Engineering Commons^™

Reduced Graphene Oxide (Rgo) Hollow Network Cages For High-Performance Electrochemical Energy Storage, Chi Zhang, Xu-Jun He, Gao-Ren Li

Journal of Electrochemistry

The reduced graphese oxide (RGO) hollow network cages were synthesized via zinc oxide (ZnO) template-assisted electrodeposition. The as-prepared RGO hollow network cages exhibited the multi-level architectures, from nano sheets, porous structures, networks, to 3D microscaled hollow cages, which can simultaneously optimize transport of electroactive species, utilization rate of electrode material, and super capacitive performance. Electrochemical measurements confirmed the superior performance of RGO hollow network cages for supercapacitors (SCs), such as high Csp (393 F⋅g^-1 at 1.0 A⋅g^-1), excellent rate capability (21.2% Csp loss from 1.0 to 20 A⋅g^-1), and superior cycling stability (< 1% Csp loss after 10000 cycles).

Electrochemical And In Situ X-Ray Absorption Fine Structure Study Of Li-Rich Cathode Materials, Meng-Yan Hou, Hong-Liang Bao, Ke Wang, Jian-Qiang Wang, Yong-Yao Xia

Journal of Electrochemistry

A series of the lithium-rich and manganese-based layered structure xLi₂MnO₃•(1-x)LiMn_1/3Ni_1/3Co_1/3O₂ (x = 0.3,0.5,0.7) materials were synthesized by a co-precipitation method, and followed by a solid-state reaction process. By comparing the first cycle efficiency, the reversible discharge capacity, the cycling stability and the voltage decay during the charge/discharge cycling process, the material with the composition of 0.5Li₂MnO₃•0.5LiMn_1/3Ni_1/3Co_1/3O₂was found to show the best electrochemical performance. The lithium storage mechanism and thermal stability of the de-lithiated compound were also investigated …

Preparation And Characterization Of Van Der Waals Heterostructures, Horacio Coy Diaz

USF Tampa Graduate Theses and Dissertations

In this dissertation different van der Waals heterostructures such as graphene-MoS₂ and MoTe₂-MoS₂ were prepared and characterized. In the first heterostructure, polycrystalline graphene was synthesized by chemical vapor deposition and transferred on top of MoS₂ single crystal. In the second heterostructure, MoTe₂ monolayers were deposited on MoS₂ by molecular beam epitaxy.

Characterization of graphene-MoS₂ heterostructures was conducted by spin and angle resolve spectroscopy which showed that the electronic structure of the bulk MoS₂ and graphene in this van der Waals heterostructures is modified. For MoS₂ underneath the graphene, a band …

Impact Of Sludge Layer Geometry On The Hydraulic Performance Of A Waste Stabilization Pond, Faissal Romaric Ouedraogo

USF Tampa Graduate Theses and Dissertations

Improving the hydraulic performance of waste stabilization ponds (WSPs) is an important management strategy to not only ensure protection of public health and the environment, but also to maximize the potential reuse of valuable resources found in the treated effluent. To reuse effluent from WSPs, a better understanding of the factors that impact the hydraulic performance of the system is needed. One major factor determining the hydraulic performance of a WSP is sludge accumulation, which alters the volume of the pond.

In this study, computational fluid dynamics (CFD) analysis was applied to investigate the impact of sludge layer geometry on …

Tunable Nano-Delivery System For Cancer Treatment: A New Approach For Targeted Localized Drug Delivery, Rana Falahat

USF Tampa Graduate Theses and Dissertations

Localized drug delivery systems have been widely studied as potential replacements for conventional chemotherapy with the capability of providing sustained and controlled drug release in specific targeted sites. They offer numerous benefits over conventional chemotherapy such as enhancing the stability of embedded drugs and preserving their anticancer activity, providing sustained and controlled drug release in the tumor site, reducing toxicity and diminishing subsequent side effects, minimizing the drug loss, averting the need for frequent administrations, and minimizing the cost of therapy.

The aim of this study is to develop a localized drug delivery system with niosomes embedded in a chitosan …

Mechanical Engineering News, Georgia Southern University

Mechanical Engineering: News & Publications (2013-2023)

• NSF RET Grant Awarded to Dr. Soloiu

Synthesis, Structural Diversity, And Redox Control Of Cyclometalated Monoruthenium Complexes, Zhong-Liang Gong, Jiang-Yang Shao, Yu-Wu Zhong

Journal of Electrochemistry

Cyclometalated ruthenium complexes have received increasing attractions recently due to their excellent redox and photophysical properties. One structural feature of these complexes is that there is a ruthenium-carbon (Ru-C) σ bond presented in the molecule. Three common methods, namely, the “late metalation”, “early metalation”, and “transmetalation” methods, for the synthesis of cyclometalated ruthenium complexes are discussed and summarized. General strategies for the design of cyclometalating ligand and cyclometalated ruthenium complexes are introduced. By using different ancillary ligands, such as pyridine, imidazole, triazole, and pyrimidine, a great number of ruthenium complexes can be prepared. The presence of the Ru-C bond significantly …

3, 4-Ethylenedioxythiophene Monomer As Safety-Enhancing Additive For Lithium Ion Batteries, Wei-Xiao Ji, Feng Wang, Jiang-Feng Qian, Yu-Liang Cao, Xin-Ping Ai, Han-Xi Yang

Journal of Electrochemistry

Safety concern is a major obstacle hindering the wide applications of large-capacity lithium ion batteries (LIBs) in electric vehicles. In this paper, a polymerizable monomer of 3, 4-ethylenedioxythiophene (EDOT) was proposed and tested as an electrolyte additive for enhancing the safety of LIBs. The electro-oxidative polymerization behaviors and influence of PEDOT additive on the thermal behavior of LiCoO₂ cathode, as well as the safety performance and electrochemical properties of LiCoO₂-based LIBs were investigated. The results from cyclic voltammetry (CV) and transmission electron microscope (TEM) characterizations indicated that the monomer additive can be electro-oxidatively polymerized to form a …

Electrochemiluminescence Immunosensor Based On Platinum Nanoparticles For The Determination Of Apolipoprotein A1, Ni Liao, Ying Zhuo, Ruo Yuan

Journal of Electrochemistry

In this paper, a novel electrochemiluminescence (ECL) immunosensor for the detection of apolipoprotein A1 was constructed based on flower-like platinum nanoparticles (PtNFs) via a one-pot chemical synthesis method. The PtNFs was used to immobilize the secondary antibody and enzyme (GOD). Then the prepared bioconjugates were introduced onto the electrode via sandwich immunoreactions. Accordingly, the ECL luminophore peroxydisulfate (S₂O₈^2-) was presented in the working buffer solution containing an appropriate amount of glucose. Through the ECL responses of S₂O₈^2- and O₂, a dramatically amplified ECL signal was obtained for the reason …

Developments Of Photo-Assisted Fuel Cells, Ling-Ling Zhang, Shao-Jun Dong

Journal of Electrochemistry

The exploitation and utilization of fossil fuels have led to serious energy crisis and environmental pollution. In this case, the development of renewable energy is an alternative to traditional energy consumption. Fuel cells (FCs) can convert chemical energy into electricity via the electrochemical reaction, which is green and environment-friendly. Photo-assisted FCs integrate photo-responsive components into FCs, leading to the dual routes of energy conversion including light energy to electricity and chemical energy to electricity, and thus, improving the energy utilization efficiency. The development of photo-assisted FCs is significant for practical application and promising to solve the coming energy crisis. In …

Simultaneous Specimen Current And Time-Dependent Cathodoluminescence Measurements On Gallium Nitride, E. M. Campo, L. Hopkins, M. Pophristic, I. T. Ferguson

Electrical and Computer Engineering Faculty Research & Creative Works

Time-dependent cathodoluminescence (CL) and specimen current (SC) are monitored to evaluate trapping behavior and evolution of charge storage. Examination of CL and SC suggests that the near band edge emission in GaN is reduced primarily by the activation of traps upon irradiation, and Gallium vacancies are prime candidates. At the steady state, measurement of the stored charge by empiric-analytical methods suggests that all available traps within the interaction volume have been filled, and that additional charge is being stored interstitially, necessarily beyond the interaction volume. Once established, the space charge region is responsible for the steady state CL emission and, …

Uniform Nanoshells For Functional Materials: Constructions And Applications, Shu-Yi Duan, Wei Zhang, Jun-Yu Piao, An-Min Cao, Li-Jun Wan

Journal of Electrochemistry

As a significant protocol for materials treatment, surface modification has found broad applications in different fields including catalyst, photochemistry, and electrochemistry. Herein, we introduced the representative synthetic methodologies for the constructions of different functional materials with a focus on their core-shell structures. By taking the electrode materials in lithium ion batteries as an example, we demonstrated the importance of surface modification on the electrode materials. Different coating materials ranging from metal oxides, metal phosphates to carbon have been discussed. We also showed that an accurate control on the surface layer can be crucial for optimizing the electrochemical performances of the …

Full Proceedings: Hydraulic Structures And Water System Management, International Association For Hydro-Environmental Engineering And Research, United States Society On Dams

International Symposium on Hydraulic Structures

No abstract provided.

Energy Consumption Prediction With Big Data: Balancing Prediction Accuracy And Computational Resources, Katarina Grolinger, Miriam Am Capretz, Luke Seewald

Electrical and Computer Engineering Publications

In recent years, advances in sensor technologies and expansion of smart meters have resulted in massive growth of energy data sets. These Big Data have created new opportunities for energy prediction, but at the same time, they impose new challenges for traditional technologies. On the other hand, new approaches for handling and processing these Big Data have emerged, such as MapReduce, Spark, Storm, and Oxdata H2O. This paper explores how findings from machine learning with Big Data can benefit energy consumption prediction. An approach based on local learning with support vector regression (SVR) is presented. Although local learning itself is …

Hydraulic Structures And Water System Management-Ishs2016 In Perspective, Brian M. Crookston, Blake Tullis

International Symposium on Hydraulic Structures

Hydraulic structures are vital features in our water infrastructure, as they help meet the diverse and challenging demands of society, including conveyance, flood protection, environmental and ecological impacts, and systems management. Indeed, there are a number of challenges facing engineers today. This 6^th IAHR International Symposium on Hydraulic Structures (ISHS2016) brought together domestic and international expertise from research, practice, and implementation in a forum for knowledge exchange and networking discussion on critical issues related to hydraulic structure research, performance, operations, maintenance, and community implications. It continued the rich tradition of this series by stimulating interest on advancement in the …

Simultaneous Metal-Insulator And Antiferromagnetic Transitions In Orthorhombic Perovskite Iridate Sr0.94Ir0.78O2.68 Single Crystals, Hao Zheng, Jsaminka Terzic, Feng Ye, X. G. Wan, D. Wang, Jinchen Wang, Xiaoping Wang, P. Schlottmann, Shujuan Yuan, Gang Cao

Center for Advanced Materials Faculty Publications

The orthorhombic perovskite SrIrO₃ is a semimetal, an intriguing exception in iridates where the strong spin-orbit interaction coupled with electron correlations tends to impose an insulating state. We report results of our investigation of bulk single-crystal S_r0.94Ir_0.78O_2.68 or Ir-deficient, orthorhombic perovskite SrIrO₃. It retains the same crystal structure as stoichiometric SrIrO₃ but exhibits a sharp, simultaneous antiferromagnetic (AFM) and metal-insulator (MI) transition occurring in the basal-plane resistivity at 185 K. Above it, the basal-plane resistivity features an extended regime of almost linear temperature dependence up to 800 K but the strong …

The Development Of A Prosthetic Training Software For Upper Limb Amputees, Tyler Kayne Sullins

USF Tampa Graduate Theses and Dissertations

The purpose of this study was to develop an intuitive software that aids in the field of prosthetic training and rehabilitation by creating an individualized visualization of joint angles. This software is titled “the prosthetic training software (PTS) for individualized joint angle representation”, and it enables the individualized portrayal of predicted or pre-recorded joint angles. The PTS is an intuitive program for clinicians and prosthesis users that produces an animation of a virtual avatar reflecting the user’s segment lengths and amputation for rehabilitation and training purposes.

The PTS consists of a graphical user interface (GUI) and a 3D visualization of …

Dynamic Simulation And Analysis Of Fsae Racer For Development Of Stability Control System, Stone D. Williford

Honors College Theses

Using Adams/Car software, a computer model of Georgia Southern University’s 2016 Formula Society of Automotive Engineers (FSAE) racecar was developed with the purpose of researching vehicle stability under dynamic conditions. Previous research in this field of study has been conducted to verify that Adams/Car simulations provide accurate results using data acquisition systems, so the major work for the current research has been to create an updated version of the vehicle designed and fabricated by Eagle Motor Sports. With this new model, vehicle roll, and pitch data as well as vehicle traction were collected during dynamic simulations. The overall goal for …

Biophysical Characterization And Theoretical Analysis Of Molecular Mechanisms Underlying Cell Interactions With Poly(N-Isopropylacrylamide) Hydrogels, Michael C. Cross

USF Tampa Graduate Theses and Dissertations

So-called, “Dynamic biomaterials” comprised of stimuli-responsive hydrogels are useful in a wide variety of biomedical applications including tissue engineering, drug delivery, and biomedical implants. More than 150,000 peer-reviewed articles (as of 2016) have been published on these materials, and more specifically, over 100,000 of these are on the most widely studied, poly(N-isopropylacrylamide). This thermoresponsive polymer in a crosslinked hydrogel network undergoes a large volume phase transition (𝑉/𝑉₀ ~ 10 − 100) within a small temperature range (𝑇 ~ 1 − 3𝐾) making it particularly useful for tissue engineering applications because of the ability to control the topographical configuration of …

Jazzing Up Next-Gen Librarians For Freshman Engineering Instruction Delivery, Marian G. Armour-Gemmen, Chanelle Pickens, Robin A.M. Hensel, Mary L. Strife, Mariam Jalalifard

Faculty & Staff Scholarship

Because of the need for science and engineering librarians, both nationwide and at West Virginia University (WVU), a model of Introduction to STEM Disciplines’ Information Use and Mentoring

occurred at WVU. The engineering librarians introduced new resident librarians and a graduate research assistant to the Freshman Engineering program and involved them in teaching several engineering information literacy sessions. The goal of engaging the new librarians into the educational activities was to motivate their learning, gain feedback on current teaching strategies and fresh ideas for possible future implementation, and facilitate buy-in of the need for and role of STEM-specific librarians. The …

Small-Scale And Large-Scale Interventions To Improve [State] Student’S College Readiness, Virgil U. Pierce, Javier A. Kypuros, Shirley J. Mills

Mechanical Engineering Faculty Publications and Presentations

We are conducting two interventions aimed at improving entering students’ college readiness and mathematics placement. The small-scale intervention is aimed at working with students on the university campus. Students who are targeted have high school course work indicating that they have experience in Calculus or Pre-Calculus courses, but whose placement tests have not indicated they are ready for Calculus. At our institution this is a significant number of students and the goal of the project is to develop methods to address and accelerate students in this category. The course design, to take advantage of the students’ prior experience, emphasizes practice …

Extending Wid To Train Mechanical Engineering Gtas To Evaluate Student Writing, Nancy Barr

Department of Mechanical and Aerospace Engineering Publications

Beyond first-year composition, the typical undergraduate mechanical engineering curriculum provides few opportunities to develop writing skills without a concerted effort by faculty to incorporate writing into their courses. One underutilized path for BSME students to strengthen those skills is the required sequence of laboratory courses, where students write several lab reports, evaluated by graduate teaching assistants (GTAs), many of whom speak English as a second language. Historically, engineering GTAs have not been trained in evaluating student writing in a way that helps students improve their technical communication skills, a method known as formative assessment. Formative assessment can be a key …

Promoting School Earthquake Safety Through A Classroom Education Grassroots Approach, Lelli Van Den Einde, Heidi Tremayne, Thalia Anagnos, James Mallard

Faculty Publications

The earthquake engineering community has recognized that in seismically active regions throughout the United States, hundreds of thousands of students and staff unknowingly study and work in structurally vulnerable school and university buildings. The School Earthquake Safety Initiative (SESI), spearheaded by the Earthquake Engineering Research Institute (EERI), is a collaborative network of diverse, expert, and impassioned professionals who are committed to creating and sharing knowledge and tools that enable broadminded, informed decision making around school earthquake safety. The Classroom Education and Outreach Subcommittee of SESI is tackling the problem of school safety from a grassroots approach, with the goal of …

Development Of An Instrument To Measure The Entrepreneurial Mindset Of Engineering Students, Cheryl Q. Li, Ronald S. Harichandran, Maria-Isabel Carnasciali, Nadiye O. Erdil, Jean Nocito-Gobel

Civil Engineering Faculty Publications

This work in progress describes the development of an instrument to measure entrepreneurial mindset of engineering students. The need for developing the entrepreneurial mindset of engineering students is being recognized by many universities. However, very few comprehensive, generalized and well-validated instruments are available for assessing the entrepreneurial mindset of engineering students. Most research and educational efforts focus on the design and implementation of engineering entrepreneurship programs, but assessment practices have not kept up.1-2 There are several reasons for the shortfall in assessment practices: 1) Introducing engineering students to entrepreneurship is a relatively new trend and it will take time for …

Integrating E-Learning Modules Into Engineering Courses To Develop An Entrepreneurial Mindset In Students, Nadiye O. Erdil, Ronald S. Harichandran, Jean Nocito-Gobel, Maria-Isabel Carnasciali, Cheryl Q. Li

Engineering and Applied Science Education Faculty Publications

Engineering graduates who will be leaders in today’s rapidly changing environment must possess an entrepreneurial mindset and a variety of professional skills in addition to technical knowledge and skills. An entrepreneurial mindset applies to all aspects of life, beginning with curiosity about our changing world, integrating information from various resources to gain insight, and identifying unexpected opportunities to create value. The Kern Entrepreneurial Engineering Network (KEEN) defines curiosity, connections and creating value as three core components of an entrepreneurial mindset. These 3Cs coupled with associated engineering skills forms KEEN’s entrepreneurial mindset framework. An entrepreneurial mindset enables engineers to develop sound …

What Does It Mean To Be An Engineer? A Comparison Of Adult Students At Three Institutions, Tressa Kay Mikel, Pedro Sh Kim, Maria-Isabel Carnasciali, Shannon Ciston

Engineering and Applied Science Education Faculty Publications

Our work is motivated by the need to cultivate a diverse group of talented future engineers. Adult undergraduate students over the age of 25 are an important source of engineers, with life experience that can enhance student experience, but not much is understood yet about this specific group. Adult students face challenges specific to their demographic due to responsibilities in other aspects of their life as employees, parents, spouses, and more. This paper examines adult engineering students’ conceptions of what an engineer is, across three distinct academic environments: a community college, a small private undergraduate university, and a large public …

Preliminary Assessment Of And Lessons Learned In Pitch: An Integrated Approach To Developing Technical Communication Skills In Engineers, Nadiye O. Erdil, Ronald S. Harichandran, Michael A. Collura, Jean Nocito-Gobel, David J. Adams, Amanda Simson

Mechanical and Industrial Engineering Faculty Publications

The Project to Integrate Technical Communication Habits (PITCH) has been implemented across seven engineering and computer science undergraduate programs starting in fall 2012. The overarching goal of PITCH is to develop written, oral and visual communication skills and professional habits in engineering students. PITCH activities begin in the very first semester and are reinforced and extended through all four years of each program. After three years of progressively more extensive development and deployment, a preliminary assessment of student writing over their first three years in programs was performed. In May 2016 the first cohort of students will have completed the …

Dango (Doings And Goings On) - Vol. 22 | Issue 6, Hannah Hamilton, Matthew Kimball, Aric Tate, Haley Stien, Vicente Rojas, Caleb Hicks, Zhaojia Xi, Joshua Daniel Martinez, Reuben Byrd, Paul Carstens, Mike Daugherity, Donald Isenhower

DANGO: Doings and Goings On: Summer Research Newsletter, Department of Engineering and Physics

Weekly newsletter from ACU Physics and Engineering

Why This Flip Wasn't A Flop: What The Numbers Don't Tell You About Flipped Classes, Heather Noel Fedesco, Troy Cary

IMPACT Publications

This paper details the conversion of a large, required Civil Engineering fluid mechanics course into a more student-centered, active learning-oriented course through the flipping of one lecture per week. In the flipped class, students collaboratively solve homework problems in groups while receiving “expert” feedback from instructors and TAs. To offset the lost lectures, some course material that has been delivered in traditional lectures has been placed online in the form of short videos and textbook readings, with low-stakes quizzes for assessment.

Student learning gains were quantitatively assessed by comparing quiz and final exam scores for three semesters (1 pre-flip and …

All Active All The Time? What Are The Implications Of Teaching A Traditional Content-Rich Machine Components/Mechanical Systems Design Course Using Active Learning?, James M. Widdmann, Peter Schuster

Mechanical Engineering

This paper examines the use of research-proven Active Learning techniques to transform the teaching of a traditional Machine Components/Mechanical Systems Design class. We know from research in Active learning that use of these methods can often lead to greater conceptual understanding and greater engagement of the students with engineering course materials, yet a common concern among engineering faculty is that the adoption of Active learning techniques will not allow the full breadth and depth of traditional content coverage. In this work, the authors reimagined one of the most content-heavy courses in a traditional Mechanical Engineering curriculum by including many Active …