Engineering Commons^™

An Stm Study On The Structure Of Pt(100)/Ionic Liquid Omipf6 Interface, Jin Peng, Mian-Gang Li, Li-Qiang Xie, Jia-Wei Yan, Bing-Wei Mao

Journal of Electrochemistry

Potential-dependent structures of Pt(100)/ionic liquid 1-methyl-3-octylimidazolium hexafluorophosphate (OMIPF₆) interface have been studied by electrochemical scanning tunneling microscopy (ECSTM). The cation OMI⁺ forms ordered structure on Pt(100) surface, which exists in a potential region of about 1.2 V. When the potential is more negative than -0.6 V, it can be seen that the ordered structure transforms to disordered structure. When the potential shifts positively to +0.6 V, the desorption of cations OMI⁺ occurs, which indicates that strong electrostatic repulsion is needed to overcome chemical interaction between OMIPF6 and Pt(100) surface, leading to the desorption. The above results …

A Study On The Oxidation Of Hydrogen Peroxide At Au(111) And Au(100) Electrodes, Yong-Li Zheng, Jie Wei, Yan-Xia Chen

Journal of Electrochemistry

The oxidation reactions of hydrogen peroxide (H₂O₂) at Au(111) and Au(100) electrodes in 0.1 mol·L^-1 HClO₄ were investigated by using rotating disk electrode system. It was found that H₂O₂ could be readily oxidized to O₂ at both Au(100) and Au(111) surfaces with the onset potential close to its equilibrium potential. In contrast, the onset overpotential for H₂O₂ reduction was above 0.4 V, while the onset overpotential for H₂O₂ oxidation at Au(100) was ca. 0.1 V more negative than that at Au(111), this is probably …

Stability And Interfacial Viscoelasticity Of Oil-Water Nanoemulsions Stabilized By Soy 2 Lecithin And Tween 20 For The Encapsulation Of Bioactive Carvacrol, Jerome J. Nash, Kendra Erk

School of Materials Engineering Faculty Publications

The rheology of oil-in-water (O/W) droplet interfaces stabilized by food-grade emulsifiers (soy lecithin or Tween 20) under controlled aqueous conditions was investigated to elucidate its contribution in the kinetic stabilization of nanoemulsion-based delivery systems containing carvacrol, a naturally-derived antimicrobial compound. Dilational rheology of surfactant-laden O/W interfaces was measured using axisymmetric drop shape analysis. The kinetic stability of corresponding nanoemulsions (containing mixtures of carvacrol and medium-chain triglyceride (MCT) oil dispersed in water (pH 7)) was characterized using dynamic light scattering. Zwitterionic lecithin molecules adsorbed to the O/W interface for 24 h formed a notably viscoelastic layer, compared to nonionic Tween 20 …

Stm Investigation Of Oxygen Reduction Reaction On Solid Interface In Fuel Cell, Zhen-Feng Cai, Bing Sun, Wen-Jie Jiang, Ting Chen, Dong Wang, Li-Jun Wan

Journal of Electrochemistry

An electrocatalyst for oxygen reduction reaction (ORR) is an important component for fuel cells. An investigation at interfacial electrochemical reactions toward ORR at a molecular scale benefits mechanistic understanding as well as rational design of catalysts. Scanning tunneling microscopy (STM) has been proven to be a powerful tool to monitor chemical reactions and to provide in-situ information about the interfacial electrochemical reactions at a molecular level. This review summarizes the recent STM studies in monitoring the interface processes such as morphological changes, molecular changes, reaction intermediates, and oxidation products. The prospects of future development in this field are outlined.

Chitosan/Nonahydrate Gel Derived Fe-N-Doped Porous Carbon Sheet As High-Efficient Orr Electrocatalyst, Fan-Lu Meng, Xin-Bo Zhang, Jun-Min Yan

Journal of Electrochemistry

The chitosan/nonahydrate gel was used as a precursor to realize the uniform mixture of N-polymer and metal salt. After lyophilization treatment, the gel went through heat treatment and acid etch. Accordingly, the Fe-N-doped porous carbon sheet with homogenous composition and microstructure was prepared. Compared with the commercial Pt/C catalyst, the Fe-N-doped porous carbon sheet exhibited more positive onset potential and half-wave potential, higher current density, and especially, excellent durability. The power density of 318 mW·cm^-2 was obtained in alkaline fuel cell with the Fe-N-doped porous carbon sheet as a cathode catalyst, which is higher than 267 mW·cm^-2 with …

Synthesis Of Ultrathin Co3O4 Nanoflakes Film Material For Electrochemical Sensing, Hui-Juan Wang

Journal of Electrochemistry

Ultrathin cobalt oxide (Co₃O₄) nanoflakes film material was synthesized by using an electro-deposited cobalt layer as a raw material through a simple oxidation method and followed by a heat treatment at 350 ^oC. The physical characterizations of the Co₃O₄ nanoflakes film were performed by scanning electron microscopy (SEM), X-ray diffraction (XRD) and transmission electron microscopy (TEM) technologies, and the electrochemical activity was measured by cyclic voltammetry (CV). As a promising material for electrochemical sensing, the as-synthesized ultrathin Co₃O₄ nanoflakes film material exhibited excellent electrochemical activity for H₂O …

Lithium-Sulfur (Selenium) Batteries: Interface Issues And Solving Strategies, Nian-Wu Li, Ya-Xia Yin, Yu-Guo Guo

Journal of Electrochemistry

The stable interface is still a challenge for lithium-sulfur (selenium) batteries because of the low conductivity of sulfur (selenium), dissolution of polysulfide (polyselenide), volume expansion of sulfur (selenium), and lithium dendrite growth. This review describers some recent developments in lithium-sulfur (selenium) batteries and highlights our efforts in this field. The possible strategies for building stable interface in the lithium-sulfur (selenium) batteries including nano-restriction effect, chemical bonding, interface adsorption, surface coating, electrolyte optimization, and Lithium anode treatment have been discussed.

Hydrogen Evolution Properties On Individual Mos2 Nanosheets, Yu Gao, Juan Zhou, Yu-Wen Liu, Sheng-Li Chen

Journal of Electrochemistry

Molybdenum disulfide (MoS₂) has been acknowledged to play important roles in hydrogen evolution reaction (HER) for hydrogen energy technology. Both computational and experimental results have suggested that the promising catalytic activity of MoS₂ for the HER could be attributed to the sulfur edges of two-dimensional nanosheets, while their basal planes were catalytically inert. In order to verify this conclusion, we prepared single MoS₂ sheet electrodes which were made of individual MoS₂ sheets attached on the self-assembly monolayers (SAM) of SH(CH₂)₁₅COOH at Au ultramicroelectrodes (Au/SAM/MoS₂). The single MoS₂ sheet …

Electrochemical Behaviors And Determinations Of Terbutaline Sulfate At Poly Eriochrome Black T Modified Electrode, Yan-Jie Zheng, Hong Yao, Shao-Huang Weng, Hua-Ping Peng, Shi-Wen Gong, Li Huang, Qiang Dai, Xin-Hua Lin

Journal of Electrochemistry

The poly eriochrome black T modified electrode was prepared by electropolymerization. This modified electrode was characterized by scanning electron microscopy(SEM), electrochemical impedance spectroscopy(EIS) and cyclic voltammetry (CV). The electrochemical behaviors of terbutaline sulfate were studied by CV, while the recoveries were measured by differential pulse voltammetry (DPV). The modified electrode shows excellent electrocatalytic characteristics for terbutaline sulfate. In pH 7.0 phosphate buffer solution, the oxidation peak currents obtained by DPV were linear to the terbutaline sulfate concentrations over the range of 1.2x10^-7~2.0x10^-6 mol•L^-1. The detection limit was estimated to be 1.5x10^-8  mol•L^-1 and …

Lithium Plating Identification From Degradation Behaviors Of Lithium-Ion Cells, Jian-Bo Zhang, Lai-Suo Su, Xin-Yu Li, Hao Ge, Ya-Kun Zhang, Zhe Li

Journal of Electrochemistry

Lithium plating has huge impact on the lifetime and safety of lithium-ion cells. It is, therefore, necessary to identify lithium plating. In this study, the accelerated stress tests of lithium-ion cells were conducted under different conditions with multi-stress loads. Based on the different effects of the two major aging mechanisms, namely, SEI (Solid Electrolyte Interface) layer growth and lithium plating, on the degradation behaviors, two lithium plating identification methods of resistance-capacity plot and Arrhenius plot were employed. The experimental results revealed that the two identification methods are highly consistent with each other. Furthermore, the origins of capacity loss were distinguished …

Intrinsic Interfacial Property Between High-Voltage Lini0.5Mn1.5O4 Cathode And Electrolyte, Li Li, Jing-Jing Xu, Shao-Jie Han, Wei Lu, Li-Wei Chen

Journal of Electrochemistry

To obtain high energy density, developing high-voltage cathode materials is an effective approach. The cathode/electrolyte interface stability is the key factor for the cycle performance and safety performance of high-voltage lithium ion batteries. It is, therefore, of significant importance to study the stability of cathode/electrolyte interface. However, many reports have shown that at the cathode/electrolyte interface the cathodes were prepared by coating the mixture of active materials with a conductive additive and a binder on an Al current collector. The introduction of additives will interfere the surface morphology and component analyses, resulting in difficulty to acquire the intrinsic information at …

Shear Driven Micro-Fluidic Pump, Nihad E. Daidzic

Aviation Department Publications

United States Patent, Patent Number US 9,528,503 B2, Date of Patent December 27, 2016.

An example includes an apparatus to pump a fluid. The apparatus includes a housing extending along a length defining an elongate interior, an actuator in the housing, conforming to the elongate interior, the actuator including a plurality of lumens, each having a length extending substantially parallel to the elongate interior, each from around 10 to 200 micrometers across and an actuator configured to oscillate the actuator in the actuator houslng along the length of the elongate interior with a rate differential between movement in a first …

Viscous Sealing Glass Compositions For Solid Oxide Fuel Cells, Cheol-Woon Kim, Richard K. Brow

Nuclear Engineering and Radiation Science Faculty Research & Creative Works

A sealant for forming a seal between at least two solid oxide fuel cell components wherein the sealant comprises a glass material comprising B₂O₃ as a principal glass former, BaO, and other components and wherein the glass material is substantially alkali-free and contains less than 30% crystalline material.

Usu Engineering Faculty Receives Prestigious Nsf Career Grant | College Of Engineering, Usu College Of Engineering

College of Engineering News

News Release – Dec. 26, 2016 – A Utah State University professor who specializes in the emerging field of engineering education has been selected to receive a major grant from the National Science Foundation for her ongoing research into improving engineering teaching practices.

Table Of Contents

International Journal of Nuclear Security

No abstract provided.

From The Editor’S Desk

International Journal of Nuclear Security

No abstract provided.

Opportunities And Challenges In Developing Nuclear Security In Africa, James Larkin Mfr

International Journal of Nuclear Security

Those involved in nuclear security recognize that regions of significant instability in Africa have an impact on the safety and security of the continent's nuclear material and un-enriched uranium; however, some countries outside of continental Africa have taken counterproductive approaches to this issue. Despite challenges, the nuclear security community continues to develop and apply appropriate levels of nuclear security where needed. The community also takes every opportunity to make significant contributions to the global discourse on nuclear security culture.

Legal And Regulatory Framework Of Nuclear Security In Indonesia, Dahlia Cakrawati Sinaga

International Journal of Nuclear Security

Nuclear security is one of the most important topics for regulatory purposes in Indonesia. Nuclear security measures exist to prevent, detect, and respond to unauthorized removal of radioactive material and the sabotage of nuclear and radiation facilities. Indonesia participates in bilateral and multilateral cooperation and international events such as the Nuclear Security Summit. Indonesia has also ratified several international instruments related to nuclear security. Based on commitment to international events and ratification, Indonesia has developed nuclear security infrastructures by strengthening legislation and regulation, enhancing building capacity, and strengthening equipment and facilities. Badan Pengawas Tenaga Nuklir (BAPETEN) is Indonesia’s nuclear energy …

Nuclear Security Risk Analysis: An Insider-Outsider Collusion Scenario, Mohammad A. Hawila, Sunil S. Chirayath

International Journal of Nuclear Security

This study analyses the vulnerability of the physical protection system (PPS) deployed at a hypothetical facility. The PPS is designed to prevent and eliminate threats to nuclear materials and facilities. The analysis considers possible outsider and insider threats. A modified adversary sequence diagram (ASD) evaluates threat pathways to test an insider-outsider collusion case. The ASD also measures the probability of adversary interruption by demonstrating the methodology for a typical nuclear facility.

Nuclear Security Culture And Batan’S Assessment: Batan’S Experience, Anhar R. Antariksawan

International Journal of Nuclear Security

Organizations should increase safety to minimize the harmful effects of nuclear materials. Additionally, organizations should take measures to protect security culture within the organization itself. This paper covers the National Nuclear Energy Agency of Indonesia’s (BATAN’s) promotion of nuclear security culture and self- assessment projects, which is based on the International Atomic Energy Agency’s (IAEA) methodology.

Modified Fault Tree Method For Vulnerability Analysis Of Nuclear Medicine Facility Security System Case Study: Radiotherapy Facility, Sardjito General Hospital, Haryono Budi Santosa

International Journal of Nuclear Security

Assessing the vulnerability of physical protection systems (PPS) in nuclear medicine facilities is needed to prevent a security incident that could lead to the malicious use of nuclear material. Theft and sabotage of nuclear materials is becoming globally recognized. The current methods of assessing vulnerability tend to be oriented toward complex nuclear security; consequently, it is excessive to use such methods in simple facilities (i.e., radiotherapy facilities in hospitals).

The fault tree analysis is a method to assess vulnerability for a simple nuclear facility. The method’s primary events (i.e., basic events and undeveloped events) are able to accommodate fault causes …

A Novel Method For Sensorless Speed Detection Of Brushed Dc Motors, Ernesto Vazquez-Sanchez, Joseph Sottile, Jaime Gomez-Gil

Mining Engineering Faculty Publications

Many motor applications require accurate speed measurement. For brushed dc motors, speed can be measured with conventional observers or sensorless observers. Sensorless observers have the advantage of not requiring any external devices to be attached to the motor. Instead, voltage and/or current are measured and used to estimate the speed. The sensorless observers are usually divided into two groups: those based on the dynamic model, and those based on the ripple component. This paper proposes a method that measures the current of brushed dc motors and analyses the position of its spectral components. From these spectral components, the method estimates …

Effects Of Transportation Hazards On High Barrier Flexible Packaging Films, Kyle Dunno

Journal of Applied Packaging Research

Two flexible food packaging barrier material film structures were employed for this research study to evaluate the effects of over-the-road truck transport. The films containing different barrier materials, ethylene-vinyl alcohol (EVOH) or aluminum oxide (AlOx), were selected based on their abundant use within the flexible food packaging arena. Pouches were formed and filled with tomato paste before being thermally processed then palletized for shipment. Pouches were shipped over-the-road via truck transport a distance of 2,500 miles. After transport, the oxygen transmission rate (OTR) of the pouches located on the bottom and top layers of the palletized loads were obtained and …

Mannequin Challenge | Biological Engineering, Usu College Of Engineering

College of Engineering News

Who says that learning about the various properties of Biomaterials is boring? Clearly, they haven't taken Dr. Yu Huang's BENG 2330 Properties of Biomaterials course. Not only do these students know how to distinguish the differences between natural and synthetic biomaterials.They know how to have a good time bringing the mannequin challenge into their lab clean up.

Experimental And Numerical Study Of Dysphagia, Yash G. Potdar

Masters Theses

Dysphagia, meaning difficulty in swallowing, is a symptom of disease that occurs in young children and elderly people. It occurs particularly due to two reasons, weak neural network and/or deformities in oral section/s. The Helen DeVos Children’s Hospital’s Intensive Feeding Program takes care of children suffering from Dysphagia. In order to make the swallowing process easier and in some cases safer, thickener is added to the liquids. Depending on the requirement of thickness, the amount of thickener is varied. Although the directions to prepare the mixtures are given by the thickener product company, the required thickness is not achieved when …

Landfill Elevated Internal Temperature Detection And Landfill Fire Index Assessment For Fire Monitoring, Aurora Musilli

Theses and Dissertations

Landfill fires are becoming a real threat to both people and environment due to lack of predictions and control methods. Processing of the infrared band from level-1 satellite images was employed and decades worth of archived data from USGS Earth Explorer databases were analyzed to obtain surface temperature values of Atlantic Waste Landfill, Virginia and Bridgeton Landfill, Missouri. Multitemporal thermal maps and frequency of maxima analysis maps of these two landfills showed the hotspots spreading through the waste site. A Landfill Fire Index (LFI) was created by investigating eight factors that give information about the hazardousness of the landfill conditions …

Integrated Circuit Wear-Out Prediction And Recycling Detection Using Radio-Frequency Distinct Native Attribute Features, Randall D. Deppensmith

Theses and Dissertations

Radio Frequency Distinct Native Attribute (RF-DNA) has shown promise for detecting differences in Integrated Circuits(IC) using features extracted from a devices Unintentional Radio Emissions (URE). This ability of RF-DNA relies upon process variation imparted to a semiconductor device during manufacturing. However, internal components in modern ICs electronically age and wear out over their operational lifetime. RF-DNA techniques are adopted from prior work and applied to MSP430 URE to address the following research goals: 1) Does device wear-out impact RF-DNA device discriminability?, 2) Can device age be continuously estimated by monitoring changes in RF-DNA features?, and 3) Can device age state …

Spacex: Breaking The Barrier To The Space Launch Vehicle Industry, Matthew M. Liskowcyz

Theses and Dissertations

The Space Launch Vehicle (SLV) industry has been around for a long time, but few companies have managed to enter this industry. SpaceX was founded only 10 years ago, but it has managed to become a leader in the U.S. industry and a dominant player worldwide. The purpose of this thesis research is to discover what it took for SpaceX to break into this tightly controlled industry. A qualitative analysis was performed to compare SpaceX to companies that overcame the barriers of entry for their respective industries. SpaceX, like FedEx, could implement a unique technique to the industry and find …

Electrical & Computer Engineering News, Georgia Southern University

Electrical & Computer Engineering: News & Publications (2014-2023)

• Lim receives Biomedical Seed Grant with Augusta University to Improve Sleep Quality Monitoring for Patients with Parkinson's Disease

Overexpression Of Timp-3 In Chondrocytes Produces Transient Reduction In Growth Plate Length But Permanently Reduces Adult Bone Quality And Quantity, Blandine Poulet, Ke Liu, Darren A. Plumb, Phoung Vo, Mittal Shah, Katherine Ann Staines, Alexandra Sampson, Hiroyuke Nakamura, Hideaki Nagase, Alessandra Carriero, Sandra J. Shefelbine, Andrew A. Pitsillides, George Bou-Gharios

Biomedical Engineering and Sciences Faculty Publications

Bone development and length relies on the growth plate formation, which is dependent on degradative enzymes such as MMPs. Indeed, deletion of specific members of this enzyme family in mice results in important joint and bone abnormalities, suggesting a role in skeletal development. As such, the control of MMP activity is vital in the complex process of bone formation and growth. We generated a transgenic mouse line to overexpress TIMP3 in mouse chondrocytes using the Col2a1-chondrocyte promoter. This overexpression in cartilage resulted in a transient shortening of growth plate in homozygote mice but bone length was restored at eight weeks …