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Articles 173461 - 173490 of 198025

Full-Text Articles in Engineering

Managing Cultural Differences For Engineers, Halvard E. Nystrom Jan 1997

Managing Cultural Differences For Engineers, Halvard E. Nystrom

Engineering Management and Systems Engineering Faculty Research & Creative Works

Understanding cultural issues, developing cross-cultural communication skills and recognizing the need to effectively apply these skills in the global arena are becoming critical success factors for an increasing number of engineers. To address these needs, an engineering management class has been developed at the University of Missouri-Rolla, USA, that uses a team project approach as the major method to achieve the learning objectives. The student teams develop training manuals for dealing with engineers from specific international cultures, based on the material learned in class as well as personal interactions with individuals of the specific ethnic background. An application of this …


Short-Term Resource Scheduling With Ramp Constraints [Power Generation Scheduling], Chung-Li Tseng, Chao-An Li, A. J. Svoboda, R. B. Johnson Jan 1997

Short-Term Resource Scheduling With Ramp Constraints [Power Generation Scheduling], Chung-Li Tseng, Chao-An Li, A. J. Svoboda, R. B. Johnson

Engineering Management and Systems Engineering Faculty Research & Creative Works

This paper describes a Lagrangian relaxation-based method to solve the short-term resource scheduling (STRS) problem with ramp constraints. Instead of discretizing the generation levels, the ramp rate constraints are relaxed with the system demand constraints using Lagrange multipliers. Three kinds of ramp constraints, startup, operating and shutdown ramp constraints are considered. The proposed method has been applied to solve the hydro-thermal generation scheduling problem at PG&E. An example alone with numerical results is also presented


Vehicle Performance Optimization Utilizing The Air Turbo-Ramjet Propulsion System; Methodology Development And Applications, Kirk Christensen Jan 1997

Vehicle Performance Optimization Utilizing The Air Turbo-Ramjet Propulsion System; Methodology Development And Applications, Kirk Christensen

Doctoral Dissertations

"The ATR (Air TurboRocket) is an air breathing propulsion system in which the turbocompressor turbine is powered by a hot drive gas which is generated independently of the air flow through the compressor. The ATR has a lower specific impulse (Isp) and higher thrust compared to a similar size turbojet but a lower thrust and higher Isp compared to similar size solid rocket motor (SRM). This work defines the benefits of ATR propulsion for tactical vehicles.

ATR simulation codes were developed to support analysis of hypothetical ATR powered vehicles. Both turbojet powered and SRM powered vehicles were also evaluated against …


Tradeoffs In The Design Of A Spaceborne Scanning Pencil Beam Scatterometer: Application To Seawinds, David G. Long, Chialin T. Wu, Michael W. Spencer Jan 1997

Tradeoffs In The Design Of A Spaceborne Scanning Pencil Beam Scatterometer: Application To Seawinds, David G. Long, Chialin T. Wu, Michael W. Spencer

Faculty Publications

SeaWinds is a spaceborne wind scatterometer to be flown on the second Japanese Advanced Earth Observing Satellite (ADEOS-II) in 1999. An important international element of NASA's Earth Observing System (EOS), SeaWinds is an advanced follow-on to the NASA scatterometer (NSCAT) on the first ADEOS platform. Unlike previous operational spaceborne scatterometer systems. SeaWinds employs a scanning "pencil-beam" antenna rather than a "fan-beam" antenna, making the instrument more compact and yielding greater ocean coverage. The goals of this paper are twofold. First, the overall SeaWinds functional design and backscatter measurement approach are described, and the relative advantages of the pencil-beam technique are …


A Study Of Τ Decays Involving Η And Ω Mesons, D. Buskulic, M. Thulasidas Jan 1997

A Study Of Τ Decays Involving Η And Ω Mesons, D. Buskulic, M. Thulasidas

Research Collection School Of Computing and Information Systems

The 132 pbt - 1 of data collected by ALEPH from 1991 to 1994 have been used to analyze η and ω production in τ decays. The following branching fractions have been measured: B(τ−→ντωh−)=(1.91±0.07±0.06)×10−2,B(τ−→ντωh−)=(1.91±0.07±0.06)×10−2, B(τ−→ντωh−π0)=(4.3±0.6±0.5)×10−3,B(τ−→ντωh−π0)=(4.3±0.6±0.5)×10−3, B(τ−→ντηK−)=(2.9+1.3−1.2±0.7)×10−4,B(τ−→ντηK−)=(2.9−1.2+1.3±0.7)×10−4, B(τ−→ντηh−π0)=(1.8±0.4±0.2)×10−3B(τ−→ντηh−π0)=(1.8±0.4±0.2)×10−3 and the 95% C.L. limit B(τ− → ντηπt -) t - 4 has been obtained. The ωπt- and ηπt -π0 rates and dynamics are found in agreement with the predictions made from e+e∼ - annihilation data with the help of isospin invariance (CVC).


Immobilization Of Radioactive Materials In Iron Phosphate Glass, Melissa G. Mesko Jan 1997

Immobilization Of Radioactive Materials In Iron Phosphate Glass, Melissa G. Mesko

Doctoral Dissertations

"The current study investigates the feasibility of using iron phosphate glass for the immobilization of radioactive wastes considered incompatible with borosilicate glass. Wastes may be incompatible with borosilicate glass due to high phosphorus content (Hanford tank sludges), the presence of halides (CsCl and SrF2 capsules), or large amounts of uranium (SNF).

Between 20 and 60 wt% Hanford tank sludge was vitrified with an iron phosphate glass at ≤ 1200°C in 1 hour. The chemical durability of iron phosphate glassy wasteforms was as good as, or better than a reference borosilicate glass (10-9 g/cm2/min) in distilled water …


Service Quality Using The Deviation-Score Approach To Fit In Contingency Theory In A U.S. Army Corps Of Engineers Setting, Donald Robert Groh Jan 1997

Service Quality Using The Deviation-Score Approach To Fit In Contingency Theory In A U.S. Army Corps Of Engineers Setting, Donald Robert Groh

Doctoral Dissertations

"The purpose of this study is to learn how organizational work unit context, structure, and processes relate to service quality. The theoretical basis for the research is that organizational work units should be structured based on the work that they perform. If the work that a unit performs is highly variable, then the work unit should be structured in such a way as to provide flexibility, that is, few rules and procedures and highly decentralized decision making. If the work that a unit performs is not variable, then the work unit should be structured to provide a non-varying product or …


An Investigation On The Effect Of Aging And Fatigue Damage On The Mechanical Properties Of A Graphite/Bismaleimide Composite, William M. Johnston Jr. Jan 1997

An Investigation On The Effect Of Aging And Fatigue Damage On The Mechanical Properties Of A Graphite/Bismaleimide Composite, William M. Johnston Jr.

Mechanical & Aerospace Engineering Theses & Dissertations

This investigation utilizes the open hole tension (OHT) specimen loaded in tension-tension fatigue under isothermal, fixed frequency conditions. A range of load levels and temperature levels where chosen to assess performance. These loads and temperatures ranged from relatively benign conditions (low stress, room temperature) up through aggressive conditions (high stress, high temperature). Measurements of stiffness, damage accumulation, residual strength, weight loss, and glass transition temperature (Tg) were made. Results from this work will help explain the roles of aging, load and fatigue in the performance of elevated temperature OHT specimens as well as provide insights to the individual and synergistic …


Reflection High-Energy Electron-Diffraction Study Of Melting And Solidification Of Pb On Graphite, Z. H. Zhang, P. Kulatunga, H. E. Elsayed-Ali Jan 1997

Reflection High-Energy Electron-Diffraction Study Of Melting And Solidification Of Pb On Graphite, Z. H. Zhang, P. Kulatunga, H. E. Elsayed-Ali

Electrical & Computer Engineering Faculty Publications

The melting and solidification of Pb thin films on pyrolytic graphite are investigated in situ by reflection high-energy electron diffraction. Thin films with thicknesses of 4-150 monolayers are investigated. The surface morphology of the thin films were studied by scanning electron microscopy. Superheating of the Pb thin films by 4±2 to 12±2 K is observed from diffraction intensity measurements. Upon cooling the substrate, the Pb on graphite is seen to supercool by ∼69±4 K.


Microwave Plasma Chemical Vapor Deposited Diamond Tips For Scanning Tunneling Microscopy, Sacharia Albin, Jianli Zheng, John B. Cooper, Weihai Fu, Arnel C. Lavarias Jan 1997

Microwave Plasma Chemical Vapor Deposited Diamond Tips For Scanning Tunneling Microscopy, Sacharia Albin, Jianli Zheng, John B. Cooper, Weihai Fu, Arnel C. Lavarias

Electrical & Computer Engineering Faculty Publications

Diamond microparticles were grown on etched tungsten wires using a microwave plasma-assisted chemical vapor deposition process. The apexes on cubo-octahedral particles bound by {100} and {111} facets were effectively used as tunneling tips for scanning tunneling microscopy. The atomically resolved surface image of highly oriented pyrolytic graphite was acquired. Tunneling characteristics revealed a higher electron emission from the diamond tips than that from the platinum–iridium tips. The same diamond tips were used to produce surface indentation and its image. © 1997 American Institute of Physics.


Optical And Electrical Properties Of Cualse² Thin Films Obtained By Selenization Of Cu/Al/Cu... Al/Cu Layers Sequentially Deposited, J. C. Bernède, S. Marsillac, C. El Moctar, A. Conan Jan 1997

Optical And Electrical Properties Of Cualse² Thin Films Obtained By Selenization Of Cu/Al/Cu... Al/Cu Layers Sequentially Deposited, J. C. Bernède, S. Marsillac, C. El Moctar, A. Conan

Electrical & Computer Engineering Faculty Publications

Optical and electrical properties of CuAlSe2 thin films obtained by selenization of Cu/Al/Cu...Al/Cu layers sequentially deposited have been investigated. It is shown that the expected energy gap (2.67 eV) is measured for well crystallized films, whereas a slightly higher value is measured for films not so well crystallized. Raman diffusion also shows differences between well and poorly crystallized films with peaks corresponding to the reference powder for the former samples. A p-type conductivity is found whatever the crystalline quality of the samples. The conductivity of the films depends also strongly on their crystalline properties. When the films are badly …


Cualse² Thin Films Obtained By Chalcogenization, S. Marsillac, K. Benchouk, C. El Moctar, J. C. Bernède, J. Pouzet, A Khellil, M. Jamali Jan 1997

Cualse² Thin Films Obtained By Chalcogenization, S. Marsillac, K. Benchouk, C. El Moctar, J. C. Bernède, J. Pouzet, A Khellil, M. Jamali

Electrical & Computer Engineering Faculty Publications

CuAlSe2 thin films have been synthesized by chalcogenization of thin Cu and Al layers sequentially deposited by evaporation under vacuum. It is shown that CuAlSe2 films are obtained with some Cu2-δSe and Se phases present at the surface. These surface phases are suppressed by annealing under vacuum and by chemical etching in a KCN solution. At the end of the process, the XRD spectrum demonstrates that textured CuAlSe2 films have been obtained with preferential orientation of the crystallites along the (112) direction. The gap of the films is 2.7 eV as expected. The …


Measurement Of The Spectral Functions Of Vector Current Hadronic Tau Decays, R. Barate, M. Thulasidas Jan 1997

Measurement Of The Spectral Functions Of Vector Current Hadronic Tau Decays, R. Barate, M. Thulasidas

Research Collection School Of Computing and Information Systems

A measurement of the spectral functions of non-strange τ vector current final states is presented, using 124 358 τ pairs recorded by the ALEPH detector at LEP during the years 1991 to 1994. The spectral functions of the dominant two- and four-pion τ decay channels are compared to published results of e + e - annihilation experiments via isospin rotation. A combined fit of the pion form factor from τ decays and e + e - data is performed using different parametrizations. The mass and the width of the ρ ±(770) and the ρ 0(770) are separately determined in order …


Modeling Of Fading Dynamics For The Indoor Microwave Channel, Mangeet Singh Jan 1997

Modeling Of Fading Dynamics For The Indoor Microwave Channel, Mangeet Singh

Theses : Honours

This report outlines the multipath fading phenomenon and its relationship to wireless system design. The work was conducted for the academic year of 1996. This report provides the reader with an insight into the phenomenon called fading and its relevance when designing wireless systems. Fading is an important consideration when wireless systems are to be designed. Because fading is very unpredictable and it cannot to totally eliminated in a wireless system, systems engineers have a hard time trying to design and commission efficient communication systems for a particular environment. Over the years, there has been a existing need worldwide to …


Fractal Relationships And Spatial Distribution Of Ore Body Modelling, D. J. Kentwell Jan 1997

Fractal Relationships And Spatial Distribution Of Ore Body Modelling, D. J. Kentwell

Theses: Doctorates and Masters

The nature of spatial distributions of geological variables such as ore grades is of primary concern when modelling ore bodies and mineral resources. The aim of any mineral resource evaluation process is to determine the location, extent, volume and average grade of that resource by a trade off between maximum confidence in the results and minimum sampling effort. The principal aim of almost every geostatistical modelling process is to predict the spatial variation of one or more geological variables in order to estimate values of those variables at locations that have not been sampled. From the spatial analysis of these …


Building Embankments Of Fly/Bottom Ash Mixtures, Ahmed M.K. Karim, C. W. Lovell, Rodrigo Salgado Jan 1997

Building Embankments Of Fly/Bottom Ash Mixtures, Ahmed M.K. Karim, C. W. Lovell, Rodrigo Salgado

JTRP Technical Reports

This research investigates the engineering properties of mixtures of bottom ash and Class F fly ash relevant to their utilization in highway embankment construction. The research included ash samples from two major power plants in Indiana that disposed of their ash differently. The first power plant disposes of the bottom ash and fly ash separately and hence explicit mixtures were synthetically formed and tested. The second power plant disposes of the bottom ash and fly ash together in a common location and hence they become homogeneous samples for the research. Characterization of the ash included grain size analysis, specific gravity, …


Chemical Stability Study Of Bace0.9Nd0.1O3−Α High Temperature Proton-Conducting Ceramic, Fanglin Chen, O. Toft Sorensen, Guangyao Meng, Dingkum Peng Jan 1997

Chemical Stability Study Of Bace0.9Nd0.1O3−Α High Temperature Proton-Conducting Ceramic, Fanglin Chen, O. Toft Sorensen, Guangyao Meng, Dingkum Peng

Faculty Publications

BaCe0.9Nd0.1O3−a (BCN) ceramic is known to be an excellent high-temperature proton conductor and is a candidate electrolyte for use in solid oxide fuel cells, hydrogen or steam sensors and steam electrolysers. In this work, the chemical stability of BCN was investigated systematically by combining XRD and DTA–TG techniques to study its processing compatibility and its feasibility in potential applications. It was found that above 1200 °C, BCN reacted with alumina or zirconia, leading to the loss of barium and an excess of cerium. In cold water, both sintered BCN disks and powder samples had very …


Preparation Of Nd-Doped Baceo3 Proton-Conducting Ceramics By Homogeneous Oxalate Coprecipitation, Fanglin Chen, Ping Wang, O. Toft Sorensen, Guangyao Meng, Dingkum Peng Jan 1997

Preparation Of Nd-Doped Baceo3 Proton-Conducting Ceramics By Homogeneous Oxalate Coprecipitation, Fanglin Chen, Ping Wang, O. Toft Sorensen, Guangyao Meng, Dingkum Peng

Faculty Publications

Nd-doped BaCeO3 have been obtained from homogeneous coprecipitated oxalates when calcined at temperatures T≥1000 °C. Ball-milling of the calcined powders well disperses the agglomerates and consequently has a beneficial effect in the densification process. The calcination temperature has a major influence on the sintering process and powders calcined at 1100 °C possess good sinterabilities. The pressure applied to press the green pellets has no apparent influence on the sintered density at sintering temperatures of T≥1400 °C. By controlling the processing variables it was possible to obtain near fully dense Nd-doped BaCeO3 ceramics with homogeneous microstructure at a sintering …


Environmental Industrial Auditing In An Egyptian Textile Industry, Ahmed Reda El Sotouhy Jan 1997

Environmental Industrial Auditing In An Egyptian Textile Industry, Ahmed Reda El Sotouhy

Archived Theses and Dissertations

No abstract provided.


Field Measurement Of Uncontrolled Air Flow And Depressurization In Restaurants, Florida Solar Energy Center, James Cummings Dec 1996

Field Measurement Of Uncontrolled Air Flow And Depressurization In Restaurants, Florida Solar Energy Center, James Cummings

FSEC Energy Research Center®

Field investigations were done in seven restaurants (subsample of a 63 commercial buildings study) to identify uncontrolled air flows and pressure imbalances. Testing included building airtightness tests, identification of building air barrier location, duct system airtightness, characterization of pressure differentials, building air flow balance, and infiltration/ventilation rates. All restaurants were found to operate at negative pressures which ranged from -0.003 inWC (-0.8 Pa) to -0.173 inWC (-43 Pa) and averaged -0.051 inWC (-12.7 Pa) under normal operation. The variables which affect depressurization are large exhaust fans, missing or undersized make-up air, intermittent outdoor air caused by the cycling of air …


High-Speed Craft (Hsc) : A Study Of Their Safe Operation And Navigation, And Their Impact Upon The Malacca Strait, Lim Yew Seng Dec 1996

High-Speed Craft (Hsc) : A Study Of Their Safe Operation And Navigation, And Their Impact Upon The Malacca Strait, Lim Yew Seng

World Maritime University Dissertations

The dissertation is a study of the safe operation and navigation of High-speed Craft (HSC) and their impact upon the Malacca Strait. The definitions of HSC are compared and illustrated. The future trend, growth and development of current types of HSC and their inherent design limitations are investigated. The maneuvering systems and characteristics of HSC are analyzed. The active safety system employed by HSC is compared to the passive safety system of conventional vessels. The operation and navigation problems due to high-speed are investigated. The human resource management methods of reducing human errors are discussed. The navigational requirements of the …


A Study Of Teaching Automation For Marine Engineers, Myat Moe Dec 1996

A Study Of Teaching Automation For Marine Engineers, Myat Moe

World Maritime University Dissertations

This dissertation is a research into a study of teaching automation for marine engineers which is conducted at the Institute of Marine Technology (IMT)of the Union of Myanmar as related to the Fundamentals of Automation, Instrumentation and Control systems, module 9 of IMO model course 7.02. This course is now included in the mandatory part of STCW Code A of the revised STCW Convention. An examination is made of the fundamentals of ship automation and a brief overview is given of the modem developments in ship automation system. This includes modem developments in main engine automation, navigation/ bridge control, integrated …


Expression Of Human Protein C In Mammary Tissue Of Transgenic Mammals , William H. Velander Dec 1996

Expression Of Human Protein C In Mammary Tissue Of Transgenic Mammals , William H. Velander

Department of Chemical and Biomolecular Engineering: Patents

Recombinant protein C characterized by a high percentage of active protein can be obtained in the milk of transgenic mammals that incorporate DNAs according to the present invention. Transgenic mammals of the present invention are produced by introducing into developing embryos DNA that encodes protein C, such that the DNA is stably incorporated in the DNA of germ line cells of the mature mammals and inherited in normal, mendelian fashion.


Towards New Technology : An Overview Of The Development And Potential Use Of The Electronic Chart, King Kurwijira Ngabho Chiragi Dec 1996

Towards New Technology : An Overview Of The Development And Potential Use Of The Electronic Chart, King Kurwijira Ngabho Chiragi

World Maritime University Dissertations

No abstract provided.


The Transport Properties Of Nanocrystalline Srce0.95yb0.05o3 Thin Films, Igor Kosacki, Harlan U. Anderson Dec 1996

The Transport Properties Of Nanocrystalline Srce0.95yb0.05o3 Thin Films, Igor Kosacki, Harlan U. Anderson

Materials Science and Engineering Faculty Research & Creative Works

The results of electrical transport measurements on nanocrystalline SrCe0.95Yb0.05O3 thin films are presented. Dense SrCe0.95Yb0.05O3 thin films with 30-70 nm grain size have been obtained using a spin-coating technique. These films exhibit about 103 higher electrical conductivity when compared with the bulk polycrystalline material. The grain size of thin films is stable to temperatures as high as 1000 °C since no grain-coarsening was observed. These unique electrical properties of nanocrystalline SrCe0.09Yb0.05O3 thin films are attributed to a dominant role of grain boundaries and/or interfaces. © 1996 American Institute of Physics.


Magnetic Dynamics In Underdoped Yba2⁢Cu3⁢O7−X: Direct Observation Of A Superconducting Gap, Pengcheng Dai, Mohana Yethiraj, Herbert A. Mook, Terrence B. Lindemer, Fatih Dogan Dec 1996

Magnetic Dynamics In Underdoped Yba2⁢Cu3⁢O7−X: Direct Observation Of A Superconducting Gap, Pengcheng Dai, Mohana Yethiraj, Herbert A. Mook, Terrence B. Lindemer, Fatih Dogan

Materials Science and Engineering Faculty Research & Creative Works

Polarized and unpolarized triple-axis neutron measurements were performed on an underdoped crystal of YBa2⁢Cu3⁢O7−x (x = 0.4 ±0.02, Tc = 62.7⁢K). Our results indicate, contrary to earlier evidence, that the spin excitations in the superconducting state are essentially the same as those in the fully doped material except that the unusual 41 meV resonance is observed at 34.8 meV. The normal state spin excitations are characterized by a weakly energy-dependent continuum whose temperature dependence shows the clear signature of a superconducting gap at Tc. The enhancement at the resonance is accompanied by …


Trade-Off Study And Computer Simulation For Assessing Spacecraft Pointing Accuracy And Stability Capabilities, Marcelo C. Algrain, Richard M. Powers Dec 1996

Trade-Off Study And Computer Simulation For Assessing Spacecraft Pointing Accuracy And Stability Capabilities, Marcelo C. Algrain, Richard M. Powers

Department of Electrical and Computer Engineering: Faculty Publications

A case study, written in a tutorial manner, is presented where a comprehensive computer simulation is developed to determine the driving factors contributing to spacecraft pointing accuracy and stability. Models for major system components are described. Among them are spacecraft bus, attitude controller, reaction wheel assembly, star-tracker unit, inertial reference unit, and gyro drift estimators (Kalman filter). The predicted spacecraft performance is analyzed for a variety of input commands and system disturbances. The primary deterministic inputs are the desired attitude angles and rate set points. The stochastic inputs include random torque disturbances acting on the spacecraft, random gyro bias noise, …


Modeling And Simulation Of Optical Characteristics Of Microelectromechanical Mirror Arrays, Peter C. Roberts Dec 1996

Modeling And Simulation Of Optical Characteristics Of Microelectromechanical Mirror Arrays, Peter C. Roberts

Theses and Dissertations

MEMS (Micro-Electro-Mechanical Systems) micromirror devices can be used to control the phase of a propagating light wavefront, and in particular to correct aberrations that may be present in the wavefront, due to either atmospheric turbulence or any other type of fixed or time and space varying aberrations. In order to shorten the design cycle of MEMS micromirror devices, computer software is developed to create, from MEMS micromirror device design data, a numerical model of the MEMS device. The model is then used to compute the far field diffraction pattern of a wavefront reflected from the device, and to predict the …


An Object-Oriented Discrete-Event Simulation System For Hierarchical Parallel Simulations, Kenneth W. Stauffer Dec 1996

An Object-Oriented Discrete-Event Simulation System For Hierarchical Parallel Simulations, Kenneth W. Stauffer

Theses and Dissertations

The purpose of this research is to design and implement an object-oriented discrete-event simulation system which supports hierarchically constructed players in a parallel or distributed environment. This system design considers modularity and portability so additional modules may be implemented to experiment with new algorithms for both partitioning and synchronization. A simulation system which meets these requirements was partially implemented on an eight-node Intel Hypercube in C. A desired goal was to maintain the functionality of the existing BattleSim application. Test cases used measure the performance and correct operation of the new simulation architecture using a BattleSim subclass. Test results prove …


Low Temperature Hydrothermal Synthesis Of Nanophase Batio3 And Bafe12019 Powders, Fatih Dogan, Shawn O'Rourke, Mao-Xu Qian, Mehmet Sarikaya Dec 1996

Low Temperature Hydrothermal Synthesis Of Nanophase Batio3 And Bafe12019 Powders, Fatih Dogan, Shawn O'Rourke, Mao-Xu Qian, Mehmet Sarikaya

Materials Science and Engineering Faculty Research & Creative Works

Nanocrystalline powders with an average particle size of 50 nm have been synthesized in two materials systems under hydrothermal conditions below 100°C. Processing variables, such as temperature, concentration and molar ratio of reactants and reaction time were optimized to obtain particles of reduced size and stoichiometric compositions. Hydrothermal reaction takes place between Ba (OH)2 solution and titanium/iron precursors in sealed polyethylene bottles in the BaTiO3 and BaFe12019 systems, respectively. While crystalline BaTiO3 forms relatively fast within a few hours, formation of fully crystalline and stoichiometric BaFe12019 require considerably longer reaction times up to several weeks and strongly …