Engineering Commons^™

Mno2/Carbon Material Cathode For Rechargeable Aqueous Electrolyte-Based Zinc-Ion Batteries, Sonti Khamsanga

Chulalongkorn University Theses and Dissertations (Chula ETD)

This research focused on improvement of the electrical conductivity of cathode material by using the MnO2 on carbon material for the rechargeable aqueous electrolyte-based zinc-ion batteries (ZIBs). This study has been divided into two sections. delta-MnO2 with nanoflower structure supported on graphite flake (MNG) was synthesized for cathode material in first section. MNG exhibits a fast insertion/extraction of Zn2+ ions with diffusion scheme and pseudocapacitive behavior. The battery using MNG cathode exhibited a high initial discharge capacity of 235 mA h/g at 200 mA/g specific current density compared to 130 mA h/g which is displayed by the pristine delta-MnO2 cathode …

Techno-Economic Analysis Of Acetaldehyde Production Via Partial Oxidative Dehydrogenation Of Ethanol, Sudarat Sompong

Chulalongkorn University Theses and Dissertations (Chula ETD)

Due to the increased attention regarding the battery electric vehicles, the demand for ethanol as a biofuel may be reduced in the future. Therefore, ethanol transformation towards acetaldehyde is conducted in this work, primarily because of the higher selling price and several advantages of acetaldehyde. Regarding the acetaldehyde preparation, acetaldehyde is produced by partial oxidative dehydrogenation of ethanol. According to the economic analysis results, at the same price of acetaldehyde, an annual production capacity of 120,000 tons is the most profitable production size. In addition, the potential process of producing acetaldehyde from ethanol is acetaldehyde production process at 200°C since …

Engine Oil Change Lead Time Reduction Of Commercial Vehicle Service Center In Thailand, Sufee Datoh

Chulalongkorn University Theses and Dissertations (Chula ETD)

In the high competition, the service time is one of many important factors that some customers are likely to concern. This thesis would like to investigate the root causes of the unnecessary activities in a selected authorised service centre which can be improved overall service lead time especially engine oil changing service and light commercial vehicles only (Pick-up and SUV) and to be a prototype improvement plan to suggest other authorised service centres in Thailand in the future. The procedure of engine oil change service can be grouped into 3 phases including the pre-checking, maintenance and post-checking phase. The idea …

A Comparison Of Forecasting Methods For Rotable Spare Parts In A Thai Low-Cost Airline, Supannika Thummathid

Chulalongkorn University Theses and Dissertations (Chula ETD)

This research intents to compare and evaluate 3 different methods for forecasting irregular demand of aircraft spare parts by focusing on Rotable part group of Company A which is the leading low-cost airline in Thailand and operate by Airbus A320 model. Based on the demand classification, it is observed that most of the spare part demands presented an intermittent demand pattern. The forecasting methods Croston's, Holt's Linear and Multi-Layer Perceptron trained with Backpropagation of Neural Network Model are applied on the historical data of 36 Rotable spare parts by dividing into 2 sets which are initialization set period 60 months …

Esterification Of Ethanol And Lactic Acid With Wo3 On Montmorillonite Catalysts For Ethyl Lactate Production, Suthicha Mukjinda

Chulalongkorn University Theses and Dissertations (Chula ETD)

This research aims to study the characteristics, catalytic properties and stability of tungsten oxide (13.5 wt%) supported on montmorillonite (W/MMT) catalysts prepared by using three different calcination temperatures including 375 (W/MMT375), 475 (W/MMT475) and 575 (W/MMT 575) °C. All catalysts were examined in esterification of ethanol and lactic acid at 80 °C. Characterization studies showed that the W/MMT475 catalyst exhibited the highest acidity, followed by W/MMT375 and W/MMT575, respectively. However, from the surface area result, W/MMT375 exhibited the highest surface area, followed by W/MMT475 and W/MMT575, respectively. When all catalysts were tested in esterification of ethanol and lactic acid, it …

Real-Time Instance Segmentation And Point Cloud Extraction For Japanese Food Using Rgb-D Camera, Suthiwat Yarnchalothorn

Chulalongkorn University Theses and Dissertations (Chula ETD)

Innovation in technology is playing an important role in the development of food industry, as is indicated by the growing number of food review and food delivery applications. Similarly, it is expected that the process of producing and packaging food itself will become increasingly automated using a robotic system. The shift towards food automation would help ensure quality control of food products and improve production line efficiency. One key enabler for such automated system is the ability to detect and classify food object with great accuracy and speed. In this study, we explore real-time food object segmentation using RGB-D depth …

Proactive Customer Service Operations Development For An Automotive Tyre Service Centre, Suttida Wittayapichet

Chulalongkorn University Theses and Dissertations (Chula ETD)

The purpose of this research is to create new customer service model in fleet management for Company A which is the automotive tyre service centre due to change the company administration to be proactive management by developing relationship with customers. Also, the research focuses on customers in private companies, which are fleets of large vehicles, in order to maximize customer loyalty with the main customer group of company. Therefore, the design of this research used Business Model Canvas (BMC) to be the structure of the research and adapting Vendor Managed Inventory (VMI) concept to develop in the form of Vendor …

Novel Electrochemical Packed-Bed Reactor For Carbon Dioxide Reduction, Suwakul Chaiwarit

Chulalongkorn University Theses and Dissertations (Chula ETD)

Electrochemical reduction of carbon dioxide (CO2) is a promising strategy to recycle CO2 into valuable chemical products. Nevertheless, a conventional apparatus which usually utilizes stack design to maximize its surface-to-volume ratio requires many elements and complicated instruction assembly. The stack design often requires feed streams to flow in narrow channels throughout the cell, which is also constrained by membrane size roughly 1 m2 by current manufacture technology. This research focuses on development of a new type of electrochemical reactor that is suitable for industrial-scale applications. The novel electrochemical packed-bed reactor is designed for the electroreduction to covert CO2 into CO …

Effect Of Molecular Sieve Addition On Methanol Synthesis From Co2 And H2 Through Alcohol Assisted Method Over Cu/Zno Catalyst, Tanawut Boonamnuay

Chulalongkorn University Theses and Dissertations (Chula ETD)

Low-temperature methanol synthesis from CO2 and H2 was carried out using ethanol as catalytic solvent. The alcohol-assisted method reduced synthesis temperature and enhanced methanol yield (35.8%) at 150 oC (5.0 MPa, Cu/ZnO catalyst). However, ethyl acetate and water were generated as byproducts from the reaction. The byproducts formed azeotrope mixture with methanol and led to a complex product purification. Therefore, in this study, molecular sieves (MS) were introduced to adsorb the byproducts. The effect of different MS (3A and 5A) was studied. It was found that MS helped enhancing methanol yield. The highest methanol yield (42.6%) was obtained when adding …

Identifying, Analyzing, And Managing Challenges In Administering Construction Contracts Of Large Public Projects In Bhutan, Tandin Gyem

Chulalongkorn University Theses and Dissertations (Chula ETD)

Construction projects encompass three major phases: pre-construction, construction, and post-construction. Although various problems are inevitable in every phase, most of them occur during construction and can be mitigated by adopting a good construction contract for project management. A construction contract is a formal agreement between the project owner and the construction contractor. An important contract document is the conditions of contract (COC), which encompass the rules and regulations for administering the contract. In Bhutan, all public construction projects are mandated to follow the Bhutan Standard Bidding Documents for Procurement of Works 2019 and the form of General Conditions of Contract …

Med-Asa Smart Task-Volunteer Matching System, Taweesin Wongpinkaew

Chulalongkorn University Theses and Dissertations (Chula ETD)

In the context of healthcare, volunteers play an important role in improving the patient's experience and lowering the operational cost. However, the process which facilitate their management is reported to be problematic. In this thesis, the problems of the current system is explored, and a potential solution of a new IT system is outlined. The system was tested for a duration of 2 month during the COVID-19 outbreak in Thailand. SUS and an in-depth interview was conducted in order to gauge the usability and the effectiveness the system. The time it takes for the volunteers to go through with the …

Process Analysis And Economic Evaluation Of Acetaldehyde Production From Ethanol Via Non-Oxidative Dehydrogenation, Thanakarn Suthirojn

Chulalongkorn University Theses and Dissertations (Chula ETD)

At present, there is an awareness of global warming. The use of combustion fuel in cars is another cause of carbon dioxide emission which can caused global warming. As a result, electric vehicles (EV) have a greater role in the world Including Thailand, resulting in lower fuel consumption. For this reason, the demand for ethanol may decreased. Due to the higher price and wide range of applications, it is interesting to find alternatives to convert ethanol into acetaldehyde in this work. In this research, Aspen plus will be utilized for the process simulation and economic evaluation of two processes by …

Analysis Of Mass Transfer Coefficient Of Co2 Absorbed By Two-Component Amine Mixture In A Packed Bed Column, Thanakornkan Limlertchareonwanit

Chulalongkorn University Theses and Dissertations (Chula ETD)

Nowadays, coal fired plant has an important role in generating energy all over the world. It affects to greenhouse gases effect (GHGs) and global warming. Carbon dioxide (CO2) is a product of coal combustion that is the amount of number one in the world. However, most of the CO2 usually remove from post-combustion process by chemical absorption which is Monoethanolamine (MEA). Anyway, MEA has a disadvantage such as low CO2 loading and corrosion. Therefore, this study needs to investigate the effect of the mass transfer for a new solvents, 2-(Methylamino)ethanol (2-MAE) and Dimethylaminoethanol (DMAE), compensate for the drawbacks of MEA …

Synthesis Of Alkane From Lauric Acid Via Electrochemical Reaction In Microreactor, Thantip Kiattinirachara

Chulalongkorn University Theses and Dissertations (Chula ETD)

In the present work, decarboxylation of lauric acid to undecane was conducted by Kolbe electrochemical oxidation process in a microreactor. The microreactor is widely used to study reaction kinetics as well as reaction mechanisms because of negligible heat and mass transfer resistances within the reactor. The reactor is also very effective in the control of residence time. The 250-micron thick reactor was formed between graphite anode and stainless steel cathode sheets. Reactive alkyl radicals were produced from the supplied electrical potential and their combination with proton produced alkane with the release of carbon dioxide. The experiments were conducted to study …

Effect Of Cocatalyst Combination In Titanium-Based Ziegler-Natta Catalyst On Olefin Polymerization, Thanyaporn Pongchan

Chulalongkorn University Theses and Dissertations (Chula ETD)

This research focused on effect of cocatalyst types (TEA, TnOA, and TEA+TnOA) on titanium-based Ziegler-Natta catalyst in olefin polymerization both in slurry and gas-phase systems. This study has been divided into four sections. The commercial titanium-based catalyst was selected to investigate effect of reaction temperature and oxidation state of titanium from ESR measurement on slurry ethylene and propylene polymerization in the first and the second parts, respectively. The commercial catalyst with TEA exhibited the highest activity in ethylene polymerization. However, divalent, and trivalent of titanium (Ti2+ and Ti3+) was active in ethylene polymerization to produce more polymer. Stability of Ti3+ …

A Theoretical And Experimental Study Of Charge Transport In Organic Thermoelectric Materials And Charge Transfer States In Organic Photovoltaics, Ashkan Abtahi

Theses and Dissertations--Physics and Astronomy

Applications of organic electronics have increased significantly over the past two decades. Organic semiconductors (OSC) can be used in mechanically flexible devices with potentially lower cost of fabrication than their inorganic counterparts, yet in many cases organic semiconductor-based devices suffer from lower performance and stability. Investigating the doping mechanism, charge transport, and charge transfer in such materials will allow us to address the parameters that limit performance and potentially resolve them. In this dissertation, organic materials are used in three different device structures to investigate charge transport and charge transfer. Chemically doped π-conjugated polymers are promising materials to be used …

Higher Tensile Forces Across Cellular Junctions And An Intact Nuclear Linc Complex Is Required For Epithelial Function And Stability, Fnu Vani Narayanan

Theses and Dissertations

Recent advances in three-dimensional (3D) cell culture systems have provided key insights into the understanding of biochemical and physiological states of native tissue. A significant progress in the field of mechanobiology involves measuring cellular traction forces in a more native 3D environment. However, the effects of mechanical forces exerted across cellular junctions and the nuclear LINC complex, in an organized 3D system has not been investigated thus far. Epithelial cells spontaneously form acini (also known as cysts or spheroids) with a single, fluid-filled central lumen, when grown in 3D matrices. The size of the lumen is dependent on apical secretion …

Beneficiation Of Coal Using Supercritical Water And Carbon Dioxide Extraction, Matthew Decuir Virginia Commonwealth University Cl

Theses and Dissertations

This work explores the use of carbon dioxide, water, and their mixtures as solvent for the pre-combustion beneficiation of raw coal without using any toxic mineral acids in the temperature range of 200-400℃. The fluid polarity, ionic constant, and supercritical point can be adjusted by H₂O/CO₂ ratio and temperature. Adding carbon dioxide to hydrothermal fluid also increases the ionization by forming carbonic acid. Extractions with supercritical fluids have several benefits including enhanced mass transport, ease of separation and recycle, wide range of extractive capability and tunability, better inherent safety, and in the case of carbon dioxide and …

Data Science Methods For Standardization, Safety, And Quality Assurance In Radiation Oncology, Khajamoinuddin Syed

Theses and Dissertations

Radiation oncology is the field of medicine that deals with treating cancer patients through ionizing radiation. The clinical modality or technique used to treat the cancer patients in the radiation oncology domain is referred to as radiation therapy. Radiation therapy aims to deliver precisely measured dose irradiation to a defined tumor volume (target) with as minimal damage as possible to surrounding healthy tissue (organs-at-risk), resulting in eradication of the tumor, high quality of life, and prolongation of survival. A typical radiotherapy process requires the use of different clinical systems at various stages of the workflow. The data generated in these …

Self-Assembled Metal Nanoparticle/Polymer Nanocomposites As Nanoreactors For One-Pot Reactions, Andrew Harrison

Theses and Dissertations

Polymer nanoreactors incorporating gold nanoparticle catalysts were self-assembled via Flash Nanoprecipitation. The incorporated gold nanoparticles maintained catalytic activity, which was evaluated using reduction of 4-nitrophenol with sodium borohydride as a model reaction. The diffusion coefficient for 4-nitrophenol was determined by NMR and used to calculate the second Damköhler number, which indicated that the systems were not diffusion limited. Despite similar diffusion coefficients, catalytic performance was strongly affected by the co-precipitant. For example, the apparent reaction rate per surface area using castor oil was over 8-fold greater than polystyrene. Thus, we measured the partition coefficient of 4-nitrophenol between water and castor …

Evaluation Of 1-D And 2-D Hydraulic Models For Designing And Assessing Fullspan Stream Crossings, Alyssa Sachiko Virgil

Cal Poly Humboldt theses and projects

This project compared design decisions and hydraulic analyses of full-span stream crossings using one- and two-dimensional (1-D and 2-D) hydraulic models. The project was initiated by the California Department of Transportation’s interest in moving from 1-D to 2-D hydraulic modeling and by the Federal Highways Administration’s support for adopting SRH-2D (Sedimentation and River Hydraulics-2D developed by the US Bureau of Reclamation) in Aquaveo, LLC’s Surface-water Modeling System as their standard design model. Two-dimensional hydraulic models calculate more detailed water depths and velocities than 1-D models, which can better identify fish passage conditions, areas of potential scour or deposition, and aquatic …

A Comparison Of Zinc Levels In Runoff From Rubberized Hot Mix Asphalt And Conventional Pavement, Peter A. Duin

Cal Poly Humboldt theses and projects

High levels of dissolved zinc in water bodies can be toxic to aquatic organisms. There are currently over 40 waterways in California that have on occasion been in exceedance of Clean Water Act minimum toxicity threshold standards for zinc. Recycled tires that contain 1-2% zinc by mass are commonly used in California paving formulations known as Rubberized Hot Mix Asphalt (RHMA). The addition of tires to RHMA increases the zinc content of the pavement in comparison to conventional HMA. This research assesses the zinc content and leaching rate of RHMA in field and laboratory settings to estimate its contribution of …

Accounting For The Local Field When Determining The Dielectric Loss Spectra Of Metals In The Region Of The Frequencies Of Volume, Surface And Localized Plasmon Oscillations, Tatiana Perova, Igor Shaganove, Kevin Berwick

Articles

The optical constant of bulk metal is used to determine the dispersion of the local field under one-dimensional (1D), two-dimensional (2D) and three-dimensional (3D) confinement. 3D confinement, expressed as ε mic 2 (ω3D), corresponds to the dielectric loss spectra of spherical particles with a diameter, d, much less than the wavelength of the beam used to measure the spectrum (d << λ). Excellent agreement with the results of Mie theory and experimental data for solid colloids within alkali halide crystals was observed. The function expressed as ε mic 2 (ω1D) allows the measurement of spectral micro-characteristics in the frequency range of the longitudinal collective motion of the free electrons. This corresponds to the spectrum of dielectric losses of bulk plasma oscillations. The function ε mic 2 (ω2D) describes the spectra of the dielectric losses of surface plasma oscillations in thin metal films. It is shown that the peak positions of ε mic 2 (ω3D), ε mic 2 (ω2D) and ε mic 2 (ω1D) spectra for simple metals, viz. alkali metals as well as Al, Be, Mg, Ga, In, Sn and Si, are in agreement with experimental results from electron-energy-loss spectroscopy and various optical techniques.

The Effect Of High Background And Dead Time Of An Ingaas/Inp Single-Photon Avalanche Photodiode On The Registration Of Microsecond Range Near-Infrared Luminescence, P. S. Parfenov, A. P. Litvin, D. A. Onishchuk, K. A. Gonchar, Kevin Berwick, A. V. Fedorov, A. V. Baranov

Articles

The effects of a high background count and a microsecond dead time interval on a gated InGaAs/InP single-photon avalanche photodiode (SPAD) during microsecond luminescence decay registration are discussed. It is shown that the background count rate of the SPAD limits its use for time-resolved and steady-spectral measurements, and that a “pile-up” effect appears in the microsecond range.

3.8 Mm Thick Aluminum 5754-O Friction Stir Weld Data, Johnathon Hunt, Yuri Hovanski, Brian A. Mazzeo, Carl Sorensen

ScholarsArchive Data

The data sets that are included are the following:

1) Raw measured data for 30 friction stir welds made from 5754-O aluminum alloy. (matlab .m file)

2) Radiographic images of the same welds.

(.tiff images)

3) Cross sectional images at certain location from some of the welds

(.jpeg)

4) An excel spread sheet that has a key to the data

Deep Uv Fluorescence Scanning Microscopy For Breast Tumor Margin Detection, Tongtong Lu, Julie M. Jorns, Mollie Patton, Renee Fisher, Amanda Emmrich, Todd Doehring, Taly Gilat-Schmidt, Dong Hye Ye, Tina Yen, Bing Yu

Biomedical Engineering Faculty Research and Publications

Breast cancer is the most commonly diagnosed cancer among women. Positive margin status after breast-conserving surgery (BCS) is a predictor of higher rates of local recurrence. Intraoperative margin detection helps to complete tumor excision at the first operation. A margin tool that is capable of imaging all six margins of large lumpectomy specimens with both high resolution and fast speed (within 20 min) is yet to be developed. Deep UV light allows simultaneous excitation of multiple fluorophores and generating surface fluorescence images. We have developed a deep UV fluorescence scanning microscope (DUV-FSM) for slide-free, high-resolution and rapid examination of tumor …

Arising: Hurricane (Superstorm) Sandy’S Impact On Design/Planning Professionals, Maxinne R. Leighton

Antioch University Dissertations & Theses

Standing by my bedroom window, looking out at the ocean, a huge wave comes and swallows up my building. Everything around me is gone, including me. I wake up. I am 13 years old and living in the Coney Island Houses on Surf Avenue, Brooklyn, New York. With ongoing anthropogenic changes to the natural environment such as sea level rise and intensifying storms, coastal communities, especially ones segregated by class and culture, are particularly vulnerable in this context that challenges a way of life, and in some instances, threatens that life's survival. This dissertation focuses specifically on what one massive …

Using Ai And Machine Learning To Indicate Shale Anisotropy And Assist In Completions Design, Cole E. Palmer

Graduate Theses, Dissertations, and Problem Reports (ETD)

Operating companies in the unconventional Marcellus shale play have all faced a similar and problematic issue, while attempting to produce natural gas over the last decade. Companies have quickly realized that not every perforation along their horizontal wells are producing gas. In fact, producing perforations are only ranging from 15%-70% of the total perforations along the horizontal wellbore [1]. This unexplained issue results in millions of dollars in lost revenue per well, in addition to the sunk cost of paying for completions that are not actually yielding any produced gas.

What is causing these perforations to have no produced gas? …

Dose Deposition And Electrostatic Charging Of Kapton Films Irradiated With Electrons, Youssef Abouhussien, Gennady Miloshevsky

Graduate Research Posters

Kapton films are widely utilized in harsh radiation environments where radiation resistant insulating materials are required. For space applications, Kapton polymers are used on satellites as substrates for solar arrays and outer layers of thermal systems. Kapton is also used in nuclear power plants as wire insulation. Kapton materials can be exposed in nuclear reactors to a reactive chemical environment in addition to severe radiation. It is of utmost important to understand how Kapton materials behave under high irradiation conditions and mitigate radiation damage effects. High-energy electrons can deposit ionizing dose and electric charge deeply inside Kapton materials. The charge …

Jxb Force Effects On Beryllium Melt Splashing In Fusion Devices, Cheng Zhang, Gennady Miloshevsky

Graduate Research Posters

Instability and disruption of high-temperature plasma in fusion devices may result in the edge-localized modes (ELMs) and lead to melting of plasma facing components (PFCs) causing their damage. Beryllium (Be) is used as a first wall for PFCs due to its low density, high strength, and high thermal conductivity. However, melting of Be on the surface of first wall is of a great concern as splashing of a molten Be layer will result in the plasma contamination and termination of fusion reaction. Therefore, it is important to understand the physics mechanisms characterizing the splashing of Be from a pool under …