Engineering Commons^™

An Equilibrium Study Of The System Bi-S-H₂, Don Hie Lee

Masters Theses

"An experimental study has been conducted to determine the equilibrium behavior of the system Bi-S-H₂. The system was studied by equilibrating H₂-H₂S gas mixtures with Bi(l)- Bi₂S₃(s) two-phase mixtures at temperatures of 500°, 600°, 700° and 750°C in a circulating type equilibrium apparatus. The equilibrium gas mixtures were analyzed by a Fisher Gas Partitioner with a reproducibility of approximately 0.06 %.

A linear free energy equation has been derived from the results with an average deviation of ± 1 Kcal. This deviation is well within the accepted experimental accuracy for …

A Simplified Method Of Estimating Drilling And Blasting Costs Of A Highway Through-Cut Excavation In Rock, Donald J. Roberts

Masters Theses

"The development of cost estimating methods has been the most neglected phase of highway engineering. Overlooked in particular has been the development of an easily understood and easily applied method of estimating the costs of the drilling and blasting operations involved in a highway through-cut excavation in rock.

This investigation developed such a method by adapting and applying recent developments in the blasting planning field. The study was limited to small diameter blastholes and excavations in lifts of less than thirty feet. Normal efficient construction practices were presumed.

It was found from the investigation that the blast geometry and, subsequently, …

Viscosities Of Various Binary Non-Polar Gaseous Mixtures., Gerald Lee Stevenson

Masters Theses

"Viscosity is an important physical property involving the transport of momentum in a fluid. Momentum is transferred within a fluid under an existing velocity gradient as the driving force. Since momentum transfer is actually attained by the dynamic interaction between particles of mass, a description of molecular interaction is essential in order to accurately predict the viscosity of a fluid. Temperature affects fluid viscosity by increasing the kinetic energy of the fluid system and thus the frequency by which molecules are involved in interaction. There have been many theoretical studies made concerning the intermolecular potential energy statements which serve as …

Behavior Of Clay Under Compaction By Vibratory Rollers., Glenn R. Taylor

Masters Theses

"This thesis presents an analysis of the behavior of a lean clay when compacted by commercial vibratory rollers using the results of field investigations conducted by the U. S. Army Engineer Experiment Station, Vicksburg, Mississippi. Conclusions reached indicate that a lean clay soil will behave substantially the same under compaction by a vibratory roller as it does under other conventional methods of field compaction. The relationship of amplitude to the density and moisture content is also examined in this paper with the conclusion that the variations in amplitude of a vibratory roller is not significant as a measure of the …

Methods For The Determination Of The Thermal Conductivity Of Solids., A. M. Sivadasan

Masters Theses

"The thermal conductivity of materials is of considerable practical and theoretical interest. Numerous publications on this subject have been presented with widely varying approaches and applications being made. Perhaps for no other thermal property are the published results so widely divergent and subject to such great uncertainty, particularly at high temperatures. This is partly due to unsolved difficulties in measurement, but perhaps to an even greater extent to the fact that the thermal conductivity of a material depends on its physical characteristics as well as some environmental factors such as humidity and temperature. In the case of metals or alloys, …

Determination Of The Standard Free Energy Of Formation Of Zr₃S₂, Peter E. Otten

Masters Theses

"The Knudsen effusion method was used to find the equilibrium magnesium pressure for the reaction

3 Zr (s) + 2 MgS (s) = 'Zr₃S₂' (s) + 2 Mg (v)

By using known standard free energy data for the formation of magnesium sulfide and by using the equilibrium magnesium pressure, the standard free energy of formation of Zr₃S₂ was calculated and could be expressed by the equation

Δ F° = -139,800 + 49.13 T cal/mole

in the temperature range 900 to 1100°C.

It was also found that Zr₃S₂ was the zirconium …

Swelling Properties Of Putnam Soil, Oscar M. Palma

Masters Theses

"Volume change of Putnam soil under different moisture contents and the swelling pressure developed by the soil at the same moisture contents were investigated using standard test procedures.

The theory of one dimensional consolidation of Terzaghi was reviewed as well as the literature on swelling and swell pressure.

It was found that swell depends mainly on the initial water content, while swelling pressure depends mainly on the dry density of the soil"--Abstract, page ii.

The Design, Construction, And Calibration Of A Hydrodynamic Journal Bearing Testing Machine., John H. Roberts

Masters Theses

"The purpose of this investigation was to design, construct, and calibrate a journal bearing testing apparatus. The design, construction, and operation of the apparatus are described.

Two bronze bearings with length to diameter ratios of 1.0 and 0.5 were tested using a gravity oil reed system. The speed and the location of inlet oil supply were varied, and the resulting coefficients or friction, oil flow rates, outlet oil temperatures, bearing shell temperatures, and eccentricities of the bearings were determined. These results were evaluated and compared with theoretical solutions.

The results compared favorably with the theoretical solutions and substantiated the use …

A Thermodynamic Study Of The Molybdenum-Sulfur System At 1100⁰C, Seth C. Schaefer

Masters Theses

"A static method was used to determine equilibrium sulfur pressure for molybdenum-sulfur mixtures at 1100°C.

The results obtained were:
(1) The molybdenum disulfide phase was stable in a sulfur pressure range of 1.023 x 10^-5 to 6.026 x 10^-1 atmospheres. A range of non-stoichiometry from MoS_2.00 to MoS_2.22 was determined under these conditions.
(2) The upper limit of sulfur content of molybdenum sesquisulfide (Mo₂S₃) is nearly stoichiometric.
(3) The extent of solid solution of sulfur in molybdenum is approximately 1.5 atomic % (0.5 wt %).
(4) Molybdenum sesqu-isulfide (Mo₂S_{3 …}

A Study Of The Solubility Of Gold In Aluminum And The Extent Of The Al₂Au Phase., Kuldip Singh Chopra

Masters Theses

"The lattice constant of pure aluminum (99.998%) at 25° C 0 was determined to be 4.04953 A and the limit of solubility of gold in aluminum at 58O° c was found to be about o.4 weight percent gold. The minimum of the lattice constant was observed at O.75 weight percent gold. No change in the lattice constant with time was found.

The Al₂Au phase has a range from 77.66 to 78.94 weight percent gold with the theoretical composition of Al₂Au nearly in the middle of the phase. The thermal coefficient of expansion, the density and the …

An Investigation Of A Constant Velocity Paper Unwinding Device, Jerry L. Gilmore

Masters Theses

"This thesis outlines one approach in designing a system which involves a second order nonlinear differential equation. A large number of variables are involved in this analysis. Therefore, there are many solutions to the problem but only a few of these will satisfy all required conditions. The analysis will be aided by the use of an analog computer. This computer can be manipulated to obtain optimum values for the different variables.

The computer results are presented in graphical form. Reasonable values for the different variables are obtained from these graphs.

The characteristics of the unwinding device were simulated on the …

Influence Of Porosity On The Fracture Stresses Of Electrical Porcelain., Edward Anton Snajdr

Masters Theses

"Spherical pores were induced in a typical quartz electrical porcelain body. Three levels of pore size and four levels of concentration were studied. Large strength sample sizes were employed using a three-point loading and diametral loading method. Data for induced quartz particles is also included"--Abstract, p.ii

The Construction And Evaluation Of A Small Scale Laboratory Fermentor For Batch And Continuous Studies., Robert Murray Logan

Masters Theses

"The purpose or this investigation was to design and construct a suitable apparatus for the aerobic culture or microorganisms to be used for preliminary batch studies and eventually, continuous fermentations.

The general design of the apparatus was patterned after small scale equipment described in the literature. Construction or the apparatus was carried out in the shop of the Department of Chemical Engineering and Chemistry. All of the necessary machining was done by the author.

The aeration-agitation system was evaluated by the use or the sulfite oxidation rate determination. The oxygen transfer rate provided by the apparatus was round to be …

Effect Of Stiffness Ratio On Stresses In A Rigid Frame., James Juh-Ling Tang

Masters Theses

"The elastic center method has been used to analyze several rigid frames with different geometric configurations and with component members of variable cross-sections. The basic approach is to divide the frame into small segments to solve this problem. From this analysis the best frame which is in the range of an economical design may be obtained for a given loading condition"--Abstract, p.2

Compensator Design For Unity Feedback Systems On The Digital Computer., Ping Liang

Masters Theses

"In control systems engineering it is frequently necessary to compensate a fixed plant whose transfer function cannot be changed. Usually the characteristics of the resulting system are established in terms of steady state and transient performance specifications. Generally it is necessary to insert a compensator which permits the system to satisfy the specifications as well as to provide an absolutely stable system.

In this thesis a method is developed to determine the transfer function of the compensator. Each system performance specification can be expressed in a differentiable inequality form composed of the system closed-loop gain, zeros, and poles. First, the …

Linear System Transfer Function Identification, Tuh-Kai Koo

Masters Theses

“An approach using a high speed special purpose digital computer to identify the transfer function of a linear system is presented in this thesis. The data for computation are obtained by measuring the system response and its derivatives periodically with a periodic test signal (impulse) input.

The order of the system is first determined by evaluating the rank of a Hankel matrix. Then, the transfer function is determined by solving two sets of system equations.

Theoretical analysis is emphasized in the study. Two examples are given for the purpose of illustrating the theory

Small Signal Gain Analysis For A Seven Cavity Klystron Amplifier., William E. Hord

Masters Theses

"The problem was to find a suitable method of using the digital computer to calculate the small signal gain characteristics of a seven cavity klystron amplifier. Background material relevant to the problem was reviewed. The differential equations for small signal conditions in a gridless gap klystron were developed. These equations were then solved and put in a matrix form suitable for digital computer analysis. Suggestions for additional development were proposed"--Abstract p. ii

Convective Heat Transfer In Small Enclosed Air Spaces., Joseph Charles Kroutil

Masters Theses

No abstract provided.

Pattern Calculations On A Loaded Spiral Antenna., Jose Briceno

Masters Theses

"The purpose of this thesis is to calculate and p lot the radiation patterns o f a ferrotron-loaded spiral antenna made of semicircles. In particular, this work is confined to a balanced spiral free to radiate in all directions.

The current distribution used in the evaluation of the vector potential is taken from a synthesized current obtained from experimental information on a ferrotron-loaded spiral antenna at a frequency of operation of 200 MC.

The calculated patterns of the spiral antenna are in general single lobed in a direction perpendicular to the plane of the antenna. The beamwidth varies from 62° …

Infrared Modulation Using The Field-Effect Properties Of Germanium., Lloyd E. Brunkhorst

Masters Theses

"The absorption of infrared radiation, by free carriers in germanium, has been used to amplitude modulate infrared radiation. In the experiment, a space charge layer consisting of free carriers is established at the inner surface of a germanium sample by using the field-effect technique. Infrared radiation of a wavelength to which the germanium is transparent is then Internally reflected from this surface. The infrared radiation passes twice through the space charge layer for each internal reflection. With each pass through the space charge layer, the amplitude of the transmitted infrared is decreased. Amplitude modulation of the transmitted infrared is accomplished …

Some Effects Of Impact Of Low Magnitude On The Deformation Of Prestressed Gypsum Cylinders., Arthur Joe Bush

Masters Theses

"A review of the literature pertaining to the subject is presented. Many series or impacts were made on specimens of gypsum which were already under a static load. A special. repetitive impact machine was used to allow a variety or weights to fall from predetermined heights. Tests were conducted inside a roan constructed especially for these tests. Heat gained or lost through the ceiling and walls was kept at a minilI1um by a lining or aluminum-covered, fiber glass insulation. Temperature and humidity conditions were kept nearly constant by a combination air-conditioner and dehumidifier.

Repetitive loading of the prestressed specimen was …

The Justification For And Design Of A Lunar Radio Observatory., Thomas Van Doren

Masters Theses

"The purpose of a radio telescope is to record information concerning the strength, spectrum, polarization, and direction of arrival of extraterrestrial electromagnetic radiation at radio frequencies. Earthly based radio observatories are hampered in their attempt to achieve this purpose by atmospheric absorption and reflection of the radiation. A lunar based system would not have this problem because the Moon possesses practically no atmosphere. However, other environmental conditions, such as micrometeorites, high frequency radiation, and extreme temperature variations, must be overcome. This thesis justifies the need for a lunar radio observatory and also describes a particular radio telescope system which should …

Effects Of Gamma Radiation On Ion Exchange Membranes., John R. C. Roop

Masters Theses

No abstract provided.

Composite Beams In Building Constructions., Mahendrasinhji M. Jhala

Masters Theses

"The use of composite beams is very common in bridge and. in building construction due to the fact that a savings in material is effected.

The study herein shows a simplified procedure for design of composite beams. A number of design charts for rapid selection of a wide-flange section and the necessary cover plates are presented herein. These charts are based on economic sections of steel beams when used in a simple span, if one knows the approximate depth of the beam, slab thickness, allowable stresses in the steel and concrete and live load moment, it is very easy to …

Application Of Photoelasticity To The Stability Of Slopes In Open-Pit Mines., Aly Hemedah Gomah

Masters Theses

"A study of the stability of wall slopes in open pit mines was performed by preparing photoelastic epoxy-resin models representing open pit mines with various slope angles. The models were loaded centrifugally, using the 'locked-in' stress technique. Due to the relatively large sizes of the models, stress distributions could not be recorded with the photographic equipment available. Therefore, fringes and isoclinics were plotted directly on the models themselves. The fringes were used to calculate the shear stress concentrations at arbitrary points in the model from known stresses at control points in the models. The type of slope failure that was …

Digital Computer Design Of Compensation For Linear Control Systems, Larry C. Amsler

Masters Theses

"If a control system is to be synthesized, it is inferred that a plant or process is present which must be controlled, and the problem of how to design the control system then arises. The first step is to decide on performance specifications to which the complete system must conform. These specifications may involve such things as the system steady state response, transient response, or frequency response. Any of several synthesis methods may then be applied to complete the system design.

In this study a synthesis method is developed for single-loop linear feedback systems. First, the number of compensating poles …

The Electrochemical Degradation Of Alkyl Benzene Sulfonate., Melvin David Rickard

Masters Theses

"The ever increasing use of nonbiodegradable synthetic detergents, mainly the alkyl benzene sulfonates, has created difficulties in water and wastewater treatment, and in stream pollution. Although considerable attention has been given to this problem, no solution has been developed which can be effectively employed in the abatement of detergent pollution.

The purpose of this investigation was to determine the feasibility of the use of direct current electrochemical degradation in the removal of alkyl benzene sulfonates (ABS) from water. The rate and degree of completion of the electrochemical reactions were determined, and the nature of the end products formed was investigated. …

An Electrolytic Polishing And Recrystallization Study Of Zinc And Zinc Alloys., Roy Ashley Smith

Masters Theses

"A Unitron hot stage and polarized light were used to enable direct observation of recrystallization in high purity (99.99 per cent) zinc and high zinc content alloys. Electrolytic polishing was investigated in an attempt to prepare unetched surfaces which would show good structural contrast under polarized light and thus permit structural changes occurring during recrystallization to be observed.

Kinetic data obtained from a sequence of photographs during each recrystallization trial showed typical sigmoidal isothermal reaction curves characteristic of a nucleation and growth process. It was determined that rates of nucleation and grain growth are a maximum over the same time …

Permeability Of Organic Protective Coatings And Relation To Film Thickness, Bipin N. Doshi

Masters Theses

“Special types of coating systems are used to protect industrial products and structures against corrosion. Many millions of dollars are spent each year for these coatings. The ability of protective coatings to reduce or inhibit corrosion depends on a variety of factors such as dry film thickness, resistance to permeation of ions and vapors, temperature, pressure, structure of binder, nature of pigment, electrolytic resistance, and many others.

The initial work done by Larry Inglis on the permeability of coatings and it's relation to thickness of coating films showed that the permeability, as determined by under film corrosion, was independent of …

A Study Of The Relative Electric Resistance Of Commercial Steels And Pure Iron, William Eugene Wistehuff

Masters Theses

"The change in relative electric resistance of five commercial steels, Armco Ingot Iron and Pure Iron were studied over the temperature range of 800°C to 1100°C in an attempt to correlate the phenomena of hot or red shortness with a change in the Electric resistance .

The results from the above resistance measurements were compared with mechanical tests of the same steels to show that at the point at which the iron sulfide liquid forms there is a definite change in the slope of the electric resistance vs temperature curve.

Also studied was a discontinuity in the electric resistance vs …