Engineering Commons^™

Far-Field Optical Microscopy Based On Stimulated Emission Depletion, Yunxia Wang

Theses and Dissertations

Conventional lens-based (far-field) fluorescence microscopy is a widely used imaging technique with spatial resolution up to 150–350 nm. However, this technology cannot discern very small structural features, because the spatial resolution is limited by diffraction to about half of the wavelength of light (λ/2，λ is the wavelength of light). Hence, most of the developments in microscopy aim at improving resolution. In the past decades, stimulated emission depletion (STED) microscopy has been developed to bypass the diffraction limit for the application in biological imaging with resolution approaching the nanoscale. The basic principle of STED microscopy is to employ a doughnut-shape laser …

Wideband Low Side Lobe Aperture Coupled Patch Phased Array Antennas, Dhruva Poduval

Theses and Dissertations

Low profile printed antenna arrays with wide bandwidth, high gain, and low Side Lobe Level (SLL) are in great demand for current and future commercial and military communication systems and radar. Aperture coupled patch antennas have been proposed to obtain wide impedance bandwidths in the past. Aperture coupling is preferred particularly for phased arrays because of their advantage of integration to other active devices and circuits, e.g. phase shifters, power amplifiers, low noise amplifiers, mixers etc. However, when designing such arrays, the interplay between array performance characteristics, such as gain, side lobe level, back lobe level, mutual coupling etc. must …

An Application Of Dempster-Shafer Fusion Theory To Lithium-Ion Battery Prognostics And Health Management, John Weddington

Theses and Dissertations

Prognostics and Health Management (PHM) is the discipline involving diagnostics and prognostics of components or systems, with the primary objective of increasing the overall reliability and safety of these components or systems. PHM systems convert raw sensor data into features, and utilize state observers to estimate the current damage state online. Popular state observers are the traditional Kalman filter, along with its non-linear extensions, and the particle filter. Each technique has differing advantages. This thesis investigates the fusion of results from different techniques in order to achieve a more trustworthy probability of detection (PoD) during diagnosis and a more reliable …

Promotional Effect Of Molten Carbonates On Proton Conductivity And Oxygen Reduction Reaction – An Experimental And Computational Study, Xiaolei Xiong

Theses and Dissertations

Recent research of Solid oxide fuel cells (SOFCs) is aimed to lower the operating temperature to an intermediate temperature (IT) range of 500 to 700^oC, while maintaining a proper performance. This Ph.D. research project investigates the promotional effects of alkaline carbonate eutectics on the proton conductivity of proton conducting electrolytes and cathodic ORR reactivity in SOFCs by both experimental and computational methods. The ionic conductivity of the MC-BZY composite above 500^oC increases with the higher loading of MC. The sample exhibited nearly a factor of two higher conductivity in H₂-containing atmosphere than in air. …

High Quality Low Offcut 4h-Sic Epitaxy And Integrated Growth Of Epitaxial Graphene For Hybrid Graphene/Sic Devices, Anusha Balachandran

Theses and Dissertations

Power electronic semiconductor devices are critical components in next-generation power systems such as hybrid electric vehicles and smart grid power controls enabling reduction in system size, weight, and cost. Wide bandgap materials such as SiC, GaN, and diamond have been investigated to replace silicon, due to their superior material properties. Of these, 4H-SiC is considered the most viable candidate beyond 3kV due to its technological maturity, its wide band gap (3.23 eV), high breakdown field (4×106 V/cm), high thermal conductivity (5 W/cm/K) and, more importantly, its indirect bandgap.

The main contribution of my research relates to the development and investigating …

Investigating The Feedstock Properties And Process Conditions Influencing The Characteristics Of Products Generated From The Hydrothermal Carbonization Of Organic Feedstocks, Liang Li

Theses and Dissertations

Hydrothermal carbonization (HTC) is a novel environmentally beneficial thermal conversion process for the transformation of organic feedstocks to value-added products. However, little is known about the role of feedstock properties and/or process conditions during carbonization. This study was conducted to determine the parameters most influential during the HTC of organic feedstocks. Experiments and statistical analyses were conducted to: (1) determine the effect of specific feedstocks, feedstock interactions, and process conditions on carbonization product characteristics; (2) understand how initial liquid characteristics influence product characteristics and evaluate the significance of these initial liquid characteristics in predicting product characteristics; and (3) develop statistical …

Reducing Model Selection Computational Cost By Metamodeling The Evidence, Ramin Madarshahian

Theses and Dissertations

Modeling is an abstraction of reality that lets a designer or engineer perform simulations with a “real” object or structure without testing it physically. However, the result of simulations is as good as their models. Selecting the best model among many candidates is another challenge.

Complex models could translate into more accurate predictions, but they also require larger computational effort. The Bayes factor is often used to compare different models considering the data and analyst’s experience. To obtain the Bayes factor, the Bayesian model evidence is calculated; however, calculating the Bayesian model evidence of computationally expensive models is not a …

Study Of Mos2 And Graphene-Based Heterojunctions For Electronic And Sensing Applications, Ifat Jahangir

Theses and Dissertations

Since the discovery of graphene, there has been an increase in two-dimensional (2D) materials research for their scalability down to atomic dimensions. Among the analogs of graphene, transition metal dichalcogenides (TMDs) are attractive due to their exceptional electronic and optoelectronic properties. MoS2, a TMD, has several advantages over graphene and the industry workhorse Si, and has been reported to demonstrate excellent transistor performances. The key obstacle in the commercialization of MoS2 technology is low carrier mobility over large areas for top-down devices. Although there were several early reports on synthesis of atomically thin MoS2 with moderate mobility, transferring large area …

Distributed Optimization Method For Intelligent Control Of Dc Microgrids, Yuanyuan Fan

Theses and Dissertations

Most of the distributed energy resources, loads and energy storage systems in a DC microgrid are equipped with power electronic converters. With the integration of advanced power electronics devices, a microgrid is able to utilize a broader range of technologies in its design and operation. A key feature of power electronic converter based systems is the ability to direct energy flow within a system with their coordinated operation. A system level control is needed for coordination where converters execute reference points dictated by a system-level control in order to achieve system level goals. System goals can be expressed as a …

Theoretical Investigation Of The Catalytic Hydrodeoxygenation Of Levulinic Acid Over Ru (0001) Catalyst Surface, Osman Mamun

Theses and Dissertations

Due to the rapidly declining fossil fuel reserves and the onset of global climate change, the development of active, selective, and stable catalytic materials for the efficient production of biomass derived platform chemicals, i.e., levulinic acid (LA), succinic acid (SA), γ-valerolactone (GVL) etc., is receiving considerable attention in order to produce second generation biofuels and commodity chemicals. Though solid lignocellulosic biomass is significantly cheaper than petroleum; however, the available technology is the significant barrier for large scale utilization of biomass for the production of biofuels. The development of biomass conversion technology requires, 1) identification of potential biomass chemicals that can …

Nondestructive Evaluation And Health Monitoring Of Adhesively Bonded Composite Structures, William Walker Roth

Theses and Dissertations

As the growth of fiber reinforced composite materials continues in many industries, structural designers will have to look to new methods of joining components. In order to take full advantage of composite materials, such as increased stiffness, decreased weight, tailored material properties and increased fatigue life, mechanical fasteners will need to be replaced by adhesive bonding or welding, when possible. Mechanical fasteners require the drilling of holes, which damages the laminate and becomes the source of further fatigue damage. Also, an increase in laminate thickness or inclusion of other features is required for the material to withstand the bearing stress …

Mechanical Characterization And Non-Destructive Evaluation Of Sicf-Sicm Composite Tubing With The Impulse Excitation Technique, Nathaniel Truesdale

Theses and Dissertations

With growing interest on ceramic fiber reinforced ceramic matrix composites (CMC) for accident tolerant fuel, the need for mechanical characterization of ceramic composite arises. It has been of particular interest to non-destructively evaluate the mechanical performance of these composites. Impulse excitation (IE) is a well-established method for non-destructive mechanical characterization of homogeneous isotropic material of well-defined shapes. In this thesis, impulse excitation technique was applied for non-destructive characterization of composite tube for the first time as far as we know. CMC, when stressed beyond its damage threshold, will experience various forms of structural damage, such as matrix micro-cracking, fiber-matrix debonding, …

Improving The Performance And Time-Predictability Of Gpus, Yijie Huangfu

Theses and Dissertations

Graphic Processing Units (GPUs) are originally mainly designed to accelerate graphic applications. Now the capability of GPUs to accelerate applications that can be parallelized into a massive number of threads makes GPUs the ideal accelerator for boosting the performance of such kind of general-purpose applications. Meanwhile it is also very promising to apply GPUs to embedded and real-time applications as well, where high throughput and intensive computation are also needed.

However, due to the different architecture and programming model of GPUs, how to fully utilize the advanced architectural features of GPUs to boost the performance and how to analyze the …

Investigation Of Polymeric Composites For Controlled Drug Release, Hsi-Wei Yeh

Theses and Dissertations

The Electrospray (ES) technique is a promising particle generation method for drug delivery due to its capabilities of producing monodisperse PLGA composite particles with unique configurations and high drug encapsulation efficiency. In the dissertation work, the coaxial dual capillary ES was used to generate drug-loaded core-shell PLGA particles to study the effects of particle filling materials, drug loading locations and particle shell thicknesses on the resultant in vitro release behaviors of the hydrophilic and/ or hydrophobic model drugs. Through release profile characterization of drug-loaded PLGA particles (particle size: 400 nm and 1 μm), it was confirmed that the co-encapsulation of …

Growth And Characterization Of Anisotropic Gase Semiconductor For Radiation Detection And Thz Applications, Haseeb Nazir

Theses and Dissertations

Anisotropic wide-bandgap gallium selenide (GaSe) crystals were grown using high purity (7N) Ga and zone refined (ZR) Se precursor materials. The crystal growth was performed using a modified vertical Bridgman method (VBM) with a slow crystallization from the melt and with a pre-determined temperature profile. The structure, surface morphology, and the composition of the grown crystals were characterized using x-ray diffraction (XRD), scanning electron microscopy (SEM), and energy dispersive analysis by x-rays (EDAX), respectively. Optical absorption and transmission properties were characterized and optical bandgap was determined. Electrical resistivity has been determined using current-voltage (I V) measurements using van der Pauw …

Blind Change Point Detection And Regime Segmentation Using Gaussian Process Regression, Sourav Das

Theses and Dissertations

Time-series analysis is used heavily in modeling and forecasting weather, economics, medical data as well as in various other fields. Change point detection (CPD) means finding abrupt changes in the time-series when the statistical property of a certain part of it starts to differ. CPD has attracted a lot of attention in the artificial intelligence, machine learning and data mining communities. In this thesis, a novel CPD algorithm is introduced for segmenting multivariate time-series data. The proposed algorithm is a general pipeline to process any high dimensional multivariate time-series data using nonlinear non-parametric dynamic system. It consists of manifold learning …

Bayesian Approach On Quantifying The Safety Effects Of Pedestrian Countdown Signals To Drivers, Angela E. Kitali

UNF Graduate Theses and Dissertations

Pedestrian countdown signals (PCSs) are viable traffic control devices that assist pedestrians in crossing intersections safely. Despite the fact that PCSs are meant for pedestrians, they also have an impact on drivers’ behavior at intersections. This study focuses on the evaluation of the safety effectiveness of PCSs to drivers in the cities of Jacksonville and Gainesville, Florida. The study employs two Bayesian approaches, before-and-after empirical Bayes (EB) and full Bayes (FB) with a comparison group, to quantify the safety impacts of PCSs to drivers. Specifically, crash modification factors (CMFs), which are estimated using the aforementioned two methods, were used to …

Finite Element Modeling Of The Plantar Fascia: A Viscohyperelastic Approach, Alexander Knapp

UNF Graduate Theses and Dissertations

The present work details the creation and analysis of a finite element model of the foot, wherein the plantar fascia was modeled as a viscohyperelastic solid. The objective of this work was to develop a fully functional CAD and Finite Element Model of the foot and plantar fascia for analysis by examining the transient stresses on the plantar fascia through the use of a viscohyperelastic material model. The model’s geometry was developed through the use of image processing techniques with anatomical images provided by the National Institutes of Health. The finite element method was used to analyze the transient response …

Pore Formation In Aluminum Castings: Theoretical Calculations And The Extrinsic Effect Of Entrained Surface Oxide Films, Pedram Yousefian

UNF Graduate Theses and Dissertations

Aluminum alloy castings are being integrated increasingly into automotive and aerospace assemblies due to their extraordinary properties, especially high strength-to-density ratio. To produce high quality castings, it is necessary to understand the mechanisms of the formation of defects, specifically pores and inclusion, in aluminum. There have been numerous studies on pore formation during solidification which lead to hot tearing and/or reduction in mechanical properties. However, a comprehensive study that correlates pore formation theory with in situ observations and modeling assumptions from the literature as well as experimental observations in not available. The present study is motivated to fill this gap. …

Anomaly Detection In Rfid Networks, Alaa Alkadi

UNF Graduate Theses and Dissertations

Available security standards for RFID networks (e.g. ISO/IEC 29167) are designed to secure individual tag-reader sessions and do not protect against active attacks that could also compromise the system as a whole (e.g. tag cloning or replay attacks). Proper traffic characterization models of the communication within an RFID network can lead to better understanding of operation under “normal” system state conditions and can consequently help identify security breaches not addressed by current standards. This study of RFID traffic characterization considers two piecewise-constant data smoothing techniques, namely Bayesian blocks and Knuth’s algorithms, over time-tagged events and compares them in the context …

Product Qualification And Performance Assessment Of Hsrm Prestressed Concrete Railroad Ties Through Laboratory Testing, Ali Haider Abdulqader

Theses and Dissertations

This study focuses on the performance assessment of prestressed concrete railroad ties made of a newly developed High Strength Reduce Modulus (HSRM) concrete. The HSRM material has been developed by researchers at the University of South Carolina laboratories. The HSRM material was originally considered as a high-performance concrete for highway bridge girders, but it was rejected because it shows very low modulus of elasticity. A current project at USC proposed to use this HSRM material in prestressed concrete railroad ties. The experimental tests during the material development phase of the project showed that the HSRM-HPC has a reduced Modulus of …

Fiber Optic Guided Wave Sensors For Structural Health Monitoring, Erik Frankforter

Theses and Dissertations

Risks and costs associated with aging infrastructure have been mounting, presenting a clear need for innovative damage monitoring solutions. One of the more powerful damage monitoring approaches involves using ultrasonic guided waves which propagate through a structure and carry damage-related information to permanently bonded sensors. Ultrasonic fiber-optic sensors are one of the most promising technologies for this application: they are immune to electromagnetic interference, present no ignition hazard, and transmit their data over tens of kilometers. However, before they can be widely employed, several limitations need to be overcome: poor sensitivity, unidirectional sensing, and loss of ultrasonic functionality due to …

Software Modelling For Real World Faults On Ac Transmission Protective Systems Analysis And Effects, Iandale Tualla

Theses and Dissertations

The Electric Power Utilities serves many diverse customers from regular households to major processing plants that develop parts for gasoline vehicles. Those varying customer usages has adverse effects on the Electric Grid in many ways, that requires continuing analysis by the engineers and technical skills specialists who keep the Electric Grid stable. Several papers have been written about harmonics and Non- Sinusoidal waveforms and its effect on the Electric Grid. This thesis will exam a realworld fault event on a transmission line, its effects on the AC Transmission Protection Systems (TPS) that provides electrical energy to a nonlinear load, specifically …

Multi-Model Structural Analysis, Wesley Holt

Theses and Dissertations

The uncertainty in modeling earthquake loading is investigated through the comparison of various openSEES models. A series of models is created and the responses compared with each other as well as with a full scale shake table experiment. The openSEES models selected for comparison include two linear models, a nonlinear model using the Steel01 material for the entire cross section, and eight fiber models using reinforcing steel material and various concrete materials.

The models are subjected to a series of nine simulated earthquakes, matching the excitations applied to the shake table test. It is found that all of the models …

Determination And Validation Of High-Pressure Equilibrium Adsorption Isotherms Via A Volumetric System, Hind Jihad Kadhim Shabbani

Theses and Dissertations

Adsorption equilibrium isotherms for N2, CO2, and CH4 on zeolite 13X were investigated at three different temperatures (25.5, 50.5 and 75.5 ̊ C) and a pressure range of (0-6.89475) MPa for CH4 and N2 and in the range of (0-4.82633) MPa for CO2 using built in volumetric apparatus. The results were validated using with a volumetric system (ASAP) at the same temperatures and a pressure up to (160-110) KPa respectively. The experimental results were correlated using three process Langmuir (TPLM). The correlated isotherms were then used to calculate the isosteric heat of adsorption for the three gases on 13X. The …

Stilbenes: Therapeutic Interventions Targeting Amyloid Β Protein Aggregation In Alzheimer’S Disease, Yiying Wang

Theses and Dissertations

Alzheimer’s disease (AD) is the most common form of dementia and accounts for 60-80 % of all dementia cases. In the United States, AD is ranked as the 6th leading cause of death and it is the only one among the top 10 that cannot be prevented, treated or even slowed. All FDA approved drugs focus on attenuating the symptoms for a limited time by regulating neurotransmitters without any intervention with the underlying disease process. A major player in the initiation and development of this debilitating disorder is the misfolding and subsequent aggregating of amyloid-β (Aβ) peptide. This aggregation process …

A Lebesgue Sampling Based Diagnosis And Prognosis Methodology With Application To Lithium-Ion Batteries, Wuzhao Yan

Theses and Dissertations

Fault diagnosis and prognosis (FDP) plays an important role in the modern complex industrial systems to maintain their reliability, safety, and availability. Diagnosis aims to monitor the fault state of the component or the system in real-time. Prognosis refers to the generation of long-term predictions that describe the evolution of a fault and the estimation of the remaining useful life (RUL) of a failing component or subsystem.

Traditional Riemann sampling-based FDP (RS-FDP) takes samples and executes algorithms in periodic time intervals and, in most cases, requires significant computational resources. This makes it difficult or even impossible to implement RS-FDP algorithms …

Atherosclerotic Plaque Adhesion Strength And Its Role In Plaque Rupture, Bilal Merei

Theses and Dissertations

Cardiovascular diseases are disorders affecting the blood vessels and the heart. According to the World Health Organization, cardiovascular diseases are one of the leading causes of death worldwide. They are responsible for over 17.1 million deaths per year worldwide, representing 31.5% of deaths 1, 2. Atherosclerosis, a chronic inflammatory disorder affecting large arteries, is the underlying cause of many cardiovascular diseases. Plaque rupture is a serious complication of advanced atherosclerosis, often leading to life-threatening clinical consequences such as myocardial infarction (heart attack) or stroke. 75% of newly developed myocardial infarction cases are caused by atherosclerotic plaque rupture. It affects approximately …

Improving Peptide Identification By Considering Ordered Amino Acid Usage, Ahmed Al-Qurri

Theses and Dissertations

Proteomics has made major progress in recent years after the sequencing of the genomes of a substantial number of organisms. A typical method for identifying peptides uses a database of peptides identified using tandem mass spectrometry (MS/MS). The profile of accurate mass and elution time (AMT) for peptides that need to be identified will be compared with this database. Restricting the search to those peptides detectable by MS will reduce processing time and more importantly increase accuracy. In addition, there are significant impacts for clinical studies. Proteotypic peptides are those peptides in a protein sequence that are most likely to …

Ultrathin Graphene Oxide Membranes For Water Purification: Fundamentals & Potential Applications, Weiwei Xu

Theses and Dissertations

To develop ultrathin GO membranes with both high permeation rate and excellent selectivity, it is essential to understand the interlayer nanostructure and its influence on water purification performance. We purposely deposited GO at a fast rate and at a rate ~12 times slower to control the interlayer nanostructure of the resulting membranes. The d-spacing difference between proposed thermodynamically favored interlayer structure which formed at slow deposition rate and another relative randomly packed interlayer structure formed at fast deposition rate were corroborated by XRD, organic vapor deposition, and AFM. Molecular dynamics simulations further confirmed that, in type I structure, functionalized patches …