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Articles 9361 - 9390 of 197998
Full-Text Articles in Engineering
Evaluation Of Thermal And Emission Performances Of Briquettes Produced From Carbonized Corn Cob And Corn Husk, Karina S. Motani
Evaluation Of Thermal And Emission Performances Of Briquettes Produced From Carbonized Corn Cob And Corn Husk, Karina S. Motani
Tanzania Journal of Engineering and Technology (TJET)
The Mozambican agro-industrial sector relies heavily on various crops, with maize being the most significant. During processing, substantial waste is generated, which is often discarded as organic matter or burned, contributing to environmental pollution and the loss of potential energy resources. This study evaluated the thermal and emission performance of briquettes made from carbonized corn cob (CCC) and carbonized corn husk (CCH), using cashew nut skin as a binder for clean cooking applications. The briquettes were assessed against firewood and charcoal as control fuels, focusing on several energy performance parameters: water boiling time (WBT), combustion index (CI), thermal efficiency (TE), …
The Impacts Of Renewable Energy Sources: A Review On Grid Inertia And Frequency Regulation, Sospeter Gabriel
The Impacts Of Renewable Energy Sources: A Review On Grid Inertia And Frequency Regulation, Sospeter Gabriel
Tanzania Journal of Engineering and Technology (TJET)
The power system is gradually transitioning into low inertia due to integrating substantial intermittency quantity of converter-based renewable energy sources, such as wind and photovoltaic power, into the current power grid network. This integration presents significant inertia and frequency control challenges to the network as a result of a decrease in the percentage of synchronous generators. Moreover, faster frequency deviations are posed by the mismatch between the supply and demand during contingencies, which creates difficulties in preserving the frequency stability of the power system. This research explores the impacts of renewable energy sources (RESs) on grid inertia and frequency management …
Analysis Of An Improved Reliability Dual-Buck Structured Three-Level Flying Capacitor Inverter, Almachius Kahwa Dr.
Analysis Of An Improved Reliability Dual-Buck Structured Three-Level Flying Capacitor Inverter, Almachius Kahwa Dr.
Tanzania Journal of Engineering and Technology (TJET)
With the increased demand for high-reliability power converters in the electric drive-train and propulsion systems, the efforts to design and analyze converters with high fault tolerance have become apparent. Among the emerging trends to improve the reliability of power converters is the incorporation of dual-buck (DB) structures in traditional converter topologies. Thus, this paper studies a single-phase dual-buck structured three-level flying capacitor (FC) inverter. The dual-buck flying capacitor (DBFC) inverter was constructed in such a way as to suppress the shoot-through problems that may occur because of the switching mismatch and gate driver delay, as exhibited in the traditional FC …
Calibration Of Measurement Tools In The Experimental Test Rig For Hydropower Performance Evaluation, Ombeni J. Mdee
Calibration Of Measurement Tools In The Experimental Test Rig For Hydropower Performance Evaluation, Ombeni J. Mdee
Tanzania Journal of Engineering and Technology (TJET)
The demonstration of a typical hydropower plant requires the development of a test rig with the installation of tools to measure the performance parameters. The measurement tools require a calibration process to improve the quality of recorded data. This study involved the calibration of traditional and automated measurement tools connected to the hydropower test rig through an Arduino microprocessor. The automated measurement tools included a pressure transducer, flow meter, digital tachometer, and torque transducer, while traditional measurement tools, including a pressure gauge, concrete water tank, contact tachometer, and force lever arm balance, were connected in the same test rig during …
Review On Gas-To-Liquids Conversion Technology: Lessons From Case Studies And Potential Strategies For Implementation In Tanzania, Joseph H. Kihedu
Review On Gas-To-Liquids Conversion Technology: Lessons From Case Studies And Potential Strategies For Implementation In Tanzania, Joseph H. Kihedu
Tanzania Journal of Engineering and Technology (TJET)
This review paper explores the transformative potential of Gas-to- Liquids (GTL) technology for harnessing Tanzania's vast natural gas resources. With significant discoveries of natural gas reserves totalling up to 57 Tcf in fields such as Songosongo, Mnazi Bay, Block 1, 2, 3 and 4. Tanzania is positioned to leverage GTL technology to convert these resources into high-value liquid fuels like gasoline, diesel and naphtha. Review of GTL process, its products and applications has been done. By analysing successful GTL projects globally and drawing lessons applicable to Tanzania, this paper provides strategic recommendations for policymakers and stakeholders to foster GTL development. …
A Review Of Lithium-Ion Battery Capacity Fade Deceleration At Power Fluctuations In Renewable Energy Systems, Isaac Gwayi
A Review Of Lithium-Ion Battery Capacity Fade Deceleration At Power Fluctuations In Renewable Energy Systems, Isaac Gwayi
Tanzania Journal of Engineering and Technology (TJET)
Application of lithium-ion (Li-ion) batteries to store energy in renewable energy systems (RESs) is increasing due to their promising properties. Therefore, it is crucial to understand aging behaviours of Li-ion battery during RES life time as this directly affects cost of energy. Li-ion battery aging can be categorised into calendar aging and cycle aging. Calendar aging depends mainly on temperature and state of charge (SoC). In addition to temperature and SoC, cycle aging depends also on charge and discharge current rates and cut-off voltages. Higher current rates lead to faster Li-ion battery aging. It is necessary to identify appropriate battery …
Assessment Of Maintenance Performance Level Of Selected Hydropower Plants In Tanzania, Mahamudu H. Mtebwa
Assessment Of Maintenance Performance Level Of Selected Hydropower Plants In Tanzania, Mahamudu H. Mtebwa
Tanzania Journal of Engineering and Technology (TJET)
Despite significant progress in increasing electricity access to over 78%, electricity reliability in Tanzania remains a concern, with frequent power outages reported. Maintenance issues in hydropower plants have been identified as a critical factor contributing to this problem. However, the specific maintenance performance levels have not been fully assessed. This study conducts a comprehensive evaluation of the maintenance performance of four key hydropower plants: Kidatu (204 MW), Kihansi (180 MW), Mtera (80 MW), and New Pangani Falls (68 MW). Data collected from staff surveys and maintenance records between 2018 and 2022 were used in the study. Although staff demonstrated a …
Design And Control Of A Versatile Modular Soft Robotic System With Integrated Resource Sharing And Self-Reconfiguration Capabilities, Joshua Knospler
Design And Control Of A Versatile Modular Soft Robotic System With Integrated Resource Sharing And Self-Reconfiguration Capabilities, Joshua Knospler
Theses and Dissertations
Modular, self‑reconfigurable soft robots promise unprecedented versatility by combining the compliance of soft materials with the adaptability of modular architectures. This thesis presents an integrated system of pneumatic, bending-type soft actuator modules. Modules are compact and fully equipped with tunable magnetic and electromechanical connections for low‑power attachment and detachment and a novel power-air-communication (PAC) connector for seamless sharing of electricity, compressed air, and digital signals. This work examines two representative assemblies: ManusBot, a pinching gripper, and TendrilBot, a versatile linear configuration for various tasks. Their grasping performance, variable stiffness, and radial support capabilities are characterized. A magnetic interlock and an …
Predicting The Influence Of Aggregate Size And Distribution On Cementitious Concrete Properties: A Review, Innocent J. Macha
Predicting The Influence Of Aggregate Size And Distribution On Cementitious Concrete Properties: A Review, Innocent J. Macha
Tanzania Journal of Engineering and Technology (TJET)
Cement concrete has been in use for centuries as one of the primary construction materials. Its demand in the construction industry is expected to continue for several centuries before the full development of alternative products. However, one of the main areas of research interest is understanding how its constituents can be tailored to make its properties predictable to reduce risks associated with structural failures, reconstruction and reduced durability. These hindrances associated with cementitious concrete result from several attributes, including constituent material characteristics, mixing ratios and workmanship. Understanding the predictability of cement concrete properties requires computer modelling tools to provide reliable …
Towards Future Sustainable Infrastructure: The Role Of Technical Audit In Tanzania’S Public Works, George C. Haule
Towards Future Sustainable Infrastructure: The Role Of Technical Audit In Tanzania’S Public Works, George C. Haule
Tanzania Journal of Engineering and Technology (TJET)
This study aimed to investigate the vital role and impact of technical audits in promoting sustainable infrastructure development in Tanzania. The role and effects of technical audits in long-term infrastructure development were studied using a mixed-methods approach with both quantitative and qualitative parts. Data were collected through analysis of technical audit documentation, a semi-structured questionnaire, and stakeholder interviews. The study revealed the various dimensions of infrastructure investment projects, including initiation and planning, design, procurement of contractors and consultants, contract management, environment, health, and safety. The technical audit findings reported weaknesses or non-performance issues in infrastructure planning at the national level …
Root Cause Analysis Of Performance Degradation For An Xyz Thermal Power Plant In Tanzania, Simon I. Marandu
Root Cause Analysis Of Performance Degradation For An Xyz Thermal Power Plant In Tanzania, Simon I. Marandu
Tanzania Journal of Engineering and Technology (TJET)
Thermal power plants in Tanzania have been experiencing performance degradation, typically arising from component and subsystem failures, which contribute to power system instability and unreliability. This paper presents a case study of the root causes of performance degradation of an XYZ thermal power plant. The study was conducted by reviewing plant documentations, including maintenance and operational data logbooks, and by standardising the approach through the adoption of ISO 14224:2016 for maintenance and reliability data exchange. Data evaluation was carried out using principal component analysis and scree plot analytical techniques to enhance the depth and accuracy of root cause identification. Additionally, …
Assessment Of Digital Solutions For Conformity Assessment Of Legally Controlled Measuring Instruments In Tanzania, Faraja Nyoni
Assessment Of Digital Solutions For Conformity Assessment Of Legally Controlled Measuring Instruments In Tanzania, Faraja Nyoni
Tanzania Journal of Engineering and Technology (TJET)
The advent of state-of-the-art digital technologies since 2011 has led to the digital transformation of legal metrology practices to ensure the trustworthiness of software-controlled measuring instruments globally. Despite the digital transformation in legal metrological practices, the conformity assessment of legally controlled measuring instruments is manually done (i.e., paper-based) in Tanzania. The paper-based conformity assessment of legally controlled measuring instruments is prone to error and lacks efficiency and effectiveness. This study aimed to assess digital solutions for improving conformity assessment through a comprehensive survey conducted across various regions in Tanzania, targeting a stratified sample of 51 respondents from organizations involved in …
Optimizing The Processing Temperature For Synthesis Of Silver Nanoparticles Within Cellulose-Wool Keratin Supramolecular Matrix Using Butylmethylimmidazolium Chloride Ionic Liquid, Ngesa E. Mushi
Tanzania Journal of Engineering and Technology (TJET)
To date, the synthesis of silver nanoparticles on the surface of cellulose and wool keratin biopolymer, while dissolved in ionic liquid, is attractive because of its biomedical potential. However, the optimal processing temperature for the nanoparticle formation is unclear. The previously reported temperature of approximately 120°C gives unpredictable results. The current study employs a combination of 50% cellulose and 50% keratin, along with 69 mg of silver chloride, in Butylmethylimidazolium Chloride BMImCl ionic liquid, using a single-pot process to produce a supramolecular film via non-derivatized mechanochemical interactions. The primary objective is to experimentally establish the processing temperature to achieve stable …
Effect Of Sorbitol Plasticizer On Bioplastics Properties Based On Oil Palm Empty Fruit Bunches (Opefb) And Jackfruit Seed Starch, Nia Sasria, Vita Nur Afifah, Gusti Umindya Nur Tajalla
Effect Of Sorbitol Plasticizer On Bioplastics Properties Based On Oil Palm Empty Fruit Bunches (Opefb) And Jackfruit Seed Starch, Nia Sasria, Vita Nur Afifah, Gusti Umindya Nur Tajalla
Makara Journal of Science
In bioplastics, natural materials that are easily decomposed are used to minimize plastic waste. In this research, the compositions used were cellulose from oil palm empty fruit bunches (OPEFB), jackfruit seed starch, and carboxymethyl cellulose (CMC) as a filler with sorbitol as a plasticizer. This study aimed to analyze the effect of a sorbitol plasticizer on bioplastic properties. The study began by extracting jackfruit seed starch and OPEFB cellulose. Subsequently, bioplastics were prepared by varying sorbitol, namely 0 (S – 0), 0.5 mL (S – 0.5), 1 mL (S – 1), and 1.5 ml (S – 1.5), with CMC 20%. …
Development Of An Ann-Based Predictive Model For The Efficient Treatment Of Industrial Wastewater, Alisher Khudoyberdi Ugli Rakhimov, Hasan Siddiq Ugli Murodov, Farrukh Bakhtiyorovich Igitov, Shuhrat Ahmadjonovich Mutalov, Jaloliddin Abdurazzakovich Eshbobaev
Development Of An Ann-Based Predictive Model For The Efficient Treatment Of Industrial Wastewater, Alisher Khudoyberdi Ugli Rakhimov, Hasan Siddiq Ugli Murodov, Farrukh Bakhtiyorovich Igitov, Shuhrat Ahmadjonovich Mutalov, Jaloliddin Abdurazzakovich Eshbobaev
Chemical Technology, Control and Management
The effective removal of free chlorine ions from industrial wastewater is critical to ensure process safety, minimize equipment corrosion, and protect aquatic environments. In this study, a laboratory-scale activated carbon filtration system was developed and tested to treat chlorine-contaminated water collected from sludge collectors at industrial facilities. A total of 200 experimental trials were conducted under varied operational conditions, including changes in flow rate, initial chlorine concentration, pressure, pH, temperature, and activated carbon dosage. The resulting dataset was used to train a predictive model based on a feedforward backpropagation artificial neural network (ANN) implemented in MATLAB. The ANN model demonstrated …
Modeling Of Carbonization And Absorption Processes In Soda Ash Production, Nadirbek Rustambekovich Yusupbekov, Djalolitdin Paxritdinovich Mukhitdinov, Fatima Faxritdinovna Iskhakova
Modeling Of Carbonization And Absorption Processes In Soda Ash Production, Nadirbek Rustambekovich Yusupbekov, Djalolitdin Paxritdinovich Mukhitdinov, Fatima Faxritdinovna Iskhakova
Chemical Technology, Control and Management
The article considers the problem of modeling the ammonia-soda process of soda ash production and presents the chemistry of sodium bicarbonate (NaHCO₃) formation. The equation of the kinetics of the reaction, used as a model of the carbonation process, is derived from a system of equations and its computer model is compiled. The system of differential equations reflecting the kinetics of the process was solved in the Mathcad package. The result of the modeling is presented. Based on the experimental data, the dependence of the absorption column performance on temperature and the dependence reflecting the optimal value of the absorption …
Design Of Automation For The Absorption Process In Hydrogen Purification From Carbon Dioxide, Azizbek Nodirbekovich Yusupbekov, Saidamirkhon Oripov, Diyoraxon Zokirxon Qizi Oripova
Design Of Automation For The Absorption Process In Hydrogen Purification From Carbon Dioxide, Azizbek Nodirbekovich Yusupbekov, Saidamirkhon Oripov, Diyoraxon Zokirxon Qizi Oripova
Chemical Technology, Control and Management
This article discusses the automation of the methanol-acetone mixture absorption process to improve control efficiency. The existing local automatic control system (ACS) was upgraded to a cascade system, reducing component concentration deviations by 12% and decreasing the transition process time from 1606 to 1592 seconds. A mathematical model of the gas absorption process was developed, incorporating material balance equations, mass transfer equations, and transfer functions. The parameters of the PI controller were calculated to ensure system stability under ±10% coefficient variations. A comparative analysis of system characteristics before and after modernization confirmed a reduction in overshoot to 0% and an …
The Importance Of The Analog-To-Digital Converter In The Measurement System, Aliev Ravshan, Anvar Djalilov
The Importance Of The Analog-To-Digital Converter In The Measurement System, Aliev Ravshan, Anvar Djalilov
Chemical Technology, Control and Management
At the moment, many scientific researches are being conducted all over the world on the economical use of water and energy resources. Most of the scientific research works are aimed at improving measurement techniques and technologies, that is, increasing their accuracy. With this in mind, a high-precision analog-to-digital converter due to its unique metrological and technical characteristics was studied in this research paper. As a result of the study, it became clear that the use of a small-sized, high-precision sigma-delta analog-to-digital converter in modern measuring technology has a positive effect on its accurate and efficient operation.
Energy Conversion In Nuclear Batteries, Suhrob Vahob O'G'Li Ibrohimov
Energy Conversion In Nuclear Batteries, Suhrob Vahob O'G'Li Ibrohimov
Chemical Technology, Control and Management
The transformation of energy in nuclear reactors or processes involves converting mass into energy as a result of nuclear reactions. This can include nuclear fission (splitting heavy atomic nuclei) or nuclear fusion (combining light nuclei). In these processes, energy is released in the form of heat, which can be used for electricity generation or other purposes.
Optimisation Of Astatic Controllers In Automatic Control Systems, Isamiddin Xakimovich Siddikov, Dilnoza Maxamadjanovna Umurzakova
Optimisation Of Astatic Controllers In Automatic Control Systems, Isamiddin Xakimovich Siddikov, Dilnoza Maxamadjanovna Umurzakova
Chemical Technology, Control and Management
This article examines the influence of various factors on the efficiency of optimizing station controllers in automatic control systems. The main focus is on minimizing static errors and improving the reliability of controllers. Optimization methods for PID and PI2D controllers are discussed, including the use of modern approaches such as genetic algorithms. The necessity of compromise solutions to achieve high-quality system responses to various impacts is investigated. It was also suggested that there is a need for an integrated approach to setting up controllers in order to increase their reliability and flexibility in conditions of dynamically changing processes. …
Adaptive Control Of Air Purification Processes In Industrial Painting Workshops: A Review Of Scientific Literature, N.A Kabulov, Sh. Mamatbekov
Adaptive Control Of Air Purification Processes In Industrial Painting Workshops: A Review Of Scientific Literature, N.A Kabulov, Sh. Mamatbekov
Chemical Technology, Control and Management
This article examines modern approaches to adaptive control of air purification processes in industrial facilities, particularly in paint shops for parts coating. The relevance of the study is driven by the need to enhance air purification efficiency, ensure worker safety, and comply with environmental regulations. The paper analyzes adaptive control methods, including the use of neural networks, machine learning, and adaptive control algorithms, which enable real-time optimization of purification systems. Special attention is given to the utilization of sensor data for predicting pollution levels and automatically adjusting purification parameters. The article also discusses the advantages and limitations of implementing adaptive …
Algorithms For Making Control Systems Based On Neural Network Technology To Automate Dynamic Plants, Jasur Sevinov, Abdishukurov Maqsudovich Shavkat
Algorithms For Making Control Systems Based On Neural Network Technology To Automate Dynamic Plants, Jasur Sevinov, Abdishukurov Maqsudovich Shavkat
Chemical Technology, Control and Management
This paper examines the stages of multilayer neural network technology for the control and identification of dynamic systems. It is seen many ways to use multilayer neural networks in control systems. Neural controllers are based on several models and algorithms. Examples of such algorithms include the predictive model-based control algorithm, the Narma-L2 control algorithm, and the benchmark model-based control algorithm. These controllers illustrate various general ways to use multilayer neural networks in control systems. Common, standard linear control architectures have been proposed for many neural controllers.
Data-Driven Constrained Control, Ali Kashani
Data-Driven Constrained Control, Ali Kashani
Mechanical Engineering ETDs
Ensuring safety is a fundamental challenge. Traditional methods often rely on precise mathematical models, which are difficult, impractical, or costly to obtain for real-world systems with complex, nonlinear dynamics. This dissertation develops direct data-driven control approaches that enable safe and efficient operation of nonlinear systems without requiring explicit models or performing system identification. This effort leverages machine learning, optimization, and control theory to bridge theoretical rigor and practical applicability. Deterministic guarantees are provided based on the Lipschitz continuity of the system, and probabilistic guarantees through scenario optimization. The computation of safe sets is performed using one-shot approaches with broad neural …
Advancements In Refreshable Braille Display Technology: A Comprehensive Survey, Maryam Etezad, Rajeev Joshi, Franceli L. Cibrian
Advancements In Refreshable Braille Display Technology: A Comprehensive Survey, Maryam Etezad, Rajeev Joshi, Franceli L. Cibrian
Engineering Faculty Articles and Research
This paper provides a comprehensive mapping literature review of the advancements in refreshable Braille display (RBD) technology, which employs dynamically movable pins or dots to render Braille characters for individuals with blindness and visual impairment. This literature review, which includes 96 papers, aims to summarize the current evidence on six distinct types of RBDs: piezoelectric, electromagnetic, electroactive polymer (EAP), pneumatic, shape memory alloy (SMA), and microfluidic technologies. For each type, we discuss the underlying mechanisms, alongside the current trends and research opportunities. This comparative analysis aims to inform the selection of appropriate RBD technology based on specific user needs and …
Fabrication Of A Pineapple Peeling Machine And Performance Evaluation As Influenced By Pineapple Dimensions, Dare E. Ibiyeye, Olusegun J. Adedipe, Oluwole S. Ariwoola, Taiye R. Afolabi, Funmilayo B. Okanlawon, Paul O. Ogunbamowo, Afolake E. Roberts
Fabrication Of A Pineapple Peeling Machine And Performance Evaluation As Influenced By Pineapple Dimensions, Dare E. Ibiyeye, Olusegun J. Adedipe, Oluwole S. Ariwoola, Taiye R. Afolabi, Funmilayo B. Okanlawon, Paul O. Ogunbamowo, Afolake E. Roberts
Journal of Bioresource Management
A pineapple peeling machine was completed, and the functionality was. The Central composite rotate strategy CCRD involving three variables at five (5) stages was employed for the investigations plus the investigational variables been weight, diameter and height of pineapple, while weights of peeled pineapple and peel, machine peeling time and efficiency were the dependent variables. Data was analysed using quadratic interaction regressions model at P ≤ 0.05 levels of significance, then the working variables were correlated to the pineapple machine peeling efficiency. The investigational outcomes were applied to confirm the predicted optimal settings. Maximal pineapple peeling efficacy of 91.89 % …
The Dynamics Of Word-Of-Mouth Marketing: An Agent-Based Modeling Approach To Message Credibility And Consumer Engagement, Ali Nasirzonouzi, Carlos Gershenson
The Dynamics Of Word-Of-Mouth Marketing: An Agent-Based Modeling Approach To Message Credibility And Consumer Engagement, Ali Nasirzonouzi, Carlos Gershenson
Northeast Journal of Complex Systems (NEJCS)
Word-of-mouth (WOM) marketing is a critical factor in the dissemination of information and adoption of products in social networks. This paper investigates the impact of two important factors message credibility and consumer engagement on WOM adoption dynamics using agent-based modeling (ABM). This study proposes a simple qualitative model to investigate how these factors influence adoption rates through both broadcast communication and peer-to-peer influence by simulating interactions on a spatially clustered network.
The findings show that increased message credibility significantly boosts adoption, achieving a balance between broadcast and social mechanisms. Also, consumer engagement primarily affects the adoption mechanism, shifting the effect …
Carbon Efficiency Of Natural Organic Honey-Memristor Based Neuromorphic Computing, Harshvardhan Uppaluru, Zoe Templin, Shah Zayed Riam, Feng Zhao, Jinhui Wang
Carbon Efficiency Of Natural Organic Honey-Memristor Based Neuromorphic Computing, Harshvardhan Uppaluru, Zoe Templin, Shah Zayed Riam, Feng Zhao, Jinhui Wang
Electrical and Computer Engineering Faculty Research & Creative Works
Natural organic memristors manufactured using honey have exhibited promising synaptic behavior, offering notable advantages such as environmental sustainability, low production and disposal costs, non-volatile storage capabilities, and bio/CMOS compatibility. In this paper, experimental evaluations of honey-memristor based neuromorphic systems are reported with a focus on estimating their carbon footprint. First, manufacturing and testing of honey-memristors is briefly described. To suppress variations and improve accuracy, an optimization technique - parallel memristors is applied. Experimental results indicate that this optimization method significantly improves the device performance of up to. However, it also leads to higher energy consumption and a higher carbon footprint …
Magnetic Nanoparticles: Synthesis And Applications In Life Sciences, Kishore Chand, Erick Salvador Vasquez
Magnetic Nanoparticles: Synthesis And Applications In Life Sciences, Kishore Chand, Erick Salvador Vasquez
Chemical and Materials Engineering Faculty Publications
Magnetic nanoparticles (MNPs) are multifunctional materials with superparamagnetic properties and tunable surface chemistries, making them valuable across diverse fields, such as biomedicine, environmental remediation, and agriculture. This review examines recent advancements in MNP synthesis, encompassing chemical, physical, and environmentally friendly methods while highlighting improvements in size, morphology, and composition control that enhance application-specific performance and environmental sustainability. The review discusses various architectures, including single-core, core–shell, hybrid composites, and stimuli–responsive systems, with an emphasis on their stability, scalability, and functionalization potential. In biomedical applications, MNPs show promise in targeted drug delivery, magnetic hyperthermia, and magnetic resonance imaging contrast enhancement, where biocompatibility, …
Vacuum Consistent Electrochemistry In Ionic Liquid Combined With Oxide Epitaxy, Yuji Matsumoto
Vacuum Consistent Electrochemistry In Ionic Liquid Combined With Oxide Epitaxy, Yuji Matsumoto
Journal of Electrochemistry
We introduce our state-of-the art of “vacuum consistent electrochemistry” to an investigation of the interfaces between oxides and ionic liquid (IL). Pulsed laser deposition (PLD) has been one of the powerful and sophisticated techniques to realize nanoscale preparation of high-quality epitaxial oxide thin films. On the other hand, electrochemistry is a simple, very sensitive, and non-destructive analysis technique for solid-liquid interfaces. To ensure the reproducibility in experiment of the interfaces of such epitaxial oxide films, as well as bulk oxide single-crystals, with IL, we employ a home-built PLD-electrochemical (EC) system with IL as an electrolyte. The system allows one to …
Pm Irras Studies Of Organized Molecular Films At A Gold Electrode Surface, Zhang-Fei Su, Ai-Cheng Chen, Jacek Lipkowski
Pm Irras Studies Of Organized Molecular Films At A Gold Electrode Surface, Zhang-Fei Su, Ai-Cheng Chen, Jacek Lipkowski
Journal of Electrochemistry
This feature article illustrates the potential of polarization modulation infrared reflection absorption spectroscopy (PM IRRAS) to provide molecular-level information about the structure, orientation and conformation of constituents of thin films at electrode surfaces. PM IRRAS relies on the surface selection rules stating that the p-polarized IR beam is enhanced, while the s-polarized beam is attenuated at the metal surface. The difference between p- and s-polarized beams eliminates the background of the solvent and provides IR spectra at a single electrode potential. In contrast, two other popular in situ IR spectroscopic techniques, namely, subtractively normalized interfacial Fourier transform infrared spectroscopy (SNIFTIRS) …