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Full-Text Articles in Engineering

Semi-Annual Progress Report #11, Missouri University Of Science And Technology. Inspire - University Transportation Center Sep 2022

Semi-Annual Progress Report #11, Missouri University Of Science And Technology. Inspire - University Transportation Center

Semi-Annual Progress Reports

No abstract provided.


Estimation Of The Bubble Point Pressure Of Multicomponent Reservoir Hydrocarbon Fluids, Benjamin Sunday Usen, Chidi Obi Sep 2022

Estimation Of The Bubble Point Pressure Of Multicomponent Reservoir Hydrocarbon Fluids, Benjamin Sunday Usen, Chidi Obi

Makara Journal of Science

This study developed a novel C-sharp (C#) programming language for the estimation of bubble point pressure (BPP) of various hydrocarbon mixtures at equilibrium state. The methodology was based on vapor–liquid equilibrium calculation using Peng Robinson equation of state implementation, thermodynamic equilibrium calculation and Newton-Raphson’s method for the successive substitution of the unknown variables. The equal fugacity constraint can be satisfied by obtaining the equilibrium which serves as a criterion for two or more phases to exist at equilibrium. The problem was resolved by searching for a pressure that will satisfy the two constraints. Complex calculation was performed by successively substituting …


Synthesizing And Printing Of Tin Oxide Nanoparticles Using A Single Ultrafast Laser System: A Feasibility Study, Enrique Contreras Lopez, Farid Ahmed, Jianzhi Li Sep 2022

Synthesizing And Printing Of Tin Oxide Nanoparticles Using A Single Ultrafast Laser System: A Feasibility Study, Enrique Contreras Lopez, Farid Ahmed, Jianzhi Li

Manufacturing & Industrial Engineering Faculty Publications

In laser-based manufacturing, processing setup customization is one of the popular approaches used to enhance diversity in material processing using a single laser. In this study, we propose setup design modification of an ultrafast laser system to demonstrate both Tin Oxide (SnO2) nanoparticle synthesis from bulk metal, and post printing of said nanoparticles using Laser Induced Forward Transfer (LIFT) method. Using the Pulse Laser Ablation in Liquid (PLA-L) method, nanoparticles were synthesized from a bulk tin metal cube submerged in distilled water. Such nanoparticles dispersed in water can form colloidal ink that can be used for different printed electronics applications. …


Hydrogel And Graphene Embedded Piezoresistive Microcantilever Sensor For Solvent And Gas Flow Detection, Dipannita Ghosh, Md. Ashiqur Rahman, Ali Ashraf, Nazmul Islam Sep 2022

Hydrogel And Graphene Embedded Piezoresistive Microcantilever Sensor For Solvent And Gas Flow Detection, Dipannita Ghosh, Md. Ashiqur Rahman, Ali Ashraf, Nazmul Islam

Electrical and Computer Engineering Faculty Publications

Piezoresistive microcantilever sensor is widely used in sensing applications including liquid and gas flow detection. Microcantilevers can function as an embedded system if they are coated with polymers or nanomaterials to improve sensing performance. In this paper, we investigated the performance of piezoresistive microcantilevers (PMC) with and without additional coating. We studied the sensitivity of the PMC sensor after coating it with a three-dimensional porous hydrogel and piezoresistive graphene oxide layer. Hydrogel embedded piezoresistive microcantilever (EPM) showed better results than PMC during solvent sensing application. The resistance change for hydrogel embedded PMC was higher compared to bare PMC by 430% …


A Numerical Study On The Powder Flowability, Spreadability, Packing Fraction In Powder Bed Additive Manufacturing, Yeasir Mohammad Akib, Ehsan Marzbanrad, Farid Ahmed, Jianzhi Li Sep 2022

A Numerical Study On The Powder Flowability, Spreadability, Packing Fraction In Powder Bed Additive Manufacturing, Yeasir Mohammad Akib, Ehsan Marzbanrad, Farid Ahmed, Jianzhi Li

Manufacturing & Industrial Engineering Faculty Publications

The powder bed fusion (PBF) process is widely adopted in many manufacturing industries because of its capability to 3D print complex parts with micro-scale precision. In PBF process, a thermal energy source is used to selectively fuse powder particles layer by layer to build a part. The build quality in the PBF process primarily depends on the thermal energy deposition and properties of the powder bed. Powder flowability, powder spreading, and packing fraction are key factors that determine the properties of a powder bed. Therefore, the study of these process parameters is essential to better understand the PBF process. In …


Ultrafast Laser Direct Writing Of Conductive Patterns On Polyimide Substrate, Ishrat Jahan Biswas, Enrique Contreras Lopez, Farid Ahmed, Jianzhi Li Sep 2022

Ultrafast Laser Direct Writing Of Conductive Patterns On Polyimide Substrate, Ishrat Jahan Biswas, Enrique Contreras Lopez, Farid Ahmed, Jianzhi Li

Manufacturing & Industrial Engineering Faculty Publications

Laser direct writing (LDW) is a fast and cost-effective method for printing conductive patterns in flexible polymer substrates. The electrical, chemical, and mechanical properties of polyimide (PI) make it an attractive material choice for laser writing of conductive circuits in such polymer. Electrically insulating PI has shown great potential for flexible printed electronics as LDW enables selective carbonization in the bulk of such material leading to the formation of conductive lines. However, existing studies in this area reveal a few key limitations of this approach including limited conductivity of written structures and fragility of carbonized PI. Therefore, more research is …


Investigation Of Adhesion, Deformation Mechanics, And Electrical Properties Of Ag/Sio2/Pdms Tri-Layers For Stretchable Electronic Applications, Rhandy Joe Paladines Sep 2022

Investigation Of Adhesion, Deformation Mechanics, And Electrical Properties Of Ag/Sio2/Pdms Tri-Layers For Stretchable Electronic Applications, Rhandy Joe Paladines

Theses and Dissertations

The motivation behind this research is to improve the interfacial layer bonding of metallic thin films to PDMS substrates with the aid of a buffer layer. The physical vapor deposition (PVD) technique of sputtering was used to deposit bilayer thin films of silver (Ag) and silicon dioxide (SiO2) on PDMS. Two chamber pressures were used in this work, 5 and 20 mTorr, to investigate the role of this parameter in determining the interfacial adhesion and the role in determining the resistance sensitivity. Studies of the surface energy and increased bonding strength for metallization are carried out. Surface characterization using atomic …


Pulsed Lased Deposition Of Single-Crystalline (001) Oriented Pb(Zr0.5t0.5)O3 Thin Film On Prsco3 Substrate, Mahamudu H. Mtebwa, Nava Setter Sep 2022

Pulsed Lased Deposition Of Single-Crystalline (001) Oriented Pb(Zr0.5t0.5)O3 Thin Film On Prsco3 Substrate, Mahamudu H. Mtebwa, Nava Setter

Tanzania Journal of Science

High quality thin films are important for domain engineering applications such as on-volatile memory applications. Single crystalline (001) oriented Pb (Zr0.5T0.5)O3 thin films have been grown by pulsed laser deposition on PrScO3 with strontium ruthenate (SRO) electrodes. Thin films were prepared from PZT ceramic targets with 15% excess PbO to compensate for lead loss at high deposition temperature. Layer by layer/step flow growth mode observed on AFM images has been realised by using a single terminated PrScO3 substrate as well as optimized deposition parameters. XRD measurements have confirmed the highly (001) oriented tetragonal symmetry. Furthermore, analysis conducted using piezoresponse force …


Effects Of Multilayer Structure On The Microstructure And Optical Properties Of The Dc Sputtered Chromium Thin Films For Selective Solar Absorber Applications, Justine J. Tibaijuka, Margaret E. Samiji, Mmantsae Diale, Nuru R. Mlyuka Sep 2022

Effects Of Multilayer Structure On The Microstructure And Optical Properties Of The Dc Sputtered Chromium Thin Films For Selective Solar Absorber Applications, Justine J. Tibaijuka, Margaret E. Samiji, Mmantsae Diale, Nuru R. Mlyuka

Tanzania Journal of Science

Chromium thin films exhibit several properties that make them potential for solar thermal applications. In this work the effect of film thickness and sputtering power based multilayer structure on the optical properties of DC sputtered chromium thin films is reported. The structural, topological, and optical properties of these films were determined by X-ray diffractometer, Atomic Force Microscopy, and Ultraviolet-Visible-Near Infrared spectrophotometer, respectively. XRD spectra revealed a single peak with preferential orientation of (200) and (210) for single layer and multilayer chromium films, respectively. The grain size and roughness were relatively higher for the multilayer compared to single layer Chromium films. …


Synthesis Of Alginate/Hydroxyapatite Beads For Acetaminophen Delivery, Anesylvia Angan, Nonni Soraya Sambudi Sep 2022

Synthesis Of Alginate/Hydroxyapatite Beads For Acetaminophen Delivery, Anesylvia Angan, Nonni Soraya Sambudi

Makara Journal of Science

Conventional drug delivery systems usually involve the intake of multiple drugs, which could amplify the risk of overdosing. Acetaminophen is a widely used pain relief substance that is prone to accidental overdosing. Hence, a controlled drug delivery system is needed to ensure its efficacy. A nanocomposite hydroxyapatite/alginate system that was used as a drug carrier for acetaminophen was synthesized through the sol-gel method, and the mechanism underlying its controlled drug delivery was investigated. Spherical nanocomposite bead samples were synthesized by incorporating 5 wt%, 10 wt%, and 15 wt% hydroxyapatite into mixtures containing alginate. The mixtures were then dropped into calcium …


Machine Learning-Based Peripheral Artery Disease Identification Using Laboratory-Based Gait Data, Ali Al-Ramini, Mahdi Hassan, Farahnaz Fallahtafti, Mohammad Ali Takallou, Hafizur Rahman, Basheer Qolomany, Iraklis I. Pipinos, Fadi M. Alsaleem, Sara A. Myers Sep 2022

Machine Learning-Based Peripheral Artery Disease Identification Using Laboratory-Based Gait Data, Ali Al-Ramini, Mahdi Hassan, Farahnaz Fallahtafti, Mohammad Ali Takallou, Hafizur Rahman, Basheer Qolomany, Iraklis I. Pipinos, Fadi M. Alsaleem, Sara A. Myers

Department of Mechanical and Materials Engineering: Faculty Publications

Peripheral artery disease (PAD) manifests from atherosclerosis, which limits blood flow to the legs and causes changes in muscle structure and function, and in gait performance. PAD is underdiagnosed, which delays treatment and worsens clinical outcomes. To overcome this challenge, the purpose of this study is to develop machine learning (ML) models that distinguish individuals with and without PAD. This is the first step to using ML to identify those with PAD risk early. We built ML models based on previously acquired overground walking biomechanics data from patients with PAD and healthy controls. Gait signatures were characterized using ankle, knee, …


Machine Learning-Based Peripheral Artery Disease Identification Using Laboratory-Based Gait Data, Ali Al-Ramini, Mahdi Hassan, Farahnaz Fallahtafti, Mohammad Ali Takallou, Basheer Qolomany, Iraklis I. Pipinos, Fadi Alsaleem, Sara A. Myers Sep 2022

Machine Learning-Based Peripheral Artery Disease Identification Using Laboratory-Based Gait Data, Ali Al-Ramini, Mahdi Hassan, Farahnaz Fallahtafti, Mohammad Ali Takallou, Basheer Qolomany, Iraklis I. Pipinos, Fadi Alsaleem, Sara A. Myers

Department of Mechanical and Materials Engineering: Faculty Publications

Peripheral artery disease (PAD) manifests from atherosclerosis, which limits blood flow to the legs and causes changes in muscle structure and function, and in gait performance. PAD is underdiagnosed, which delays treatment and worsens clinical outcomes. To overcome this challenge, the purpose of this study is to develop machine learning (ML) models that distinguish individuals with and without PAD. This is the first step to using ML to identify those with PAD risk early. We built ML models based on previously acquired overground walking biomechanics data from patients with PAD and healthy controls. Gait signatures were characterized using ankle, knee, …


Pace Oci Short-Wave Infrared Detection Assembly Frequency-Dependent Linearity Characterization And Uncertainty Analysis, Kenneth J. Squire, Jacob Hedelius, David K. Moser, James Q. Peterson, Eric T. Gorman, Emily Kan, D. Brent Mott, Ulrik B. Gliese, Gerhard Meister Sep 2022

Pace Oci Short-Wave Infrared Detection Assembly Frequency-Dependent Linearity Characterization And Uncertainty Analysis, Kenneth J. Squire, Jacob Hedelius, David K. Moser, James Q. Peterson, Eric T. Gorman, Emily Kan, D. Brent Mott, Ulrik B. Gliese, Gerhard Meister

Space Dynamics Laboratory Publications

The Ocean Color Instrument (OCI), the primary payload of the Plankton, Aerosol, Cloud, ocean Ecosystem (PACE) observatory, will collect data to monitor the health of Earth’s oceans and atmosphere. The Short-Wave Infrared (SWIR) Detection Assembly (SDA) was built and characterized by the Utah State University Space Dynamics Laboratory (SDL) and is a subsystem of OCI. The SDA measures seven bands centered at 940, 1038, 1250, 1378, 1615, 2130, and 2260 nm, with standard- and high-gain varieties for the 1250 and 1615 nm bands, resulting in nine total detection configurations in the SWIR. The delivery of high-quality science data is critically …


Infrared Spectral Responses Of The Ocean Color Instrument (Oci) Pre-Assembly And Integration, Jacob K. Hedelius, Kenneth J. Squire, James Q. Peterson, Branimir Blagojević, Ulrik B. Gliese, Eric T. Gorman, David K. Moser, Zakk Rhodes, Pedro Sevilla, Gerhard Meister Sep 2022

Infrared Spectral Responses Of The Ocean Color Instrument (Oci) Pre-Assembly And Integration, Jacob K. Hedelius, Kenneth J. Squire, James Q. Peterson, Branimir Blagojević, Ulrik B. Gliese, Eric T. Gorman, David K. Moser, Zakk Rhodes, Pedro Sevilla, Gerhard Meister

Space Dynamics Laboratory Publications

Spectral characterizations were made of the Ocean Color Instrument (OCI) short-wave infrared (SWIR) Detection Subassembly (SDS) responses (940–2260 nm) prior to their integration. Using modulated output light from a Fourier transform spectrometer, the in-band relative spectral responses of the nine different configurations of SDSs were found along with out-of-band (OOB) sensitivity. From these spectral responses, the center wavelengths (λ0), full widths at half of the maximum, full widths at 1% of the maximum, and OOB rejection ratios were determined. All spectral parameters are within requirements. There are 2–8 repeats of each configuration, and the 1 σ spread among …


Heterogeneous Learning Method Of Ensemble Classifiers For Identification And Classification Of Power Quality Events And Fault Transients In Wind Power Integrated Microgrid, Arangarajan Vinayagam, Veerapandiyan Veerasamy, Mohd Tariq, Asma Aziz Sep 2022

Heterogeneous Learning Method Of Ensemble Classifiers For Identification And Classification Of Power Quality Events And Fault Transients In Wind Power Integrated Microgrid, Arangarajan Vinayagam, Veerapandiyan Veerasamy, Mohd Tariq, Asma Aziz

Research outputs 2022 to 2026

This paper proposes heterogeneous based ensemble Classifiers (voting and stacking method) to identify and classify different power system disturbances (power quality (PQ), faults, transients, and wind power variation) in wind integrated microgrid network. In the pre-processing stage of classification, a Discrete wavelet transform (DWT) technique is applied to extract the features from power system disturbance signals. The classification process for the proposed ensemble models involves two levels of classification. At the first level, the extracted features from the simulated power system events are used to learn the different individual base classifiers (logistic regression (LR), K-Nearest Neighbor (KNN), and J48 Decision …


2022 Symposium On Education In Entertainment And Engineering Supplemental Program, Mary K. Pillotte, Rich Dionne Sep 2022

2022 Symposium On Education In Entertainment And Engineering Supplemental Program, Mary K. Pillotte, Rich Dionne

Symposium on Education in Entertainment and Engineering

No abstract provided.


2022 Symposium On Education In Entertainment And Engineering, Mary K. Pillotte, Rich Dionne Sep 2022

2022 Symposium On Education In Entertainment And Engineering, Mary K. Pillotte, Rich Dionne

Symposium on Education in Entertainment and Engineering

No abstract provided.


Studio D Institute – Making At A Distance And The Impact Of Collaboration, Marlo Ransdell, Robert H. Coleman Sep 2022

Studio D Institute – Making At A Distance And The Impact Of Collaboration, Marlo Ransdell, Robert H. Coleman

Symposium on Education in Entertainment and Engineering

No abstract provided.


The Impact Of Passenger Characteristics On Use Of Self-Service Technologies For Check-In Process: A Case Study Of Sydney Airport, Sarika Tyagi, Gabriel Lodewijks Sep 2022

The Impact Of Passenger Characteristics On Use Of Self-Service Technologies For Check-In Process: A Case Study Of Sydney Airport, Sarika Tyagi, Gabriel Lodewijks

Journal of Aviation Technology and Engineering

Due to the severe global competition in the aviation industry, airports give top priority to passenger services. Therefore, a study of characteristics associated with passenger services is one of the most important measurements in the aviation industry. The objective of this study was to analyze the impact of passenger characteristics on the use of self-service technology (SST) for the check-in process at Sydney Kingsford Smith Airport. A survey was conducted online amid the COVID-19 pandemic for data collection. Based on the collected responses, this study analyzed the sociological and demographic characteristics of the passengers and situational factors related to characteristics …


Towards Environmentally Sustainable, High-Performance, Lightweight Composites For Automotive Applications, Jasmin Zamudio Vasquez Sep 2022

Towards Environmentally Sustainable, High-Performance, Lightweight Composites For Automotive Applications, Jasmin Zamudio Vasquez

Theses and Dissertations

The increasing public demand in the world automotive industry to improve the environmental sustainability of their manufactured vehicles without sacrificing drivers' comfort and safety and the high cost of lightweight materials have driven researchers to reconsider materials used in the automotive application. Thus, this work aims toward the production of environmentally sustainable, high-performance, lightweight composites, utilizing recycled carbon fibers (RCFs) and pyrolyzed tire particles (PTPs) reclaimed from pyro-gasification of CFRP wastes and end-of-life tires (ELTs), respectively, as reinforcements for cardanol-based epoxy resins. The fabricated composites exhibited rubbery-like behavior at 25 °C. Spectroscopic, rheological, physical, thermal, thermomechanical, and mechanical characterizations were …


Investigating The First/Last Mile Problem In Underserved Communities: A Case Study In Camden City, Nj, Ruqaya Alfaris Sep 2022

Investigating The First/Last Mile Problem In Underserved Communities: A Case Study In Camden City, Nj, Ruqaya Alfaris

Theses and Dissertations

The first/last mile (FLM) is defined as the distance a transiting person should complete before boarding or after alighting at a transit station. The FLM trip is one of the major barriers to access transit, which significantly affects individuals' accessibility to critical services. Specifically, this is prevalent in underserved communities in which public transportation constitutes the major mode of travel. As a case study, the current study discusses the FLM barriers in Camden City, NJ. The study comprehensively reviews the existing literature of the FLM practice to identify the lessons learned from previously conducted plans and programs. To supplement the …


Toward Mental Effort Measurement Using Electrodermal Activity Features, William Romine, Noah Schroeder, Tanvi Banerjee, Josephine Graft Sep 2022

Toward Mental Effort Measurement Using Electrodermal Activity Features, William Romine, Noah Schroeder, Tanvi Banerjee, Josephine Graft

Computer Science and Engineering Faculty Publications

The ability to monitor mental effort during a task using a wearable sensor may improve productivity for both work and study. The use of the electrodermal activity (EDA) signal for tracking mental effort is an emerging area of research. Through analysis of over 92 h of data collected with the Empatica E4 on a single participant across 91 different activities, we report on the efficacy of using EDA features getting at signal intensity, signal dispersion, and peak intensity for prediction of the participant's self-reported mental effort. We implemented the logistic regression algorithm as an interpretable machine learning approach and found …


Statistical Modeling And Optimization Of Process Parameters For 2, 4-Dichlorophenoxyacetic Acid Removal By Using Ac/Pdmaema Hydrogel Adsorbent: Comparison Of Different Rsm Designs And Ann Training Methods, Irvan Dahlan, Emilia Eizleen Md Azhar, Siti Roshayu Hassan, Hamidi Abdul Aziz, Yung-Tse Hung Sep 2022

Statistical Modeling And Optimization Of Process Parameters For 2, 4-Dichlorophenoxyacetic Acid Removal By Using Ac/Pdmaema Hydrogel Adsorbent: Comparison Of Different Rsm Designs And Ann Training Methods, Irvan Dahlan, Emilia Eizleen Md Azhar, Siti Roshayu Hassan, Hamidi Abdul Aziz, Yung-Tse Hung

Civil and Environmental Engineering Faculty Publications

In this study, the response surface methodology (RSM) and artificial neural network (ANN) were employed to study the adsorption process of 2,4-dichlorophenoxyacetic acid (2,4-D) by using modified hydrogel, i.e., activated carbon poly(dimethylaminoethyl methacrylate) (AC/PDMAEMA hydrogel). The effect of pH, the initial concentration of 2,4-D and the activated carbon content on the removal of 2,4-D and adsorption capacity were investigated through the face-centered composite design (FCCD), optimal design and two-level factorial design. The response surface plot suggested that higher removal of 2,4-D and adsorption capacity could be achieved at the higher initial concentration of 2,4-D and lower pH and activated carbon …


Non-Proprietary Ultra-High Performance Concrete (Uhpc) With Application For Retrofitting Deteriorating Infrastructure, Harshdutta I. Pandya Sep 2022

Non-Proprietary Ultra-High Performance Concrete (Uhpc) With Application For Retrofitting Deteriorating Infrastructure, Harshdutta I. Pandya

Theses and Dissertations

This research describes a study on the stiffness degradation of reinforced concrete beams due to corrosion of reinforcement and the effect of subsequent retrofitting. A total of eleven beams were tested under cyclic loading history, where the amplitude on subsequent cycles is increased until the beam fails. The two corroded-repaired beams were repaired with a non-proprietary UHPC applied to the tension and compression surfaces, respectively. The results indicated substantial stiffness degradation of the corroded beam that was not retrofitted. The control beam passed the ACI 437 acceptance criteria (Ipr = 0.22, IR = 100.1, IDL = -0.036). The corroded beam …


An Introductory Module In Medical Image Segmentation For Bme Students, Christine Buffinton, Donna Ebenstein, James W. Baish Sep 2022

An Introductory Module In Medical Image Segmentation For Bme Students, Christine Buffinton, Donna Ebenstein, James W. Baish

Faculty Journal Articles

To support recent trends toward the use of patient-specific anatomical models from medical imaging data, we present a learning module for use in the undergraduate BME curriculum that introduces image segmentation, the process of partitioning digital images to isolate specific anatomical features. Five commercially available software packages were evaluated based on their perceived learning curve, ease of use, tools for segmentation and rendering, special tools, and cost: ITK-SNAP, 3D Slicer, OsiriX, Mimics, and Amira. After selecting the package best suited for a stand-alone course module on medical image segmentation, instructional materials were developed that included a general introduction to imaging, …


Preface To Special Issue On Water Electrolysis For Hydrogen Production, Li Li, Jin-Song Hu, Zi-Dong Wei Sep 2022

Preface To Special Issue On Water Electrolysis For Hydrogen Production, Li Li, Jin-Song Hu, Zi-Dong Wei

Journal of Electrochemistry

No abstract provided.


Recent Development Of Low Iridium Electrocatalysts Toward Efficient Water Oxidation, Jing Ni, Zhao-Ping Shi, Xian Wang, Yi-Bo Wang, Hong-Xiang Wu, Chang-Peng Liu, Jun-Jie Ge, Wei Xing Sep 2022

Recent Development Of Low Iridium Electrocatalysts Toward Efficient Water Oxidation, Jing Ni, Zhao-Ping Shi, Xian Wang, Yi-Bo Wang, Hong-Xiang Wu, Chang-Peng Liu, Jun-Jie Ge, Wei Xing

Journal of Electrochemistry

Developing high-performance and low-cost electrocatalysts for oxygen evolution reaction (OER) is the key to implementing polymer electrolyte membrane water electrolyzer (PEMWE) for hydrogen production. To date, iridium (Ir) is the state-of-the-art OER catalyst, but still suffers from the insufficient activity and scarce earth abundance, which results in high cost both in stack and electricity. Design low-Ir catalysts with enhanced activity and stability that can match the requirements of high current and long-term operation in PEMWE is thus highly desired, which necessitate a deep understanding of acidic OER mechanisms, unique insights of material design strategies, and reliable performance evaluation norm, especially …


The Rapid Preparation Of Efficient Mofeco-Based Bifunctional Electrocatalysts Via Joule Heating For Overall Water Splitting, Ao Zhou, Wei-Jian Guo, Yue-Qing Wang, Jin-Tao Zhang Sep 2022

The Rapid Preparation Of Efficient Mofeco-Based Bifunctional Electrocatalysts Via Joule Heating For Overall Water Splitting, Ao Zhou, Wei-Jian Guo, Yue-Qing Wang, Jin-Tao Zhang

Journal of Electrochemistry

Water electrolysis is an available way to obtain green hydrogen. The development of highly efficient electrocatalysts is a current research hotspot for water splitting, but it remains challenging. Herein, we demonstrate the synthesis of a robust bifunctional multi-metal electrocatalysts toward water splitting via the rapid Joule-heating conversion of metal precursors. The composition and morphology were well regulated via altering the ratio of metal precursors. In particular, the trimetal MoC/FeO/CoO/carbon cloth (CC) electrode revealed the outstanding bifunctional electrocatalytic performance due to the unique composition and large electrochemical active surface area. Typically, the MoC/FeO/CoO/CC catalyst needed low overpotentials of 121 and 268 …


Perovskite-Type Water Oxidation Electrocatalysts, Xiao Liang, Ke-Xin Zhang, Yu-Cheng Shen, Ke Sun, Lei Shi, Hui Chen, Ke-Yan Zheng, Xiao-Xin Zou Sep 2022

Perovskite-Type Water Oxidation Electrocatalysts, Xiao Liang, Ke-Xin Zhang, Yu-Cheng Shen, Ke Sun, Lei Shi, Hui Chen, Ke-Yan Zheng, Xiao-Xin Zou

Journal of Electrochemistry

The development of energy conversion/storage technologies can achieve the reliable and stable renewable energy supply, and bring us a sustainable future. As the core half-reaction of many energy-related systems, water oxidation is the bottleneck due to its sluggish kinetics of the four-concerted proton-electron transfer (CPET) process. This necessitates the exploitation of low cost, highly active and stable water oxidation electrocatalysts. Perovskite-type oxides possess diverse crystal structures, flexible compositions and unique electronic properties, enabling them ideal material platform for the optimization of catalytic performance. In this review, we provide a comprehensive summary for the crystal structures, electronic structures and synthetic methods …


Self-Supporting Nife Ldhs@Co-Oh-Co3 Nanorod Array Electrode For Alkaline Anion Exchange Membrane Water Electrolyzer, Dan-Dan Guo, Hong-Mei Yu, Jun Chi, Zhi-Gang Shao Sep 2022

Self-Supporting Nife Ldhs@Co-Oh-Co3 Nanorod Array Electrode For Alkaline Anion Exchange Membrane Water Electrolyzer, Dan-Dan Guo, Hong-Mei Yu, Jun Chi, Zhi-Gang Shao

Journal of Electrochemistry

The development of efficient and durable electrodes for anion exchange membrane water electrolyzers (AEMWEs) is essential for hydrogen production. In this work, 2D NiFe layered double hydroxides (NiFe LDHs) nanosheets were grown on the 1D cobaltous carbonate hydroxide nanowires array (Co-OH-CO3) and the unique 3D layered self-supporting nanorod array (NiFe LDHs@Co-OH-CO3/NF) electrode was obtained. Importantly, we demonstrated an efficient and durable self-supporting NiFe LDHs@Co-OH-CO3/NF electrode for oxygen evolution reaction (OER) and as the anode of the AEMWE. In a three-electrode system, the self-supporting NiFe LDHs@Co-OH-CO3/NF electrode showed excellent catalytic activity for OER, …