Engineering Commons^™

Fundamentals Of Electrochemical Impedance Spectroscopy For Macrohomogeneous Porous Electrodes, Xiang Li, Qiu-An Huang, Wei-Heng Li, Yu-Xuan Bai, Jia Wang, Yang Liu, Yu-Feng Zhao, Juan Wang, Jiu-Jun Zhang

Journal of Electrochemistry

Electrochemical impedance spectroscopy (EIS) can be used to diagnose charge transfer reactions and mass transport in porous electrodes. The charge transfer reactions include interfacial charge accumulation and charge conduction as well as electrochemical reaction. In this paper, the complex phasor method is developed under the macrohomogeneous assumption to build an impedance model of porous electrodes for clarifying several vague expressions in the traditional approaches. The following researches are carried out: (1) Identifying characteristic parameters for the porous electrodes, including electrode electronic conductivity σ₁, electrolyte ionic conductivity σ₂, interface charge transfer conductivity g_ct, unit area …

Janus-Tinbco2 For Hydrogen Evolution Reaction With High Conductivity And Catalytic Activity, Li-Li Xu, Dong-Yan Ren, Xiao-Feng Zhao, Yong Yi

Journal of Electrochemistry

Exploring the potential hydrogen evolution reaction (HER) catalysts with the high activity and high conductivity has always been a hot spot in the research of renewable energy development. Ti₂C, as one of the 2D-MXene, has excellent properties relating to many active sites, mechanical stability, conductivity, etc., and has become a potential HER catalyst. However, the modification of the surface of Ti₂C by terminal O will reduce the conductivity, thereby limiting the transport of electrons between the valence band and the conduction band. In this study, an electric double layer Janus-TiNbCO₂ was constructed by Nb doping. …

Application Of Ti/Ruo2-Iro2-Sno2-Sb2O5 Anode In Rural Drinking Water Disinfection, Jing-Ru Guo, Xue-Jiao Zhang, Shuai Liao, Xue-Ming Chen

Journal of Electrochemistry

Sodium hypochlorite disinfection has many advantages, including reliable operation, low cost, easily available raw materials. It is, therefore, suitable for disinfection of drinking water in remote rural areas. The service life and chlorine evolution efficiency of the anode are the main factors restricting the performance of the sodium hypochlorite generator. The special conditions of frequent shutdown and low electrolyte concentration in the rural drinking water application also put forward high requirements on the performance of the anode. In this study, Ti/RuO₂-IrO₂-SnO₂-Sb₂O₅,a new-type and efficient chlorine evolution anode, was prepared by …

Synthesis Of Nickel Phosphide/Nitrogen Phosphorus Co-Doped Carbon And Its Application In Lithium Ion Batteries, Jian Hu, Yan-Shuang Meng, Qian-Ru Hu

Journal of Electrochemistry

In recent years, the nickel-based phosphide has drawn great attention because of its low intercalation/deintercalation platform and lower polarization compared to sulfides and oxides as anodes for next-generation high-energy lithium-ion batteries. The Ni₂P anode can deliver high theoretical specific capacity of 542 mAh·g^-1, but it subject to a conversion reaction mechanism, which make them unsuitable for commercial applications. The agglomeration of Ni₂P nanoparticles during material fabrication and the structural deterioration of electrode associated with large volume change during charge-discharge process lead to poor cycle stability and low utilization of active materials. Meanwhile, the low …

Performance And Mechanism Of PtXCuY/C Electrocatalyst For Methanol Oxidation, Jia Tang, Xiao-Ming Zhang, Shan-Sheng Yu, Su-Li Wang, Gong-Quan Sun

Journal of Electrochemistry

Direct methanol fuel cell (DMFC), which directly converts the chemical energy of methanol fuel into electrical energy, has the advantages of high energy conversion efficiency, environmental friendliness, and abundance of fuel sources. DMFC is considered as the promising substitutes in the field of portable devices, military applications, and stationary power stations, while the broad application is severely hindered by the sluggish kinetic of methanol oxidation reaction (MOR) in the anode and the high cost of platinum (Pt)-based anodic electrocatalysts. Herein, a series of carbon supported Pt_xCu_y (Pt_xCu_y/C) binary metal electrocatalysts, featured with high …

Effect Of Alkyl Chain Length Of Symmetrical Quaternary Ammonium Hydroxide On Oxalic Acid Electroreduction Reaction, Bo Huang, Xin-Sheng Zhang, Dong-Fang Niu, Shuo-Zhen Hu

Journal of Electrochemistry

Glyoxylic acid with the dual characteristics of acid and aldehyde is an important chemical raw material and organic synthesis intermediate, which is extensively used in the perfumery, pharmaceutical and fine chemical industries. A family of symmetric quaternary ammonium hydroxides (QAHs) with different alkyl chain lengths was used as the additives in generating glyoxylic acid from oxalic acid electroreduction reaction (OAER). The effects of alkyl chain length on OAER and the corresponding side reaction, i.e., hydrogen evolution reaction (HER), were investigated. Linear sweep voltammetric (LSV) results showed that the adsorption of the additives suppressed more on the HER than that on …

A Review Of Mobile Apps For Chronic Kidney Disease Patients, Clarisse Zigan, Carl Russell Iii, Kirsten Wozniak, Kshaunish Soni

The Journal of Purdue Undergraduate Research

No abstract provided.

Collision Tracking And Brain Mapping, Carl Russell Iii

The Journal of Purdue Undergraduate Research

No abstract provided.

Continuous Liquid-Liquid Extraction Of Lomustine Synthesis, Devna Grover

The Journal of Purdue Undergraduate Research

No abstract provided.

Multiphase Energetic Experiments: Application Of Multiple Object Tracking, Sarah Davis Finch

The Journal of Purdue Undergraduate Research

The process of using computer vision for multiple-objects tracking is incredibly complex. Thus, simulated data was created to mimic the complexities of more realistic data. These test cases would isolate a few of the inaccuracies of real data and allow the researchers to determine what factor of said data is the most detrimental to the object-tracking process. Due to the large quantity of factors at play, Cotter’s method was used to analyze the significance of each factor. The number of detections and the number of centroids were the main dependent results that were utilized to analyze the data. The overall …

Visualizing Bacteriophage Evolution Through Sequence And Structural Phylogeny Of Lysin A And Terminase Proteins: An Analysis Of Protein Structure Across Phage Clusters, Maansi Asthana, Alyssa Easton, Julia Mollenhauer, Sean Renwick, Anita Golpalrathnam

The Journal of Purdue Undergraduate Research

Understanding how genes evolve and persist is a critical part of viral genomics. Bacteriophages can provide unique insight about viral evolution because of their abundance and largely unexplored history. Traditionally, phylogenetic trees have used DNA sequence comparison to visualize evolutionary paths between organisms. However, DNA sequence similarity does not reflect key alterations to protein structure and therefore how the protein performs its function. Phylogenetic trees based on predicted protein structure could provide an alternative lens through which to view evolutionary paths. From each of the 10 largest clusters included in the Actinobacteriophage Database, three mycobacteriophage genomes were selected. Lysin A …

Dataset Of Concurrent Eeg, Ecg, And Behavior With Multiple Doses Of Transcranial Electrical Stimulation, Nigel Gebodh, Zeinab Esmaeilpour, Abhishek Datta, Marom Bikson

Publications and Research

We present a dataset combining human-participant high-density electroencephalography (EEG) with physiological and continuous behavioral metrics during transcranial electrical stimulation (tES). Data include within participant application of nine High-Definition tES (HD-tES) types, targeting three cortical regions (frontal, motor, parietal) with three stimulation waveforms (DC, 5 Hz, 30 Hz); more than 783 total stimulation trials over 62 sessions with EEG, physiological (ECG, EOG), and continuous behavioral vigilance/alertness metrics. Experiment 1 and 2 consisted of participants performing a continuous vigilance/alertness task over three 70-minute and two 70.5-minute sessions, respectively. Demographic data were collected, as well as self-reported wellness questionnaires before and after each …

Phenolic, Carotenoid And Saccharide Compositions Of Vietnamese Camellia Sinensis Teas And Herbal Teas, Danh C. Vu, Sophie Alvarez

Nebraska Center for Biotechnology: Faculty and Staff Publications

Tea (Camellia sinensis) and herbal tea have been recognized as rich sources of bioactive constituents with the ability to exert antioxidant actions. The aims of this study were to analyze phenolic, carotenoid and saccharide contents in a set of Vietnamese tea and herbal tea and compare the results with those of green and black teas marketed in the U.S. In total, 27 phenolics, six carotenoids and chlorophylls, and three saccharides were quantitatively identified. Catechins, quercetin glycosides and chlorogenic acid were the predominating phenolics in the teas, with the concentrations following the order: jasmine/green teas > oolong tea > black tea. …

Generating Synthetic Training Data For Deep Learning-Based Uav Trajectory Prediction, Brendan T. Morris, Stefan Becker, Ronny Hug, Wolfgang Huebner, Michael Arens

Electrical & Computer Engineering Faculty Research

Deep learning-based models, such as recurrent neural networks (RNNs), have been applied to various sequence learning tasks with great success. Following this, these models are increasingly replacing classic approaches in object tracking applications for motion prediction. On the one hand, these models can capture complex object dynamics with less modeling required, but on the other hand, they depend on a large amount of training data for parameter tuning. Towards this end, we present an approach for generating synthetic trajectory data of unmanned-aerial-vehicles (UAVs) in image space. Since UAVs, or rather quadrotors are dynamical systems, they can not follow arbitrary trajectories. …

Effects Of Nitrate On Arsenic Mobilization During Aquifer Storage And Recovery, Hania Hawasli

USF Tampa Graduate Theses and Dissertations

Aquifer storage and recovery technology is used to sustain water resources and to prevent saltwater intrusion. The injected water can come from various resources, including treated wastewater. In pilot ASR studies in the Tampa Bay region, researchers found high As concentrations in the recovered water from the oxidation of the arsenopyrite that is embedded in the aquifers. The presence of dissolved O2 in the injected water is a major factor in the arsenopyrite oxidation during ASR, however the effects of NO3- on the arsenopyrite has not been studied yet. This is an important knowledge gap because injected water may contain …

Polyethyleneimine-Based High Yield Fluorescent Soluble Covalent Organic Framework, Haonan Wang

USF Tampa Graduate Theses and Dissertations

In this thesis, we report a novel covalent organic framework (COF) with fluorescence and water-soluble features, F-COF-PT with high gravimetric yield (~ 89%), that was generated by the reactions of branched polyethyleneimine (PEI) and 1,3,6,8-Tetrabromopyrene (TBP). The surface area and pore volume were about up to 63.2 m2/g and 0.41 m3/g. The prepared COFs maintained the TBP fluorescent performance in water solutions at 440-460 nm. Furthermore, Cu(II) ion solution would impact the quenching activity with F-COF-PT3, and NaOH treated F-COF-PT3 has the 5.6 m2/g capacity of uptake CO2. Finally, the zeta potential and particle diameter of original and treated F-COF-PT3s …

Plasma Treatment Of High-Density Polyethylene, Linear Low-Density Polyethylene, And Polyvinyl Chloride Geomembranes By Air And Oxygen, Merve Koca Uyar

USF Tampa Graduate Theses and Dissertations

High-density polyethylene (HDPE), linear low-density polyethylene (LLDPE), and polyvinyl chloride (PVC) geomembranes were treated with air and oxygen plasma. The purpose of air and oxygen plasma treatment of geomembrane surface is to increase the surface wettability of these materials, thereby increasing adhesive properties. Increasing adhesive properties enables a surface to be coated with a desired material with antibacterial, antioxidant, and UV resistant characteristics, without changing bulk material properties. To protect the geomembranes from oxidation degradation, UV degradation and biological degradation, it is important to increase the antibacterial, antioxidant, and UV resistant properties of geomembrane. Before and after the plasma treatments …

Modeling The Ambient Conditions Of A Manufacturing Environment Using Computational Fluid Dynamics (Cfd), Yang Liu

USF Tampa Graduate Theses and Dissertations

As manufacturing equipment evolve to higher speed and require high precision operations, the impact of environmental changes on machine accuracy becomes critical. Due to thermal expansion, the structure of the machine can change when ambient temperature varies. When the airflow in the laboratory changes, this also alters the operator's thermal comfort. Either the change in machine structure or operator comfort can ultimately affect machine accuracy. The manufacturing industry is currently using heating, ventilation, and air-conditioning (HVAC) systems to regulate the temperature of the working environment. However, since conventional HVAC systems determine whether to activate the HVAC system by collecting the …

Parents’ Perspectives On A Smartwatch Intervention For Children With Adhd: Rapid Deployment And Feasibility Evaluation Of A Pilot Intervention To Support Distance Learning During Covid-19, Franceli L. Cibrian, Elissa Monteiro, Elizabeth Ankrah, Jesus A. Beltran, Arya Tavakoulnia, Sabrina E. B. Schuck, Gillian R. Hayes, Kimberley D. Lakes

Engineering Faculty Articles and Research

Distance learning in response to the COVID-19 pandemic presented tremendous challenges for many families. Parents were expected to support children’s learning, often while also working from home. Students with Attention Deficit Hyperactivity Disorder (ADHD) are at particularly high risk for setbacks due to difficulties with organization and increased risk of not participating in scheduled online learning. This paper explores how smartwatch technology, including timing notifications, can support children with ADHD during distance learning due to COVID-19. We implemented a 6-week pilot study of a Digital Health Intervention (DHI) with ten families. The DHI included a smartwatch and a smartphone. Google …

Optimization In The Application Of Varnishes Barrier On Cartonboard Packaging, Andre Ramalheiro De Andrade, Maria Isabel Rodrigues Phd, Eduardo Luiz Machado Phd

Journal of Applied Packaging Research

In this work adjustments in the rotogravure printing process are proposed to the varnish water vapor transmission rate (WVTR) aiming to obtain results smaller than 20g/m²/24h. One case study was used for the propositions for improvements, where focused on varnish application process in a gravure printer for an eight-printing unit cartonboard packaging, maximum printing speed of 175 m/min and a 285 g/m² weight cartonboard. The possible variables that influenced the WVTR result were selected from the technical expertise of the people involved in the project, the analysis in the printing process with the application of directed trials using experimental designs …

État Des Récentes Avancées En Matière De Développement De Sièges À Suspension, Subhash Rakheja, Pierre Marcotte, Karim Hamouda, Krishna Dewangan, Darshan Dorugade

Rapports de recherche scientifique

Dans divers secteurs d’activité du Québec, les conducteurs de véhicules sont exposés à des niveaux notables de vibrations globales du corps (VGC) et à des chocs intermittents, associés dans les deux cas à un risque accru de douleurs lombaires et de dégénérescence de la colonne vertébrale. Les sièges à suspension sont largement utilisés pour limiter l'exposition des conducteurs aux VGC. L’efficacité d'un siège à suspension à réduire les vibrations est fortement dépendante de la nature des vibrations du véhicule (amplitude, direction et fréquence). Un siège à suspension ne peut donc offrir une efficacité optimale que lorsque la suspension est mise …

State-Of-The-Art In Recent Developments Concerning Suspension Seats, Subhash Rakheja, Pierre Marcotte, Karim Hamouda, Krishna Dewangan, Darshan Dorugade

Rapports de recherche scientifique

Dans divers secteurs d’activité du Québec, les conducteurs de véhicules sont exposés à des niveaux notables de vibrations globales du corps (VGC) et à des chocs intermittents, associés dans les deux cas à un risque accru de douleurs lombaires et de dégénérescence de la colonne vertébrale. Les sièges à suspension sont largement utilisés pour limiter l'exposition des conducteurs aux VGC. L’efficacité d'un siège à suspension à réduire les vibrations est fortement dépendante de la nature des vibrations du véhicule (amplitude, direction et fréquence). Un siège à suspension ne peut donc offrir une efficacité optimale que lorsque la suspension est mise …

Method Of Making Temperature-Immune Self-Referencing Fabry–Pérot Cavity Sensors, Hengky Chandrahalim, Jonathan W. Smith

AFIT Patents

A method of making passive microscopic Fabry-Pérot Interferometer (FPI) sensor includes forming a three-dimensional microscopic optical structure on a cleaved tip of an optical fiber that reflects a light signal back through the optical fiber. The reflected light is altered by refractive index changes in the three-dimensional structure that is subject to at least one of: (i) thermal radiation; and (ii) volatile organic compounds.

Material And Topographically Optimized Thermal Dissipation For High-Performance Electronic Devices Utilizing Vapor Chambers, Derek Joseph Daniels

USF Tampa Graduate Theses and Dissertations

Advances in materials science and engineering in the field of thermal transport and dissipation enable the use of higher-performance electronic devices that are smaller and generate more heat. Phase change thermal transport systems such as heat pipes and vapor chambers enable passive dissipation from devices that generate excessive heat without the need for actively pumped cooling systems. Properly designed vapor chamber enabled systems easily exceed the thermal conductivity of manufactured diamond at a small fraction of the cost.[1][2][3] While heat pipe phase change systems are generally one-dimensional with a limited cross section, vapor chambers are generally two-dimensional with a small …

Texturing In Bi2Te3 Alloy Thermoelectric Materials: An Applied Physics Investigation, Oluwagbemiga P. Ojo

USF Tampa Graduate Theses and Dissertations

Thermoelectric devices provide the means for direct conversion between heat and electricity. The device conversion efficiency, or performance, is directly related to the thermoelectric figure of merit, ZT, of the working materials. Bismuth telluride alloys are the materials currently in use in most thermoelectric devices for near room temperature solid-state refrigeration and power conversion applications. The vast majority of publications in the literature on thermoelectricity report on investigations towards developing new materials with enhanced thermoelectric properties, however Bi₂Te₃ alloys have been used in thermoelectric devices for decades.

In this thesis, an investigation of crystallographic texturing on large …

Observed Risk And User Perception Of Road Infrastructure Safety Assessment For Cycling Mobility, Salvatore Cafiso, Giuseppina Pappalardo, Nikiforos Stamatiadis

Civil Engineering Faculty Publications

The opportunities for data collection in smart cities and communities provide new approaches for assessing risk of roadway components. This paper presents and compares two different methodological approaches for cycling safety assessment of objective and perceived risk. Objective risk was derived from speed and direction profiles collected with Global Navigation Satellite System (GNSS) and camera installed on an instrumented bicycle. Safety critical events between cyclists and other road users were identified and linked to five different roadway components. A panel of experts was asked to score the severity of the safety critical events using a Delphi process to reach consensus. …

Assessing The Vertical Displacement Of The Grand Ethiopian Renaissance Dam During Its Filling Using Dinsar Technology And Its Potential Acute Consequences On The Downstream Countries, Hesham El-Askary, Amr Fawzy, Rejoice Thomas, Wenzhao Li, Nicholas Lahaye, Erik Linstead, Thomas Piechota, Daniele Struppa, Mohamed Abdelaty Sayed

Mathematics, Physics, and Computer Science Faculty Articles and Research

The Grand Ethiopian Renaissance Dam (GERD), formerly known as the Millennium Dam, is currently under construction and has been filling at a fast rate without sufficient known analysis on possible impacts on the body of the structure. The filling of GERD not only has an impact on the Blue Nile Basin hydrology, water storage and flow but also poses massive risks in case of collapse. Rosaries Dam located in Sudan at only 116 km downstream of GERD, along with the 20 million Sudanese benefiting from that dam, would be seriously threatened in case of the collapse of GERD. In this …

Expedited Pcr With Stirring, Hendrik J. Viljoen

Department of Chemical and Biomolecular Engineering: Faculty Publications

Disclosed are an apparatus and methods for rapid amplifi cation of nucleic acids . More particularly , the present dis closure relates to an apparatus for mixing a reaction solution during amplification of nucleic acids and to methods for amplifying nucleic acids . Also disclosed are methods for lysing cells in a sample and amplifying nucleic acids .

Expedited Pcr With Stirring, Hendrik Viljoen

Department of Chemical and Biomolecular Engineering: Faculty Publications

Disclosed are an apparatus and methods for rapid amplification of nucleic acids. More particularly, the present dis closure relates to an apparatus for mixing a reaction solution during amplification of nucleic acids and to methods for amplifying nucleic acids. Also disclosed are methods for lysing cells in a sample and amplifying nucleic acids.

Evolution Of Publications, Subjects, And Co-Authorships In Network-On-Chip Research From A Complex Network Perspective, Weilong Chen, Xiaohang Wang, Ye Sun, Qiao Hu, Letian Huang, Yingtao Jiang, Amit Kumar Singh, Terrence Mak, Mei Yang

College of Engineering Faculty Research

The academia and industry have been pursuing network-on-chip (NoC) related research since two decades ago when there was an urgency to respond to the scaling and technological challenges imposed on intra-chip communication in SoC designs. Like any other research topic, NoC inevitably goes through its life cycle: A. it started up (2000-2007) and quickly gained traction in its own right; B. it then entered the phase of growth and shakeout (2008-2013) with the research outcomes peaked in 2010 and remained high for another four/five years; C. NoC research was considered mature and stable (2014-2020), with signs showing a steady slowdown. …