This research utilized Facility Sustainment, Restoration, and Modernization (FSRM) funding data, statistical analyses, and regression modeling, to evaluate how Environmental Severity Index (ESI) categories influence Base Condition Index (BCI) trends and the efficacy of the Facility Sustainment Model (FSM). The analysis revealed that installations in higher ESI categories required significantly greater investment per square foot to achieve comparable improvements in BCI. The …

Materials Reliability In Direct-To-Chip Cooling: A Systematic Study Of Aluminum Corrosion In Next-Generation Data Center Coolants, Fnu Harish Gangadhara

Mechanical and Aerospace Engineering Theses - Archive

Data centers are rapidly scaling to support artificial intelligence, cloud platforms, and other high-performance workloads, driving a sharp increase in chip and rack power densities that are now approaching, and in some cases surpassing, 50–100 kW per rack. In response, direct-to-chip liquid cooling has become a key enabling technology for managing these extreme thermal loads, yet the durability of materials in contact with the coolant remains a major reliability concern over system lifetimes. Copper has traditionally been used for cold plates and cooling-loop components, but its relatively high cost, mass, and supply-chain uncertainty are motivating a shift toward aluminum as …

Rhamnolipid As An Effective Srb Biocide – Determining A Solution To Replicate Anticipated Conditions, Elizabeth Zimmerer

Williams Honors College, Honors Research Projects

This project aimed to develop a laboratory-scale solution that replicates produced water conditions (CO₂ + brine) found in crude pipelines, with the added requirement of promoting the growth of sulfate-reducing bacteria (SRB). A previously successful study was used as a reference, which employed a hybrid salt solution containing essential nutrients and environmental factors. The proposed solution included 10 g sodium chloride, 1 g sodium pyruvate, 0.2 g ammonium chloride, and 0.8 g sodium sulfate per liter of deionized water. Electrochemical testing (Linear Polarization Resistance and Electrochemical Impedance Spectroscopy) was performed on solutions with and without rhamnolipid. Results from the …

Separating The Impacts Of A Corrosion Inhibitor From Copper Corrosion Products On Antibiotic Resistance In Drinking Water, Veronika Folvarska, Maya Adelgren, Emily Lou Lamartina, Ryan J. Newton, Yin Wang, Patrick J. Mcnamara

Civil and Environmental Engineering Faculty Research and Publications

Antibiotic resistance is a growing threat to public health, and environmental factors, including metals in drinking water distribution systems, are increasingly recognized as contributors to the spread of antibiotic resistant bacteria (ARB) and antibiotic resistance genes (ARGs). Zinc orthophosphate, a common corrosion inhibitor, and copper corrosion products (CuO and Cu₂O) are frequently present in drinking water systems. While each has been shown to increase ARB and ARGs individually, their combined effects remain unknown. The objective of this study was to evaluate the combined impact of copper corrosion products and the corrosion inhibitor zinc orthophosphate on antibiotic resistance. Two …

Experimental Evaluation Of Corrosion Of Strands And Wires To Estimate Corrosion Rate In Grout And Concrete, Dipendra Shrestha

Dissertations and Doctoral Documents, University of Nebraska-Lincoln, 2023–

Premature failure of prestressed and post-tensioned concrete structures is frequently caused by undetected corrosion of prestressing steel. Although extensive research has addressed corrosion rates in conventionally reinforced concrete, the interpretation of non-destructive parameters, such as half-cell potential (HCP) and concrete/grout resistivity, for estimating corrosion rates in prestressing steel are not adequately investigated.

This research experimentally evaluates chloride-induced corrosion of prestressing steels to establish material-specific relationships between in-situ measurable parameters and corrosion rate. Thirty-six macrocell specimens incorporating plain wires, indented wires, and seven-wire strands in structural concrete and commercial post-tensioning grout- half with pre-formed surface cracks, were subjected to accelerated cyclic …

Corrosion Of Pipes In Soil Under Cathodic Protection, Ashley Chow

Williams Honors College, Honors Research Projects

This research project focuses on understanding how various soil properties affect the corrosion of buried pipelines that are protected by cathodic protection (CP) systems. Specifically, the study seeks to evaluate key soil characteristics, including resistivity, moisture content, and pH levels to determine their influence on the efficiency of CP systems in mitigating corrosion. Through controlled laboratory experiments, carbon steel specimens were exposed to a range of simulated soil conditions to mimic real-world environments. Corrosion rates were assessed using advanced electrochemical techniques, such as linear polarization resistance (LPR) and Tafel slopes, along with traditional mass loss methods. The primary objectives of …

Urotropine As A Corrosion Inhibitor In Steel Rebar: A Molecular Dynamics Study, Tyler Zadrozny

Williams Honors College, Honors Research Projects

This project investigates the behavior of corrosion in rebar, a critical component in infrastructure such as roads and skyscrapers. Corrosion of rebar can lead to structural instability, visible as cracks or pitting on the surface. The primary focus is on the potential of urotropine as a corrosion inhibitor. Urotropine, known for its ability to inhibit corrosion in mild steel in acidic environments, is hypothesized to be effective in preventing corrosion on rebar. To explore this, molecular dynamics simulations using LAMMPS were conducted, modeling urotropine molecules in an acidic solution (PH = 1) interacting with iron atoms, mimicking rebar. Simulations were …