Engineering Commons^™

The Influence Of Cathode Ingredients In Zinc Chloride Type Battery On The Discharge Ability, Qi Shen, Biao Zhuang

Journal of Electrochemistry

The influence of cathodic powder ingredients in ZnCl₂ type heavy duty battery on the discharge ability has been studied, a suitable battery ingredients is founds.

Kinetic Behavior Of The Pt/Ysz Solid Electrolyte Interface Exposed To O2+He Mixture, Yi Jiang, Wenzhao Li, Lixin Cao, Jingwang Yan

Journal of Electrochemistry

Electrochemical behavior of the Pt/YSZ solid electrolyre interface has been investigated by cyclic voltammetry and linear potential sweep technique. It was found that the electrochemical adsorption of oxygen on the Pt surface follows the Temkin adsorption model. The amount of oxygen species increases logarithmically with time. Two oxygen species are electrochemically formed on the Pt surface. One is atomically adsorbed, the other probably subsurface oxygen or Pt oxide. The electrochemical reduction of adsorbed oxygen is kinetically irreverable. The cathodic peak potential is affected both by the potential sean rate and the amount of oxygen ahorbed on the surface. Kinetic parameters, …

Determination Of Transport Number Of The Modified Liclo4-(Peo)20 Polymer Electrolyte, Ruqi Zhou, Qngguo Liu, Weihua Qiu, Yun Zhang, Yuee Zhao, Leiling Yang

Journal of Electrochemistry

In this work a combination method of A.C. Impedance and chronoamperometry was used to determine the lithium ion transport number of LiClO₄·(PEO)₂₀·(PC)₁₂·(EC)₁₂ polymer electrolyte. It is known that lithium is thermodynamically unstable in non-aqueous or polymer electrolytes, leading to the formtion of a film on lithium surface, called as solid electrolyte interphase (SEI). The presence of SEI layer will greatly influence the experimental result of lithium ion transport number. The new method avoid the effect of SEI layer, and can give correct transport number of lithium ion in the electrolyte of DCIO_{4 …}

Preparation Techique Of Foamed Nickel By Electrodeposition, Xihua He, Ronghui Hu, Hanxi Yang, Zhengzhong Zuo

Journal of Electrochemistry

This paper describes the preparation technique and operation conditions for manufacturing foamed nickel by chemilcal pretreament, electrodeposition and heat treatment. The foamed nickel made in this method showed high porosity, uniformity and considerable strength and tenacity,applicable for various secondary battery electrodes.

The Electrochemical Behavior Of C60-Chemically Modified Poly(N-Vinylcarhzole)In 1 Mol/L Liclo4-Thf Solutions, Yu Chen, Zuen Huang, Ruifang Cai, Fupin Zhang

Journal of Electrochemistry

The electrochemical behavior of C₆₀-PNVC copolymer in 1 mol/L LiClO₄-THF solutions has been studied by cyclic voltammetry. The results demonstrated that there are considerable differences of electronic structure between PNVC (Poly (N-vinylcarbazole)) and C₆₀-PNVC copolymer, this being consistent with the ESR results and the oxidstion-reduction activarion of pure PNVC by C₆₀-chemical modification. In the potential region, 1.3V～-3.5V, five steps, 0. 90V/0.60V, 0.20V/0.00V, -1.05V/-1.30 V, -1.25V/-1.75 V, -2.00V/-2.50V, of oxidation/reduction proceases were indicated in the cyclic voltammetry for pure PNVC, whereas seven steps, 0.20V/0.20V, -0.30V/-0.50 V, -0. 60V/-0.60 V, -0.80V/-1.10 V, -1.95V/-2.10 V, …

Study On The Manufacture Of Pt/C Gas-Diffusion Electrodes, Yonglin Ma

Journal of Electrochemistry

The various methods of manufacturing gas-diffusion electrodes are reviewed and a new method of preparing the Pt/C electrocatalyst and the gas-diffusion electrodes is explored in this paper. The electrochemical performance of resulting electrodes in concentrated phosphoric acid for oxygen reduction at 150℃ are compared with the commercial electrode which purched from Giner Inc. (U. S. A). The results show that the performance of the Pt/C electrodes which manufactured by the method in this paper has been greatly improved. Therefor, a fuel cell using such electrodes has high industrial value.

Method Of Coating A Substrate With A Metal Oxide Film From An Aqueous Solution Comprising A Metal Cation And A Polymerizable Organic Solvent, Harlan U. Anderson, Magdi M. Nasrallah, Chieh-Cheng Chen

Materials Science and Engineering Faculty Research & Creative Works

A method for preparing a substrate coated with a polycrystalline, metal oxide film using polymeric precursors. The oxide films prepared by the method of the present invention are dense (i.e., substantially free of cracks and pinholes) and may be used, for example, as an electrolyte or electrode in intermediate temperature solid oxide fuel cells (SOFCs) or as gas separation membranes.

Modelling And Analysis Of The Elution Stage Of "Perfusion Chromatography" Effects Of Intraparticle Convective Velocity And Microsphere Size On System Performance, Y. Xu, Athanasios I. Liapis

Chemical and Biochemical Engineering Faculty Research & Creative Works

A mathematical model describing the dynamic elution (elution stage) in columns with spherical bidisperse perfusive or spherical bidisperse purely diffusive adsorbent particles is presented and its solution is obtained numerically. The desorption of bovine serum albumin (BSA) from spherical anion-exchange porous particles was studied for different values of the intraparticle Peclet numbers of the adsorbate, (Peintra)a, and eluent, (Peintra)e, and of the microsphere diameter, dm. It was found that as (Peintra)a increases, the asymmetry of the elution peak of the adsorbate (at the exit of the column) decreases, the peak height increases and the time, Te, required for the elution …

Nonlinearities In The Base Emitter Junction Of Heterojunction Bipolar Transistors, Oliver Woywode

Dissertations and Theses

The nonlinear behaviour of the base emitter junction in HBTs is investigated. Nonlinearities cause troublesome distortion and intermodulation of signals and raise the bit error rate. They are therefore a key issue in microwave communication systems. Hewlett-Packard's Microwave Design System (MDS) software package has been used to simulate these phenomena. The simulation results are verified by an analytical method called nonlinear current method which is a derivative of the Volterra series approach. With the aid of this method new analytical expressions are derived that provide insight into the subtleties of nonlinear phenomena. These expressions are evaluated by the program MAPLE …

The Discrete Laguerre Transform: Derivation And Applications, Giridhar Dhati Mandyam

Electrical and Computer Engineering ETDs

The discrete Laguerre transform (DLT) belongs to the family of unitary transforms known as Gauss-Jacobi transforms. Using classical methodology, the DLT is derived from the orthonormal set of Laguerre functions. Moreover, using recursion relationships common to all sets of orthonormal polynomials, generalized systolic arrays for forward and inverse unitary transform operations are derived and applied to the DLT. By examining the basis vectors of the transform matrix, the types of signals that can be best represented by the DLT are determined, namely oscillatory and damped oscillatory signals. Applications are demonstrated in the area of frequency domain adaptive filters, where the …

Ccfss Technical Bulletin February 1996, Wei-Wen Yu Center For Cold-Formed Steel Structures

CCFSS Technical Bulletins (1993 - 2020)

No abstract provided.

Constraints On Initial Ahs Deployment And The Concept Definition Of A Shuttle Service For Ahs Debut, H.-S. Jacob Tsao

Faculty Publications

The concept of automated highway system (AHS) was motivated primarily by its potential for large capacity and safety gains without requiring significant right-of-way acquisition. However, highway automation involves a multitude of design options as well as systems issues. Compounded by the crucial dimension of evolving the current highway system towards the mature AH& there exist a large number of possible evolutionary paths to AHS. Perhaps due to the immense complexity, little attention has been paid to the evolution dimension.Particularly important and difficult in defining a deployment sequence is the very first step,i.e. the first user service involving fully automated (hands-off …

Stage Definition For Ahs Deployment And An Ahs Evolutionary Scenario, H.-S. Jacob Tsao

Faculty Publications

The concept of automated highway systems (AHS) as a means to solve the fast-worsening highway congestion problem has received renewed attention recently. Pros and cons of various mature AHS have been a subject of intense study. However, such discussions are nothing but intellectual exercises unless the issue of how to evolve the current highway systems towards these mature AHS can be resolved. There exist a large number of different possible mature AHS. The additional dimension of evolution leads to an even larger number of possible evolutionary scenarios. This paper proposes an approach to defining evolutionary scenarios and illustrates it with …

Wright State University College Of Engineering And Computer Science Bits And Pcs Newsletter, Volume 12, Number 2, February 1996, College Of Engineering And Computer Science, Wright State University

BITs and PCs Newsletter

A fourteen page newsletter created by the Wright State University College of Engineering and Computer Science that addresses the current affairs of the college.

High-Temporal-Resolution, High-Sensitivity Imaging Of Streamers In A Long Atmospheric Pressure Gap, W. J. Yi, B. J. Hankla, P. F. Williams

P. F. (Paul Frazer) Williams Publications

We present time-resolved shutter photographs of streamers in a 13-cm gas-filled atmospheric pressure gap. The photographs show that in pure N₂, the streamers split readily in two. In mixtures containing O₂ , on the other hand, this bifurcation is substantially reduced.

A Modified Ruler Experimental Apparatus, Said Shakerin

All Faculty Articles - School of Engineering and Computer Science

No abstract provided.

Acuta Enews February 1996, Vol. 25, No. 2

ACUTA Newsletters

In This Issue

From the President

The Michelangelo Virus

DC at a Glance

UCLA Switches on Its 6800

From ACUTA Headquarters

Variable-Complexity Trellis Decoding Of Binary Convolutional Codes, David W. Matolak, S. G. Wilson

Faculty Publications

Considers trellis decoding of convolutional codes with selectable effort, as measured by decoder complexity. Decoding is described for single parent codes with a variety of complexities, with performance "near" that of the optimal fixed receiver complexity coding system. Effective free distance is examined. Criteria are proposed for ranking parent codes, and some codes found to be best according to the criteria are tabulated, Several codes with effective free distance better than the best code of comparable complexity were found. Asymptotic (high SNR) performance analysis and error propagation are discussed. Simulation results are also provided.

Riblet Effects On Gortler Vortex Development Over A Concave Surface, James A. Rothenflue

Theses and Dissertations

Riblet effects on Goertler vortex development in laminar and transitional flows were measured using three-dimensional laser-Doppler anemometry. Three freestream velocities were tested such that riblet spacing corresponded to Goertler vortex (GV) wavelengths which presumably would be either strongly amplified, weakly amplified, or attenuated by centrifugal forces on a curved surface. Experiments revealed the development of paired, counterrotating vortices within the riblet valleys over both flat and concave surfaces. For riblet spacings equivalent to weakly or non-amplified GV wavelengths, GV development on a curved surface was above the riblets and was delayed by the addition of riblets. The GV wavelength was …

The Multirate Simulation Of Facts Devices In Power System Dynamics, J. G. Chen, Mariesa Crow

Electrical and Computer Engineering Faculty Research & Creative Works

In this paper, the multirate method is applied to the problem of simulating the dynamics of a power system which contains fast components such as induction machine loads and FACTS devices. Results concerning the numerical stability and accuracy of the multirate method are presented. Implementation concerns are also addressed by studying an example power system which contains a wide range of time response behavior

Schlieren Photography Of Current Filaments In Surface-Related Breakdown Of Silicon, B. J. Hankla, P. F. Williams

P. F. (Paul Frazer) Williams Publications

We have used a modified Schlieren technique to photograph current filaments formed inside silicon during the very early stages of surface-related breakdown. We believe that the features we see are due to heating in the filamentary channel. The very rapid formation of these channels suggests that they result from streamer-like phenomena in the bulk silicon.

Heat Transfer In Rarefied Gas At A Gas-Solid Interface, Yaşar Demirel, Satish C. Saxena

Papers in Physical Chemistry

Modified expressions for the heat-transfer fluxes at the interface of a solid surface and a gas are given for different Knudsen-number regimes. These expressions for diatomic gases contain both a gas-reflection and a thermal accommodation coefficient. Parallel-plate, coaxial-cylindrical and concentric spherical surfaces are considered. A general expression for the thermal accommodation coefficient is based on experimental data. Sample numerical calculations of heat flux in different heat-transfer regimes are presented in terms of the reciprocal Knudsen number.

Nonlinear Lateral Pile Deflection Prediction In Sands, Shamsher Prakash, Sanjeev Kumar

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

A method has been developed to predict the load-displacement relationship for single piles subjected to lateral load, embedded in sands, considering soil nonlinearity using subgrade reaction. This is the first systematic study to develop lateral load-deflection curves using modulus degradation with strain. Based on the analysis of 14 full-scale lateral pile-load tests, an empirical equation of modulus degradation with strain and a range of k hmax values, i.e., k h at 0.002 strain at 1 m (3.28 ft) depth, has also been proposed. An example problem is included to demonstrate its use. Based on this method, the computed load deflections …

Bs News

Building Services Engineering

No abstract provided.

Ccfss News February 1996, Wei-Wen Yu Center For Cold-Formed Steel Structures

CCFSS Newsletters (1999 - 2008)

No abstract provided.

On The Adaptive Multi-Stage Detector For Cancellation Of Multiuser Interference In Cdma Wireless Communication Systems, Nadir Sezgin

Dissertations

The classical multiple access techniques such as Frequency Division Multiple Access (FDMA) and Time Division Multiple Access (TDMA) schemes are band limited in terms of their capacity to be used for mobile radio communication. Recent developments in the area of digital signal processing, makes Code Division Multiple Access (CDMA) as a possible solution to the demand of capacity for the mobile radio communication. The capacity of CDMA is limited by multiuser interference, that is the interference from the other users.

The goal of this dissertation is to improve the multiuser CDMA detector with high Bit Error Rate (BER) performance, low …

Real Time Control Of Nonlinear Dynamic Systems Using Neuro-Fuzzy Controllers, Amitava Jana

Dissertations

The problem of real time control of a nonlinear dynamic system using intelligent control techniques is considered. The current trend is to incorporate neural networks and fuzzy logic into adaptive control strategies. The focus of this work is to investigate the current neuro-fuzzy approaches from literature and adapt them for a specific application. In order to achieve this objective, an experimental nonlinear dynamic system is considered. The motivation for this comes from the desire to solve practical problems and to create a test-bed which can be used to test various control strategies. The nonlinear dynamic system considered here is an …

Investigation Of Dynamic Friction In Lubricated Surfaces, Hanuman Rachoor

Dissertations

The research reported in this dissertation is concerned with the development of friction models for lubricated contacts. A few analytical models have been developed to investigate the friction under dynamic velocity conditions. In this study, two different tribological situations such as conformal and non-conformal contacts have been chosen. Friction modeling covers boundary, mixed and full fluid film friction regions. A new theory based on the elastic properties of the surface materials, and fluid film properties of the lubricant at the contact has been developed to determine the dynamic friction in boundary, mixed and full hydrodynamic lubrication regions. In the full …

Adaptive Space-Time Processing For Wireless Communications, Xiao Cheng Bernstein

Dissertations

Adaptive space-time processing techniques have been found to increase the capacity of two major, multiple-access wireless communication systems: Time Division Multiple Access (TDMA) and Code Division Multiple Access (CDMA).

In an IS-54 TDMA system, the frequency re-use factor has to be set to 7 so that cells with the same spectrum are separated far enough to meet a required carrier-to-interference ratio (CIR). Space processing uses multiple antennas which, in turn, provide alternative signal paths in order to cancel interferences and combat multipath fading. We have proposed the eigencanceler method and have reviewed the theoretical optimum combining and the feasible direct …

On Optimal Design And Applications Of Linear Transforms, Mehmet V. Tazebay

Dissertations

Linear transforms are encountered in many fields of applied science and engineering. In the past, conventional block transforms provided acceptable answers to different practical problems. But now, under increasing competitive pressures, with the growing reservoir of theory and a corresponding development of computing facilities, a real demand has been created for methods that systematically improve performance. As a result the past two decades have seen the explosive growth of a class of linear transform theory known as multiresolution signal decomposition. The goal of this work is to design and apply these advanced signal processing techniques to several different problems.

The …