Open Access. Powered by Scholars. Published by Universities.®

Engineering Commons

Open Access. Powered by Scholars. Published by Universities.®

Dissertations

Discipline
Institution
Keyword
Publication Year
Publication Type

Articles 1 - 30 of 1866

Full-Text Articles in Engineering

Engineered Porous Structures For Propellants Using Additive Manufacturing, Elbert Caravaca Aug 2026

Engineered Porous Structures For Propellants Using Additive Manufacturing, Elbert Caravaca

Dissertations

Foamed polymers are widely used today for shock absorption and packaging materials to prevent damage to their contents. Typical foamed densities vary from 0.1 g/cm3 to 0.4 g/cm3 depending on the polymeric materials used. There is a need to explore foaming densities above 0.4 g/cm3 for propellants with highly engineered surface area progression for increased combustion performance. One way to achieve this is through highly controlled and engineered graded foam structures. To further exploit this approach, additive manufacturing coupled with a tunable means to generate foamed structures is the target of this work. To generate foam structures …


Optimizing Few-Shot Learning In Pruned Large Language Models With Task-Specific Prompts, Danyal Aftab Aug 2026

Optimizing Few-Shot Learning In Pruned Large Language Models With Task-Specific Prompts, Danyal Aftab

Dissertations

Few-shot learning enables large language models to efficiently perform tasks given only a limited number of labeled examples. However, training these models entirely from scratch requires substantial computational resources, making it challenging for many organizations to fully leverage their potential. This thesis explores how structured pruning, task-specific prompting, and parameter-efficient fine-tuning can be combined to preserve few-shot learning capabilities in compressed LLMs, while also extending their utility to real-world recommendation systems.

In this research, we propose the Tailored LLM framework, which first reduces model size through structured pruning and then enhances few-shot learning performance using carefully designed prompts. We experiment …


Constructing Female High School Students’ Stem Self-Efficacy: The Role Of High School Stem Research Experiences, Hyunjin Son Aug 2026

Constructing Female High School Students’ Stem Self-Efficacy: The Role Of High School Stem Research Experiences, Hyunjin Son

Dissertations

In the U.S., nearly a quarter of the workforce is employed in Science, Technology, Engineering, and Mathematics (STEM) occupations. However, the STEM workforce lacks diversity, limiting perspectives to address real-world problems facing society. While many factors influence decisions to pursue STEM majors in college and enter the STEM workforce, one factor commonly associated with performance and persistence in STEM is STEM self-efficacy. Independent research experiences have been shown to increase conceptual understanding and confidence in STEM, leading to STEM degrees and careers. As high school co-curricular STEM research opportunities become more common, the effects of such experiences on students’ STEM …


Machine Learning For Predictive Energy And Emissions Modeling Of Vehicles And Power Grids In The United States, S M Tanvir Faysal Alam Chowdhoury Aug 2026

Machine Learning For Predictive Energy And Emissions Modeling Of Vehicles And Power Grids In The United States, S M Tanvir Faysal Alam Chowdhoury

Dissertations

The environmental benefits of electric vehicle (EV) adoption depend on more than replacing internal combustion engine vehicles with electric powertrains. EV adoption reshapes electricity demand, interacts with regional generation mixes, and influences travel behavior and congestion, creating a coupled transportation-energy system in which vehicle and power-plant emissions must be evaluated together. This dissertation develops machine-learning frameworks for predicting energy consumption and emissions from vehicles and power grids under rising EV adoption. The first component forecasts grid emissions from EV charging. Using simulation data from NREL's Cambium database, a Prophet-based time-series framework predicts carbon dioxide, nitrous oxide, and methane emission rates …


Monitoring And Short-Term Forecasting Of Atmospheric Air Pollutants Using Deep Neural Networks, Prasanjit Dey Jul 2026

Monitoring And Short-Term Forecasting Of Atmospheric Air Pollutants Using Deep Neural Networks, Prasanjit Dey

Dissertations

Accurate forecasting of near-surface atmospheric air pollutants such as PM2.5, NO2, SO2, CO, and O3 remains a critical scientific and societal challenge. This difficulty arises from several factors, including nonlinear pollutant dynamics, sparse ground monitoring net works, heterogeneous satellite observations, and strong cross-pollutant interdependencies. Substantial advances have been achieved in temporal deep learning, probabilistic modeling, satellite-based estimation, physics-informed methods, and foundation models. However, these paradigms have largely evolved in isolation. As a result, existing systems are often station-dependent or pollutant-specific and optimized for a single forecasting task. This limits their robustness and generalizability across regions and heterogeneous data regimes.

This …


Strategies For Extending The Service Life Of Prestressed Concrete I-Shaped Beams, Sanjoy Kumar Bhowmik Jun 2026

Strategies For Extending The Service Life Of Prestressed Concrete I-Shaped Beams, Sanjoy Kumar Bhowmik

Dissertations

Prestressed concrete (PSC) I-shaped beams are widely used in bridge construction because of their structural efficiency and durability. The service life of these beams is reduced and the maintenance frequency is increased due to the distress during fabrication and subsequent deterioration. Although several mitigation strategies have been proposed and implemented, beam end cracking during fabrication remains a major concern. The causes and mitigation strategies for beam end cracking have been studied for decades, but there have been no comprehensive studies utilizing beam end strains during fabrication and lifting at prefabrication plants under normal operational conditions. Moreover, existing maintenance and repair …


Quantum And Conventional Informatics Studies Of Synthesis Energetics And Defect Formation In Nitride Crystal Epitaxy, Andrew Steven Messecar Jun 2026

Quantum And Conventional Informatics Studies Of Synthesis Energetics And Defect Formation In Nitride Crystal Epitaxy, Andrew Steven Messecar

Dissertations

Machine learning is a valuable approach for the processing and analysis of complex information. By estimating relationships from recorded data, machine learning methodologies can be effective strategies for pattern recognition, enabling investigations and technological applications based thereon. The potential for improved understanding of high-dimensional data has drawn interest towards machine learning from across the sciences, including the research and development of new and improved material systems. In the context of experimental materials research, much of the reported efforts to incorporate machine learning into conventional practice have been primarily focused on either the enhanced analysis of characterization experiment data or the …


Mechanics And Physical Attributes Of Nature-Based Alterations: Rock Reinforcement And Urban Heat Island Assessment, Mary Chikondi Ngoma May 2026

Mechanics And Physical Attributes Of Nature-Based Alterations: Rock Reinforcement And Urban Heat Island Assessment, Mary Chikondi Ngoma

Dissertations

Ground improvement is critical to geotechnical and geo-engineering systems, where modification of the properties of geomaterials (rocks and soils) is required to maintain stability and prevent failure of infrastructure installed within and around them. This need has become increasingly important with rapid urbanization and population growth, which intensify demands on surface and subsurface systems and further challenge the performance of supporting geomaterials. As a result, there is growing interest in nature-based solutions, particularly biologically mediated processes such as biocementation, which can enhance the physical, hydraulic, and mechanical properties of geomaterials while offering environmentally sustainable alternatives to conventional ground improvement techniques. …


Enabling Ml/Ai In 6g And Future Wireless Communication With Privacy Preservation, Mec Offloading And Quantum Computing, Changshi Zhou May 2026

Enabling Ml/Ai In 6g And Future Wireless Communication With Privacy Preservation, Mec Offloading And Quantum Computing, Changshi Zhou

Dissertations

The forthcoming sixth-generation (6G) and future wireless networks are envisioned to support an unprecedented range of services, delivering ultra-low latency, massive connectivity, and intelligent real-time responsiveness. These capabilities will enable emerging applications such as extended reality (XR), autonomous vehicles (AVs), industrial robotics, and the Internet of Things (IoT) to reach their full potential. Achieving this vision requires the integration of enabling technologies such as artificial intelligence and machine learning (AI/ML) and quantum computing, which are poised to play central roles in shaping the landscape of wireless communication systems.

In AI-native, data-driven, and computing-centric 6G networks, ML models will be deeply …


Holistic Dram Enhancements: From Intrinsic In-Memory Operations To Robust Security Mechanisms, Ranyang Zhou May 2026

Holistic Dram Enhancements: From Intrinsic In-Memory Operations To Robust Security Mechanisms, Ranyang Zhou

Dissertations

Dynamic Random-Access Memory (DRAM) is both the performance bottleneck and a critical security boundary of modern computing systems. Its physical properties make it an attractive substrate for near-data computation—yet those same properties expose it to disturbance-based hardware attacks. This dissertation argues that these two dimensions are not independent: the architectural choices that make DRAM efficient also reshape its threat landscape. Addressing both requires a unified approach to memory architecture and security co-design.

The first part of this dissertation attacks the memory wall through four processing-in-DRAM (PIM) frameworks. ReD-LUT and LT-PIM unify lookup-table arithmetic with charge-sharing logic, achieving up to 37.8x …


Vergence Task-Based Neural Pathways With Binocularly Normal Vision And Comorbid Persistent Post-Concussive Symptoms -Convergence Insufficiency, Ayushi Sangoi May 2026

Vergence Task-Based Neural Pathways With Binocularly Normal Vision And Comorbid Persistent Post-Concussive Symptoms -Convergence Insufficiency, Ayushi Sangoi

Dissertations

Binocular dysfunctions are more prevalent in the persistent post-concussive symptoms (PPCS) population than in the general population. The most prevalent binocular disorder is convergence insufficiency (CI), affecting 3-17% of the general population and up to 10 times as many people with PPCS. CI makes it difficult to fuse or maintain fusion on targets at near, and its symptoms include double or blurry vision and headaches when performing close-range tasks such as reading, which can exacerbate PPCS symptoms. Given controversy over the subjectivity and effectiveness of diagnostic tools and symptom surveys for both PPCS and CI, understanding why CI has high …


A Generative Ai-Driven Computational Framework For Industry-Scale Discovery Of Novel Battery Materials, Joy Datta May 2026

A Generative Ai-Driven Computational Framework For Industry-Scale Discovery Of Novel Battery Materials, Joy Datta

Dissertations

The growing demand for sustainable, high-energy-density electrochemical storage has motivated the exploration of multivalent-ion batteries based on earth-abundant elements such as aluminum, calcium, magnesium, and zinc. While multivalent charge carriers offer higher theoretical energy density than lithium, their practical deployment is hindered by sluggish ion transport, strong ion-host interactions, and structural degradation of electrode materials. Identifying host materials that can reversibly accommodate multivalent ions while maintaining structural integrity remains a fundamental challenge. The dissertation develops a scalable, end-to-end computational framework that integrates density functional theory (DFT), machine learning (ML), and generative artificial intelligence (GenAI) to accelerate the discovery of next-generation …


Toward Learning-Based Reconstruction And Part Decomposition Of Man-Made 3d Geometry: Neural Implicit Representations And Scalable Supervision, Shen Fan May 2026

Toward Learning-Based Reconstruction And Part Decomposition Of Man-Made 3d Geometry: Neural Implicit Representations And Scalable Supervision, Shen Fan

Dissertations

Digital three-dimensional (3D) models are central to engineering design, analysis, and manufacturing, but learning pipelines for man-made geometry often operate on sampled carriers that do not preserve all of the structure present in exact CAD representations. This dissertation studies learning-based reconstruction and part decomposition for structured man-made 3D geometry, from general object benchmarks to CAD-derived datasets, with a focus on neural implicit representations trained from signed-distance samples, point clouds, and tessellated meshes. The goal is to make these models more accurate, more part-aware, and more consistently supervised.

First, signed distance function (SDF) reconstruction with implicit neural representations is improved through …


Significant Crash Characteristics Associated With E-Scooter And E-Bike Crashes, Aimee Jefferson May 2026

Significant Crash Characteristics Associated With E-Scooter And E-Bike Crashes, Aimee Jefferson

Dissertations

Micromobility devices—namely e-scooters and e-bikes—have rapidly gained popularity in the United Sates, rising from 35 million annual shared rides in 2017 to over 133 million in 2023 (NACTO 2024). But also increasing is the number of injuries associated with these devices; however, most research emphasizes injury and demographic patterns rather than crash characteristics that would inform prevention strategies. Most existing crash research also relies on small sample sizes, lacks nuance distinguishing between involved parties (motorists, pedestrians, single device), and fails to distinguish between bicycle and micromobility crash patterns despite micromobility devices often being instructed to use conventional bicycle facilities. These …


Glass Transition Temperature Of Plga Nanoparticles And The Application In Drug Delivery, Guangliang Liu May 2026

Glass Transition Temperature Of Plga Nanoparticles And The Application In Drug Delivery, Guangliang Liu

Dissertations

The glass transition temperature (Tg) of poly(D,L-lactic-co-glycolic acid) (PLGA) nanoparticles plays a crucial role in governing molecular mobility, diffusion, and consequently, drug release kinetics. However, the interaction among residual surfactant, drug effect, nanoscale confinement, and release medium on Tg remains insufficiently characterized. This study aims to bridge this gap by correlating the thermal behavior of PLGA nanoparticles with their drug release behavior under physiologically relevant conditions.

In the present study, PLGA nanoparticles were synthesized using both nano-emulsion and surfactant-free nano-precipitation approaches. The influence of residual surfactants - poly(vinyl alcohol) (PVA) and didodecyldimethylammonium bromide (DMAB) - was systematically …


Membrane-Engineered Nanotherapeutic Platforms For Drug Delivery: Hollow Fiber Membrane Synthesis Of Lipid Nanoparticles, Biomimetic Nanocarriers, And Nanobubbles, Zhixiang Liu May 2026

Membrane-Engineered Nanotherapeutic Platforms For Drug Delivery: Hollow Fiber Membrane Synthesis Of Lipid Nanoparticles, Biomimetic Nanocarriers, And Nanobubbles, Zhixiang Liu

Dissertations

Lipid-based nanocarriers have emerged as a cornerstone technology for RNA therapeutics, enabling effective intracellular delivery for applications ranging from vaccination to gene regulation. However, current manufacturing approaches, particularly microfluidic-based platforms, face inherent limitations in scalability, throughput, and structural tunability due to their reliance on confined channel geometries and restricted mixing architectures. Addressing these challenges requires fundamentally new strategies that decouple nanoparticle formation from traditional microscale flow constraints while maintaining precise control over physicochemical properties.

This dissertation presents a comprehensive framework for the design, engineering, and application of advanced lipid-based nanocarriers, centered on a hollow fiber membrane (HFM)—assisted nanopore-mediated assembly platform. …


Transcranial Ac Modulation Of Cerebellar Nuclear Activity In Awake Animals, Nuran Kavakli May 2026

Transcranial Ac Modulation Of Cerebellar Nuclear Activity In Awake Animals, Nuran Kavakli

Dissertations

Entrainment of cerebellar nuclear (CN) cells via cerebellar transcranial alternating current stimulation (ctACS) has been reported in animals under ketamine/xylazine anesthesia. Our main objective was to demonstrate modulation of CN activity in unanesthetized, freely moving animals using ctACS. Multi-channel carbon-fiber electrodes were implanted into the interpositus nucleus for recording multi-unit (MU) activity, and thin-film electrodes were implanted subcutaneously over the posterior cerebellum for stimulation. A frequency-domain-based metric was developed to quantify modulation from MU signals. The results demonstrated modulation in a wide range of frequencies (4 Hz-300 Hz) as in anesthetized animals. In contrast, the amplitude of the peak in …


Enhancing Control Charting Schemes And Exploring New Assessment Metrics To Advance Quality Control And Cyber-Attack Detection In Manufacturing, Ahmad Al Majali May 2026

Enhancing Control Charting Schemes And Exploring New Assessment Metrics To Advance Quality Control And Cyber-Attack Detection In Manufacturing, Ahmad Al Majali

Dissertations

The increasing integration of digital technologies and industrial control systems in modern manufacturing has introduced new cybersecurity vulnerabilities within cyber–physical production environments. Malicious actors can exploit these vulnerabilities to induce subtle process deviations that degrade product quality while remaining undetected by conventional statistical monitoring tools. Such attacks can be deliberately engineered to manipulate process behavior through transient shifts that vary in magnitude, duration, and frequency. Despite extensive research on transient shifts caused by assignable causes in Statistical Process Control (SPC), limited attention has been given to intelligently designed cyber–physical attacks that exploit the structural characteristics and limitations of control charting …


Behavior Of A Mildly Skewed Network Tied-Arch Bridge During Construction And Early Service Life, Harsha Amunugama May 2026

Behavior Of A Mildly Skewed Network Tied-Arch Bridge During Construction And Early Service Life, Harsha Amunugama

Dissertations

This dissertation work investigated the structural performance of the 2nd Avenue Bridge in Detroit, Michigan, the first skewed, unbraced network tied-arch bridge in the U.S. The 245-ft long, 96.5-ft wide bridge features an 18-degree skew. The bridge was constructed using accelerated bridge construction (ABC) techniques, including off-site fabrication at a bridge staging area (BSA) and installation via self-propelled modular transporters (SPMTs) and lateral launching, enabling the completion of construction with minimal disruptions to I-94 traffic and improved safety.

Given the unique structural configuration of the bridge, the use of innovative construction techniques, and differences observed in structural responses predicted by …


Active Listening And Reassurance In Text-Based Virtual Health Coaches, Ghulam Hussain Apr 2026

Active Listening And Reassurance In Text-Based Virtual Health Coaches, Ghulam Hussain

Dissertations

Conversational agents (CAs) have strong potential to support health and physical wellbeing through text-based coaching, but they remain limited in their ability to demonstrate supportive social behaviours that are important in human coaching interactions. In particular, relatively little is known about how Active Listening and Reassurance are perceived, modelled, and evaluated in text-based virtual healthcare coaching, or how such behaviours should be adapted to individual users.

This dissertation investigates how supportive interaction behaviours can enhance text based virtual health coaching, with an initial focus on Active Listening and Reassurance and a later theoretical emphasis on Active Listening. Across five unique …


Efficient Energy Management In Networked Microgrids Using Multi-Agent Deep Reinforcement Learning In The Presence Of Uncertainties, Ayodele Benjamin Chukwuyem Apr 2026

Efficient Energy Management In Networked Microgrids Using Multi-Agent Deep Reinforcement Learning In The Presence Of Uncertainties, Ayodele Benjamin Chukwuyem

Dissertations

Microgrid technology is essential in facilitating the transition to smart energy grids in developed countries and mitigating energy poverty in developing countries, particularly in areas where grid extensions are not feasible. Recently, the concept of networked microgrids (NMGs) has garnered tremendous attention due to the plausibility of interactions among interconnected microgrids leading to power networks that are more resilient, reliable, and stable. However, because each microgrid has diverse distributed generation resources (renewables and controllable generators) and each microgrid operator (MO) has different objectives, coordinated energy management is required to satisfy local and system-wide goals under conditions with significant uncertainty. Existing …


Feedback In Digital Game-Based Learning: A Taxonomy And The Design And Empirical Evaluation Of A Feedback System In A Mathematics Serious Game, André Almo Mar 2026

Feedback In Digital Game-Based Learning: A Taxonomy And The Design And Empirical Evaluation Of A Feedback System In A Mathematics Serious Game, André Almo

Dissertations

Digital Game-Based Learning (DGBL) is an active, student-centred pedagogical approach in which feedback plays a central role by informing learners’ actions, guiding decision-making and shaping motivation and engagement. Despite its importance, feedback in serious games is often described inconsistently and insufficiently in research, limiting comparability across studies and the accumulation of design knowledge, particularly for children. This thesis addresses these gaps through two complementary contributions: the development of a taxonomy for feedback design in digital serious games and the empirical evaluation of a taxonomy-informed feedback system in a mathematics game for primary school students. First, this work introduces the Taxonomy …


A Capability Maturity Model For Artificial Intelligence Integration In Supply Chain Management, Lordt Becklines Feb 2026

A Capability Maturity Model For Artificial Intelligence Integration In Supply Chain Management, Lordt Becklines

Dissertations

Artificial Intelligence (AI) is transforming Supply Chain Management (SCM), yet many organizations struggle to assess their readiness for AI adoption and to understand how AI capabilities develop across maturity stages. This dissertation addresses this gap by developing a Capability Maturity Model (CMM) for AI integration in SCM, grounded in Organizational Information Processing Theory (OIPT), the Resource-Based View, and related capability frameworks. The model provides a structured approach for evaluating an organization's information-processing requirements, resource configurations, and alignment needed for effective AI-enabled supply chain operations.

Using a design science research approach, the AI-SCM CMM and its associated assessment instrument were derived …


Optical Fiber Sensors Using Vernier Effect In Cascaded Fiber Interferometers, Zhouchen Wang Feb 2026

Optical Fiber Sensors Using Vernier Effect In Cascaded Fiber Interferometers, Zhouchen Wang

Dissertations

The optical Vernier effect has emerged as a powerful tool to enhance the sensitivity of optical fiber interferometer-based sensors, opening new opportunities for developing highly sensitive fiber sensing systems. Optical fiber interferometric sensors based on the Vernier effect are widely used for various applications due to their ultra-compact size, high sensitivity, immunity to electromagnetic interference, electrical isolation, resistance to harsh environments, flexibility, multiplexing capability, and remote operation. The aim of this doctoral thesis was to gain a deeper fundamental understanding of the Vernier effect in optical fiber structures and to develop and investigate a series of novel Vernier effect optical …


Sharing Patient-Generated Health Data With Electronic Health Record: A Standardised Provenance And Context-Rich Information Model And Clinician Evaluation, Abdullahi Abubakar Kawu Jan 2026

Sharing Patient-Generated Health Data With Electronic Health Record: A Standardised Provenance And Context-Rich Information Model And Clinician Evaluation, Abdullahi Abubakar Kawu

Dissertations

With the advent of Patient-Generated Health Data (PGHD) through wearable, mobile, and home monitoring systems, there is immense potential for ongoing monitoring and patient engagement. But integrating PGHD with Electronic Health Record (EHR) is challenged by sub-optimal support for contextual metadata and its relevant elements, lack of semantic interoperability among disparate systems, poor knowledge regarding the factors that impact clinician acceptance, and absence of globally agreed standards for data exchange. This thesis explores how contextually relevant patient-generated health data can be shared with EHRs through a FAIR standardized information model that ensures semantic and syntactic interoperability.

The study addresses six …


Computational Design Of Nanoporous Materials For The Adsorption Of Per- And Polyfluoroalkyl Substances, Daniel D. Mottern Dec 2025

Computational Design Of Nanoporous Materials For The Adsorption Of Per- And Polyfluoroalkyl Substances, Daniel D. Mottern

Dissertations

Per- and polyfluoroalkyl substances (PFAS) are a large family of chemicals that have seen wide usage due to their fluorinated carbon backbone. The presence of strong C-F bonds in the backbone lends PFAS molecules high thermal and chemical stability, as well as strong hydrophobicity and lipophobicity. This combination of properties has led to heavy use of PFAS as surfactants, non-stick coatings, and aqueous foam forming films and flame retardants. However, these properties bring their own consequences. The high chemical and thermal stability of PFAS renders them persistent, with the C-F bonds resisting naturally occurring forms of degradation. Existing forms of …


Entropic Forces Near Fluctuating Surfaces, Rubayet Hassan Dec 2025

Entropic Forces Near Fluctuating Surfaces, Rubayet Hassan

Dissertations

Nanoscale structures are inherently dynamic due to persistent thermal fluctuations. Even in solid materials, these random deformations, driven by ambient thermal energy, can become significant when their characteristic scale approaches that of the structure itself and strongly influence their overall mechanical behavior. Examples of such structures include crystalline membranes, appearing in diverse forms such as nanotubes, nanoribbons, and kirigami/origami structures. Similarly, biological nanostructures, including lipid membranes, microtubules, actin filaments, and DNA, exhibit extreme flexibility and responsiveness due to their low bending rigidity. Numerous physiological processes are intrinsically linked to these thermal fluctuations, including exocytosis and endocytosis, membrane fusion, pore formation, …


Material Degradation And Analysis Of N-Doped Graphene/Mof Nanocatalysts For Orr In Electrochemical Energy Systems, Niladri Talukder Dec 2025

Material Degradation And Analysis Of N-Doped Graphene/Mof Nanocatalysts For Orr In Electrochemical Energy Systems, Niladri Talukder

Dissertations

The development of advanced electrochemical energy conversion and storage systems is crucial for achieving sustainable energy security. As alternatives to precious metal-based catalysts in electrochemical systems, especially for the oxygen reduction reaction (ORR), Nitrogen-doped Graphene with Metal-organic Frameworks (N-G/MOF) nanocatalysts have shown exceptional promise in recent years. This research advances the understanding of N-G/MOF nanocatalysts by systematically examining their structural features, degradation traits, correlated performance losses, and other aspects related to catalytic activities.

First, nitrogen-doped graphene (N-G) nanocatalysts were thoroughly investigated, resolving their physical properties, the influence of synthesis parameters, molecular-level material structures, and chemical and electronic structural details of …


Data-Driven Analysis And Atomistic Simulations Of Next-Generation Materials For Energy Conversion And Storage, Yuliang Shi Dec 2025

Data-Driven Analysis And Atomistic Simulations Of Next-Generation Materials For Energy Conversion And Storage, Yuliang Shi

Dissertations

Metal-organic frameworks (MOFs), with their modular architectures and tunable properties, represent an especially rich domain for accelerated material design and discovery for a range of diverse applications. Within this class of multifunctional materials, two-dimensional (2D) electrically conductive MOFs (EC MOFs) are of particular interest, as their 7r-stacked layered structures combine permanent porosity with electronic conductivity, enabling potential breakthroughs in energy storage, energy conversion, and quantum sensing. But the discovery and design of new EC MOFs based on expensive experimental screening is increasingly impractical due to the infinite chemical space. Furthermore, the practical implementation of EC MOFs for specific tasks depends …


Additive Manufacturing Of Carbons From Commodity Polyolefins, Paul Smith Dec 2025

Additive Manufacturing Of Carbons From Commodity Polyolefins, Paul Smith

Dissertations

Though tremendous progress has been made engineering carbon materials across length-scales from the molecular to the macroscopic, on-demand macro-structural control of carbons is still developing. Many carbon materials like graphene, carbon nanotubes, activated carbons, and carbon fibers have powder or fiber form factors. Recent research has pioneered on-demand carbon production through additive manufacturing (AM) via 1) extrusion and post-processing of highly filled carbon slurries, or 2) printing and pyrolysis of polymeric carbon precursors such as polyimides, acrylated polyethylene glycol, and phenolics. While groundbreaking, most methods face challenges with adoption due to costly/complex materials and manufacturing processes, and large dimensional changes …