Engineering Commons^™

Investigation Of Cation Exchange Behaviors Of FaXMa1-XPbl3 Films Using Dynamic Spin Coating, Hyang Mi Yu, Byeong Geun Jeong, Dae Young Park, Seong Chu Lim, Gon Namkoong, Mun Seok Jeong

Applied Research Center Publications

In this study, we fabricated and characterized uniform multi-cation perovskite FA_xMA_1−xPbI₃ films. We used the dynamic spin-coating method to control the cation ratio of the film by gradually increasing the FA+, which replaced the MA+ in the films. When the FA+ concentration was lower than xFA ~0.415 in the films, the stability of the multi-cation perovskite improved. Above this concentration, the film exhibited δ-phase FAPbI₃ in the FA_xMA_1−xPbI₃ films. The formation of δ-phase FAPbI₃ disturbed the homogeneity of the photoluminescence spatial distribution and suppressed the absorption spectral bandwidth …

Effect Of Hydrogen Co-Feeding On Ethylene Polymerization With Ziegler-Natta Catalysts With Different Amounts Of Titanium, Santhakamol Kittibanpacha

Chulalongkorn University Theses and Dissertations (Chula ETD)

Effect of hydrogen on the prepared TiCl4-MgCl2 catalysts having loading amounts of titanium was investigated via ethylene homopolymerization and ethylene/1-hexene copolymerization in slurry polymerization process. First, the catalysts were prepared to obtain different Ti loadings from 4.4 to 6.5 wt%. Then, all catalysts were characterized and tested in ethylene homopolymerization and ethylene/1-hexene copolymerization in the presence and absence of hydrogen during polymerization. It was found that hydrogen enhanced the catalyst activities on the catalyst with high Ti content (6.5 wt%) for 2.6 times and 1.9 times for ethylene homopolymerization and ethylene/1-hexene copolymerization, whereas it decreased the activity of the catalyst …

Simulation Of Flexural Performance Of Mill-Cut Steel Fiber Reinforced Concrete Beam Degraded By Mild Corrosion, Minh Khanh Vo

Chulalongkorn University Theses and Dissertations (Chula ETD)

The reinforced concrete structure is widely used for various applications structure due to its many advantages, so it is easily exposed to severe environments and corrosion of steel occurred shortening the life durable of the structure which may cause danger to humans and economic damage. Corrosion occurred as a significant factor leading to the further deterioration of performance and reduction of the loading resistance of reinforced concrete structures. Therefore, durable corroded structures should be dealt with to ensure user safety. In recent decades, steel fiber reinforced concrete is studied and applied cause of provides better durability. Nevertheless, there is a …

Surface Enhanced Raman Spectroscopy Analysis Of Thin-Smear-Contamination On Hdd Read-Write Head, Charin Seesomdee

Chulalongkorn University Theses and Dissertations (Chula ETD)

Surface-enhanced Raman spectroscopy (SERS) is one of the most powerful analytical techniques for the identification of molecules in microelectronics industry for failure analysis protocol. In this work, a dry-processed gold nanoclusters were prepared by magnetron sputtering deposition to promote the enhancement of the Raman signal for the best intensity gain from selected common polymers found in hard disk drive as surface contamination. The optimized sputtering conditions was applied for SERS on polycarbonate (PC), polyethylene terephthalate (PET), polypropylene (PP), and high-density polyethylene (HDPE). The Raman spectrum showed the average Raman signal intensity gain at about 114%, 78%, 254%, and 226% respectively. …

Communities Of Nitrifying Microorganisms From Recirculating Aquaculture Systems (Rass) Under Different Ammonium Concentration And Salinity, Preeyaporn Pornkulwat

Chulalongkorn University Theses and Dissertations (Chula ETD)

Bioaugmentation of nitrifying cultures can accelerate nitrification during startup and transition periods of recirculating aquaculture systems (RASs) operations. To formulate nitrifying cultures for RASs, impacts of ammonia and salinity (NaCl) on culturing nitrifying microorganisms were comprehensively investigated by including currently known groups of nitrifying microorganisms (ammonia-oxidizing archaea (AOA), ammonia oxidizing bacteria (AOB), comammox, Nitrospira, and Nitrobacter). Initially, community structure of nitrifying microorganisms was observed in biofilters from water recirculation units of shrimp holding tanks operated at two different salinities of 2 and 15 g/L. Unique patterns of nitrifying communities consisting of AOA, comammox, and Nitrospira (without AOB and Nitrobacter) were …

การจัดสมดุลสายการประกอบผลิตภัณฑ์ผสมแบบขนานหลายวัตถุประสงค์ที่ทำงานโดยคนงานและหุ่นยนต์, สุพิชชา งามพานิช

Chulalongkorn University Theses and Dissertations (Chula ETD)

ในงานวิจัยนี้ได้เสนอวิธีแก้ปัญหาของการจัดสมดุลสายการประกอบผลิตภัณฑ์ผสมลักษณะขนาน ที่มีการดำเดินงานการประกอบผลิตภัณฑ์โดยหุ่นยนต์, คนงาน และคนงานผู้พิการ สำหรับสายการประกอบแบบขนาน เป็นระบบการประกอบที่ประกอบด้วยสายการประกอบเส้นตรงตั้งแต่ 2 สายการประกอบขึ้นไป ถูกนำมาจัดเรียงในแนวขนานกัน มีข้อดีคือ ทำให้สามารถลดรอบเวลาของสายการประกอบลงได้ โดยเฉพาะอย่างยิ่งในกรณีที่เวลาดำเนินงานของบางขั้นงานมีค่าสูงกว่ารอบเวลาที่ต้องการของสายการประกอบ ในงานวิจัยนี้มีวัตถุประสงค์ในการแก้ปัญหาของจัดสมดุลสายการประกอบ 5 วัตถุประสงค์ ได้แก่ 1) ประสิทธิภาพของสายการประกอบมากที่สุด 2) ปริมาณการปล่อยฝุ่น PM2.5 จากหุ่นยนต์เฉลี่ยมีค่าน้อยที่สุด 3) ความแตกต่างของภาระงานเฉลี่ยระหว่างสถานีงานน้อยที่สุด 4) ค่าความแปรปรวนจากการใช้พลังงานของพนักงานน้อยที่สุด 5) มูลค่าภาษีที่สามารถประหยัดได้จากการจ้างงานคนพิการมากที่สุด ซึ่งถือเป็นปัญหาแบบเอ็นพีแบบยาก (NP-hard) ทำให้เป็นไปได้ยากที่จะได้คำตอบที่ดีที่สุด (Optimal Solution) ในระยะเวลาที่จำกัด ดังนั้นจึงจะประยุกต์ใช้อัลกอริทึมวิธีการเชิงวิวัฒนาการแบบมากวัตถุประสงค์ ที่ถูกจัดว่าเป็นเมตาฮิวริสติก (Metaheuristic) ในการแก้ปัญหา, พัฒนาคำตอบ และค้นหาค่าที่ดีที่สุดพร้อมๆกันไปของแต่ละวัตถุประสงค์ โดยอัลกอริทึมที่จะศึกษาและทำการเปรียบเทียบประสิทธิภาพในการแก้ปัญหาของงานวิจัยนี้คือ วิธีการเชิงวิวัฒนาการแบบหลายวัตถุประสงค์โดยยึดหลักการจำแนก (MOEA/D) และ วิธีเชิงพันธุกรรมแบบการจัดลำดับที่ไม่ถูกครอบงำ III (NSGA-III) จากผลการเปรีบยเทียบตัวชี้วัดสมรรถนะของงานวิจัยแสดงให้เห็นว่า NSGA-III มีสมรรถนะที่ดีเหนือกว่า MOEA/D ในเกือบทุกโจทย์ปัญหา

Preference-Aware Task Assignment In Mobile Crowdsensing, Fatih Yucel

Theses and Dissertations

Mobile crowdsensing (MCS) is an emerging form of crowdsourcing, which facilitates the sensing data collection with the help of mobile participants (workers). A central problem in MCS is the assignment of sensing tasks to workers. Existing work in the field mostly seek a system-level optimization of task assignments (e.g., maximize the number of completed tasks, minimize the total distance traveled by workers) without considering individual preferences of task requesters and workers. However, users may be reluctant to participate in MCS campaigns that disregard their preferences. In this dissertation, we argue that user preferences should be a primary concern in the …

Pore Microstructure Impacts On Lithium Ion Transport And Rate Capability Of Thick Sintered Electrodes, Ziyang Nie, Rohan Parai, Chen Cai, Charles Michaelis, Jacob M. Lamanna, Daniel S. Hussey, David L. Jacobson, Dipankar Ghosh, Gary M. Koenig Jr.

Mechanical & Aerospace Engineering Faculty Publications

Increasing electrode thickness is one route to improve the energy density of lithium-ion battery cells. However, restricted Li⁺ transport in the electrolyte phase through the porous microstructure of thick electrodes limits the ability to achieve high current densities and rates of charge/discharge with these high energy cells. In this work, processing routes to mitigate transport restrictions were pursued. The electrodes used were comprised of only active material sintered together into a porous pellet. For one of the electrodes, comparisons were done between using ice-templating to provide directional porosity and using sacrificial particles during processing to match the geometric density …

A Geometric Description Of The Set Of Stabilizing Pid Controllers, Keqin Gu, Qian Ma, Huiqing Zhou, Mahzoon Salma, Xingzi Yang

SIUE Faculty Research, Scholarship, and Creative Activity

This article developed a new method to described the set of stabilizing PID control. The method is based on D-parameterization with natural description of the set. It was found that the stability crossing surface is a ruled surface that is completely determined by a curve known as discriminant. The discriminant is divided into sectors at the cusps. Corresponding to the sectors, the stability crossing surface is divided into positive and negative patches. A systematic study is conducted to identify the regions with a fixed number of right half-plane characteristic roots. The crossing directions of characteristic roots for positive patches and …

Raw And Pure Education In The Society, Iwasan D. Kejawa

Department of Educational Administration: Dissertations, Theses, and Student Research

What does education mean to individuals in the world today? Education is a way one can attain or improve his or her ability to lead and survive in the society of ours. Without educational training of the mind, it may be impossible to realize the importance of adaptability of living in the environment. Without education, It may also be difficult to embellish the use of both the mental and physical attributes possessed by individual beings.

What really is education? Education is the training of the mind to perform desire functions or to perpetuate the modality of obtaining an end or …

Applied Machine Learning In Extrusion-Based Bioprinting, Shuyu Tian

Theses and Dissertations

Optimization of extrusion-based bioprinting (EBB) parameters have been systematically conducted through experimentation. However, the process is time and resource-intensive and not easily translatable across different laboratories. A machine learning (ML) approach to EBB parameter optimization can accelerate this process for laboratories across the field through training using data collected from published literature. In this work, regression-based and classification-based ML models were investigated for their abilities to predict printing outcomes of cell viability and filament diameter for cell-containing alginate and gelatin composite hydrogels. Regression-based models were investigated for their ability to predict suitable extrusion pressure given desired cell viability when keeping …

Multidimensional Extensions To Generalized Averaged Models For Multi-Frequency-Excited Dynamic Systems, Kartikeya Jayadurga Prasad Veeramraju, Jonathan W. Kimball

Electrical and Computer Engineering Faculty Research & Creative Works

In this paper, a novel Harmonic Axis Decoupling (HAD) method is proposed for extending the capabilities of the Generalized Averaged Modeling (GAM) technique. The conventional GAM technique is first revisited, and the problems encountered in the multiplication of two Double Fourier Series (DFS) signals in the time domain are investigated. The method of translating Fourier vectors to Discrete Fourier Images (DFI) in the frequency plane is proposed, and the ramifications of this conversion on DFS product terms in the time domain are investigated. The two-dimensional DFI convolution technique resulting from HAD is used for the dynamic modeling of power converters …

Detection Of Gaussian Attacks In Power Systems Under A Scalable Kalman Consensus Filter Framework, Arnold Fernandes, Rui Bo, Jonathan W. Kimball, Bruce M. Mcmillin

Electrical and Computer Engineering Faculty Research & Creative Works

The dynamic non-linear state-space model of a power-system consisting of synchronous generators, buses, and static loads has been linearized and a linear measurement function has been considered. A distributed dynamic framework for estimating the state vector of the power system has been designed here. This framework employs a type of distributed Kalman filter (DKF) known as a Kalman consensus filter (KCF) which is located at distributed control centers (DCCs) that fuse locally available noise ridden measurements, state vector estimates of neighboring control centers, and a prediction obtained by the linearized model to obtain a filtered state vector estimate. Further, the …

Artificial Neural Networks For Asymmetric Selective Harmonic Current Mitigation-Pwm In Active Power Filters To Meet Power Quality Standards, Amirhossein Moeini, Morteza Dabbaghjamanesh, Jonathan W. Kimball, Jie Zhang

Electrical and Computer Engineering Faculty Research & Creative Works

The main objective of an active power filter (APF) is to control the harmonics of nonlinear loads in power systems. In addition, the reactive power (fundamental component of the AC power) at the point of common coupling (PCC) can be compensated by using an APF. This paper investigates a technique for the modulation technique of the active power filters. Using the artificial neural network (ANN) technique, real-time fundamental and harmonic compensations can be achieved for the low-frequency modulation techniques such as asymmetric selective harmonic elimination/mitigation-pulse width modulation (ASHE/ASHM-PWM) and asymmetric selective harmonic current mitigation-PWM (ASHCM-PWM). This means that different phases …

Using Gated Recurrent Units For Selective Harmonic Current Mitigation-Pwm In Grid-Tied Cascaded H-Bridge Converters, Morteza Dabbaghjamanesh, Amirhossein Moeini, Jonathan Kimball, Jie Zhang

Electrical and Computer Engineering Faculty Research & Creative Works

Grid-tied converters become more popular for electric vehicle, renewable energy, and energy storage systems applications. Different modulation techniques such as low-frequency (e.g., selective harmonic elimination-PWM, selective harmonic mitigation-PWM, and selective harmonic current mitigation-PWM (SHCM-PWM)) and high-frequency modulation techniques (e.g., phase shift-PWM and space vector modulation) are used in the literature for grid-tied converters. Low-frequency modulation techniques have a high-efficiency due to the low-switching power losses. One of the main challenges of low-frequency modulation techniques such as SHCM-PWM is how to implement the proposed technique in real-time, due to the transcendental Fourier equations of SHCM-PWM. In this paper, a deep learning …

Dynamic Pricing In Electric Power Markets Affected By Distributed Energy Generation Using Agent-Based Modeling, Gasser G. Ali, Islam H. El-Adaway

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

The power infrastructure in the US is facing many challenges concerning capacity, reliability, and sustainability. Some of those challenges are associated with the integration of distributed energy resources (DER) into the conventional grid system. DER may offer reliable and cost-effective distributed small-scale generation near or at end-consumers. However, it also creates new challenges for utilities and generating companies due to the uncertainties in estimating demands. Accordingly, the goal of this research is to investigate dynamic pricing in electric power markets considering the effect of the increasing penetration of DER. To achieve that goal, a complex system-of-systems model that combines agent-based …

Test 2084a: John Deere 7r 270, Nebraska Tractor Test Lab

Nebraska Tractor Tests

ABOUT THE TEST REPORT AND USE OF THE DATA The test data contained in this report are a tabulation of the results of a series of tests. Due to the restricted format of these pages, only a limited amount of data and not all of the tractor specifications are included. The full OECD report contains usually about 30 pages of data and specifications. The test data were obtained for each tractor under similar conditions and therefore, provide a means of comparison of performance based on a limited set of reported data. EXPLANATION OF THE TEST PROCEDURES Purpose The purpose of …

Test 2090a: John Deere 7r 230, Nebraska Tractor Test Lab

Nebraska Tractor Tests

ABOUT THE TEST REPORT AND USE OF THE DATA The test data contained in this report are a tabulation of the results of a series of tests. Due to the restricted format of these pages, only a limited amount of data and not all of the tractor specifications are included. The full OECD report contains usually about 30 pages of data and specifications. The test data were obtained for each tractor under similar conditions and therefore, provide a means of comparison of performance based on a limited set of reported data. EXPLANATION OF THE TEST PROCEDURES Purpose The purpose of …

Test 2231: John Deere 8r 250, Nebraska Tractor Test Lab

Nebraska Tractor Tests

ABOUT THE TEST REPORT AND USE OF THE DATA The test data contained in this report are a tabulation of the results of a series of tests. Due to the restricted format of these pages, only a limited amount of data and not all of the tractor specifications are included. The full OECD report contains usually about 30 pages of data and specifications. The test data were obtained for each tractor under similar conditions and therefore, provide a means of comparison of performance based on a limited set of reported data. EXPLANATION OF THE TEST PROCEDURES Purpose The purpose of …

Test 2243a: New Holland T8 435 Ultra Command Smartrax, Nebraska Tractor Test Lab

Nebraska Tractor Tests

ABOUT THE TEST REPORT AND USE OF THE DATA The test data contained in this report are a tabulation of the results of a series of tests. Due to the restricted format of these pages, only a limited amount of data and not all of the tractor specifications are included. The full OECD report contains usually about 30 pages of data and specifications. The test data were obtained for each tractor under similar conditions and therefore, provide a means of comparison of performance based on a limited set of reported data. EXPLANATION OF THE TEST PROCEDURES Purpose The purpose of …

Test 2243: Case Ih Magnum 400 Rowtrac, Nebraska Tractor Test Lab

Nebraska Tractor Tests

ABOUT THE TEST REPORT AND USE OF THE DATA The test data contained in this report are a tabulation of the results of a series of tests. Due to the restricted format of these pages, only a limited amount of data and not all of the tractor specifications are included. The full OECD report contains usually about 30 pages of data and specifications. The test data were obtained for each tractor under similar conditions and therefore, provide a means of comparison of performance based on a limited set of reported data. EXPLANATION OF THE TEST PROCEDURES Purpose The purpose of …

Test 2242: Case Ih Magnum 400, Nebraska Tractor Test Lab

Nebraska Tractor Tests

ABOUT THE TEST REPORT AND USE OF THE DATA The test data contained in this report are a tabulation of the results of a series of tests. Due to the restricted format of these pages, only a limited amount of data and not all of the tractor specifications are included. The full OECD report contains usually about 30 pages of data and specifications. The test data were obtained for each tractor under similar conditions and therefore, provide a means of comparison of performance based on a limited set of reported data. EXPLANATION OF THE TEST PROCEDURES Purpose The purpose of …

Nebraska Summary 1218s: Fendt 724 Vario Gen6, Nebraska Tractor Test Lab

Nebraska Tractor Tests

ABOUT THE TEST REPORT AND USE OF THE DATA The test data contained in this report are a tabulation of the results of a series of tests. Due to the restricted format of these pages, only a limited amount of data and not all of the tractor specifications are included. The full OECD report contains usually about 30 pages of data and specifications. The test data were obtained for each tractor under similar conditions and therefore, provide a means of comparison of performance based on a limited set of reported data. EXPLANATION OF THE TEST PROCEDURES Purpose The purpose of …

Test 2240: Kubota M8-231, Nebraska Tractor Test Lab

Nebraska Tractor Tests

ABOUT THE TEST REPORT AND USE OF THE DATA The test data contained in this report are a tabulation of the results of a series of tests. Due to the restricted format of these pages, only a limited amount of data and not all of the tractor specifications are included. The full OECD report contains usually about 30 pages of data and specifications. The test data were obtained for each tractor under similar conditions and therefore, provide a means of comparison of performance based on a limited set of reported data. EXPLANATION OF THE TEST PROCEDURES Purpose The purpose of …

Product Failure Recognition Via Comparison Of Sequential And Quickest Detection Algorithms, Christopher M. Beachler

UNF Graduate Theses and Dissertations

Under similar conditions, products that are designed and used for similar tasks fail similarly. Developers may become aware of various product failure modes during the initial stages of new product generation, where redesign and failure mitigation processes can occur with minimal detriment to consumer safety. Developers strive to mitigate the potential for catastrophic failures. This thesis concentrates on when these failures occur outside of controlled conditions, specifically where the development of processes feature low accuracy sensing techniques that impact the safety and operation of the end user. This thesis develops a set of statistical analysis simulation techniques using two existing …

Determination Of Extreme Flood Events In The Black Creek, Julington Creek, Dubin Creek, Big Davis Creek, Ortega River, And Pablo Creek Sub-Basins Of The Lower St. Johns River Basin, Florida, Usa, Samantha Kovalenko

UNF Graduate Theses and Dissertations

Extreme flood estimation is a continuously developing field of research. Economic and community well-being are dependent on flood risk preventative planning, which can only be successfully implemented through sound flood estimating methods. Without the execution of proper flood prevention measures, many communities remain at risk. In addition to a new extreme flood estimation methodology, this research presents a new approach to establish flood estimates. Traditionally, more than one flood estimate per return frequency storm does not exist. This research produced a set of 10-, 25-, 50-, and 100-year flood estimates for the Black Creek, Julington Creek, Durbin Creek, Big Davis …

Advance Metallic Reinforcement Of Vat Photo Polymerized Parts, Scott Zinn

UNF Graduate Theses and Dissertations

The metallization or metallic reinforcement of polymer parts has been widely used in industry for several decades. Polymer parts are classically metalized for aesthetics, chemical and thermal resistance, electrical conductivity, and mechanical strength. Metallization has been shown to increase strength of polymer parts when compared to the strength of the bulk material without metallization. Additive manufacturing (AM) techniques that have emerged in the last few decades produce parts with different surface features and chemistry than the typical polymer part produced through injection molding. AM parts are typically weaker than traditionally manufactured parts from the same material due to intrinsic details …

Energy Considerations In Blockchain-Enabled Applications, Cesar Enrique Castellon Escobar

UNF Graduate Theses and Dissertations

Blockchain-powered smart systems deployed in different industrial applications promise operational efficiencies and improved yields, while mitigating significant cybersecurity risks pertaining to the main application. Associated tradeoffs between availability and security arise at implementation, however, triggered by the additional resources (e.g., memory, computation) required by each blockchain-enabled host. This thesis applies an energy-reducing algorithmic engineering technique for Merkle Tree root and Proof of Work calculations, two principal elements of blockchain computations, as a means to preserve the promised security benefits but with less compromise to system availability. Using pyRAPL, a python library to measure computational energy, we experiment with both the …

Predicting Anthropogenic Underwater Pile Driving Noise Using Pile Driving Analyzer (Pda) Data, Brandon Alfredo Rivera

UNF Graduate Theses and Dissertations

In the past several years, there has been increasing concern about anthropogenic noise generated during marine pile driving. This concern is expected to increase concomitantly with increases in waterfront construction efforts associated with aging infrastructure and sea level rise. Several guidelines are available to help predict underwater noise transmission due to pile driving, but the issue with all these methods is that they require one to measure sound pressure levels at one locus or more from the driven pile. In the context of marine construction, adding specifications for underwater noise collection may be expensive or difficult because contractors typically have …

A Microscopic Simulation Approach For Developing Ramp Metering Activation Guidelines For Weekends, Sarah T. Kasomi

UNF Graduate Theses and Dissertations

Traffic congestion is one of the major concerns in urban motorways. Agencies are implementing various Transportation Systems Management and Operations (TSM&O) strategies to reduce traffic congestion on roadway networks. Ramp metering is a TSM&O strategy that utilizes signals installed at freeways’ on-ramps to dynamically manage traffic entering the freeway. RMSs have been effective at alleviating recurring congestion. Recurring congestion, however, constitutes less than half of all congestion. More than half of all congestion is due to non-recurring events such as incidents, work zones, adverse weather conditions, special events, etc., that adversely affect the performance of a highway. Non-recurring congestion on …