Engineering Commons^™

Multipurpose Fluorescent Carbon Dots From Papaya Seed Waste As Sensing Materials For Cu2+ Detection And Diethyl Ether Vapor Sensor Via Electronic Nose System, Nichaphat Thongsai, Aphinya Chuiduang, Sumana Kladsomboon, Insik In, Peerasak Paoprasert

Journal of Metals, Materials and Minerals

Herein, carbon dots (CDs) as biocompatible, fluorescent carbon-based nanomaterials were synthesized from papaya seed waste as renewable carbon sources for the first time via a facile acid pyrolysis method. The papaya seed-derived CDs showed blue fluorescence emission under UV light (365 nm) with a quantum yield of 2.74%, and contained oxygen-, and nitrogen- containing functional groups. Due to their surface functionality, the CDs have a great potential for using as fluorescence sensing probe in metal ion sensing application. The CD solution exhibited the most selective detection to Cu2+ as presented the highest fluorescence quenching with the limit of detection (LOD) …

Synthesis And Characterization Of Electron Beam Irradiated Glutinous Rice Husk-Derived Biochar And Activated Carbon For Aqueous Electrochemical Capacitors, Kittapas Kitsanadecha, Charlita Sinmak, Patchanan Onchomchan, Kanit Hantanasirisakul, Tanagorn Kwamman, Suranan Anantachaisilp

Journal of Metals, Materials and Minerals

Glutinous rice husk, an abundant agricultural biowaste in Thailand, was pretreated with high energy electron beam irradiation (EBI) at doses of 500 kGy, 1000 kGy, and 1500 kGy prior to fabrication into biochar by carbonization at 500℃ under nitrogen atmosphere. The biochar was then treated with KOH and subsequently heated at 800℃, yielding activated carbon (GAC). The physical, chemical, and electrochemical properties of the as-received biochar (GB) and activated carbon (GAC) were investigated. Scanning electron microscopic images (SEM) suggested that biochar irradiated with 1500 kGy (GB-1500) has the highest porosity compared to the other samples. The electrochemical properties of GB …

Polyol Method And Surface Functionalization Of Silver Nanowires Using Bovine Serum Albumin For Surface-Enhanced Raman Scattering Application, Khoa Tien Cao, Khoi Khac Tran, Hue Thi Do

Journal of Metals, Materials and Minerals

Silver nanowires (AgNWs) with diverse applications are attracting the attention of many researchers around the world. In this study, we applied the polyol method to synthesize AgNWs based on Polyvinyl-pyrrolidone (PVP) average molecular weight of 360,000, ethylene glycol (EG), and AgNO3 precursor with a fresh AgCl preparation. To synthesize this material we first investigate optimal parameters through the influence of reaction temperature, time of creating AgNWs using plasmon absorption spectroscopy, and scanning electron microscope (SEM) images. The obtained AgNWs are high efficiency, large aspect ratio, and good dispersion in the solution. This sample continues to be conducted to surface functionalization …

Dispersion Mechanism Of Nanoparticles And Its Role On Mechanical, Thermal And Electrical Properties Of Epoxy Nanocomposites - A Review, Baljit Singh, Akash Mohanty, Amit Kumar Srivastava, Ajay Singh

Journal of Metals, Materials and Minerals

The combined effect of nano-reinforcements on the mechanical performance of nanocomposites, which are a novel class of epoxy matrix hybrid nanocomposites containing multiwall carbon nanotubes (MWCNT), graphene, and nanodiamonds (NDs), is drawing substantial attention from many research communities. The discussion concentrates on the dispersion techniques adopted for the preparation of epoxy composites containing different types of nanoparticles (3-D fillers, nanofibers, nanotubes, and plate-like fillers). This review paper covers the electrical, thermal, and mechanical properties of carbon nanotubes (CNTs), graphene, and nanodiamond-reinforced epoxy nanocomposites and correlates them with the topographical features, morphology, weight fraction, dispersion state, and surface functionalization of CNTs, …

Fabrication Of Granular Foam Glass Aggregates From Soda Lime Silicate Glass Waste, Pat Sooksaen, Phumin Prakaisri, Pattraporn Teerapatpanid, Pathompong Puathawee

Journal of Metals, Materials and Minerals

Granular foam glass aggregates were fabricated from a soda lime silicate glass waste which utilized crude glycerol as a foaming agent and sodium silicate as a binder. The granulation and the foaming process were carried out by a granulator and an electric rotary furnace. The study investigated at first the foaming behavior of different foam glass formulations at various sintering temperatures. Three compositions were formulated which utilized glass powder at 85 wt%, 90 wt%, and 95 wt%, respectively. Sintering was carried out at temperatures from 800℃ to 1200℃ to evaluate for the foaming and melting characteristics. Foam glass with 90% …

Study Of Corrosion Properties Of Carbon Steel, 304 And 316l Stainless Steels In Sulfuric Acid And Their Degradation Products, Eakapoj Khamme, Rachsak Sakdanuphab

Journal of Metals, Materials and Minerals

In this study, corrosion properties of carbon steel and stainless steels, and degradation of sulfuric acid by the corrosion mechanism are presented. Carbon steel (CS), 304 stainless steel (SS304), and 316L stainless steel (SS316L) specimens were analyzed through their electrochemical response by using a potentiostat measurement. The specimens were submerged in concentrated 98 wt.% of H2SO4 acid for 0 day to 60 day. The degradation of H2SO4 was determined by its volume change, turbidity, and color due to the corrosion mechanism. Corrosion rate of CS, SS304 and SS316L specimens are 43.237 mm/year, 0.420 mm/year and 0.086 mm/year, respectively. After 60 …

Microstructure And Mechanical Properties Of 0.2c-3.9al-1.12mn-0.3mo Δ-Trip Steel As A Function Of Isothermal Bainitic Transformation Temperature, Mahsa Gholambargani, Yahya Palizdar, Ali Khanlakhani, Ali Khanlakhani

Journal of Metals, Materials and Minerals

The present investigation employed a two-stage heat treatment on a δ-transformation-induced plasticity (TRIP) steel comprising 0.2C–4Al–1.2Mn–0.3Mo (wt%). The mechanical and microstructural characteristics that result from varied isothermal bainitic transformation (IBT) temperatures following inter-critical annealing at 820℃ for 10 min are thoroughly analyzed. The microstructure of the steels consisted of δ-ferrite, α-ferrite, bainitic ferrite, retained austenite (RA), and martensite, resulting in an optimum combination of the ultimate tensile strength (UTS) and total elongation (TE). The results of the investigation showed that IBT temperature had an effect on the stability of RA and the martensitic transition. Due to the increased mechanical stability …

Improvement Of Specific Capacity Of Lithium Iron Phosphate Battery By Increasing The Surface Area And Electrical Conductivity Of Cathode Electrode Using Graphene Foam, Phurida Kokmat, Patiphat Matsayamat, Kunaree Wongrach, Piyaporn Surinlert, Akkawat Ruammaitree

Journal of Metals, Materials and Minerals

Lithium iron phosphate (LFP) is widely used as an active material in a cathode electrode for lithium-ion batteries (LIBs). LFP has many remarkable properties such as high working voltage and excellent thermal stability. However, it suffers with slow ion diffusion and low electrical conductivity. Graphene foam has many outstanding properties such as large surface area and great electrical conductivity. These properties are suitable for improving the cathode electrode. In this work, the graphene foam was synthesized by chemical vapor deposition. The cathode electrode was prepared by dropping the LFP on the graphene foam. We found that the specific capacity of …

Synthesis Of Carbon Nanowalls By Oxy-Acetylene Torch Method, Bauyrzhan Zhumadilov, Aidar Kenzhegulov, Renata Nemkayeva, Gulmira Partizan, Yerassyl Yerlanuly, Maratbek Gadbullin

Journal of Metals, Materials and Minerals

This work presents a relatively new method for the synthesis of carbon nanowalls (CNWs) based on oxy-acetylene torch as a function of deposition time. The morphological and structural properties of the obtained CNW films were studied by scanning electron microscopy and Raman spectroscopy. Changes in the morphology and structural properties of the CNW films depending on the synthesis time were revealed. Shorter growth times lead to the formation of thinner CNW films with a dense labyrinth-like structure, while longer growth times lead to thicker CNW films with a petal-like structure. In addition, this study opens up the possibility of synthesizing …

Sustainable Innovation In Ballistic Vest Design: Exploration Of Polyurethane-Coated Hemp Fabrics And Reinforced Sandwich Epoxy Composites Against 9 Mm And .40 S&W Bullets, Tannachart Wantang, Manop Pipathattakul, Fasai Wiwatwongwana

Journal of Metals, Materials and Minerals

This research aimed to evaluate the bulletproof capabilities of hemp fabrics and optimize the design factors for effective ballistic vests. Three main aspects were investigated: enhancing toughness with polyurethane-coated hemp fabrics, determining optimal placement of fabric-reinforced hemp epoxy composites in various configurations, and identifying the optimal number of fabric layers for performance against 9 mm and .40 S&W bullets. Penetration depth was measured in ballistic gelatin to analyze the results. The study showed strong statistical correlations between factor variables and penetration depth shifts. The most effective strategies included polyurethane-coated hemp on all layers and increased layering. The ammunition of 9 …

Structural And Electrical Properties Of 0.98(Ko0.5na0.5onboo3)-0.02(Bio0.5nao0.5tioo3) Ceramics, Swayam Aryam Behera, Sugato Hajra, Swati Panda, Ali Amanat, P. G. R. Achary

Journal of Metals, Materials and Minerals

In the present communication, lead-free ceramics having composition 0.98(K0.5Na0.5NbO3)-0.02(Bi0.5Na0.5TiO3) were synthesized by a high-temperature solid-state reaction route. The Rietveld refinement for the 0.98KNN-0.02BNT reveals an MPB with phase fraction Amm2 (87.76 %) and Pm-3m (12.27%). The SEM study predicted a mean diameter of 0.98KNN-0.02BNT grains as 0.52µm±0.19. The 0.98KNN-0.02BNTceramic displayed a typical hysteresis loop with a remnant polarisation(Pr) of 7.0 μC/cm2, saturation polarization (Ps) of 16 μC/cm2, and a coercive field (Ec) of 26 kV/mm. The electrical, Raman spectra, dielectric, and hysteresis loop study supported a morphotropic phase boundary. The synthesized KNN-BNT lead-free material can be an excellent material for …

The Effects Of The Preparation Factors On The Properties Of Co2 Capture Sorbent Derived From Local Waste Eggshell, Janjeera Chuanchob, Pornpote Piumsomboon, Benjapon Chalermsinsuwan, Saowaluck Chanchairoek

Applied Environmental Research

In this study, the CaO adsorbent was prepared by using local waste eggshell as a raw material. The influence of preparation parameters including calcination temperature, calcination time and particle size of eggshell powder on the adsorption surface area were investigated. By means of statistically experiment design, the interesting parameters were investigated by a full 23 factorial design. The prepared sorbent material was characterized by X–ray diffraction (XRD), Scanning electron microscopy (SEM) and the Brunauer–Emmet–Teller (BET). The results showed the particle size of eggshell powder greatly affected the BET surface area. By applying the prepared condition of 149 μm in particle …

Evaluation Of E-Waste Generation Through G-Pestle Analysis In The City Of Zamboanga, Philippines: Basis For Management Strategies, Mary Ann Beth L. Kong, Edwin R. De Los Reyes, Francis Dave C. Siacor

Applied Environmental Research

Due to a growth in the production of electronic waste (e-waste), the Philippines, particularly Zamboanga City, a top-tier, highly urbanized city on the Zamboanga Peninsula, is coping with an e-waste problem. Understanding the outside forces influencing e-waste management is necessary for creating effective strategies. With the help of a G-PESTLE analysis (geographical, political, economic, social, technical, legal, and environmental) and recommendations for improvement, this study assessed the city's existing e-waste management situation. The study looks at possibilities and problems, then offers management tactics based on the results. The study employed a hybrid methodology. Using the G-PESTLE analysis framework, the external …

Phosphorus Speciation And Heavy Metal Levels In Ogun River Sediments At Different Anthropogenic Locations In Abeokuta, Ogun State, Olayinka Oluwafunmilayo Olasunbo, Opatoyinbo Oluwabamise Esther, Olujimi Olarenwaju Olusoji, Azeez Jamiu Oladipupo, Oyebanji Adedayo Olamide

Applied Environmental Research

Phosphorus (P) is an essential nutrient for phytoplankton growth in water bodies and an important element in biochemical processes. Also, excessive P in river causes eutrophication which endangers aquatic organisms while sediment acts as sink for inorganic and organic pollutants and nutrients. To assess the availability of P and heavy metals (HMs) in Ogun River, surface sediment samples were collected at twelve anthropogenic sites for three months. The surface sediment samples were sequentially extracted to determine five phosphorus fractions [loosely-sorbed P (LS-P), iron-bound P (Fe-P), authigenic apatite, biogenic apatite and CaCO3-bound P (CFA-P), detrital apatite (Det-P) and other inorganic P …

Removal Of Diclofenac In Wastewater By Activated Sludge In Batch And Moving-Bed Biofilm Reactor Experiments, Keletso Chakalisa, Piriyakorn Injai, Kullapa Chanawanno, Panaya Kotchaplai, Pumis Thuptimdang

Applied Environmental Research

This study aimed to determine the diclofenac removal in wastewater by sludge taken from an operating wastewater treatment facility. Laboratory experiments were conducted in two parts: batch and moving-bed biofilm reactor (MBBR) experiments. Results from batch experiments showed that 0.1–2 mg L-1 of diclofenac could be removed more than 80% within 72 h, and the removal efficiency reduced to less than 60% for higher concentrations. The increase in the removal rate from 0.00058 to 0.16527 mg L-1 h-1 was observed when the initial diclofenac concentration increased from 0.1 to 10 mg L-1, respectively. The average first-order rate constants of 24-h …

The Role Of Bacteria And Factors Affecting The Decomposition Of Pollutants In The Biofilter Reactor: A Review, Muliyadi Muliyadi, Purwanto Purwanto, Sri Sumiyati, Sudarno Sudarno, Budiyono Budiyono, Budi Warsito, Hadiyanto Hadiyanto

Applied Environmental Research

The findings showed that several types of bacteria can help biodegrade organic pollutants, such as Comamonadacea, which can biodegrade volatile fatty acids and aromatic compounds. Proteobacteria, Bacteroidetes, and Actinobacteria can biodegrade ammonium. Burkholderiales can biodegrade ferric ions and hydrogen. Comamonas testosteroni is able to biodegrade nitrates. Pseudomonas taiwanensis, Acinetobacter guillouiae, and Klebsiella pneumoniae can reduce copper, chromium and zinc levels. Azolla biomass reduces strontium. Rhodospirillum sp. can biodegrade cadmium, mercury, lead, and nickel. Gallionella ferruginea and Leptothrix sp. can biodegrade arsenic and manganese. Gracilaria sp. can biodegrade aluminum, chromium, and zinc. Desulfovibrio sp. can …

An Unmanned Aircraft System For Marking Live Power Lines To Prevent Bird Collisions, Mattheuns D. Pretorius, Lourens Leeuwner, Kaajial Durgapersad, Constant Hoogstad, Peter Beckedahl, Michael D. Michael, Kishaylin Chetty

Human–Wildlife Interactions

Collisions with overhead power lines represent a significant cause of mortality for a number of large bird species worldwide. Certain threatened species are severely impacted by power line collisions, particularly those for which there are no other known significant threats. In South Africa, bird collisions with overhead power line cables, including collisions with phase conductors and shield wires, contribute significantly to annual threatened bird species mortalities associated with Eskom power lines. The most practical mitigation measure is to attach bird anti-collision devices as markers on the cables. Current marking methods involve installations by hand, where linemen are hoisted up to …

The American Multi-Modal Energy System: Model Development With Structural And Behavioral Analysis Using Hetero-Functional Graph Theory, Dakota John Thompson

Dartmouth College Ph.D Dissertations

In the 21st century, infrastructure is playing an ever greater role in our daily lives. Presidential Policy Directive 21 emphasizes that infrastructure is critical to public confidence, the nation's safety, and its well-being. With global climate change demanding a host of changes across at least four critical energy infrastructures: the electric grid, the natural gas system, the oil system, and the coal system, it is imperative to study models of these infrastructures to guide future policies and infrastructure developments. Traditionally these energy systems have been studied independently, usually in their own fields of study. Therefore, infrastructure datasets often lack the …

Fostering Safer Evacuations Aboard Commercial Aircraft: A Problem-Solution Analysis, George Skinner

Student Works

This problem-solution analysis analyzes factors impeding safe and orderly evacuations for the Federal Aviation Administration (FAA). Although rarely used, evacuation procedures are critical for keeping passengers safe during emergency situations. However, there are flaws in these procedures and many factors exist which make aircraft evacuations slow and dangerous. During a situation in which time is of the essence, these impediments can make the difference between an incident and a fatal accident. This report focuses on data gathered through full-scale evacuation simulations and analyzes shortcomings and strengths in three accidents. This information is then compared to current procedures and regulations that …

Solar Sailing Adaptive Control Using Integral Concurrent Learning For Solar Flux Estimation, Luis Enrique Mendoza Zambrano, Riccardo Bevilacqua

Student Works

In the interest of exploiting natural forces for propellant-less spacecraft missions, this investigation proposes an adaptive control strategy to account for unknown parameters in the dynamic modeling of a reflectivity-controlled solar sail spacecraft. A Lyapunov-based control law along with integral concurrent learning is suggested to accomplish and prove global exponential tracking of the estimated parameters and states of interest, without satisfying the common persistence of excitation condition, which in most nonlinear systems cannot be guaranteed a priori. This involves estimating the solar flux or irradiance from the Sun to account for uncertainty and variation over time in this value. To …

Dual Quaternion Relative Dynamics For Gravity Recovery Missions, Ryan Kinzie, Riccardo Bevilacqua, Seo Dongeun

Student Works

A dual quaternion modeling approach is compared to traditional modeling methods for formation flying spacecraft utilized for gravity recovery missions. A modeling method that has traditionally been used for gravity recovery missions is presented which models the motion of two formation flying spacecraft and a test mass. This is followed by the dual quaternion-based formulation for the equations of motion of the twelve degree-of-freedom coupled relative dynamics of formation flying spacecraft and a test mass. Lastly, utilizing data products from the Gravity Recovery and Climate Experiment Follow-On mission, a comparison of these two modeling methods is presented which proves the …

Experimental Validation Of Inertia Parameters And Attitude Estimation Of Uncooperative Space Targets Using Solid State Lidar, Alessia Nocerino, Roberto Opromolla, Giancarmine Fasano, Michele Grassi, Spencer John, Hancheol Cho, Riccardo Bevilacqua

Student Works

This paper presents an experimental activity aimed at assessing performance of techniques for inertia and attitude parameters estimation of an uncooperative but known space target. The adopted experimental set-up includes a scaled-down 3D printed satellite mock-up, a spherical air bearing and a low-cost solid-state LIDAR. The experimental facility also comprises a motion capture system to obtain a benchmark of the pose (position and attitude) parameters and an ad-hoc designed passive balancing system to keep the centre of mass as close as possible to the centre of rotation. The LIDAR-based 3D point clouds, collected while the target rotates on the spherical …

V3: Flight Simulator Technology, Isaac Chung, Genta Adjie

Student Works

Long were the days of relying solely on textbook readings and real-time flying where pilots and crew have the chance to learn to fly from the humble Cessna to the Queen of the Skies using flight simulator technology to recreate near-identical flying environments right from your screen or cockpit mockup!

Noise Reduction Techniques In Commercial Aircraft Cabins, Hashem Hashem

Student Works

Main sources of noise heard inside an aircraft cabin:

• Engines
• Airframe & control surfaces
• Window vibrations
• Passenger announcements & activities.

Alternatives To Reducing Aviation Fuel-Burn With Technology: Fully Electric Autonomous Taxibot, Denzil Neo

Student Works

Aircraft taxiing operations in the aerodrome were identified to consume the most jet fuel apart from the cruise phase of the flight. This was also well supported by various research associating taxi operations at large, congested airports, with high jet fuel consumption, high carbon emissions, and noise pollution. Existing literature recognised the potential to address the environmental issues of aerodrome taxi operations by operating External or Onboard Aircraft Ground Propulsion Systems (AGPS). Designed to power aircraft with sources other than their main engines, external Aircraft Ground Power Systems (AGPS) have shown the potential to significantly cut jet fuel consumption and …

Directional Speaker Poster, Eugene Ng, Bryan Wong, Ruhaan Das

Student Works

Changi Airport is set to expand with a new terminal, Terminal 5. Currently, many of the airport's processes are manual, requiring a high dependence on staff. This proposal aims to incorporate automation and AI for a smoother passenger experience.

Integrated Dynamic Airline Route And Schedule Optimization, Bayan Begaliyeva

Student Works

By harnessing real-time and historical data in conjunction with advanced AI technologies, this project revolutionizes route and schedule planning, leading to enhanced efficiency, cost reduction, and an improved passenger experience.

Electrolyte Synthesis And Engineering For Alkali Metal Batteries, Yiwen Zhang

Dartmouth College Ph.D Dissertations

Batteries have been in increasing demand over the last decade for portable electronic devices, electric vehicles, and grid-scale energy storage systems. While the electrode materials define the characteristic features of a battery system, the composition of the electrolyte is of critical importance and needs to be engineered for different battery systems to ensure superior electrochemical performance. In this thesis, the basic functionality and fundamental mechanism of the electrolytes in battery systems are first introduced. Then, three major electrolyte engineering strategies are demonstrated, including electrolyte composition formulation, electrolyte-electrode component modification, and function-oriented electrolyte design. Firstly, the low-temperature capacity restraint of lithium …

Pore-Resolving Simulations Of Biomass Char Particle Combustion, Dongyu Liang, Simcha L. Singer

Mechanical Engineering Faculty Research and Publications

Biomass char morphology affects combustion behavior at the particle scale for zone II conditions, in which both heterogeneous reaction and intra-particle diffusion govern the overall rate. Furthermore, particle-scale processes affect reactor-scale outputs, and reactor-scale simulations are sensitive to particle-scale models. However, most char particle combustion models employ coarse-grained, effective-continuum approaches, which treat all porosity at the subgrid-scale. Effective-continuum approaches are not valid or accurate in the presence of large, irregular pores which can approach the size of the particle. A 3-D, pore-resolving CFD simulation approach using real biomass char particle geometries obtained from X-ray micro-computed tomography (micro-CT) is therefore used …

Aerostructural Predictions Combining Fenics And A Viscous Vortex Particle Method, Ryan Anderson, Andrew Ning, Ru Xiang, Sebastiaan P. C. Van Schie, Mark Sperry, Darshan Sarojini, David Kamensky, John T. Hwang

Faculty Publications

Electric Vertical Takeoff and Landing (eVTOL) aircraft experience complex, unsteady aerodynamic interactions between rotors, wings, and fuselage that can make design difficult. We introduce a new framework for predicting aerostructural interactions. Specifically, we demonstrate the coupling of a finite element solver with Reissner-Mindlin shell theory for computing deflections and a viscous vortex particle for capturing wakes. We perform convergence studies of the aerodynamics and the coupled aerostructural model. Finally, we share some preliminary results of the dynamic aeroelastic response of Uber’s eCRM-002 main wing, and share some qualitative observations.