Engineering Commons^™

Preparation And Performance Study Of In-Situ Self-Assembled Biphasic Smmn2O5-Nimn2O4 Composite Cathode, Neng-Chu Xia, Yu Zhou, Qin Wang, Jia-You Zhang, Chun Yu, Yang Zhang, Wan-Bing Guan, Jian-Xin Wang

Journal of Electrochemistry

Mullite-structured oxides exhibit excellent oxygen reduction reaction activity, possess a low thermal expansion coefficient due to their unique crystal structure, and can eliminate the need for a barrier layer and simplify the preparation process as they contain no alkaline earth elements. Thus, they hold great promise as novel cathode materials for solid oxide fuel cells. In this work, a mullite-spinel-structured SmMn₂O₅-NiMn₂O₄ (SMO-NMO) composite cathode was one-step synthesized via a solid-liquid composite route, and its in-situ self-assembly enabled good compatibility with the electrolyte without any barrier layer. Characterization results showed that the SMO:NMO = …

In-Situ Stm Visualization Of Molecular Structural Evolution During Electrochemical Oxidation Coupling Of Para-Aminothiophenol On Au(111), Zi-Wei Ma, Tai-Rui Wu, An-Ni Zheng, Lai-Ke Chen, Yuan-Hui Xiao, Zhao-Bin Chen, Qing-Na Zheng, Jian-Zhang Zhou, Jia-Wei Yan, De-Yin Wu

Journal of Electrochemistry

Para-aminothiophenol (PATP) is not only a widely-used probe molecule in the field of surface-enhanced Raman spectroscopy (SERS), but also an important model molecule for interfacial reactions, exhibiting distinct photo- and electro-oxidation pathways, so that PATP is selectively activated under different external fields. The evolution of products and intermediates during electrochemical oxidative coupling remains unknown. In this study, we have investigated the dynamic electrochemical oxidation process of PATP on the Au(111) surface using cyclic voltammetry, electrochemical (EC)-SERS, and in situ electrochemical scanning tunneling microscopy (EC-STM). The results showed that PATP forms an unsaturated adsorption coverage on Au(111) in an acidic solution. …

Integrated Construction Uncertainty Quantification Framework Icuqf, Felix Delmonte

Mechanical and Civil Engineering Faculty Publications

This study develops ICUQF, an integrated uncertainty framework for digitally instrumented construction megaprojects that unite probabilistic simulation, fuzzy reasoning, Bayesian networks, AI-driven anomaly detection, BIM-linked digital twins, and organizational learning into a single operational architecture. The framework classifies uncertainty into aleatory variability, epistemic gaps, data-centric and model-centric risks, and cognitive or cultural sources, mapping each class to computational treatments such as Monte Carlo engines for stochastic variability, fuzzy intervals and p-boxes for imprecise expert judgments, and hierarchical Bayesian models for coherent evidence aggregation and online updating. ICUQF specifies data pipelines that connect IoT sensing, edge processing, cloud storage, and Common …

Load Balancing Algorithms For Cloud Computing Systems, Mark Rakesh Christian

Electronic Theses and Dissertations

Cloud computing depends on load balancing to allocate user requests among virtual machines (VMs), affecting response time, utilization, and scalability. Round Robin, Equally Spread Current Execution, and standard Throttled scheduling are widely used; however, standard Throttled selects among eligible VMs using an implementation-dependent order with no explicit preference. This thesis proposes the Weighted Throttled Load Balancing (WTLB) algorithm, which introduces an explicit, deterministic selection priority among eligible VMs, implemented by modifying the Throttled scheduler within CloudAnalyst.

Evaluated under an identical six-region, multi-data-center configuration against Round Robin, ESCE, and standard Throttled, WTLB preserves the aggregate response-time, processing-time, and cost profile of …

Effect Of Geothermal Conditions On Silica Flour Modified Wellbore Cement, Travis Benjamin Broadhurst

Civil Engineering ETDs

Considerable work has been conducted on modified wellbore cements, but a knowledge gap exists in the effects of downhole conditions on cement, especially tensile strength. In this study, a pressure vessel simulates representative downhole conditions (200⁰C, 1.5 MPa) with a reference solution for geothermal brine and naturally occurring geothermal gases. Samples are removed after 28-days for unconfined compressive strength testing, Brazilian tensile strength testing, elastic moduli measurement, and chemical analyses by X-ray diffraction and electron microprobe. Aqueous chemical analysis suggests multiple active reactions between the geothermal fluid and cement that are exacerbated by higher temperatures, but do not …

Investigating Nanoparticle Capture By Condensed Phase Coacervates And Their Mixtures, Sanjna A. Bhakta

Chemical and Biological Engineering ETDs

The thermoresponsive polymers elastin-like polypeptides (ELPs) and poly(N-isopropylacrylamide) (PNIPAM) have served as a programmable bioseparation tool for applications in nanoparticle capture due to biocompatibility and tunable properties. This work investigates how the polymer composition of ELP and PNIPAM coacervates influences their phase behavior, structural morphology, and nanoparticle recruitment. In addition, the influence of interfacial interactions in nanoparticle recruitment using Tween 80 as a mechanistic probe was also investigated. Different mixtures of ELPs E1.40, E1.80, and E3 with PNIPAM14 and PNIPAM20 were used to characterize their phase behavior and analyze structural morphology using turbidity measurements and microscopy, respectively. Nanobead recruitment using …

Developing Simulation To Improve G3p3 Efficiencies, Andrew Gaudette

Mechanical Engineering ETDs

Concentrated solar power (CSP) systems offer a promising method of renewable energy generation by using heliostats to focus sunlight onto a falling particle receiver. At the National Solar Thermal Testing Facility (NSTTF), particles absorb and store solar energy for later power generation. A major source of efficiency loss is wind-driven particle escape through the receiver aperture. This thesis develops computational fluid dynamics (CFD) simulations to characterize wind flow around the G3P3 falling particle receiver and support future wind mitigation strategies. Numerical studies were conducted to establish an appropriate simulation methodology. Iteration studies showed that 2,000 iterations were sufficient for convergence, …

Control Of Reshock In A Shock Tube, Alexander Sweis

Mechanical Engineering ETDs

Reshocks can pose a threat to the structural integrity of structures and buildings. While incident shock waves pose larger threats, the study of reshocks and reshock attenuation is important to consider. This thesis investigates methods for controlling and attenuating reshock strength within a shock tube through material-based damping and modifications to baffle box geometric configurations. Experiments are performed using a custom-built shock tube in the University of New Mexico fluid mechanics laboratory. Four baffle box configurations are examined: a foam-lined configuration, a foam-lined configuration with ”egg crate-like” textured foam, an empty (no foam) configuration, and a configuration which incorporates a …

Design And Feasibility Study Of An Air-Cooled Reactor Cavity Cooling System For Fluoride-Salt-Cooled High-Temperature Reactors, Alexandra D. Martinez

Nuclear Engineering ETDs

Licensing efforts for Fluoride-Salt-Cooled High-Temperature Reactors (FHRs) are dependent on passive safety systems designed for decay heat removal, yet no prior study has evaluated an air-based Reactor Cavity Cooling System (RCCS) for this role. This thesis addresses that gap by determining whether an air-cooled RCCS can be designed to passively remove post-shutdown decay heat from the Mk 1 FHR. An RCCS configuration was developed and sized using a one-dimensional lumped-parameter design methodology, then evaluated through system-level thermal-hydraulic modeling in RELAP5-3D under a conservative, lower-bound post-shutdown transient. The analysis characterizes the radial heat-transfer pathways from the FHR core to the RCCS …

Development Of Dynamic Proof-Mass Configurations For Broadband Piezoelectric Energy Harvesting, Nico E. Galarza

Electrical and Computer Engineering ETDs

The purpose of this thesis is to investigate and develop dynamic proof-mass configurations for broadband piezoelectric energy harvesting. Conventional piezoelectric energy harvesters are typically limited by narrow operating bandwidths, restricting their performance under variable-frequency excitation. This research presents the design, fabrication, and experimental evaluation of multiple proof-mass concepts intended to increase the usable frequency range of cantilever-based piezoelectric energy harvesters. Several dynamic mass configurations were developed using additive manufacturing techniques and integrated with commercially available piezoelectric cantilevers. Experimental testing was conducted under controlled vibration conditions to characterize voltage response, resonant behavior, and bandwidth performance. The results demonstrate that dynamic proof-masses …

Synergizing Crowd Collaboration: Enhancing Crowdsourcing Matching Via Integration Of Matching Theory And Coalition Games, Rowan Aengus Kinney

Electrical and Computer Engineering ETDs

This paper tackles the challenges inherent in crowdsourcing dynamics by introducing the CROWDMATCH mechanism. Aimed at enabling crowdworkers to strategically select suitable crowdsourcers while contributing information to crowdsourcing tasks, CROWDMATCH considers incentives, information availability and cost, and the decisions of fellow crowdworkers to model the utility functions for both the crowdworkers and the crowdsourcers. Specifically, the paper presents an initial Approximate CROWDMATCH mechanism grounded in matching theory principles, eliminating externalities from crowdworkers’ decisions and enabling each entity to maximize its utility. Subsequently, the Accurate CROWDMATCH mechanism is introduced, being initiated by the outcome of the Approximate CROWDMATCH mechanism, and employing …

Investigating The Corrosion Behavior Of Stainless Steel 316 In Static Lead Lithium Eutectic Under Applied Stressed Conditions, Daniel E. Levario

Nuclear Engineering ETDs

As fusion power moves closer to feasibility, identifying structural materials compatible with breeding blanket environments remains a critical challenge. Lead-lithium eutectic (LLE) is a leading candidate breeder and coolant material due to its low melting point and combined tritium breeding and neutron multiplication capability. However, the corrosive nature of LLE toward structural steels at elevated temperatures must be characterized before these systems can be reliably deployed. This study investigates the corrosion behavior of Type 316 stainless steel in static LLE under applied stress conditions at 550°C using C-ring stress corrosion specimens. Post exposure analysis via optical microscopy, SEM, EDS, and …

Tinyml-Based Embedded Vision System For Ic Detection In Microcontroller Manufacturing, Mark M. Pallones, King Harold A. Recto, Rynne Daven A. Barrios

Electronics, Computer, and Communications Engineering Faculty Publications

Mixing of microcontroller unit (MCU) integrated circuits (ICs) during the final testing stage of semiconductor manufacturing can lead to material waste, production delays, and customer dissatisfaction. This issue often occurs when standard JEDEC Matrix Trays (JMTs) are reused without confirming that all ICs have been removed after testing, a process typically performed through manual inspection and therefore susceptible to human error due to high test volumes, small IC package sizes, and visual similarity between IC packages and tray surfaces. This study develops an automated IC Detection Test System using embedded vision to determine whether JMT trays are empty prior to …

Mapping And Modeling Threat-Evoked Brain States After Early Life Adversity, Taylor W. Uselman

Biomedical Sciences ETDs

Early life adversity (ELA) increases lifelong neuropsychiatric vulnerability. Yet how ELA reorganizes brain-wide activity and circuit coordination across later experience remains unclear. This dissertation tests the hypothesis that ELA alters adult brain-wide activity and responses to threat through disrupted coordination among neural systems that regulate emotional experience, including prefrontal-limbic and monoaminergic systems. Longitudinal manganese-enhanced MRI of adult mice exposed to standard or fragmented early care, combined with computational processing and statistical modeling, quantified brain states before, during, and long after innate predator threat. These studies established that acute threat evokes large-scale, distributed brain activity that evolves over time. ELA potentiates …

Multiscale Network Modeling Of Native And Modified Photosynthetic Light-Harvesting Complexes, Zane E. Armijo

Chemical and Biological Engineering ETDs

Photosynthetic light-harvesting complexes harvest solar energy and direct electronic excitations toward reaction centers with exceptional efficiency. This dissertation models the Fenna--Matthews--Olson complex of green sulfur bacteria, coupled to the PscA1 reaction center, as a chromophoric network. Forster resonance energy transfer theory, validated against numerically exact hierarchical equations of motion, was implemented in kinetic Monte Carlo simulations to resolve fine-grained excitation-transport pathways. The predicted charge-transfer efficiency of 77\% agrees with experiment, with the FMO2 monomer and its gateway pigment governing interfacial transfer. Systematic single, multi, and symmetry-preserving site removals, interpreted through Mobius inversion, identify critical pigments and show that cooperative effects …

Impact Of Gas Interactions With Nano Porous Geological Material In The Presence Of Water Vapor, Matthew D. Powell

Chemical and Biological Engineering ETDs

Predicting gas transport in nanoporous geological material requires understanding competitive adsorption and transport under humid conditions. However, most adsorption studies rely on single-component equilibrium measurements that do not capture these effects. This dissertation develops an experimental methodology to directly quantify multicomponent gas adsorption and breakthrough behavior under controlled relative humidity. The method was first applied to the Kr/Xe–N2–H2O system, where it resolved competitive adsorption behavior in humid porous media and produced a bivariate model relating noble gas adsorption to noble gas partial pressure and water saturation. The methodology was then extended to the CO2–N2 H2O system. Results showed that water …

Mechanisms Of Advanced And Energy Efficient Wastewater Treatment Technologies, Derek Belka

Civil Engineering ETDs

This dissertation combines meta-omics, microbial ecology, and hydrodynamic analysis to explore mechanisms of enhanced biological phosphorus removal (EBPR) and aerobic granular sludge (AGS) in municipal wastewater treatment. Metagenomic and functional gene profiling of a laboratory sequencing batch reactor fed with amino acids and proteins, and with a low abundance of known polyphosphate-accumulating organisms (PAOs), revealed abundant Herpetosiphonaceae and Dermatophilaceae families possessed key PAO metabolic traits, including phosphate scavenging, anaerobic carbon pathways, and ppk2 gene variants aligned with established PAOs. These findings suggest amino acid-driven EBPR can occur via previously unrecognized taxa, challenging current engineering assumptions and highlighting the need for …

Wildfire Impacts On Fluvial Hydrology From Watershed To National Scales, Paige G. Tunby

Civil Engineering ETDs

Wildfires alter the water quantity and quality in downstream river networks. Fires promote biodiversity, maintain habitat, and provide many ecosystem services in a fire-adapted landscape. However, changes in the natural fire regimes can alter ecosystem function and threaten the water security of impacted downstream communities. The magnitude, timing, and persistence of these impacts are difficult to predict due to the lack of high-resolution datasets with adequate coverage to evaluate spatiotemporal trends after a fire. This dissertation moves us beyond the status quo to evaluate post-fire fluvial responses across scales, from the event-scale impacts after the Hermit’s Peak-Calf Canyon wildfire in …

Helmholtz Reciprocity In Bidirectional Y-Junction Couplers, Hosuk Lee

Optical Science and Engineering ETDs

This thesis explores the light propagation characteristics in Y-junction couplers based on the Helmholtz reciprocity principle. The Helmholtz reciprocity principle is a crucial concept in optical system design, and it has primarily been understood based on input-output symmetry. However, this study emphasizes reciprocity needs to consider the entire system, beyond the traditional input-output symmetry reciprocity interpretation. For this study, we specifically examined the direction-dependent asymmetrical outputs, in the Whistle-geometry Ring Laser (WRL) structure. And the WRL results cannot be fully explained by simple input-output symmetry for reciprocity. The Y-junction coupler in the WRL structure makes different output characteristics based on …

Algorithmic Sculpting Of Complex Fused Silica Surfaces For Nondestructive, Mode-Matched Cavity Quantum Electrodynamics: Adaptive Co2 Milling And Simulation-Guided Ultrafast Inscription, From Fiber Fabry-Perot Cavities To Monolithic Architectures, Meagan E. Parker

Optical Science and Engineering ETDs

Quantum sensors achieve exceptional measurement sensitivity through coherent, well-isolated quantum systems, but practical deployment is hindered by destructive readouts that require repeated state preparation and create long system dead times. Optical cavities enable continuous, nondestructive measurements with minimal back-action, yet integrating high-finesse cavities into scalable quantum devices remains limited by existing fabrication methods. To overcome these constraints, an adaptive CO₂ laser-milling platform was developed. Guided by glass thermodynamics and melt dynamics, this closed-loop system uses in-situ phase-shifting interferometry to sculpt complex fused-silica surfaces with sub-nanometer root-mean-square roughness. The platform was validated by fabricating extended-length fiber Fabry–Pérot cavities and monolithic micro-cavity …

Non-Traditional Rare-Earth-Doped Oxide Glass As A Gain Medium, Jared S. Tolliver

Optical Science and Engineering ETDs

There is a need for mid-infrared(MIR) lasers in defense, medical, and environmental monitoring. A large part of this technological development is the study of gain media. One class of materials of special interest is glasses with a low maximum phonon energy. These have the fiberization and broad spectral features of glass, whereas glasses with high maximum phonon energy exhibit higher rates of multi-phonon relaxation and can be opaque in the MIR, both of which are detrimental to laser operation. Recent advances in container-less processing have allowed for the study of new glasses that aren’t possible with conventional fabrication techniques. One …

Developing A Dispersion Interferometer For Characterizing Power Flow Plasma Formation And Transport Studies, Nathan R. Hines

Electrical and Computer Engineering ETDs

Sandia's refurbished $Z$-pinch machine experiences persistent current loss in its post-hole convolute and inner magnetically insulated transmission line regions, widely attributed to low-density electrode plasmas whose formation and transport remain poorly constrained by existing diagnostics. This dissertation develops and validates a fiber-coupled, continuous-wave, second-harmonic orthogonally polarized dispersion interferometer for time-resolved measurements of electron areal density in millimeter-scale gaps. The diagnostic employs single-laser second-harmonic generation, non-steering differential phase control, and polarization-based phase retrieval to achieve sub-$10^{15}$~cm$^{-2}$ sensitivity, multi-hundred-megahertz bandwidth, and sub-$200$~$\mu$m effective cross-gap spatial resolution. Performance is benchmarked against a $94$~GHz interferometer on the UNM Helicon-Cathode plasma device and then fielded …

Enhanced Computational Modeling Of Photoionization And Streamer Formation, Anahita Alibalazadeh

Electrical and Computer Engineering ETDs

Photoionization is a key mechanism governing the formation and propagation of streamer discharges in air by generating electron-ion pairs ahead of the streamer front. Accurate and computationally efficient modeling of this non-local process is essential for reliable plasma simulations. However, the widely used Zheleznyak photoionization model relies on empirical assumptions and requires computationally expensive domain-wide integration.

This dissertation advances photoionization modeling in three ways. First, the classical integral model is enhanced by incorporating experimentally measured vacuum ultraviolet (VUV) emission spectra together with photoabsorption and photoionization cross-section data, enabling direct calculation of the photoionization source term as a function of pressure …

3d Electromagnetic Simulations Of A 1.6 Cell S-Band Photoinjector: Emittance Studies For Electron Microscopy, Trudy Bolin

Electrical and Computer Engineering ETDs

Modern beam-based materials research demands electron sources with increasingly precise time resolution, high brightness, and stability. For example, there are various instruments across the U.S. dedicated to ultrafast electron diffraction (UED), but fewer are dedicated to ultrafast electron microscopy (UEM), which demands beam stability. Modeling femtosecond electron bunches with ultra-low emittance < 50 nm-rad inside a 1.6-cell S-band (2856 MHz) rf photoinjector with full 3D electromagnetic simulations can require high-performance computing (HPC) environments due to the scale disparity between the macroscopic cavity geometry and the femtosecond-scale bunch kinematics. To enable optimization in a desktop computing environment, this work presents a streamlined 3D electromagnetic Particle-in-Cell (PIC) simulation framework optimized for 400-femtosecond bunch regimes. The covariance method was employed to study emittance properties for electron bunch counts ranging from thousands to millions and has successfully resolved highly transient, pure rf phase-space rotations, such as a localized energy-spread minimum occurring at the gun exit iris. To overcome the computational cost of these simulations, a machine-learning-based Bayesian optimization approach was deployed to construct multi-objective Pareto fronts from sparse datasets. Because the simulation software is scalable from desktop to HPC facilities, the framework is ready for experiments at the National Energy Research Scientific Computing Center (NERSC) at Lawrence Berkeley National Laboratory (LBNL).

Real-Time Waveform Synthesis For Rfsoc-Based Quantum Control Systems, Tiamike I. Dudley

Electrical and Computer Engineering ETDs

RFSoCs are gaining adoption in many labs for quantum control systems thanks to their compactness and affordability. Making full use of the many components on an RFSoC evaluation board is a challenging engineering problem that must be solved to realize scalable control systems. In this dissertation, I evaluate the performance of various RFSoC components in the context of quantum information science. I present two custom FPGA engines that accelerate and parallelize arbitrary waveform generation. The first engine can be instantiated many times to power low-speed DACs for ion-shuttling trap electrodes. The second engine synthesizes CPMG-XY8n dynamical decoupling pulse sequences on …

Modeling For You: A Personalized Approach To Residential Energy Simulation And Distributional Reinforcement Learning, Nestor Gabriel Pereira

Electrical and Computer Engineering ETDs

The growing complexity and uncertainty of residential energy use, driven by electric

vehicles and renewable technologies, demand more intelligent and robust

management systems. Traditional methods often fail when faced with unpredictable

electricity prices and user behavior. This dissertation addresses this gap by presenting

a novel personalized framework combining detailed household energy modeling with

a risk-aware reinforcement learning agent for appliance scheduling.

The first contribution is a probabilistic, bottom-up simulation model that captures

the interdependent behaviors of occupants, appliances, and electric vehicles to

generate realistic, high-fidelity load profiles. The second contribution is a lightweight,

tabular Distributional Q-Learning (D-QL) algorithm that schedules …

Multi-Robot Cooperative System For Complex Aerospace Manipulation Tasks: Theory And Application, Longsen Gao

Electrical and Computer Engineering ETDs

Multi-robot systems can extend manipulation capabilities beyond the limits of a single robot, particularly for tasks involving large, flexible, delicate, or free-floating payloads. Reliable cooperative manipulation, however, remains difficult when payload dynamics, contact geometry, compliance properties, deformation-induced forces, and external disturbances are only partially known, and when safety constraints must be enforced during physical interaction. This dissertation develops a two-layer control framework for resilient multi-robot manipulation under uncertainty, with emphasis on space servicing, satellite stabilization, aerial transportation, and cooperative manipulation of free-floating structures.

Rthermal: Gate Level Power And Thermal Simulation For 3d-Stacked Chips, Peter Xiong

Master's Theses

As the number of transistors in modern processors increases, heat dissipation has become a major bottleneck to scalability. The use of 3D stacking further intensifies this problem, as heat from multiple layers can accumulate vertically. These challenges create a growing need for tools that can accurately and efficiently simulate the thermal behavior of 3D chips during design and validation. Several existing tools model thermal behavior for 3D-stacked chips and can simulate average heat over large spatial regions or long time intervals. However, when heat is concentrated in a small area or over a short time window, such models can miss …

Assessment Of Anaerobic Co-Digestion Of High Strength Organic Feedstocks Diverted From Landfills, Sumaiya Sharmin

Electronic Theses and Dissertations

The increasing generation of high-strength organic wastes such as food waste and fats, oils, and grease (FOG) presents challenges for landfill capacity and waste management. Anaerobic co-digestion offers a sustainable alternative by converting these wastes into renewable energy and nutrient-rich digestate. This study evaluated the co-digestion performance of single fruit waste residuals and mixed food waste with wastewater sludge to identify substrate combinations that maximize methane production while maintaining process stability. Laboratory-scale batch experiments were conducted under mesophilic conditions using thickened waste activated sludge (TWAS) with varying proportions of food waste and co-substrates, including seaweed, aquatic weed, grease trap waste, …

A Multidimensional Conceptual Framework For Supportive Outdoor Environments In Healthcare Settings, Mona Ali, Dalia A. Beheiry, Rowaida Kamel, Hammam Serageldin

HBRC Journal

The integration of supportive outdoor environments (SOEs) in healthcare settings has gained increasing attention for their potential to enhance patient recovery, support staff well-being, and contribute to holistic therapeutic outcomes. This scoping review examines design recommendations for inclusive outdoor environments in healthcare settings that impact user health and experience. Guided by the Joanna Briggs Institute (JBI) framework for scoping reviews, a comprehensive search was conducted across five databases (Google Scholar, PubMed, ScienceDirect, JSTOR, Sage), yielding 697 records. Following screening and applying the inclusion and exclusion criteria, 18 articles were selected for analysis. This scoping review identified consistent evidence linking outdoor …