Engineering Commons^™

Improving Link Quality Estimation In Zigbee Networks, Srikar Meka

Graduate Research Theses & Dissertations

Estimation of links in a Wireless Sensor Network and using such estimates to decide between all the multiple paths available in a network is important. There are several link estimation methods available. This thesis evaluates the performance of PRR based method (P-success method), suggested in the ZigBee specification and LQI based method (LQI method) used by different organizations, in various scenarios. The performance of these two link cost estimation methods is also compared under Wi-Fi interference. This comparison is done using a network simulator (NS3). It is observed that, if there is no Wi-Fi interference, both the P-success and LQI …

The Short-Term Effects Of Interstate Highways On Small Rural Communities: A Case Study Of I-39, I-49 And I-72, 1990 To 2000, John Paul Metelko

Graduate Research Theses & Dissertations

The presence of interstate highways in rural areas improves access to nearby rural

communities and changes those communities’ spheres of influence. Research into

understanding how improved access from interstate highways affects rural communities

is needed. This case study was designed to investigate how rural communities changed

on the basis of population, vacancy, median home value, and median contract rent in the

short term after an interstate highway was completed nearby in the early 1990s.

The communities included in this study are incorporated cities, towns, villages

and census-designated places in non-metropolitan counties with at least one incorporated

city, town, village and …

Exploring Cyber-Physical Systems, Misbah Uddin Mohammed

Graduate Research Theses & Dissertations

The advances in IOT, Computer Vision, AI and Machine Learning have made these technologies ubiquitous to our daily lives. From Smart Phones to Connected Vehicles, Cyber Physical systems have been interspersed into everything we interact in today’s world. The aim or this thesis was to explore these advances in Cyber Physical Systems and analyze the different sectors they were affecting. We then hand-picked certain domains and explored further by carrying out practical projects using some of the latest software and hardware resources available. Technologies like Amazon Alexa services, NVIDIA Jetson boards, TensorFlow, OpenCV, NodeJS were heavily employed in our various …

The Effects Of Using A Mobile Digital Assistive Tutor For Circuit Analysis On Students’ Academic Achievement, Problem-Solving And Self-Efficacy, Kenie Moses

Graduate Research Theses & Dissertations

This experimental research study examined the effects of using a mobile learning environment (MLE) that provided scaffolded assistive tutoring on student achievement in a Circuit Analysis (Network Theory) course. It also aimed to examine the relationships between students’ user learning analytics and their learning outcomes. The design and development of the mobile app was based on the Model of Contingent Instruction and Metacognitive Support which critically applies scaffolding as its operative in transferring domain knowledge in expert to novice problem-solving.

This experimental research study collected data from eighty-three undergraduate college students who were randomly assigned into one of three groups …

Minimizing Total Number Of Tardy Jobs In Parallel Batch Processing Machines Using Column Generation And Simulated Annealing, Sameer Neupane

Graduate Research Theses & Dissertations

This research considers a scheduling problem where jobs need to be grouped into batches and the batches need to be scheduled on parallel batch processing machines with an objective to minimize the total number of tardy jobs. The jobs are assigned to batches in such a way that machine capacity is not violated. This research considers jobs with unequal ready times, unequal processing times and unequal sizes. The machines are identical in processing capabilities; however, their capacities are different. This research aims to develop effective solution approaches to solve the problem under study. A Mixed Integer Linear Programming (MILP) model …

A Computational Fluid Dynamics Analysis Of The Aerodynamic Performance Of Wind Turbine, Ashkan Ostovari

Graduate Research Theses & Dissertations

Renewable energy resources are likely to be a future energy solution. Among them, the wind has gained a lot of interest. Despite the theoretical limitation in wind energy harnessing efficiency, it is, still, one of the most promising renewable resources with utilizing turbines to extract this energy. Wind turbines, based on their axis of rotation are categorized into vertical axis wind turbine (VAWT) and horizontal axis wind turbine (HAWT), which HAWT’s have shown relatively higher efficiency than VAWT’s. The aim of this thesis is first to develop a scaled-down model of a wind turbine in Computational Fluid Dynamics (CFD) environment …

Computational Methods For Bicubic L1 Splines, Priyesh Koyu Rai

Graduate Research Theses & Dissertations

The past two decades have seen the development of L1 splines for interpolation and approximation of geometric data. L1 splines have been shown to preserve shapes better than the conventional L2 splines, especially for data with abrupt changes in the magnitude of spacing. Efficient computation plays an important role in the practical application of L1 splines. This thesis creates new computational methods for constructing bicubic L1 interpolating splines and bicubic L1 spline fits. The bicubic splines in this study are piecewise bicubic polynomials defined on a rectangular grid generated by the tensor product of nodes. We developed a hybrid computational …

The Study Of Scandate Cathode And Its Characterization Under Various Stages Of Processing, Xiaomeng Zhang

Theses and Dissertations--Chemical and Materials Engineering

Scandate cathode under various processing stages: scandia nano-powder, tungsten scandia mix powder, sintered and impregnated pellets, were characterized with techniques that included electron microscopy, EDS, XPS, and work function measurements. The size and shape uniformity of nano-scale scandia particles changed from round to square and polyhedron during heat treatment. Reduction in size and improvement in size uniformity as heat treating temperature increased were observed. When determining the highest Sc coverage, three assessment methods were used and with their combined results, it was concluded that set VII had the highest Sc at%. In the sintered pellets, it was observed with SEM …

Biomass-Derived Activated Carbons For Electrical Double Layer Supercapacitors: Performance And Stress Effect, Wenxin Cao

Theses and Dissertations--Chemical and Materials Engineering

The vigorous development of human civilization has significantly increased the energy consumption in recent years. There is a great need to use renewable energy sources to substitute the depleting traditional fossil fuels, such as crude oil, natural gas and coal. The development of low-cost and high-performance energy storage devices (ESDs) and systems have drawn great attention due to their feasibility as backup power supply and their applications in portable electronics and electric vehicles. Supercapacitors are among the most important ESDs because of their long charging-discharging cycle life, high power capability and a large operating temperature range. In this thesis, high-performance …

Synthesis, Functionalization, And Application Of Nanofiltration And Composite Membranes For Selective Separations, Andrew Steven Colburn

Theses and Dissertations--Chemical and Materials Engineering

Future nanofiltration (NF) membranes used for selective separations of ions and small organic molecules must maintain performance in environments where high concentrations of total dissolved solvents or foulants are present. These challenges can be addressed through the development of composite membranes, as well as the engineering of enhanced surface properties and operating conditions for existing commercial membranes.

In this work, ion transport through commercial thin film composite (TFC) polyamide NF membranes were studied in both lab-prepared salt solutions and industrial wastewater. The dependence of several variables on ion rejection was investigated, including ion radius, ion charge, ionic strength, and temperature. …

Towards The Rational Design And Application Of Polymers For Gene Therapy: Internalization And Intracellular Fate, Landon Alexander Mott

Theses and Dissertations--Chemical and Materials Engineering

Gene therapy is an approach for the treatment of acquired cancers, infectious disease, degenerative disease, and inherited genetic indications. Developments in the fields of immunotherapies and CRISPR/Cas9 genome editing are revitalizing the efforts to move gene therapy to the forefront of modern medicine. However, slow progress and poor clinical outcomes have plagued the field due to regulatory and safety concerns associated with the flagship delivery vector, the recombinant virus. Immunogenicity and poor transduction in certain cell types severely limits the utility of viruses as a delivery agent of nucleic acids. As a result, significant efforts are being made to develop …

Development Of Novel Temperature Responsive Polymeric Sorbents And Their Applications In Water Remediation, Shuo Tang

Theses and Dissertations--Chemical and Materials Engineering

Water remediation utilizing sorption has found strong interest due to its inexpensiveness, universal nature and ease of operation. In particular, thermo-responsive sorbents consisting of N-isopropylacrylamide (NIPAAm) offer significant potential as “smart” and advanced materials to remove multiple aqueous pollutants. NIPAAm exhibits excellent thermo-responsiveness, which senses the external temperature variation and changes its swelling and sorption behaviors in a sharp and rapid manner. At the beginning of this work, an extensive review of literature has been compiled to provide a summary of NIPAAm-based thermo-responsive sorbents in water/wastewater remediation applications.

Initially, we developed a novel approach to synthesize and characterize NIPAAm copolymeric …

Functionalization Of Iron Oxide Nanoparticles And The Impact On Surface Reactive Oxygen Species Generation For Potential Biomedical And Environmental Applications, Trang Mai

Theses and Dissertations--Chemical and Materials Engineering

Iron oxide nanoparticles (IONPs) have been widely studied for a variety of applications, from biomedical applications (e.g., cell separation, drug delivery, contrast agent for magnetic resonance imaging and magnetically mediated energy delivery for cancer treatment) to environmental remediations (e.g., heavy metal removal and organic pollutants degradation). It has been demonstrated that IONPs can induce the production of reactive oxygen species (ROS) via Fenton/Haber-Weiss reactions which has been shown to be one of the key underlying mechanisms of nanoparticles toxicity. This inherent toxicity of nanoparticles has been shown to enhance the efficacy of traditional cancer therapies such as chemotherapy and radiation. …

Mechanical Properties And Degradation Of High Capacity Battery Electrodes: Fundamental Understanding And Coping Strategies, Yikai Wang

Theses and Dissertations--Chemical and Materials Engineering

Rechargeable lithium ion and lithium (Li) metal batteries with high energy density and stability are in high demand for the development of electric vehicles and smart grids. Intensive efforts have been devoted to developing high capacity battery electrodes. However, the known high capacity electrode materials experience fast capacity fading and have limited cycle life due to electromechanical degradations, such as fracture of Si-based electrodes and dendrite growth in Li metal electrodes. A fundamental understanding of electromechanical degradation mechanisms of high capacity electrodes will provide insights into strategies for improving their electrochemical performance. Thus, this dissertation focuses on mechanical properties, microstructure …

Cell Surface Coatings For Mammalian Cell-Based Therapeutic Delivery, Pei-Jung Wu

Theses and Dissertations--Chemical and Materials Engineering

The cell plasma membrane is an interactive interface playing an important role in regulating cell-to-cell, cell-to-tissue contact, and cell-to-environment responses. This environment-responsive phospholipid layer consisting of multiple dynamically balanced macromolecules, such as membrane proteins, carbohydrate and lipids, is regarded as a promising platform for various surface engineering strategies. Through different chemical modification routes, we are able to incorporate various artificial materials into the cell surface for biomedical applications in small molecule and cellular therapeutics.

In this dissertation, we establish two different cell coating techniques for applications of cell-mediated drug delivery and the localization of cell-based therapies to specific tissues. The …

Impact Of Conformational Change, Solvation Environment, And Post-Translational Modification On Desulfurization Enzyme 2'-Hydroxybiphenyl-2-Sulfinate Desulfinase (Dszb) Stability And Activity, Landon C. Mills

Theses and Dissertations--Chemical and Materials Engineering

Naturally occurring enzymatic pathways enable highly specific, rapid thiophenic sulfur cleavage occurring at ambient temperature and pressure, which may be harnessed for the desulfurization of petroleum-based fuel. One pathway found in bacteria is a four-step catabolic pathway (the 4S pathway) converting dibenzothiophene (DBT), a common crude oil contaminant, into 2-hydroxybiphenyl (HBP) without disrupting the carbon-carbon bonds. 2’-Hydroxybiphenyl-2-sulfinate desulfinase (DszB), the rate-limiting enzyme in the enzyme cascade, is capable of selectively cleaving carbon-sulfur bonds. Accordingly, understanding the molecular mechanisms of DszB activity may enable development of the cascade as industrial biotechnology. Based on crystallographic evidence, we hypothesized that DszB …

Targeted Illumination Strategies For Hydrogen Production From Purple Non-Sulfur Bacteria, John D. Craven

Theses and Dissertations--Chemical and Materials Engineering

The movement towards a more sustainable energy economy may require not only the generation of cleaner fuel sources, but the conversion of waste streams into value-added products. Phototrophic purple non-sulfur bacteria are capable of metabolizing VFAs (volatile fatty acids)and generate hydrogen as a byproduct of nitrogen fixation using energy absorbed from light. VFAs are easily produced from dark anaerobic fermentation of food, agricultural, and municipal wastes, which could then be fed into photobioreactors of purple bacteria for hydrogen production.

The process of photofermentation by purple bacteria for hydrogen production remains attractive due to the capability of reaching high substrate conversions …

Development Of Magnetic Nanocomposite Materials As Reusable Adsorbents For Chlorinated Organics In Contaminated Water, Angela Gutierrez

Theses and Dissertations--Chemical and Materials Engineering

The constant growth in population worldwide over the past decades continues to put forward the need to provide access to safe, clean water to meet human needs. There is a need for cost-effective technologies for water and wastewater treatment that can meet the global demands and the rigorous water quality standards and at the same maximizing pollutant efficiency removal. Current remediation technologies have failed in keeping up with these factors without becoming cost-prohibitive. Nanotechnology has recently been sought as a promising option to achieve these goals. The use of iron oxide magnetic nanoparticles as nanoadsorbents has led to a new …

Synthesis, Characterization And Applications Of Reduced Graphene Oxide And Composite Membranes For Selective Separations And Removal Of Organic Contaminants, Ashish Aher

Theses and Dissertations--Chemical and Materials Engineering

Among the next generation materials being investigated for membrane development, partially reduced Graphene Oxide (rGO) has received increasing attention from the membrane community. rGO-based nanofiltration membranes have shown promising results in applications such as partial desalination, organic contaminant removal, gas-phase separations, and separations from solvent media. rGO offers a unique platform compared to common polymeric membranes since it can be used for separation applications in both aqueous and organic solvent media. An rGO-based platform could also be utilized to synthesize reactive membranes, giving rGO membranes the additional capability of reactively removing organic contaminants. This research focuses on the synthesis of …

Nanoharvesting And Delivery Of Bioactive Materials Using Engineered Silica Nanoparticles, Md Arif Khan

Theses and Dissertations--Chemical and Materials Engineering

Mesoporous silica nanoparticles (MSNPs) possess large surface areas and ample pore space that can be readily modified with specific functional groups for targeted binding of bioactive materials to be transported through cellular barriers. Engineered silica nanoparticles (ESNP) have been used extensively to deliver bio-active materials to target intracellular sites, including as non-viral vectors for nucleic acid (DNA/RNA) delivery such as for siRNA induced interference. The reverse process guided by the same principles is called “nanoharvesting”, where valuable biomolecules are carried out and separated from living and functioning organisms using nano-carriers. This dissertation focuses on ESNP design principles for both applications. …

The Fabrication And Characterization Of Metal Oxide Nanoparticles Employed In Environmental Toxicity And Polymeric Nanocomposite Applications, Matthew Logan Hancock

Theses and Dissertations--Chemical and Materials Engineering

Ceria (cerium oxide) nanomaterials, or nanoceria, have commercial catalysis and energy storage applications. The cerium atoms on the surface of nanoceria can store or release oxygen, cycling between Ce³⁺ and Ce⁴⁺, and can therefore act as a therapeutic to relieve oxidative stress within living systems. Nanoceria dissolution is present in acidic environments in vivo. In order to accurately define the fate of nanoceria in vivo, nanoceria dissolution or stabilization is observed in vitro using acidic aqueous environments.

Nanoceria stabilization is a known problem even during its synthesis; in fact, a carboxylic acid, citric acid, is …

Small Non-Profit Website And Social Media Efficacy, Juliana Maria Leprich

Graduate Research Theses & Dissertations

This thesis examines the website design and social media platform usage of small non-profit organizations (defined as less than $1M operating budget and less than ten staff). This research will be completed by first reviewing other studies that have been done on marketing in the non-profit sector, then by exploring marketing challenges firsthand through a mini-ethnographic case study as described in the mini-ethnographic case study approach, and finally through the examination of tax and financial data provided by Guidestar. The researcher was involved in website collaboration with The Gracie Center in a volunteer capacity and was employed with the two …

Implementation And Evaluation Of Gated Recurrent Unit For Speech Separation And Speech Enhancement, Sagar V. Shah

Graduate Research Theses & Dissertations

Hearing aids, automatic speech recognition (ASR) and many other communication systems work well when there is just one sound source with almost no echo, but their performance degrades in situations where more speakers are talking simultaneously or the reverberation is high. Speech separation and speech enhancement are core problems in the field of audio signal processing. Humans are remarkably capable of focusing their auditory attention on a single sound source within a noisy environment, by de-emphasizing all other voices and interferences in surroundings. This capability comes naturally to us humans. However, speech separation remains a significant challenge for computers. It …

Highly Efficient Gan-Based Single-Phase Transformer-Less Pv Grid-Tied Inverter, Khaled Alatawi

Electronic Theses and Dissertations

Growing energy demand and environmental concerns have led to an increased interest in renewable energy resources to provide a sustainable and low carbon emission energy supply. Among these renewable energy resources, photovoltaic (PV) systems have been the focus of many scientific researchers. The most vital component of a PV system that needs to be improved is the power converter. Grid-tied transformer-less inverters have gained a lot of interest in recent years because of their higher efficiency, reduced volume and lower cost compared to traditional line transformer inverters.

This dissertation discusses single-phase transformer-less inverter challenges and provides solutions that could lead …

Magnetotransport In Zrte5 Crystals, Maksim Andreevich Sultanov

Graduate Research Theses & Dissertations

ZrTe5 is a topological material that is predicted to have a strain or temperature induced phase transition from a topological insulator state into a Weyl/Dirac semimetal state. In this study I find that there is insufficient evidence to support the claims for the existence of such a phase transition. I performed magnetoresistivity measurements using a Quantum Design Physical Properties Measurement System (PPMS) to measure the transverse and longitudinal resistivities at various temperatures and different strengths and orientations of the magnetic field. The measurement results were analyzed using OriginPro to determine the carrier mobility and density and to determine the temperature …

Energy And Exergy Analysis Of A Thermosiphon And Forced-Circulation Flat-Plate Solar Collector Using Mwcnt/Water Nanofluid, Mahmoud Eltaweel, Ahmed A. Abdel-Rehim

Mechanical Engineering

The scientific community has focused on the use of nanofluids to enhance solar collectors' thermal efficiency. Solar energy is considered an extensively available energy resource with a weak effect on the environment. The flat-plate solar collector is considered to be the most common collector used, but the efficiency of the collector has limitations, such as the low effectiveness of the absorber in terms of energy absorption and the transmission of that energy to the working fluid. The flat-plate solar collector can be enhanced by replacing the working fluid with a nanofluid. Nanofluids are considered new media that exhibit thermophysical properties …

Synthesis Of Fault Traces In Se Louisiana Relative To Infrastructure, David Culpepper, Elizabeth Chinn Mcdade, Nancye Dawers, Mark Kulp, Rui Zhang

Publications

Geological faulting has been implicated as a contributor to subsidence, coastal land-loss and submergence of marshlands in southern Louisiana. This report reviews whether fault motion, either by slow creep or more sudden slip, can cause deformation of engineered structures resulting in increased infrastructure maintenance and repair costs. The impact of surface, or near-surface, geologic faulting on critical infrastructure is insufficiently documented in southeastern Louisiana, but the state has a vast amount of energy-sector subsurface data that to date has been under-utilized for transportation and other near-surface engineering applications. Recent and on-going work by research groups at Tulane University, University of …

Developing A Commercial Product Using A Consumer Grade 3d Printer, Calvin Smith

All Graduate Theses, Dissertations, and Other Capstone Projects

The development of affordable, quality, consumer grade 3D printers has allowed entrepreneurs to develop new products and start small businesses. As the print quality of consumer grade printers has improved entrepreneurs have been able to develop consumer quality products without the traditional expense of mass manufacturing. This change from mass manufacturing to small scale and custom production has allowed for the growth of small businesses. Websites such as www.etsy.com show hundreds of small businesses based on 3D printing, these businesses showcase thousands of products ranging from useful household items to cosplay. This thesis covers the process of a small business …

Developing A Testing Instrument To Evaluate The Performance Of 3d-Printed Body-Powered Prosthetic Hands, Araz Al-Dawoodi

All Graduate Theses, Dissertations, and Other Capstone Projects

A 3D printed prosthetic hand is an open source technology that became a good substitution for many products in the market. For many reasons, Low-cost, easy made / easy build. As an open source product, 3D printed prosthetic designs are available to anyone around the world, a good option for young children because they need to have a new prosthetic more frequent until they reach the adulthood age. Most families cannot pay a thousand dollars technology. From the research, it found that that there are not enough studies cover the open source wrist body-powered prosthetic. Other studies covered products used …

Managing Variability In Assembly Lines, Sumanth Gokapai

All Graduate Theses, Dissertations, and Other Capstone Projects

Every successful company have a diversified product portfolio based on their customer demand. Though products are branded as different variants, versions etc. most of them are similar products with little variations in their features or functions they perform. With the traditional, product centric approach to handle variation, new techniques like Clone and own were implemented in which engineers pick the most similar one available, copy it, make changes to it and present it as a new variant. Even though this approach employs reuse, but the savings occur once and only once. This project discussed how companies can exploit the commonality …