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Full-Text Articles in Engineering

Microcanonical Thermodynamics Of Small Ideal Gas Systems, David S. Corti, Donya Ohadi, Ricardo Fariello, Mark J. Uline Apr 2023

Microcanonical Thermodynamics Of Small Ideal Gas Systems, David S. Corti, Donya Ohadi, Ricardo Fariello, Mark J. Uline

Faculty Publications

We consider the thermal, mechanical, and chemical contact of two subsystems composed of ideal gases, both of which are not in the thermodynamic limit. After contact, the combined system is isolated, and the entropy is determined through the use of its standard connection to the phase space density (PSD), where only those microstates at a given energy value are counted. The various intensive properties of these small systems that follow from a derivative of the PSD, such as the temperature, pressure, and chemical potential (evaluated via a backward difference), while equal when the two subsystems are in equilibrium are nevertheless …


Fabrication Of Drug-Eluting Polycaprolactone And Chitosan Blend Microfibers For Topical Drug Delivery Applications, Mulugeta Gizaw, Diala Bani Mustafa, Shih-Feng Chou Apr 2023

Fabrication Of Drug-Eluting Polycaprolactone And Chitosan Blend Microfibers For Topical Drug Delivery Applications, Mulugeta Gizaw, Diala Bani Mustafa, Shih-Feng Chou

Mechanical Engineering Faculty Publications and Presentations

Chronic and non-healing wounds show delayed and incomplete healing process, which expose the patients to a high risk of infection. These types of wounds require frequent change of dressing, which is a burden on the patients. In addition, ideal dressing needs to meet the requirements in minimizing microbial infiltration and growth while balancing moisture and exchanging oxygen with outside environment. To overcome the challenge in frequent change of dressing and meet the design requirements, current researches have focused on the development of electrospun fibers with incorporation of small molecule drugs for sustained release purpose. In this study, electrospinning was performed …


Experimental Evaluations Of The Impact Of An Additive Oxidizing Electronic Air Cleaner On Particles And Gases, Yicheng Zeng, Aurélie Laguerre, Elliott T. Gall, Mohammad Heidarinejad, Brent Stephens Apr 2023

Experimental Evaluations Of The Impact Of An Additive Oxidizing Electronic Air Cleaner On Particles And Gases, Yicheng Zeng, Aurélie Laguerre, Elliott T. Gall, Mohammad Heidarinejad, Brent Stephens

Mechanical and Materials Engineering Faculty Publications and Presentations

Electronic air cleaning (EAC) technologies have garnered significant attention for use in buildings. Many EAC technologies rely on the addition of reactive constituents to indoor air to react with gas-phase compounds, enhance particle deposition, and/or inactivate microorganisms. However, limited data are available on the efficacy of many EAC technologies and their potential to form chemical byproducts during operation. Here we experimentally evaluate the indoor air quality impacts, specifically targeting particles and gases but not microbial constituents, of a commercially available additive oxidizing EAC that generates positive and negative ions and hydrogen peroxide (H2O2). Tests were conducted in a large unoccupied …


Mitochondrial Complex Iii Bypass Complex I To Induce Ros In Gpr17 Signaling Activation In Gbm, Sana Kari, Jeyalakshmi Kandhavelu, Akshaya Murugesan, Ramesh Thiyagarajan, Srivatsan Kidambi, Meenakshisundaram Kandhavelu Apr 2023

Mitochondrial Complex Iii Bypass Complex I To Induce Ros In Gpr17 Signaling Activation In Gbm, Sana Kari, Jeyalakshmi Kandhavelu, Akshaya Murugesan, Ramesh Thiyagarajan, Srivatsan Kidambi, Meenakshisundaram Kandhavelu

Department of Chemical and Biomolecular Engineering: Faculty Publications

Guanine nucleotide binding protein (G protein) coupled receptor 17 (GPR17) plays crucial role in Glioblastoma multiforme (GBM) cell signaling and is primarily associated with reactive oxidative species (ROS) production and cell death. However, the underlying mechanisms by which GPR17 regulates ROS level and mitochondrial electron transport chain (ETC) complexes are still unknown. Here, we investigate the novel link between the GPR17 receptor and ETC complex I and III in regulating level of intracellular ROS (ROSi) in GBM using pharmacological inhibitors and gene expression profiling. Incubation of 1321N1 GBM cells with ETC I inhibitor and GPR17 agonist decreased the ROS level, …


Bodyslam: Feasibility Of Tracking Human Kinematics With Simultaneous Localization And Mapping (Slam), Sepehr Laal Apr 2023

Bodyslam: Feasibility Of Tracking Human Kinematics With Simultaneous Localization And Mapping (Slam), Sepehr Laal

Dissertations and Theses

We evaluated a new wearable technology that fuses inertial sensors and cameras for tracking human kinematics. These devices use on-board simultaneous localization and mapping (SLAM) algorithms to localize the camera within the environment. Significance of this technology is in its potential to overcome many of the limitations of the other dominant technologies. Our results demonstrate this system often attains an estimated orientation error of less than 1° and a position error of less than 4cm as compared to a robotic arm. This demonstrates that SLAM's accuracy is adequate for many practical applications for tracking human kinematics.


Large-Scale Testing Of Lightweight Cellular Concrete Backfill For Sliver-Fill Mse Wall Configurations, Meghann Dee Morgan Apr 2023

Large-Scale Testing Of Lightweight Cellular Concrete Backfill For Sliver-Fill Mse Wall Configurations, Meghann Dee Morgan

Theses and Dissertations

Lightweight cellular concrete (LCC) is an aerated or foamed concrete where 25-80% of the concrete matrix consists of air voids. The high volume of air voids reduces the strength but significantly decreases the weight of the material, which has made it an attractive alternative to soil for retaining structure backfills. Though the use of LCC has increased, little research has been performed on the large-scale behavior of retaining structures containing LCC as backfill. This research test attempts to fill knowledge gaps found with regard to the use of LCC in a mechanically stabilized earth (MSE) wall with a trapezoidal or …


Experimental And Computational Fluid Dynamics Investigation Of Mechanisms Of Enhanced Oil Recovery Via Nanoparticle-Surfactant Solutions, Nurudeen Yekeen, Ali Masoud Ali Elakkari, Javed Akbar Khan, Muhammad Ali, Ahmed Al-Yaseri, Hussein Hoteit Apr 2023

Experimental And Computational Fluid Dynamics Investigation Of Mechanisms Of Enhanced Oil Recovery Via Nanoparticle-Surfactant Solutions, Nurudeen Yekeen, Ali Masoud Ali Elakkari, Javed Akbar Khan, Muhammad Ali, Ahmed Al-Yaseri, Hussein Hoteit

Research outputs 2022 to 2026

The enhancement in surfactant performance at downhole conditions in the presence of nanomaterials has fascinated researchers’ interest regarding the applications of nanoparticle-surfactant (NPS) fluids as novel enhanced oil recovery (EOR) techniques. However, the governing EOR mechanisms of hydrocarbon recovery using NPS solutions are not yet explicit. Pore-scale visualization experiments clarify the dominant EOR mechanisms of fluid displacement and trapped/residual oil mobilization using NPS solutions. In this study, the influence of multiwalled carbon nanotubes (MWCNTs), silicon dioxide (SiO2), and aluminum oxide (Al2O3) nanoparticles on the EOR properties of a conventional surfactant (sodium dodecyl benzene sulfonate, …


Multiple Access Techniques Enabling Diverse Wireless Services, Mehmet Mert Şahin Apr 2023

Multiple Access Techniques Enabling Diverse Wireless Services, Mehmet Mert Şahin

USF Tampa Graduate Theses and Dissertations

The growing interest in diverse wireless applications such as virtual reality (VR), digital twin, ultra-massive broadband communication (u-MBB) has led the cellular industry to look for new multiple accessing schemes and new signal processing techniques for utilization of next-generation wireless technologies. Throughout the PhD duration, different studies are performed in regards to dual-functional and interference robust multiple accessing and control of electromagnetic radiation for cognitive radio systems. Firstly, a novel concept on non-orthogonal multiple access (NOMA), which is the coexistence of different waveform structures in the same resource elements is proposed. Secondly, a novel JCR waveform is proposed to serve …


Design And Synthesis Of Plasmonic Nanoparticles For Nir Bioimaging: Investigating The Role Of Absorption And Scattering, Luis Dias Bumba Manuel Apr 2023

Design And Synthesis Of Plasmonic Nanoparticles For Nir Bioimaging: Investigating The Role Of Absorption And Scattering, Luis Dias Bumba Manuel

LSU Doctoral Dissertations

Nanoparticles have made vast advances in the realm of nanomedicine and bioimaging, enabling technologies such as photothermal therapy of malignant tumors and noninvasive monitoring of living tissue. Many of these innovations have only arisen in the last few decades with potential for growth in many avenues. The research shown in this work addresses some of the existing literature's void. Particularly solving synthesis challenges that have existed for more than 20 years in synthesizing Au nanoshells and establishing the potential for molecular-level deep imaging of plants. A novel investigation of the role of light absorption and scattering in bioimaging led to …


Stabilizing Control Schemes For Grid-Connected Hybrid Pv-Energy Storage Systems, Indra Narayana Bhogaraju Apr 2023

Stabilizing Control Schemes For Grid-Connected Hybrid Pv-Energy Storage Systems, Indra Narayana Bhogaraju

LSU Doctoral Dissertations

A nonlinear stabilizing control scheme based on Lyapunov theory is proposed for a grid- connected hybrid photovoltaic (PV)/ battery/supercapacitor (SC) system. The system dynamics is developed in the stationary reference frame, and the state-space model of the system is derived and used to formulate the Lyapunov function (LF) candidate. The global asymptotic stability of the LF-based controller is discussed in detail. The real-time implementation feasibility of the proposed control scheme is validated through hardware-in-the-loop (HIL) studies of a grid- connected hybrid system under solar energy generation and grid load variations. To address the issue of digital computational time that leads …


Numerical Flume For Wave Dissipation By Mangrove Prop Roots, Rebecca L. Schurr Apr 2023

Numerical Flume For Wave Dissipation By Mangrove Prop Roots, Rebecca L. Schurr

LSU Master's Theses

Mangroves provide shorelines with many beneficial engineering services, including shoreline stabilization, wave attenuation, and damage mitigation during tsunami or tropical cyclone events. This research focuses on wave attenuation rates and drag coefficients, and how they are affected by mangrove prop roots. Previous lab research using a physical wave flume has quantified wave height decay and drag coefficients for synthetic mangrove forests and confirmed that attenuation does indeed increase as mangrove forest density increases. This research will use a 3D numerical flume model developed in Proteus, a Python package, to simulate prior physical model experiments. This work will attempt to validate …


Evaluation Of E-Government Information Systems Agility: A Method And Case Study, Soumia Aggoune, Maohamed Amine Riahla Apr 2023

Evaluation Of E-Government Information Systems Agility: A Method And Case Study, Soumia Aggoune, Maohamed Amine Riahla

Emirates Journal for Engineering Research

Development of e-government evaluation frameworks began around 2000s. Most of the developed approaches are technologically driven in which they focus on the “E” rather than the “Government”. Moreover, they tend to evaluate tangible measures (such as costs, benefits, etc.) and neglects important intangible measures (such as agility, sustainability, etc.). The state of the art tells that the evaluation of agility within e-government has been proved to be important but complex. However, the importance is due to the increasing need for governments to justify investments, assess impacts and monitor progress in the ever-changing environment. On the other side, the complexity comes …


Engineered Production Of Bioactive Polyphenolic O-Glycosides, Jie Ren, Caleb Don Barton, Jixun Zhan Apr 2023

Engineered Production Of Bioactive Polyphenolic O-Glycosides, Jie Ren, Caleb Don Barton, Jixun Zhan

Biological Engineering Faculty Publications

Polyphenolic compounds (such as quercetin and resveratrol) possess potential medicinal values due to their various bioactivities, but poor water solubility hinders their health benefits to humankind. Glycosylation is a well-known post-modification method to biosynthesize natural product glycosides with improved hydrophilicity. Glycosylation has profound effects on decreasing toxicity, increasing bioavailability and stability, together with changing bioactivity of polyphenolic compounds. Therefore, polyphenolic glycosides can be used as food additives, therapeutics, and nutraceuticals. Engineered biosynthesis provides an environmentally friendly and cost-effective approach to generate polyphenolic glycosides through the use of various glycosyltransferases (GTs) and sugar biosynthetic enzymes. GTs transfer the sugar moieties from …


Examining The Impact Of Different Street Lighting Schemes On Traffic Safety And Drivers’ Behaviors At Unsignalized Intersections, Hisham Mohamed Abdu Kunnah Apr 2023

Examining The Impact Of Different Street Lighting Schemes On Traffic Safety And Drivers’ Behaviors At Unsignalized Intersections, Hisham Mohamed Abdu Kunnah

LSU Master's Theses

Lack of visibility is one of the main challenges that significantly impact drivers’ ability to safely perform driving tasks at night especially at unsignalized intersections. Several prior studies indicated that lighting enhances nighttime traffic safety. Nevertheless, lighting is not mandatory at unsignalized intersections in many states including Louisiana. This study aimed to investigate if lack of lighting is a contributing factor that affects traffic safety at unsignalized intersections in Louisiana. In addition, this study strived to identify current lighting policies adopted by other states, examine if there are any low-cost countermeasures implemented by other states to improve nighttime visibility, and …


Domain Specific Analysis Of Privacy Practices And Concerns In The Mobile Application Market, Fahimeh Ebrahimi Meymand Apr 2023

Domain Specific Analysis Of Privacy Practices And Concerns In The Mobile Application Market, Fahimeh Ebrahimi Meymand

LSU Doctoral Dissertations

Mobile applications (apps) constantly demand access to sensitive user information in exchange for more personalized services. These-mostly unjustified-data collection tactics have raised major privacy concerns among mobile app users. Existing research on mobile app privacy aims to identify these concerns, expose apps with malicious data collection practices, assess the quality of apps' privacy policies, and propose automated solutions for privacy leak detection and prevention. However, existing solutions are generic, frequently missing the contextual characteristics of different application domains. To address these limitations, in this dissertation, we study privacy in the app store at a domain level. Our objective is to …


A Review On The Application Of 3d Printing Technology In Pavement Maintenance, Fangyuan Gong, Xuejiao Cheng, Qinghua Wang, Yi Chen, Zhanping You, Yu Liu Apr 2023

A Review On The Application Of 3d Printing Technology In Pavement Maintenance, Fangyuan Gong, Xuejiao Cheng, Qinghua Wang, Yi Chen, Zhanping You, Yu Liu

Michigan Tech Publications, Part 1

To examine the application and significance of 3D printing technology in pavement maintenance engineering, a review of the current developments in principles, types, materials, and equipment for 3D printing was conducted. A comparison and analysis of traditional methods and 3D printing for asphalt pavement maintenance led to an investigation of 3D asphalt printing technologies and equipment. As a result, the following suggestions and conclusions are proposed: 3D printing technology can increase the level of automation and standardization of pavement maintenance engineering, leading to effective improvements in worker safety, climate adaptability, repair accuracy, etc. For on-site repair of cracks and minor …


Persistence Of Dna From Biocontained Genetically Engineered Microbes, Wentao Dai Apr 2023

Persistence Of Dna From Biocontained Genetically Engineered Microbes, Wentao Dai

McKelvey School of Engineering Graduate Student Theses & Dissertations

The utilization of genetically engineered microbes in environmental systems requires effective biocontainment mechanisms to ensure their safe operation. CRISPR-based kill switches are a promising solution, inducing cell death through site-specific DNA cleavage under specific environmental conditions. In this study, we aimed to assess the impact of CRISPR-based kill switches on the abundance and persistence of bacterial DNA. Our results revealed that while CRISPR-based kill switches were capable of achieving high reductions in viable Escherichia coli Nissle 1917 (EcN); the DNA largely remained intact. This was observed in two strains of EcN: one enabled with multi-locus genome cleavage, and the other …


Crystalline–Amorphous Nanostructures: Microstructure, Property And Modelling, Binqiang Wei, Lin Li, Lin Shao, Jian Wang Apr 2023

Crystalline–Amorphous Nanostructures: Microstructure, Property And Modelling, Binqiang Wei, Lin Li, Lin Shao, Jian Wang

Department of Mechanical and Materials Engineering: Faculty Publications

Crystalline metals generally exhibit good deformability but low strength and poor irradiation tolerance. Amorphous materials in general display poor deformability but high strength and good irradiation tolerance. Interestingly, refining characteristic size can enhance the flow strength of crystalline metals and the deformability of amorphous materials. Thus, crystalline–amorphous nanostructures can exhibit an enhanced strength and an improved plastic flow stability. In addition, high-density interfaces can trap radiation-induced defects and accommodate free volume fluctuation. In this article, we review crystalline–amorphous nanocomposites with characteristic microstructures including nanolaminates, core–shell microstructures, and crystalline/amorphous-based dual-phase nanocomposites. The focus is put on synthesis of characteristic microstructures, deformation …


Leveraging Artificial Intelligence And Machine Learning For Enhanced Cybersecurity: A Proposal To Defeat Malware, Emmanuel Boateng Apr 2023

Leveraging Artificial Intelligence And Machine Learning For Enhanced Cybersecurity: A Proposal To Defeat Malware, Emmanuel Boateng

Cybersecurity Undergraduate Research Showcase

Cybersecurity is very crucial in the digital age in order to safeguard the availability, confidentiality, and integrity of data and systems. Mitigation techniques used in the industry include Multi-factor Authentication (MFA), Incident Response Planning (IRP), Security Information and Event Management (SIEM), and Signature-based and Heuristic Detection.

MFA is employed as an additional layer of protection in several sectors to help prevent unauthorized access to sensitive data. IRP is a plan in place to address cybersecurity problems efficiently and expeditiously. SIEM offers real-time analysis and alerts the system of threats and vulnerabilities. Heuristic-based detection relies on detecting anomalies when it comes …


Assessing The Ability Of Arduino-Based Sensor Systems To Monitor Changes In Water Quality, Josiah Hacker Apr 2023

Assessing The Ability Of Arduino-Based Sensor Systems To Monitor Changes In Water Quality, Josiah Hacker

Honors College Theses

Access to safe water is vital to public health. While developed countries like the United States are recognized as having reliable and safe water, many small water utilities struggle with supplying consistent water quality. Technicians of these utilities will periodically test water samples from the influent and throughout the distribution system. However, this laborious and costly process does not capture sudden changes in influent water quality due to environmental conditions or pipes breaking in the distribution system. Here I show how an Arduino-based sensor can be used as a real-time, low-cost monitor of water quality parameters. Specifically, I developed a …


The Influence Of The Addition Of Recycled Asphalt Shingles On The Compressive Strength Of Concrete, William E. Webb Apr 2023

The Influence Of The Addition Of Recycled Asphalt Shingles On The Compressive Strength Of Concrete, William E. Webb

Honors College Theses

The purpose of this study is to explore the effect of recycled asphalt shingles (RAS) as an additive on the compressive strength of concrete. This was accomplished by designing a concrete mix and creating 4” by 8” cylindrical test specimens containing 0, 5, 10, and 15 percent RAS by weight. The compressive strength was measured through axial loading until failure utilizing a compression testing apparatus. With these results, a relationship between the content of RAS and compressive strength was able to be developed, giving insight as to how RAS could be used in concrete mixes in the future. This study …


Blockchain Accelerators And An Application On Covid-19 Contact Tracing, Tao Lu Apr 2023

Blockchain Accelerators And An Application On Covid-19 Contact Tracing, Tao Lu

LSU Doctoral Dissertations

Blockchain technology has been an emerging technology in recent years. Its nature of decentralization and anonymity enables many applications to be built in a trustless environment but can still be validated and agreed upon by all the participants. Ever since the invention of blockchain technology, its concepts and forms are explored extensively, and it has shown the potential to be used in many industries. However, the low efficiency and the poor performance have prevented the technology to be adopted in practical largescale usage. In this dissertation, we present three major works around blockchain technology. The first one is BPU, an …


Deposition, Material Characterization, And Mechanical Testing Of Cr Containing Diamond-Like Carbon Films, Nicholas Anderson Apr 2023

Deposition, Material Characterization, And Mechanical Testing Of Cr Containing Diamond-Like Carbon Films, Nicholas Anderson

LSU Master's Theses

A series of amorphous hydrogenated chromium containing diamond-like carbon films were deposited on 316 stainless steel substrates with a chromium interlayer through inductively coupled plasma assisted direct current magnetron sputtering. Details on the deposition process of these films are discussed. The film is characterized using scanning electron microscopy, X-ray photoelectron spectroscopy, X-ray diffraction, energy dispersive spectroscopy, and transmission electron microscopy. The coating hardness and indentation modulus is measured by instrumented nanoindentation. The coefficient of friction and the upper bound of the coating wear coefficient is measured using the pin-on-disk method. The fracture toughness of the diamond-like carbon film and a …


Effect Of Fast Charging On Lithium-Ion Batteries: A Review, Ehab Bayoumi Apr 2023

Effect Of Fast Charging On Lithium-Ion Batteries: A Review, Ehab Bayoumi

Mechanical Engineering

In recent years we have seen a dramatic shift toward the use of lithium-ion batteries (LIB) in a variety of applications, including portable electronics, electric vehicles (EVs), and grid storage. Even though more and more car companies are making electric models, people still worry about how far the batteries will go and how long it will take to charge them. It is common knowledge that the high currents that are necessary to quicken the charging process also lower the energy efficiency of the battery and cause it to lose capacity and power more quickly. We need an understanding of atoms …


Filter-Based Air Sampler Capable Of Integration Into Small Unmanned Aerial Vehicles, Robert M. Eninger, Stepanie A. Ohms, Jeremy M. Slagley Apr 2023

Filter-Based Air Sampler Capable Of Integration Into Small Unmanned Aerial Vehicles, Robert M. Eninger, Stepanie A. Ohms, Jeremy M. Slagley

AFIT Patents

A filter-based air sampler, more specifically a filter-based air sampler capable of integration into small unmanned aerial systems is disclosed. The filter-based air sampler may include a filter assembly which has as its component parts: an open faced air intake component, a filter, and a filter support that has a central supporting grid. The filter assembly may joined to the housing of a fan, such as a centrifugal fan, with the supporting grid of the filter support being disposed over the air inlet of the fan.


Overview Of The Application Of Remote Sensing In Effective Monitoring Of Water Quality Parameters, Godson Ebenezer Adjovu, Haroon Stephen, David James, Sajjad Ahmad Apr 2023

Overview Of The Application Of Remote Sensing In Effective Monitoring Of Water Quality Parameters, Godson Ebenezer Adjovu, Haroon Stephen, David James, Sajjad Ahmad

Civil and Environmental Engineering and Construction Faculty Research

This study provides an overview of the techniques, shortcomings, and strengths of remote sensing (RS) applications in the effective retrieval and monitoring of water quality parameters (WQPs) such as chlorophyll-a concentration, turbidity, total suspended solids, colored dissolved organic matter, total dissolved solids among others. To be effectively retrieved by RS, these WQPs are categorized as optically active or inactive based on their influence on the optical characteristics measured by RS sensors. RS applications offer the opportunity for decisionmakers to quantify and monitor WQPs on a spatiotemporal scale effectively. The use of RS for water quality monitoring has been explored in …


Urban Public Transportation Planning With Endogenous Passenger Demand, Yifei Sun Apr 2023

Urban Public Transportation Planning With Endogenous Passenger Demand, Yifei Sun

Dartmouth College Ph.D Dissertations

An effective and efficient public transportation system is crucial to people's mobility, economic production, and social activities. The Operations Research community has been studying transit system optimization for the past decades. With disruptions from the private sector, especially the parking operators, ride-sharing platforms, and micro-mobility services, new challenges and opportunities have emerged. This thesis contributes to investigating the interaction of the public transportation systems with significant private sector players considering endogenous passenger choice. To be more specific, this thesis aims to optimize public transportation systems considering the interaction with parking operators, competition and collaboration from ride-sharing platforms and micro-mobility platforms. …


Creating A Power System For A Robot, Nolan Hays Apr 2023

Creating A Power System For A Robot, Nolan Hays

Scholars Week

I will be describing the process of creating the power system for the robot that will be competing in the 2023 IEEE Hardware Competition.


Hydrogen Bonding Versus Halogen Bonding: Spectroscopic Investigation Of Gas-Phase Complexes Involving Bromide And Chloromethanes, Hayden T. Robinson, Christian T. Haakansson, Timothy R. Corkish, Peter D. Watson, Allan J. Mckinley, Duncan A. Wild Apr 2023

Hydrogen Bonding Versus Halogen Bonding: Spectroscopic Investigation Of Gas-Phase Complexes Involving Bromide And Chloromethanes, Hayden T. Robinson, Christian T. Haakansson, Timothy R. Corkish, Peter D. Watson, Allan J. Mckinley, Duncan A. Wild

Research outputs 2022 to 2026

Hydrogen bonding and halogen bonding are important non-covalent interactions that are known to occur in large molecular systems, such as in proteins and crystal structures. Although these interactions are important on a large scale, studying hydrogen and halogen bonding in small, gas-phase chemical species allows for the binding strengths to be determined and compared at a fundamental level. In this study, anion photoelectron spectra are presented for the gas-phase complexes involving bromide and the four chloromethanes, CH3Cl, CH2Cl2, CHCl3, and CCl4. The stabilisation energy and electron binding energy associated with each complex are determined experimentally, and the spectra are rationalised …


Advanced Industrial Lubricants And Future Development Trends Of Tribo-Systems For Tribological Performance Evaluation, George Totten, Simon C. Tung, Undrakh Mishigdorzhiyn Apr 2023

Advanced Industrial Lubricants And Future Development Trends Of Tribo-Systems For Tribological Performance Evaluation, George Totten, Simon C. Tung, Undrakh Mishigdorzhiyn

Mechanical and Materials Engineering Faculty Publications and Presentations

It is possible to solve challenges in the global automotive and manufacturing industries by using a multidisciplinary approach to advanced industrial lubricants, their tribological performance evaluation, and new surface engineering techniques for prospective tribosystems. Three types of approaches are reported in this Special Issue (SI): (1) Advance surface engineering technologies and protective coatings [1–4]; (2) Multipurpose lubricants with nano-additives for better performance [5–8]; (3) Oil degradation simulation thermo-oxidative ageing and dynamic degradation processes [9–12].