Engineering Commons^™

Generalization Of Polynomial Chaos For Estimation Of Angular Random Variables, Christine Louise Schmid

Doctoral Dissertations

“The state of a dynamical system will rarely be known perfectly, requiring the variable elements in the state to become random variables. More accurate estimation of the uncertainty in the random variable results in a better understanding of how the random variable will behave at future points in time. Many methods exist for representing a random variable within a system including a polynomial chaos expansion (PCE), which expresses a random variable as a linear combination of basis polynomials.

Polynomial chaos expansions have been studied at length for the joint estimation of states that are purely translational (i.e. described in Cartesian …

Applications Of Information Theory In Filtering And Sensor Management, Matthew James Gualdoni

Doctoral Dissertations

“A classical sensor tasking methodology is analyzed in the context of generating sensor schedules for monitoring resident space objects (RSOs). This approach, namely maximizing the expected Kullback-Leibler divergence in a measurement update, is evaluated from a probabilistic perspective to determine the accuracy of the conventional approach. In this investigation, a newdivergence-based approach is proposed to circumvent themyopic nature of the measure, forecasting the potential information contribution to a time of interest and leveraging the system dynamics and measurement model to do so. The forecasted objective exploits properties of a batch measurement update to frequently exhibit faster optimization times when compared …

Accurate Modeling Techniques For Power Delivery, Jingdong Sun

Doctoral Dissertations

“Power delivery is essential in electronic systems to provide reliable power from voltage sources to load devices. Driven by the ambitious user demands and technology evolutions, the power delivery design is posed serious challenges. In this work, we focus on modeling two types of power delivery paths: the power distribution network (PDN) and the wireless power transfer (WPT) system.

For the modeling of PDN, a novel pattern-based analytical method is proposed for PCB-level PDN impedance calculations, which constructs an equivalent circuit with one-to-one correspondences to the PCB’s physical structure. A practical modeling methodology is also introduced to optimize the PDN …

Integrated Approach To Investigate The Wellbore Integrity Under Downhole Conditions, Weicheng Zhang

Doctoral Dissertations

“The integrity of the cement sheath is the key part to maintain zonal isolation and prevent the inter-zonal communication. Loads arising from multiple stages of wellbore life span may induce various modes of cement failure within the cement (disking and radial cracks) and at the cement-casing and the cement-formation interfaces (debonding fractures). This research utilizes the integrated laboratory and numerical approach to investigate the cement hardening process, to predict the cement failure under various loading conditions. An innovative experimental setup is established to measure the cement pore pressure variation during the hardening process under downhole conditions, and a staged 3D …

Bond Behavior Of Advanced Fiber Reinforced Composite-Concrete Joints, Xingxing Zou

Doctoral Dissertations

“Externally bonding advanced composite materials to concrete structures is an effective way to improve their strength, ductility, and durability. The interfacial bond behavior is fundamental to understand the overall structural performance of concrete structures strengthened with advanced composite materials. This study includes a comprehensive investigation of the bond behavior of composite-concrete joints with different fiber reinforced composite types. First, a direct approach to determine the bond-slip relationship for fiber reinforced cementitious matrix (FRCM)-concrete joints based on fiber strain measurements was proposed. Then, an analytical solution to predict the full-range response of FRCM-concrete joints was derived by assuming a trilinear bond-slip …

Development Of A Modeling Algorithm To Predict Lean Implementation Success, Richard Charles Barclay

Doctoral Dissertations

”Lean has become a common term and goal in organizations throughout the world. The approach of eliminating waste and continuous improvement may seem simple on the surface but can be more complex when it comes to implementation. Some firms implement lean with great success, getting complete organizational buy-in and realizing the efficiencies foundational to lean. Other organizations struggle to implement lean. Never able to get the buy-in or traction needed to really institute the sort of cultural change that is often needed to implement change. It would be beneficial to have a tool that organizations could use to assess their …

An Emi Characterization And Modeling Study For Consumer Electronics And Integrated Circuits, Chunyu Wu

Doctoral Dissertations

“As internet-of-things (IoT) applications surge, wireless connectivity becomes an essential part of the network. Smart home, one of the most promising application scenarios of IoT, will improve our life quality enormously. However, electromagnetic interference (EMI) to the receiving antenna, either from another electronic product or from a module/an integrated circuit(IC) inside the same wireless device, will degrade the performance of wireless connectivity, thus influencing the user experience. Characterization and modeling of the EMI become increasingly important.

In the first part, an improved method to extract equivalent dipoles from magnitude- only electromagnetic-field data based on the genetic algorithm and back-and-forth iteration …

Enabling Flexibility Through Strategic Management Of Complex Engineering Systems, Walter Louis Barnes Ii

Doctoral Dissertations

”Flexibility is a highly desired attribute of many systems operating in changing or uncertain conditions. It is a common theme in complex systems to identify where flexibility is generated within a system and how to model the processes needed to maintain and sustain flexibility. The key research question that is addressed is: how do we create a new definition of workforce flexibility within a human-technology-artificial intelligence environment?

Workforce flexibility is the management of organizational labor capacities and capabilities in operational environments using a broad and diffuse set of tools and approaches to mitigate system imbalances caused by uncertainties or changes. …

Development Of Radiation Transport Techniques For Modelling A High-Resolution Multi-Energy Photon Emission Tomography System, Seth Kilby

Doctoral Dissertations

”Nondestructive characterization techniques such as gamma tomography represent powerful tools for the analysis and quantification of physical defects and radionuclide concentrations within nuclear fuel forms. Gamma emission tomography, in particular, has the ability to utilize the inherent radiation within spent nuclear fuel to provide users with information about the migration and concentration of fission and activation products within the fuel form. Idaho National Laboratory is interested in using this technology to analyze new nuclear fuel forms for potential use in next generation nuclear reactors. In this work, two aspect of the system are analyzed. The first is a semi-analytic radiation …

Removal Of Non-Metallic Inclusions From Molten Steel By Ceramic Foam Filtration, Soumava Chakraborty

Doctoral Dissertations

”Ceramic filters are routinely used in steel foundries to remove non-metallic inclusions from steel melt. Removal efficiency for both solid and liquid inclusions by magnesia-stabilized zirconia foam filters (10ppi) were evaluated and distribution of the captured inclusions through the filter thickness was also investigated. A mold design was developed using a commercial computational fluid dynamics software package to produce two castings that fill simultaneously, one with a filter and the other without a filter, from a single ladle pour, while also matching the fill rates and avoid turbulence and reoxidation during pouring. An industrial-scale experiment was also performed to investigate …

The Development Of A Project Typology And Selection Tool To Improve Decision-Making In Sustainable Projects, Rakan Alyamani

Doctoral Dissertations

"Decision-making in sustainable projects is a complex and challenging process, especially during the initiating and planning phases of project development, due to influence from several external factors, as well as the uncertain environments surrounding their creation. It is essential to improve the decision-making process in sustainable projects during these two phases by relying on strong decision-making tools. The first contribution in this work identifies gaps in the literature of how institutionalization can impact sustainable projects through the effects of institutional isomorphisms from institutional theory. This helps decision makers better understand the relationship between institutionalization and sustainable projects. The second contribution …

Studying The Effects Of Various Process Parameters On Early Age Hydration Of Single- And Multi-Phase Cementitious Systems, Rachel Cook

Doctoral Dissertations

”The hydration of multi-phase ordinary Portland cement (OPC) and its pure phase derivatives, such as tricalcium silicate (C₃S) and belite (ß-C₂S), are studied in the context varying process parameters -- for instance, variable water content, water activity, superplasticizer structure and dose, and mineral additive type and particle size. These parameters are studied by means of physical experiments and numerical/computational techniques, such as: thermodynamic estimations; numerical kinetic-based modelling; and artificial intelligence techniques like machine learning (ML) models. In the past decade, numerical kinetic modeling has greatly improved in terms of fitting experimental, isothermal calorimetry to kinetic-based modelling …

Investigation On Nanoparticle Based Combination Therapy For Targeted Cancer Treatment, Muhammad Raisul Abedin

Doctoral Dissertations

“The current treatment methods in cancer are associated with toxicity in healthy tissues, partial therapeutic response, drug resistance and finally recurrence of the disease. The cancer drugs are challenged by non-specific binding, undesired toxicity in healthy cells, low therapeutic index and finally poor therapeutic outcome. In this work, a targeted nanoscale therapeutic system Antibody Drug Nanoparticle (ADN) was engineered to selectively inhibit the breast cancer cell growth with reduced toxicity in healthy cells. The ADNs were designed by synthesizing rod shaped anoparticles using pure chemotherapeutic drug and covalently conjugating a therapeutic monoclonal antibody (mAb) on the surface of the drug …

Critical Success Factors And Risk Mitigation Strategy For New Product Development, Rodney A. Ewing

Doctoral Dissertations

”Success in new product development (NPD) offers a competitive and comparative advantage in the marketplace. A primary objective in an NPD project is to launch world class products with minimal risk. To deliver the superior quality and performance customers require, a company must develop the right NPD structure and framework for seamless execution by the NPD project teams throughout the product lifecycle. Companies must understand how to identify and mitigate risk to enable the success of their NPD projects. The costs to develop new products are often a considerable portion of an organization’s budget; however, studies have shown only 60 …

Process Intensification Of Fuel Synthesis And Electrolysis, Jeremy Lee Hartvigsen

Doctoral Dissertations

”As more renewable energy is added to the electric grid, energy storage becomes a high priority. Suggestions have been made for energy storage in the form of fuel and chemicals. Currently, Solid Oxide Electrolysis systems can operate in endothermic mode and reduce the electrical requirement by supplying heat. Fuel synthesis from syngas is exothermic and can supply heat. However, the temperature mismatch in the normal operation of the electrolysis step and fuel synthesis step makes the direct utilization of this heat impossible. This work explores possibilities of alternate arrangements of coupling electrochemical systems and chemical synthesis. This work also explores …

Strategies To Improve The Electrochemical Performance Of Lithium-Ion Batteries By Stabilizing The Interface Of Electrode/Electrolyte, Ye Jin

Doctoral Dissertations

”Lithium-ion batteries (LIBs) provide great potential for electric vehicles, and smart grids as future energy-storage devices. However, there are many challenges in the development of the LIB industry, including low energy and power density of electrode materials, poor rate performance, short cycle life of electrode materials, and safety issues caused by the flammability of the conventional organic liquid electrolytes.

In this research, we were committed to using general approach to efficiently and economically synthesize or modify LIB materials by stabilizing the interface between electrode and electrolyte. Atomic layer deposition (ALD) method was used to coat metal oxide thin films on …

Improved Attenuation And Crosstalk Modeling Techniques For High-Speed Channels, Shaohui Yong

Doctoral Dissertations

”As digital systems are moving in the direction of faster data transmission rate and higher density of circuits, the problem of the far-end crosstalk (FEXT) and frequency-dependent attenuation are becoming the major factors that limit signal integrity performance. This research is focusing on providing several more comprehensive and accurate modeling approaches for striplines on fabricated printed circuit board (PCB). By characterizing the dielectric permittivity of prepreg and core, dielectric loss tangent, and copper foil surface roughness using measurement data, a better agreement between the stripline model and measurement is achieved. First, a method is proposed to extract dielectric loss tangent …

Catalytic Utilization Of Carbon Dioxide As Renewable Feedstock For Production Of Chemicals And Fuels, Abbas Alaa Jawad

Doctoral Dissertations

"The utilization of CO₂ as a renewable feedstock for producing commodity chemicals and fuels is an interesting challenge to explore new concepts and opportunities in catalysis and industrial chemistry. This sustainable approach not only leads to production of useful chemicals, but also has the potential to mitigate anthropogenic CO₂ emissions to the atmosphere. CO₂ itself is a sustainable and inexhaustibly available carbon source, however, it is inextricably linked to its inherent inertness. It is a thermodynamically stable molecule (ΔG_f = -394.01 kJ.mol^-1) with high oxidation state, hence, reactions of CO₂ must be combined …

Geophysical Characteristics Of Nickel And Copper Deposits In Wadi Al Khadra Prospect, Southwestern Of Saudi Arabia, Abdulrahman Ahmed Aljabbab

Doctoral Dissertations

“Three geophysical datasets (self-potential, magnetics, and time - domain electromagnetics) were acquired at Wadi Al Khadra Ni-Cu prospect in southwest Saudi Arabia, and were processed and interpreted for the Saudi Geological Survey. The primary objectives were to map the distribution of metallic mineralization, map structures, verify the integration of the geophysical interpretations and its signatures in conjunction with boreholes information, distinguish the similarities and differences in the integrated interpretation of geophysical data, and design optimal processing and interpretation data parameters. The self-potential tool was used to map the variation in natural surface potential differences to map lateral variations in the …

Continuous-Flow Synthesis Of Fine Chemicals And Pharmaceutical Compounds Over Intelligent Organocatalysts With Bifunctional Reactivity, Abdo-Alslam Alwakwak

Doctoral Dissertations

“Many biological systems that utilize organic active sites to catalyze reactions under mild conditions invoke cooperative catalytic pathways, whereby two or more active sites work together to activate the reactant(s). The use of cooperative (bifunctional) catalysts and continuous flow chemistry (a reaction within the narrow channels of a micro‐ or microfluidic reactor) are commonplace in sustainable chemical transformation and attract a great deal of interest with respect to economic and environmentally-sustainable production of fine chemicals, pharmaceuticals, and agrochemicals, water treatment, as well as upgrading of biomass feedstocks. Although, some methods have been developed for immobilization of bifunctional catalysts for cooperative …

Application Of Geophysics And Remote Sensing Techniques For Economic Mineral Exploitation In Libya, Awad Abdussalam Henish Lemnifi

Doctoral Dissertations

“This study investigates crustal thickness and properties within the north central Africa region. Results obtained from 15 seismic stations belonging to the Libyan Center for Remote Sensing and Space Science are reported, in addition to 3 seismic stations publically available, using receiver functions, the first P-to-S receiver function investigation of the 410 km and 660 km depth discontinuities bounding the mantle transition zone (MTZ), and P wave tomography methods. The results from the first method show crustal thicknesses ranging from 24 km to 36 km (with uncertainties ranging between ±0.10 km and ±0.90 km). More specifically, crustal thickness ranges from …

Transition Metal Chalcogenide Hybrid Systems As Catalysts For Energy Conversion And Biosensing, Siddesh Umapathi

Doctoral Dissertations

"Generation of hydrogen and oxygen through catalyst-aided water splitting which has immense applications in metal air batteries, PEM fuel cells and solar to fuel energy production, has been one of the critical topics in recent times. The state of art oxygen evolution reaction (OER), oxygen reduction reaction (ORR), hydrogen evolution reaction (HER) catalysts are mostly comprised of precious metals. The current challenge lies in replacing these precious metal-based catalysts with non-precious earth-abundant materials without compromising catalytic efficiency.

This research explores mixed metal selenides containing Fe-Ni, Fe-Co and RhSe which were hydrothermally synthesized and/or electrodeposited and tested for OER and ORR …

Behavior Of Negative Stiffness Metamaterial Systems In Structural Engineering Applications, Yasser Darwish

Doctoral Dissertations

“Metamaterial systems with negative stiffness behavior became a point of interest in many energy dissipation applications due to their ability to dissipate high levels of energy. Negative stiffness metamaterial elements can dissipate energy through non-linear elastic behavior when transferred from one stable mode of buckling to another. Hence, the ability of such elements to be reusable for multiple loading cycles exists. Such unique properties made the metamaterial systems a perfect candidate for structural applications such as impact protection of bridges against collision. This research provides innovative metamaterial shell structure that can exhibit negative stiffness behavior by deforming from one shape …

Minimizing The Negative Effect Of Pumping On Scc Freeze-Thaw Durability, Daniel Galvez-Moreno

Doctoral Dissertations

“The durability of concrete must be ensured to reduce the carbon footprint of the production of portland cement. If concrete is properly designed to preserve its integrity under adverse exposure conditions, the service life of the material can be extended with minimum maintenance. Nevertheless, bad handling, placing, finishing or curing practices can abate the durability potential and service life of even the best mix design. Pumping concrete is a very efficient placing technique that offers significant cost reduction and versatility at the jobsite, but it also has the potential of altering the air void system parameters, which are key to …

Enhanced Electrochemical Performance Of Li-Ion Battery Cathodes By Atomic Layer Deposition, Yan Gao

Doctoral Dissertations

”Li-ion battery now plays an irreplaceable role in supplying green and convenient energy. In this work, atomic layer deposition (ALD) was used to modify Li-ion battery cathode particles for performance enhancement.

An ultrathin and conductive CeO₂ ALD film was deposited on Li-rich layered cathode particles, of which the specific capacity and cyclic stability were significantly improved. On the same cathode particles, FeO_x ALD and post-annealing resulted in a stable and conductive surface spinel phase to improve the performance.

Synergetic TiN coating and Ti doping were performed on a LiFePO₄ (LFP) cathode and extended its cycle life. The …

Complexities Observed During The Development Of A Rheological Testing Procedure For Small Cement Paste Samples, Aida Margarita Ley-Hernandez

Doctoral Dissertations

“Rheology has been widely used to describe the flow properties of fresh cement-based suspensions. The use of a rheometer to characterize these properties is not a straightforward task due to the dependency to different preparation conditions, mixing processes, testing procedures and measuring instruments employed. In addition, shear and time dependency of the material which undergoes chemical and physical particle bonding, caused by hydration of cement and flocculation. Nevertheless, the characterization and understanding of the rheological behavior of cement-based materials have become essential with the recent introduction of novel applications like digital construction in the field of civil engineering, among others. …

Structured Catalysts Designed And Manufactured By 3d-Printing Technique For Functional Integration Of Catalytic Systems, Fatima Magzoub

Doctoral Dissertations

"Microporous zeolites are widely used as heterogeneous catalysts in a wide variety of chemical and petrochemical industries to produce value-added chemicals and fuels, owing to their large surface area, acid-base properties, high thermal stability, and excellent shape-selectivity.

The overall goal of this research was to shape engineer composite zeolites and fine-tune their physiochemical properties to improve the catalytic production of dimethyl ether (DME) and light olefins that are typically used as substitution to diesel fuel and polymer precursors, respectively. Specifically, HZSM-5 and silicalite-1 zeolites were formulated into monolithic contactors using 3D printing technique, followed by subsequent SAPO-34 crystals growth through …

Forming And Processing Of Advanced Fiber Reinforced Polymer Composites, Robert Meinders

Doctoral Dissertations

“Composite materials are commonly used in industry to manufacture strong and lightweight structures. Composites feature a large degree of flexibility in materials selection and manufacturing processes to tailor the strength of manufactured parts. This study examines different manufacturing aspects of composites. In Part I, the fabrication of composite parts using the compression forming process is examined. During compression forming, metal dies are used to apply large deformations to prepreg material to fabricate composite parts. The high stresses and deformations of this process can yield manufacturing defects. T650/5320-1 prepreg is subjected to material characterization to develop simulations of large deformation forming …

Optimal Adaptive Control Of Time-Delay Dynamical Systems With Known And Uncertain Dynamics, Rohollah Moghadam

Doctoral Dissertations

"Delays are found in many industrial pneumatic and hydraulic systems, and as a result, the performance of the overall closed-loop system deteriorates unless they are explicitly accounted. It is also possible that the dynamics of such systems are uncertain. On the other hand, optimal control of time-delay systems in the presence of known and uncertain dynamics by using state and output feedback is of paramount importance. Therefore, in this research, a suite of novel optimal adaptive control (OAC) techniques are undertaken for linear and nonlinear continuous time-delay systems in the presence of uncertain system dynamics using state and/or output feedback. …

Additive Manufacturing Of Customized Lithium-Ion Batteries: Process Fundamentals And Applications, Xiaowei Yu

Doctoral Dissertations

“In the pasting decades, considerable efforts have been spent in developing the next-generation lithium-ion batteries (LIBs), from advanced active materials to new manufacturing methods. The development of additive manufacturing (AM) has brought new opportunities to LIBs. In this work, two AM methods are introduced for fabricating electrodes of LIBs. The first method is aerosol printing, which is a solvent-based wet additive method. Whereas the second method is a solvent-free, dry printing method. The commonly used materials for current collectors and active materials (including cathodes and anodes) of LIBs are aerosol printed and the electrochemical functionalities of the printed materials are …