Open Access. Powered by Scholars. Published by Universities.®
- Discipline
-
- Physical Sciences and Mathematics (40852)
- Civil and Environmental Engineering (39758)
- Electrical and Computer Engineering (36741)
- Mechanical Engineering (30007)
- Computer Engineering (25628)
-
- Computer Sciences (17307)
- Materials Science and Engineering (16662)
- Chemical Engineering (14063)
- Operations Research, Systems Engineering and Industrial Engineering (13798)
- Civil Engineering (11783)
- Biomedical Engineering and Bioengineering (11445)
- Aerospace Engineering (11113)
- Education (8199)
- Social and Behavioral Sciences (8004)
- Environmental Sciences (6952)
- Life Sciences (6294)
- Arts and Humanities (6238)
- Environmental Engineering (6111)
- Transportation Engineering (5912)
- Engineering Science and Materials (5701)
- Electrical and Electronics (5693)
- Energy Systems (5621)
- Artificial Intelligence and Robotics (5389)
- Other Mechanical Engineering (5086)
- Medicine and Health Sciences (4727)
- Geotechnical Engineering (4581)
- Mining Engineering (4559)
- Construction Engineering and Management (4453)
- Business (4345)
- Institution
-
- Missouri University of Science and Technology (21777)
- University of Nebraska - Lincoln (11222)
- California Polytechnic State University, San Luis Obispo (7975)
- University of Kentucky (6342)
- Purdue University (6326)
-
- Air Force Institute of Technology (5699)
- Utah State University (5439)
- Brigham Young University (4850)
- Old Dominion University (4692)
- Technological University Dublin (4606)
- University of Central Florida (4566)
- New Jersey Institute of Technology (4264)
- China Simulation Federation (3880)
- Chulalongkorn University (3655)
- Wright State University (3445)
- Embry-Riddle Aeronautical University (3305)
- University of Texas at Arlington (3179)
- TÜBİTAK (3106)
- Engineering Conferences International (2957)
- University of Arkansas, Fayetteville (2839)
- Louisiana State University (2820)
- Portland State University (2757)
- Michigan Technological University (2631)
- Clemson University (2584)
- University of South Carolina (2359)
- University of Texas at El Paso (2141)
- Marquette University (2086)
- Chinese Chemical Society | Xiamen University (2026)
- Washington University in St. Louis (1828)
- China Coal Technology and Engineering Group (CCTEG) (1799)
- Keyword
-
- Engineering (2859)
- Machine learning (1432)
- Optimization (1217)
- Simulation (1169)
- Applied sciences (1099)
-
- Construction (902)
- Design (873)
- Sustainability (863)
- Machine Learning (829)
- Deep learning (809)
- Modeling (743)
- Additive manufacturing (577)
- Concrete (544)
- Safety (533)
- Architecture (525)
- Computer Science (525)
- Artificial intelligence (501)
- Building (499)
- Nanoparticles (477)
- Robotics (475)
- Education (464)
- CFD (448)
- Energy (442)
- UAV (442)
- Corrosion (441)
- Engineering education (424)
- Conference (411)
- ASME (401)
- Proceedings (401)
- Mechanical Engineering (389)
- Publication Year
-
- 2026 (5236)
- 2025 (8601)
- 2024 (9232)
- 2023 (9777)
- 2022 (9373)
-
- 2021 (9975)
- 2020 (10640)
- 2019 (10505)
- 2018 (8951)
- 2017 (8353)
- 2016 (9604)
- 2015 (7524)
- 2014 (7238)
- 2013 (7289)
- 2012 (6303)
- 2011 (5801)
- 2010 (5375)
- 2009 (4158)
- 2008 (4190)
- 2007 (3831)
- 2006 (3391)
- 2005 (3074)
- 2004 (2785)
- 2003 (2071)
- 2002 (1792)
- 2001 (1795)
- 1999 (1307)
- 1998 (1354)
- 1993 (1343)
- 1991 (1363)
- Publication
-
- Theses and Dissertations (11502)
- Electronic Theses and Dissertations (4180)
- Masters Theses (3914)
- Journal of System Simulation (3880)
- Electrical and Computer Engineering Faculty Research & Creative Works (3518)
-
- Theses (3460)
- Nebraska Tractor Tests (3397)
- Faculty Publications (3294)
- Turkish Journal of Electrical Engineering and Computer Sciences (3106)
- Chulalongkorn University Theses and Dissertations (Chula ETD) (2554)
- International Conference on Case Histories in Geotechnical Engineering (2055)
- Master's Theses (2027)
- Journal of Electrochemistry (2026)
- Dissertations (1866)
- Kentucky Transportation Center Research Report (1816)
- Doctoral Dissertations (1800)
- Coal Geology & Exploration (1799)
- International Conferences on Recent Advances in Geotechnical Earthquake Engineering and Soil Dynamics (1566)
- USF Tampa Graduate Theses and Dissertations (1463)
- Articles (1409)
- Browse all Theses and Dissertations (1369)
- Computer Science & Engineering Syllabi (1312)
- LSU Master's Theses (1307)
- Journal of Marine Science and Technology–Taiwan (1299)
- Open Access Theses & Dissertations (1295)
- Mechanical and Aerospace Engineering Faculty Research & Creative Works (1287)
- Civil, Architectural and Environmental Engineering Faculty Research & Creative Works (1266)
- Publications (1255)
- All Theses (1237)
- Graduate Theses and Dissertations (1219)
- Publication Type
Articles 73381 - 73410 of 196410
Full-Text Articles in Engineering
Orbital Angular Momentum Generation Using Composite Quasi-Continuous Metasurfaces With Perfect Efficiency, Menglin L.N. Chen, Li (Lijun) Jun Jiang
Orbital Angular Momentum Generation Using Composite Quasi-Continuous Metasurfaces With Perfect Efficiency, Menglin L.N. Chen, Li (Lijun) Jun Jiang
Electrical and Computer Engineering Faculty Research & Creative Works
A composite perfect electric conductor (PEC)-perfect magnetic conductor (PMC) metasurface is proposed for orbital angular momentum (OAM) generation. Each scatterer on the metasurface consists of an anisotropic PEC layer and an isotropic PMC layer. Unlike conventional metasurfaces that composed of discrete scatterers, the scatterers on the proposed metasurface form a quasi-continuous pattern. Therefore, negative consequences of periodicity breaking from the patterned scatterers with varying sizes or orientations and their mutual coupling are avoided. We model the scatterer using Jones matrix. Its design is based on the features of PEC and PMC, which abandons complicated optimization process. The patterning of scatterers …
Numerical Modeling Of Graphene Nano-Ribbon By Dgtd Taking Into Account The Spatial Dispersion Effects, Ping Li, L. (Lijun) J. Jiang, H. Baǧci
Numerical Modeling Of Graphene Nano-Ribbon By Dgtd Taking Into Account The Spatial Dispersion Effects, Ping Li, L. (Lijun) J. Jiang, H. Baǧci
Electrical and Computer Engineering Faculty Research & Creative Works
It is well known that graphene demonstrates spatial dispersion properties [1]-[3], i.e., its conductivity is nonlocal and a function of spectral wave number (momentum operator) q. In this work, to fully account for effects of spatial dispersion on transmission of high-speed signals along graphene nanoribbon (GNR) interconnects, a discontinuous Galerkin time-domain (DGTD) algorithm is proposed. The atomically thick GNR is modeled using a nonlocal transparent surface impedance boundary condition (SIBC) [4] incorporated into the DGTD scheme. Since the conductivity is a complicated function of q (and one cannot find an analytical Fourier transform pair between q and spatial differential operators), …
"Whole-Brained" Engineering Education In Undergraduate Studies At The University Of Dayton, Kylie Moellering
"Whole-Brained" Engineering Education In Undergraduate Studies At The University Of Dayton, Kylie Moellering
Undergraduate Voices
This inquiry is a case study which explores, explicates, and summarizes the recent shift to “whole-brained” engineering education for undergraduate-level students at the University of Dayton. This case study is primarily structured around the experiences and insights of an interviewee, Dr. Ken Bloemer, who is the Director of the Visioneering Center at the University of Dayton. The Visioneering Center is principally focused on promoting the progress of engineering education at the university. Voices from scholarly literature pertaining to this vision and other undergraduate engineering curricula are then used to reinforce the interviewee’s views and give deeper insight into the various …
Undergraduate Voices, Volume 1 (2018): Addendum, Amir Kalan
Undergraduate Voices, Volume 1 (2018): Addendum, Amir Kalan
Undergraduate Voices
Additional articles approved for publication in December 2018 in Volume 1.
Effects Of Substrate Radial-Position Relative To The Sputter-Gun Axis On The Electrical, Optical And Structural Properties Of Zno Thin Films Deposited By Reactive Direct Current Magnetron Sputtering, John Paul Eneku, Tom Otiti, Julius Mwakondo Mwabora, David Horwat
Effects Of Substrate Radial-Position Relative To The Sputter-Gun Axis On The Electrical, Optical And Structural Properties Of Zno Thin Films Deposited By Reactive Direct Current Magnetron Sputtering, John Paul Eneku, Tom Otiti, Julius Mwakondo Mwabora, David Horwat
Tanzania Journal of Science
ZnO thin films were deposited using reactive direct current (dc) magnetron sputtering on glass substrates placed at seven variable radial positions (-1, 0, 1, 2, 3, 4 and 5 cm) relative to the sputter-gun (target) axis. A pure zinc target was used and sputtering carried out in argon and oxygen atmosphere with flow rates of 50 sccm and 6 sccm, respectively. XRD characterization showed that, all films crystallized homogeneously in the wurtzite phase with a strong (002) and a weak (004) orientations. Film crystallinity was very low at substrate positions located less than or equal to 1 cm from the …
Theory Of Potential-Based Integral-Form A-Φ Formulation In Electromagnetic Applications, Qin S. Liu, Li (Lijun) Jun Jiang, Sheng Sun, Qi Dai, Weng Cho Chew
Theory Of Potential-Based Integral-Form A-Φ Formulation In Electromagnetic Applications, Qin S. Liu, Li (Lijun) Jun Jiang, Sheng Sun, Qi Dai, Weng Cho Chew
Electrical and Computer Engineering Faculty Research & Creative Works
Recent progress on the theory of potential-based A-φ formulationin the integral form and its electromagnetic applications are summarized and presented here. By using Lorenz gauge and solving the vector and scalar potential formulations in tandem, the A-φ formulationac-curately captures the correct physics of both electrostatics and magnetostatics. The wide-band stable, dense-discretization breakdown free and structure-independent solver provides an alternative solution to various electromagnetic scattering and circuital problems. Also, the A-φformulationis applied to solve the characteristic modes at low frequencies.
Analysis Of 3d Printed Ndfeb Polymer Bonded And Organic Based Magnets, Chimaobi Ibeh
Analysis Of 3d Printed Ndfeb Polymer Bonded And Organic Based Magnets, Chimaobi Ibeh
Theses
Additive manufacturing (AM), or commonly known as 3D printing, has introduced to the manufacturing and commercial sectors novel ways of reducing production times, decreasing material waste, and enabling end products with multi-material configuration and complex geometric designs. From industrial scale to customer-based printers, AM has revolutionized the approach to manufacturing, prototyping, and designing in the field of medical, automotive, aerospace, biomedical, electronics and customizable products. Recently, additive manufacturing has crossed over to the area of applications in magnetism due to the economic push for the miniaturization of electronic and mechanical devices, reduction in production costs and material & design flexibility. …
Icing Thickness Prediction Model For Overhead Transmission Lines, Yue Ming
Icing Thickness Prediction Model For Overhead Transmission Lines, Yue Ming
Theses
Failures in a large electric power system are often inevitable. Severe weather conditions are one of the main causes of transmission line failures. Using the fault data of transmission lines of Shaanxi Power Grid from 2006 to 2016, in conjunction with meteorological information, this paper analyses the relationship between the temporal-spatial distribution characteristics of meteorological disasters and the fault of transmission lines in Shaanxi Province, China.
In order to analyze the influence of micro-meteorology on ice coating, a grey correlation analysis method is proposed. This thesis calculates the grey relational between ice thickness and micro-meteorological parameters such as ambient temperature, …
Amorphous Metal Oxide Semiconductor Thin Film Transistors For Printed Electronics, Mustafa Mohammad Yousef
Amorphous Metal Oxide Semiconductor Thin Film Transistors For Printed Electronics, Mustafa Mohammad Yousef
Theses
There is an acute market need for solution-processable semiconductor inks that can form the essential components of the printed analog and digital circuits. Currently, the industry is migrating beyond simply printing conductive metals for interconnects and embracing higher integration by printing transistors directly on the same substrate. This thesis focuses on investigating solution-processed amorphous indium gallium zinc oxide (IGZO) as a semiconducting channel layer of a field-effect transistor to enable low-cost, large-area printed electronics that are physically flexible and optically transparent. Specifically, we aim to achieve field-effect mobility exceeding 1 cm2/Vs, to overcome the limits faced in existing …
Optimization Of Zinc To Tin Ratio In A Sol Gel Precursor Solution On The Growth And Properties Of Annealed Czts Thin Films, Justine John Tibaijuka, Margaret E Samiji, Nuru R Mlyuka
Optimization Of Zinc To Tin Ratio In A Sol Gel Precursor Solution On The Growth And Properties Of Annealed Czts Thin Films, Justine John Tibaijuka, Margaret E Samiji, Nuru R Mlyuka
Tanzania Journal of Science
CZTS thin films were deposited by sol–gel spin coating method using precursor solutions prepared by dissolving copper acetate dihydrate, zinc acetate dihydrate, tin chloride and thiourea in methanol and monoethylamine then annealed in RTP furnace at 500 °C. Sol–gel precursor solutions were prepared with different Zn/Sn in a precursor solution and were annealed at different time intervals; and their effects on the optical and electrical properties of CZTS (Cu2ZnSnS4) films were investigated. The optical band-gap values were estimated to be between 1.30 and 1.88 eV while the absorption coefficients were in the range of 104 cm–1 in the visible region. …
Compositional And Thickness Effects On The Optical Properties Of Zinc–Doped Selenium–Antimony Thin Films, Austine A Mulama, Julius M Mwabora, Andrew O Oduor, Cosmas M Muiva
Compositional And Thickness Effects On The Optical Properties Of Zinc–Doped Selenium–Antimony Thin Films, Austine A Mulama, Julius M Mwabora, Andrew O Oduor, Cosmas M Muiva
Tanzania Journal of Science
Chalcogenide system of antimony (Sb)-selenium (Se)-zinc (Zn) system is a promising semiconductor for phase change memory devices due to its thermal stability and low power consumption. The study investigated the effect of film thickness and zinc content on the optical properties of thermally evaporated Sb10Se90-xZnx (x = 0, 5, 10 & 15 at. %) thin films. It was found that transmittance (T~ 85-40%) and optical band gap energy (Eopt ~ 1.60 eV – 1.22 eV) decreased but absorption coefficient (α~0.840–2.031 104 cm–1) increased with increase in zinc content. Furthermore, as the film thickness increased from 53 ± 5 nm to …
Effects Of Aluminium And Tungsten Co-Doping On The Optical Properties Of Vo2 Based Thin Films, Cephas J Lyobha, Nuru R Mlyuka, Margaret E Samiji
Effects Of Aluminium And Tungsten Co-Doping On The Optical Properties Of Vo2 Based Thin Films, Cephas J Lyobha, Nuru R Mlyuka, Margaret E Samiji
Tanzania Journal of Science
Aluminium and tungsten co-doped vanadium dioxide (VO2:W:Al) thin films were deposited by DC reactive magnetron sputtering technique. In this work we report on the effects of aluminium and tungsten co–doping on the optical properties of vanadium dioxide (VO2) based thin films with a view of combining both increased luminous transmittance (Tlum) and lowered transition temperature (τc). The effect of aluminium and tungsten co-doping on semiconductor-metal transition of vanadium dioxide films was investigated and compared with tungsten doped and undopedVO2films. Spectral transmittances of the films were obtained using Shimadzu SolidSpec-3700 DUV UV-VIS-NIR spectrophotometer. The results revealed that the transmittance of tungsten …
Hall Effect Parameters Of Aluminium And Tungsten Co-Doped Vo2 Thin Films, Mohamed Mussa, Nuru R Mlyuka, Margaret E Samiji
Hall Effect Parameters Of Aluminium And Tungsten Co-Doped Vo2 Thin Films, Mohamed Mussa, Nuru R Mlyuka, Margaret E Samiji
Tanzania Journal of Science
The Hall Effect parameters of Al and W co-doped VO2 thin films were studied in order to explain the effect of co-doping on the electrical properties of thermochromic VO2 films. The carrier concentrations and conductivity of the films were found to increase with increase in temperature while carrier mobility decreased reaching a minimum around the transition temperature then slightly rose and became stable at high temperatures. Tungsten doped films displayed higher carrier concentrations and conductivity on both sides of the metal insulator transition and lower mobility compared to undoped and Al and W co-doped VO2 thin films.
Interactions Between Polymer Nanoparticles And Blood Plasma Applied To Drug Delivery Systems, Mark Bannon
Interactions Between Polymer Nanoparticles And Blood Plasma Applied To Drug Delivery Systems, Mark Bannon
Theses
Targeted nanoparticle drug delivery has the potential to replace current forms of cancer therapy with previously unparalleled efficiency. Upon introduction into the human body, nanoparticles exhibit a substantial increase in diameter due to a biomolecular corona formation caused by interactions between blood plasma proteins and the nanoparticles. These interactions must be analyzed and understood for targeted delivery to reach its potential in both feasibility and efficiency.
To study the formation of the protein corona, polystyrene nanoparticles were incubated in vitro in goat blood plasma for 10-minute intervals, diluted to different degrees and then measured to obtain the hydrodynamic diameter of …
Performance Of C2H4 Reductant In Activated-Carbon-Supported Mnox-Based Scr Catalyst At Low Temperatures, Guangli Liu, Dongtai Han, Jie Cheng, Yongshi Feng, Wenbin Quan, Li Yang, Kozo Saito
Performance Of C2H4 Reductant In Activated-Carbon-Supported Mnox-Based Scr Catalyst At Low Temperatures, Guangli Liu, Dongtai Han, Jie Cheng, Yongshi Feng, Wenbin Quan, Li Yang, Kozo Saito
Mechanical Engineering Faculty Publications
Hydrocarbons as reductants show promising results for replacing NH3 in SCR technology. Therefore, considerable interest exists for developing low-temperature (< 200 °C) and environmentally friendly HC-SCR catalysts. Hence, C2H4 was examined as a reductant using activated-carbon-supported MnOx-based catalyst in low-temperature SCR operation. Its sensitivity to Mn concentration and operating temperature was parametrically studied, the results of which showed that the catalyst activity followed the order of 130 °C > 150 °C > 180 °C with an optimized Mn concentration near 3.0 wt.%. However, rapid deactivation of catalytic activity also occurred when using C2H4 as the reductant. The mechanism of deactivation was explored and is …
Profiling And Identifying Individual Usersby Their Command Line Usage And Writing Style, Darusalam Darusalam, Helen Ashman
Profiling And Identifying Individual Usersby Their Command Line Usage And Writing Style, Darusalam Darusalam, Helen Ashman
Knowledge Engineering and Data Science
Profiling and identifying individual users is an approach for intrusion detection in a computer system. User profiles are important in many applications since they record highly user-specific information - profiles are basically built to record information about users or for users to share experiences with each other. This research extends previous research on re-authenticating users with their user profiles. This research focuses on the potential to add psychometric user characteristics into the user model so as to be able to detect unauthorized users who may be masquerading as a genuine user. There are five participants involved in the investigation for …
Energy Efficiency Metrics Of University Data Centers, Leonel Hernandez, Genett Jimenez, Piedad Marchena
Energy Efficiency Metrics Of University Data Centers, Leonel Hernandez, Genett Jimenez, Piedad Marchena
Knowledge Engineering and Data Science
The data centers are fundamental pieces in the network and computing infrastructure,and evidently today more than ever they are relevant. Since they support the processing, analysis, assurance of the data generated in the network and by the applications in the cloud, which every day increases its volume thanks to technologies such as Internet of Things, Virtualization, and cloud computing, among others. Precisely the management of this large volume of information makes the data centers consume a lot of energy, generating great concern to owners and administrators. Green Data Centers offer a solution to this problem, reducing the impact produced by …
Signature Pattern Recognition Using Kohonen Network, Nadia Roosmalita Sari, Mohammad Zoqi Sarwani, Yudha Alif Aulia, Wayan Firdaus Mahmudy
Signature Pattern Recognition Using Kohonen Network, Nadia Roosmalita Sari, Mohammad Zoqi Sarwani, Yudha Alif Aulia, Wayan Firdaus Mahmudy
Knowledge Engineering and Data Science
A signature is a special form of handwriting that used for human identification process. The current identification process is extremely ineffective. People have to manually compare signatures with the previously stored data. This study proposed SOM Kohonen algorithm as the method of signature pattern recognition. This method has able to visualize high-dimensional data. The image processing method is used in this study in pre-processing data phase. The accuracy of SOM Kohonen was 70 %, indicated the method used was good enough for pattern recognition.
Digit Classification Of Majapahit Relic Inscriptionusing Glcm-Svm, Tri Septianto, Endang Setyati, Joan Santoso
Digit Classification Of Majapahit Relic Inscriptionusing Glcm-Svm, Tri Septianto, Endang Setyati, Joan Santoso
Knowledge Engineering and Data Science
A higher level of image processing usually contains some kind of classification or recognition. Digit classification is an important subfield in handwritten recognition.Handwritten digits are characterized by large variations so template matching, in general, is inefficient and low in accuracy. In this paper, we propose the classification of the digit of the year of a relic inscription in the Kingdom of Majapahit using Support Vector Machine (SVM). This method is able to cope with very large feature dimensions and without reducing existing features extraction. While the method used for feature extraction using the Gray-Level Co-Occurrence Matrix (GLCM), special for texture …
Change Vulnerability Forecasting For Southeast Asiausing Deep Learning Algorithm, Amelia Ritahani Ismail, Nur 'Atikah Binti Mohd Ali, Junaida Sulaiman
Change Vulnerability Forecasting For Southeast Asiausing Deep Learning Algorithm, Amelia Ritahani Ismail, Nur 'Atikah Binti Mohd Ali, Junaida Sulaiman
Knowledge Engineering and Data Science
Climate change is expected to change people’s livelihood in significant ways. Several vulnerability factors and readiness factors used for measuring the prediction index of that particular country on how vulnerable of a country towards global change. Primary data was collected from University of Notre Dame Global Adaptation Index (NDGAIN). The data has been trained for the forecasting purpose with support from the validated statistical analysis. The summary of the predicted index is visualized using machine learning tools. The results developed the correlation between vulnerability and readiness factors and shows the stability of the country towards climate change. The framework is …
Costs And Benefits Of Flood Mitigation In Louisiana, Arash Taghi Nezhad Bilandi
Costs And Benefits Of Flood Mitigation In Louisiana, Arash Taghi Nezhad Bilandi
LSU Doctoral Dissertations
Assessing the costs and benefits of hazard mitigation efforts is an essential component of disaster management, planning, and resilience assessment. These calculations are particularly important in locations vulnerable to multiple hazards with high frequencies, such as coastal Louisiana. This study aims to provide an improved understanding of the costs and benefits of flood mitigation efforts in Louisiana funded by federal government grants between 2005 and 2015. Project data provided by the Governor’s Office of Homeland Security and Emergency Preparedness (GOHSEP) were summarized and missing values were imputed using robust statistical approaches. Elevation project cost was investigated for prediction by statistical …
Transient Transmission Oscillations In Doped And Undoped Lithium Niobate Induced By Near-Infrared Femtosecond Pulses, Bryan J. Crossman, Gregory J. Taft
Transient Transmission Oscillations In Doped And Undoped Lithium Niobate Induced By Near-Infrared Femtosecond Pulses, Bryan J. Crossman, Gregory J. Taft
Physics Faculty Publications
Transient transmission oscillations in X-cut and Z-cut congruent, iron-doped, and magnesium-doped lithium niobate samples were measured using 50 fs, 800 nm, 0.5 nJ pulses from a self-mode-locked Ti:sapphire laser in an optical pump–probe system. Several Raman-active oscillation modes excited by these pulses were observed as changes in the transmitted probe intensity versus time delay between the pump and probe pulses. The samples were rotated to determine how the incident polarization of the pump pulses affects the mode excitations. The observed Raman-active oscillations correspond to previously reported symmetry modes measured with traditional, continuous-wave, Raman spectroscopy using the same scattering …
Recent Progress In Pt-Based Catalysts For Oxygen Reduction Reaction, Jing Li, Xin Feng, Zi-Dong Wei
Recent Progress In Pt-Based Catalysts For Oxygen Reduction Reaction, Jing Li, Xin Feng, Zi-Dong Wei
Journal of Electrochemistry
One major challenge for a large-scale commercialization of the proton-exchange membrane fuel cells (PEMFCs) technologies that enable a shift to ‘zero-emission’ personal transportation, is the expensive and unstable Pt catalysts, which are mainly used to catalyze the sluggish kinetics of the oxygen reduction reaction (ORR) occurred on the air electrode of PEMFCs. Many research works have targets to improve the stability of Pt-based catalysts and to construct Pt/transitional metal alloys with low Pt loading amount. Herein, we provide a minireview for the Pt-based ORR catalysts based on our recent work, which covers a brief background introduction, the stability improvement of …
Constructions Of Noble Metal Nanocrystals With Specific Crystal Facets And High Surface Area, Qiao-Li Chen, Hui-Qi Li, Ya-Qi Jiang, Zhao-Xiong Xie
Constructions Of Noble Metal Nanocrystals With Specific Crystal Facets And High Surface Area, Qiao-Li Chen, Hui-Qi Li, Ya-Qi Jiang, Zhao-Xiong Xie
Journal of Electrochemistry
Noble metal nanocrystals (NCs) have widespread applications in catalysis. Their catalytic performances are strongly related to the surface structures while the atomic utilization efficiency of noble metal is considerably correlated with the surface area. Thus, advantages of both specific surface structure and large surface area are highly required to show off simultaneously so as to optimize the catalytic performance and decrease the usage of noble metal. However, it seems that the two advantages are incompatible with each other in one NC since it is difficult for small NCs to keep their specific facets, while NCs with specific surface structure usually …
Stabilization Strategies Of Pt Catalysts Forproton Exchange Membrane Fuel Cells, Da-Ping He, Shi-Chun Mu
Stabilization Strategies Of Pt Catalysts Forproton Exchange Membrane Fuel Cells, Da-Ping He, Shi-Chun Mu
Journal of Electrochemistry
The low service lifetime of proton exchange membrane fuel cells (PEMFCs) is the main bottleneck for their commercial applications. One of the main factors is that the expensive metal Pt catalyst is easy to degradation under the harsh working environment of PEMFC (such as variable voltage, strong acidity, gas-liquid two-phase flow), which leads to the inevitable decay of the catalytic performance, thus, seriously restricting the lifetime of PEMFC. Therefore, the electrochemical stability of Pt-based electrocatalysts has become an important and hot topic to improve the PEMFC lifetime. In this paper, we review the recent development in enhancing the stability of …
The Pilot Application Of Electrochemical Impedance Spectroscopy On Dynamic Proton Exchange Membrane Fuel Cell, Jian-Wei Guo, Jian-Long Wang
The Pilot Application Of Electrochemical Impedance Spectroscopy On Dynamic Proton Exchange Membrane Fuel Cell, Jian-Wei Guo, Jian-Long Wang
Journal of Electrochemistry
By analyzing Electrochemical Impedance Spectroscopy (EIS) in applications of dynamic proton exchange membrane fuel cell (PEMFC), bottlenecks which restrict EIS tool development have been pointed out in this paper. Though the high-frequency resistance in EIS is largely accepted as cell inner-resistance, this can only be applied for cell with low current. The low-frequency resistance is difficult to be realized due to its relation with mass transfer. Furthermore, the improved Randles equivalent circuits are built up preliminarily, thus, penetrating into studies for mass transfer reaction, cell operation/degeneration, and high temperature fuel cell. Inspiringly, EIS is becoming an analyzing tool for stack …
Caging Porous Co-N-C Nanocomposites In 3d Graphene As Active And Aggregation-Resistant Electrocatalyst For Oxygen Reduction Reaction, Lu-Yang Xiu, Meng-Zhou Yu, Peng-Ju Yang, Zhi-Yu Wang, Jie-Shan Qiu
Caging Porous Co-N-C Nanocomposites In 3d Graphene As Active And Aggregation-Resistant Electrocatalyst For Oxygen Reduction Reaction, Lu-Yang Xiu, Meng-Zhou Yu, Peng-Ju Yang, Zhi-Yu Wang, Jie-Shan Qiu
Journal of Electrochemistry
Oxygen reduction reaction (ORR) is the cornerstone reaction of many renewable energy technologies such as fuel cells and rechargeable metal-air batteries. The Pt-based electrocatalysts exhibit the highest activity toward ORR, but their large implementation is greatly prohibiting by unaffordable cost and inferior durability. During electrode manufacturing and electrochemical reaction, severe aggregation of catalyst nanoparticles induced by size effect further limits the operational performance of electrocatalysts. We report a new strategy for fabrication of active and aggregation-resistant ORR electrocatalyst by caging metal-organic frameworks derived Co-N-C nanocomposites in permeable and porous 3D graphene cages via sprayed drying the mixed colloids of ZIF-67 …
Voltage Distribution Of Self-Humidifying Air-Cooled Pemfc, Kai-Feng Tan, Wei-Rong Chen, Ming Han, Xue-Xia Zhang
Voltage Distribution Of Self-Humidifying Air-Cooled Pemfc, Kai-Feng Tan, Wei-Rong Chen, Ming Han, Xue-Xia Zhang
Journal of Electrochemistry
In this work, the self-adaptive characteristics of self-humidifying air-cooled PEMFC stack was investigated. The performance and the unit-cell voltage distribution of the stack were measured and analyzed through the unit-cell I-V curve fitting. The operating conditions for this experimental study were set as follows: hydrogen pressure at the anode was 2 bar, the fan power used for the reactant oxygen feed and stack cooling was at 0.3 W, and the duration and time gap of water purged from hydrogen chamber were 1 s and 10 s, respectively. The experimental results showed that the self-humidifying air-cooled PEMFC stack used for this …
Research Progress In Hydrogen Evolution Low Noble/Non-Precious Metal Catalysts Of Water Electrolysis, Yang Li, Zhao-Yan Luo, Jun-Jie Ge, Chang-Peng Liu, Wei Xing
Research Progress In Hydrogen Evolution Low Noble/Non-Precious Metal Catalysts Of Water Electrolysis, Yang Li, Zhao-Yan Luo, Jun-Jie Ge, Chang-Peng Liu, Wei Xing
Journal of Electrochemistry
Hydrogen energy technology with hydrogen as an energy carrier is gaining more and more attention due to its cleanliness and high energy density. Hydrogen fuel cell vehicles have been listed as one of the ultimate energy technologies in the 21st century. Among them, sustainable hydrogen production technology is a necessary prerequisite for the future development of hydrogen energy economy. Electrolyzed water technology driven by renewable resources represents an important way to support the sustainable development of hydrogen energy economy. The development and utilization of high activity, low cost hydrogen evolution catalysts is a key factor in improving the efficiency and …
Progress Of Self-Humidifying Membrane Electrode Assembly For Low Temperature Proton Exchange Membrane Fuel Cell, Bin Chi, Yue-Kun Ye, Shi-Jie Jiang, Shi-Jun Liao
Progress Of Self-Humidifying Membrane Electrode Assembly For Low Temperature Proton Exchange Membrane Fuel Cell, Bin Chi, Yue-Kun Ye, Shi-Jie Jiang, Shi-Jun Liao
Journal of Electrochemistry
The self/non-humidification membrane electrode assembly(SH-MEA)is an important pathway towards the self- humidification fuel cell and plays a crucial role for the large scale commercialization of low temperature proton exchange membrane fuel cell (LT-PEMFC), because it not only can reduce the volume and complexity of fuel cell system, resulting in the decrease of the cost, but also can improve the output power density of the fuel cell system. Currently, the researches on the self-humidifying MEA of LT-PEMFC mainly focus on three aspects: the preparation of self-humidification proton exchange membrane, the construction of self-humidification catalyst layer, and the construction of composite self-humidifying …