Engineering Commons^™

Surface-Functionalized Chemiresistive Films That Exploit H-Bonding, Cation-Pi, And Metal-Halide Interactions., Prasadanie Karunarathna Adhihetty

Electronic Theses and Dissertations

The development of gas sensors for detection of volatile organic compounds (VOCs) has been of interest in the sensing field for decades. To date, the use of metal nanoparticle-based chemiresistors for trace VOC detection, particularly gold nanoparticle-based sensors, is of great interest due to their high chemical stability, ease of synthesis, unique optical properties, large surface to volume ratio, and high level of conductivity. Much effort has been devoted towards gold monolayer protected clusters (Au MPCs) as chemiresistors to detect harmful VOCs. The present thesis documents the results of our efforts to exploit the advantages of functionalized Au MPCs chemiresistors …

Structural, Charge Transport, Gas Sensing, Magnetic, Pseudocapacitive, And Electrocatalytic Properties Of Perovskite Oxides., Surendra Bahadur Karki

Electronic Theses and Dissertations

Perovskites are functional materials with the general formula ABO₃ (A = alkali, alkaline earth or lanthanoid cations and B = transition metal or main group cations). These materials are marked by a variety of crystal structures and interesting properties such as colossal magnetoresistance, ferroelectricity, multiferroicity, superconductivity, pseudocapacitance, gas sensing, charge transport, and electrocatalytic properties. The formula of perovskite can be written as AA’BB’O₆, when there is ordering between two cations over A and B-sites. Such compounds are called double perovskite oxides. Some amount of oxygen could be lost from crystal structure without decomposition of the phase. Such …

Engineering Lewis Acidic Materials For Biomass Conversion And Battery Applications., Md Anwar Hossain

Electronic Theses and Dissertations

My long-term goal is to develop catalytic systems to produce renewable energy for a sustainable society. The overall research objective of my dissertation is to advance understanding of Lewis acidic materials for (1) conversion of renewable lignin into phenolics and (2) enhanced cycling stability of lithium metal batteries to safely store renewable electricity from wind and solar, thereby laying the groundwork for our transition to a sustainable society. Petroleum is a conventional feedstock for current transportation fuels (gasoline, diesel, and jet fuels). However, petroleum is a finite resource and produces greenhouse gases (CO₂ and CH₄) upon processing, …

A Modeling Platform To Predict Cancer Survival And Therapy Outcomes Using Tumor Tissue Derived Metabolomics Data., Hunter Allan Miller

Electronic Theses and Dissertations

Cancer is a complex and broad disease that is challenging to treat, partially due to the vast molecular heterogeneity among patients even within the same subtype. Currently, no reliable method exists to determine which potential first-line therapy would be most effective for a specific patient, as randomized clinical trials have concluded that no single regimen may be significantly more effective than others. One ongoing challenge in the field of oncology is the search for personalization of cancer treatment based on patient data. With an interdisciplinary approach, we show that tumor-tissue derived metabolomics data is capable of predicting clinical response to …

Nucleate Boiling Under Different Gravity Values: Numerical Simulations & Data-Driven Techniques., Sandipan Banerjee

Electronic Theses and Dissertations

Nucleate boiling is important in nuclear applications and cooling applications under earth gravity conditions. Under reduced gravity or microgravity environment, it is significant too, especially in space exploration applications. Although multiple studies have been performed on nucleate boiling, the effect of gravity on nucleate boiling is not well understood. This dissertation primarily deals with numerical simulations of nucleate boiling using an adaptive Moment-of-Fluid (MoF) method for a single vapor bubble (water vapor or Perfluoro-n-hexane) in saturated liquid for different gravity levels. Results concerning the growth rate of the bubble, specifically the departure diameter and departure time have been provided. The …

Fluid Structure Interactions Within A Common Rail Diesel Injector., Russell Prater

Electronic Theses and Dissertations

The internal flow of a high-pressure diesel injector is simulated numerically to investigate the complex transient flow structures and the unsteady forces imparted to the injector needle that result from the asymmetric flow fields developed during operation. The gas-liquid two phase flow is simulated using a mixture model with the cavitation numerically modeled using the Zwart-Gerber-Belamri model. Both the k-ε model and the detached eddy simulation (DES) model are used, and the numerical results are compared. This dissertation looks at the internal flow of a generic injector at different lifts and characterizes the flow parameters at high lift and low …

Materials And Interfaces For Electrocatalytic Hydrogen Production And Utilization., Alexander Jiya Gupta

Electronic Theses and Dissertations

Mass industrialization over the last few centuries has created a global economy which is dependent upon fossil fuels to satisfy an exponentially increasing demand for energy. Aside from the possible depletion of this finite resource, the combustion of fossil fuels releases greenhouse gases into the atmosphere which cause the global temperature to rise – a phenomenon which has already begun to create geologic and geopolitical instability and shows no signs of abatement. One proposed method to rid humanity of its dependence on fossil fuels is to use green hydrogen as an energy carrier. In this scheme, excess electricity from a …

Characterization Of Fundamental Parameters That Modulate Acoustofluidic-Mediated Molecular Delivery To Cells., Connor Sterling Centner

Electronic Theses and Dissertations

Cell-based therapies represent the latest biotechnological revolution in medicine, but significant limitations exist in non-viral intracellular delivery techniques during manufacturing of cell therapies. To address these limitations, a novel acoustofluidic device was developed to deliver ultrasound waves into a flow chamber for rapid molecular delivery to human cells. Our acoustofluidic device delivers biomolecules by inducing expansion and collapse of exogenous gas-filled microbubbles (“cavitation”), which enhances molecular delivery to nearby cells. Experimental studies were conducted to characterize key parameters that influence acoustofluidic-mediated molecular delivery to human cells. A clinical ultrasound transducer was generally utilized with varying cationic microbubble concentrations. Intracellular delivery …

Automatic Testing Of Organic Strain Gauge Tactile Sensors., Brian P. Goulet

Electronic Theses and Dissertations

Human-Robot Interaction is a developing field of science, that is posed to augment everything we do in life. Skin sensors that can detect touch, temperature, distance, and other physical interaction parameters at the human-robot interface are very important to enhancing the collaboration between humans and machines. As such, these sensors must be efficiently tested and characterized to give accurate feedback from the sensor to the robot. The objective of this work is to create a diversified software testing suite that removes as much human intervention as possible. The tests and methodology discussed here provide multiple realistic scenarios that the sensors …

Recovery Of Degraded Ni-Rich Nmc811 Particles For Lithium-Ion Batteries, Han Yu, Yan Gao, James Kirtley, Gabriel Borgmeyer, Xiaoqing He, Xinhua Liang

Chemical and Biochemical Engineering Faculty Research & Creative Works

Nickel-rich cathode materials attract a lot of attention due to their high energy density. However, their sensitivity to air and moisture hinders their practical applications. Exposing Ni-rich NMC in the air will produce by-products that are not conducive to lithium-ion transmission. Water washing can be used to remove by-products on the surface, but it can also introduce new problems, such as the generation of NiO on the particle surface, which will reduce the electrochemical performance of the material. In this study, Al₂O₃atomic layer deposition (ALD) was applied on degraded NMC811 particles to recover the electrochemical performance …

Repair And Strengthening Of Concrete Bridges Using Ultra-High-Performance Concrete (Uhpc), Antony Kodsy

Department of Construction Engineering and Management: Dissertations, Theses, and Student Research

Reinforced/Prestressed concrete bridges are subjected to environmental effects that cause premature deterioration and require structural repair and strengthening during their service life. Currently 42% of bridges in the United States are at least 50 years old, and 7.5% of them are structurally deficient and need to be repaired/strengthened. Recently, new repair and strengthening techniques using Ultra-High-Performance concrete (UHPC) have shown a great potential with respect to performance, economy, and speed. UHPC is a new class of concrete that has mechanical and durability properties that are far superior to those of conventional concrete (CC). In addition, UHPC offers several advantages compared …

Inactivation Of Salmonella In Black Peppercorn By Fluidization With Hydrogen Peroxide Vapor, Edel Summers

Department of Agricultural and Biological Systems Engineering: Dissertations, Theses, and Student Research

The purpose of the present study was to assess the effectiveness of hydrogen peroxide vapor (HPV) at inactivating Salmonella inoculated in whole black pepper when used as fluidizing gas media. HPV treatment was conducted at two different temperatures (45°C and 60°C) and two dwell times (30 min and 60 min). Microbial reduction and residual hydrogen peroxide were measured at three storage times: 0 h (immediately after treatment), 24 h and 48 h post-treatment. The effect of HPV on the quality of whole black peppercorn was evaluated 48 h post-treatment based on changes in piperine content, total phenolics, antioxidant activity, total …

Generative Designs Of Lightweight Air-Cooled Heat Exchangers, Connor Miller

Mechanical Engineering Undergraduate Honors Theses

The development of high-performance air-cooled heat exchangers is required to permit the rapid growth of vehicle and aircraft electrification. In electric vehicles and airliners, the motors and power electronics are integrated into a compact space, leading to unprecedently high power density. To achieve higher overall thermal efficiency, the heat exchangers must be extremely light while maintaining their heat transfer performance and mechanical robustness. Recently advances in 3D metal printing, e.g., direct metal laser sintering, and selective laser melting, have enabled the manufacturing of high-performance robust heat exchangers by eliminating thermal boundary resistance and ensuring a uniform thermal expansion coefficient. Nonetheless, …

Orbital Debris Analysis And Orbital Decay Analysis Of Arksat-2, Will Stuff

Mechanical Engineering Undergraduate Honors Theses

ARKSAT-2 is a cube satellite developed by the University of Arkansas for its second CubeSat mission. There are two objectives of the ARKSAT-2 mission. The first objective of this mission is to test a novel cold gas thruster propulsion system using water-propylene propellant. This propulsion system will be used for attitude control of the satellite. The second objective for the ARKSAT-2 mission is to test a Solid-State Inflation Balloon (SSIB) that has been designed and developed for this mission. The SSIB is designed to be a simple and cost-effective method for deorbiting the vehicle. In cube satellites, a software known …

Durability Of Non-Metallic Materials For Additively Manufactured Heat Spreader Fabrication, Rafael Estrella

Mechanical Engineering Undergraduate Honors Theses

Power electronics are necessary to convert power from DC sources for AC applications. As this technology trends toward smaller packaging for denser power loads, the increased electrical losses result in deleterious excess heat. Thermal management devices are required to prevent the effects of thermal runaway from shortening the longevity of these modules. Nonmetallic jet impingement heat spreaders provide several benefits in terms of weight and performance over conventional cold plates while not accentuating EMI from the switches in the power module; however, the polymer makeup of the materials previously used for fabricating these devices raises durability concerns under the high …

Autonomous Material Refill For Swarm 3d Printing, William C. Jones

Mechanical Engineering Undergraduate Honors Theses

3D printing currently offers robust and cheap rapid prototyping solutions. While standard 3D printing remains at the periphery of mass production, the technology serves as a starting point for the development of swarm manufacturing. Since swarm manufacturing is predicated upon autonomy, swarm technology companies such as AMBOTS are seeking to minimize human involvement in the swarm’s functions. At present, the 3D printing swarm consists of the printers, a transporter which can take them between job sites, and the floor tiles which provide power and support the build surfaces. To add to this ecosystem, this project is focused on the design …

Computer Vision And Machine Learning Applications In Cellular Images And Clinical Data, Guochang Ye

Theses and Dissertations

With the progressive development of artificial intelligence (AI), automated analysis has been explored for substituting tedious manual methods in cellular image analysis. Additionally, medical information not included in the conventional statistical methods is now being reconsidered with AI-based personalized medicine. The adaptivity and flexibility of AI ensure its efficiency and accuracy. In this work, computer vision and machine learning (ML) methods under the scope of AI are explicitly investigated and applied to cellular images and clinical data for cytological analysis and to provide diagnosis-based assistance/predictions. Firstly, novel computer vision algorithms achieve cell detection and differentiation estimation on phase-contact microscopic images …

The Control Strategies Of Brominated Organic Disinfection By-Products: Adsorption With Pre-Chlorination And Photodegradation, Cagri Utku Erdem

All Dissertations

Increasing water pollution, scarcity, and seasonal events force water treatment plants to improve existing treatment techniques and/or implement new methods to enhance drinking water treatment and comply with disinfection by-product (DBP) regulations. A limited number of studies examine the pre-chlorination prior to activated carbon (AC) adsorption for the removal of DBP precursors, and there are no comprehensive and representative treatment conditions in current literature. Although many studies investigated photodegradation of individual DBPs by low pressure ultraviolet (UV₂₅₄) light, there is still lack of information and limited understanding of photodegradation of total organic halogens and practical implications of UV …

A Compact Natural Gas Pyrolysis Reactor For Hydrogen Fueling Stations, Andrew Richard Earls

Theses and Dissertations

With the increasing amount of greenhouse gases causing more natural disasters and sea level rise, there is a clear need for a global energy transition to less polluting fuels. A possible solution to this problem is converting a portion of the transportation sector fuel to hydrogen. In this thesis, the issues associated with such a transition are discussed and reasonable solutions are proposed. Numerous methods of hydrogen production are explored and compared on the basis of electricity consumption and CO2 emission. A plant size of 1250 kg liq. H2/day is chosen based on California regulated hydrogen refueling credits (HRI) that …

Suitability Of Low-Cost Additive Manufacturing For Polymer Electrolyte Fuel Cells, David Alexander

Open Access Theses & Dissertations

The purpose of this dissertation is to study the feasibility of low-cost additive manufacturing to fabricate polymer electrolyte fuel cell bipolar plate materials. Traditional manufacturing techniques include molding, milling, hollow embossing, hydro-forming, rolling, and electromagnetic forming. These processes are employed when a design has been selected due to higher costs at low volumes. The combination of high initial costs and bipolar plates being the most expensive component of the polymer electrolyte fuel cell creates incentive to mitigate this obstacle. The feasibility of low-cost additive manufactured bipolar plates will be proven by fabrication, post-processing, and characterization of printed test specimen. The …

Material Synthesis And Additive Manufacturing Of Ceramics, Elsa Bramasco-Rivera

Open Access Theses & Dissertations

This research is divided into two main topics: vitrimer polymers and alumina ceramics. Additive manufacturing is an emerging technology. In this research, two main methods of additive manufacturing are used: material extrusion and vat photopolymerization. The hypothesis of self-healing and mechanochromism functionalities was tested through the synthesis of vitrimers, a novel material combining properties of both thermosets and thermoplastics. These vitrimers were 3D printed using material extrusion. Casted vitrimers showed stiffening effects after submergence in water. Lithography based ceramics have gained attention in recent years due to their wide range of applications. Alumina ceramics were additively manufactured using digital light …

Application Of The Continuum Damage Mechanics Wilshire-Cano-Stewart (Wcs) Model, Jaime Aaron Cano

Open Access Theses & Dissertations

In this study, the applications of the continuum damage mechanics-based Wilshire-Cano-Stewart (WCS) model are explored to predict rupture time, minimum-creep-strain-rate (MCSR), damage, damage evolution, and creep deformation. Increase knowledge in manufacturing methods has pushed the limit of material science and the development of new materials. Conventional testing is required to qualify materials against creep which according to the ASME B&PV III code, 10,000+ hours of experiments are necessary for each heat before materials are put into service. This process is costly and not feasible for new materials. As an alternative, models have been employed to predict creep behaviors and reduce …

Performance Evaluation Of A Label Manufacturer Using Simulation Modeling, Joshua Holguin

Open Access Theses & Dissertations

Currently, the Supply Chain has been affected by freight prices, material scarcity, demand forecasting, port congestion, and digital transformation which are causing high lead times and delaying deliveries in all industries, but specifically in the labeling/printing industry. The industry is currently affected by the lack of new research improvements, optimization methodologies, supply chain disruptions, and technologies implementations within the label industry. Labeling /Printing industry has been out in business for more than 50 years, where labeling technologies such as Flexographic, Digital, and Die Cutting have advance in performance, effectiveness, complexity, and dependability over the last years. The implementation of a …

Reconstruction Of As-Built Civil Infrastructure Using Lidar To Support Digital Twin Visualization, Jose Luis Lugo

Open Access Theses & Dissertations

Digital twin (DT) technology is state-of-the-art for engineering processes using a virtual model of a physical system with near real-time data exchange (either fully or semi-automated) during the process (collection and feedback). The potential of DT for as-built civil infrastructure remains relatively unexplored. To achieve the expectation of a DT, three main capacities must be met: (1) accurate virtual twin of physical asset (2) continuous data acquisition and data management (3) automated or semi-automated decision making from the data exchange. The challenge addressed herein is to determine a feasible approach to create an accurate virtual model (efficiently) from light detection …

Rational Design Of Composite Nanomaterials For Water Treatment Applications, Mariana Marcos-Hernandez

Open Access Theses & Dissertations

Water quantity and quality have been affected in communities all around the world due to population growth, pollution, changes in land use, and climate change. In order to cope with existing and anticipated water demands and shortages, the use of treated or reclaimed water is an ongoing alternative that has helped communities all over the world address this problem. The adaptation of nanotechnology to traditional water and wastewater treatment processes offers new opportunities in technological developments. Unique size-dependent properties such as: high surface to mass ratio, high reactivity, high sorption capacities, fast dissolution, superparamagnetism, among others, provide high-tech efficient materials …

Femtosecond Laser Machining Of Drilled Holes In Silicon Nitride, Stephani Nevarez

Open Access Theses & Dissertations

In this study, the laser drilling parameters of a Nd:YAG ultrashort pulsed laser are evaluated to produce zero taper through holes on silicon nitride ceramics. Manufacturing of ceramics is expensive and difficult because of the mechanical and thermal properties of ceramics, limiting applications. Additionally, the high level hardness of the ceramic can affect the ceramic and the manufacturing tool. There is a need to explore non-contact machining such as laser machining to expand the uses of ceramics in industry applications.In order to accomplish this goal, understanding of the physical mechanisms that occurs while laser ablation is needed. Furthermore, the minimum …

Evolution Of The Magnetic Properties On Van Der Waals Layered Magnets Via Pressure And Proton Irradiation, Rubyann Olmos

Open Access Theses & Dissertations

Probing the magnetism in quasi two-dimensional materials has the potential in driving their properties towards future use in spin electronic based devices. Studying such layered magnets will enable the scientific community to uncover tunable exotic phases such as superconductivity, quantum paramagnetism, etc. This work examines the influence of two types of external perturbations, namely, the pressure and proton irradiation, on the magnetic properties of several compounds in the van der Waals crystal family.

Pressure has been found to induce structural and magnetic phase transitions in many of these materials. Using hydrostatic pressure as a disorderless approach to manipulate the interlayer …

Electric Power Grid Resilience Under Extreme Weather Events, Orlando Quezada Simental

Open Access Theses & Dissertations

Electric power distribution grids are experiencing blackouts at higher rates than ever before due to extreme weather, leaving hundreds of customers without electric energy for hours or even days. While these events are considered low-probability events, the socioeconomic costs and impacts are extensive as the distribution systems are unreliable under emergency events. The improvement of the resilience of the power distribution system can be accomplished through the implementation of microgrids (MGs) throughout the grid, which can be constituted by distributed energy resources (DERs) such as solar roof-top PV generation and electric vehicles (EVs) and many others. The development of new …

Investigation Of Refractory High Entropy Alloys For Extreme Environment Applications, Rebecca Alexandra Romero

Open Access Theses & Dissertations

High entropy alloys (HEAs) have emerged as an exciting class of materials with the potential for a wide range of structural, high-temperature applications. HEAs may be defined on a compositional basis as five or more principal elements in equimolar ratios. This definition led to the term “high entropy” due to the high configurational entropy which is obtained with principal elements in these amounts. The combination of elements has contributed to materials that may favor solid-solution phases over intermetallic phases and have the potential to possess highly desired material properties including high yield and creep strength. The inclusion of refractory metals …

Development Of An Automated Electronic Prototyping System, Cesar Yahir Sanchez Zambrano

Open Access Theses & Dissertations

Prototyping systems with interconnected components can be a time and resource expensive process. The process consists of three main phases (design, build and analysis) with each having their own associated cost. For the case of electronic circuits, the building phase is the costliest phase among the three, being prone to human errors which causes the circuit to fail. All three phases of the prototyping process are important. However, often a disproportionate amount of time is spent on the build phase due to the difficulty of making and troubleshooting circuits by hand. In this thesis we will discuss a system that …