Engineering Commons^™

Effects Of Nickel Content And Simulated Heat Affected Zone Of 2205 Duplex Stainless Steel On Pitting Corrosion, Horng-Yih Liou, Ju-Tung Lee, Wen-Ta Tsai, Rong-Iuan Hsieh, Yeongtsuen Pan

Journal of Electrochemistry

The effects of nickel content and Gleeble simulated heat affected zone (HAZ) of 2205 stainless steel on pitting corrosion were investigated in this paper. The results showed that nickel content, ranging from 4.5 wt% to 6.5 wt% in base metal, had only a minor effect on the electrochemical polarization curves, with all E_np's and E_pp's falling in the rang of 1100~1200 mV. Comparing with the base metal, the simulated HAZ microstructure caused an increase in the anodic current density, a distinct decrease in both E_np and E_pp , and a reduction in the passive …

Investigation Of Solution Chemistry In Crevice Of Carbon Steel And Its Anodic Polarization Behavior, Zhuo Chen, Cui-Wei Du, Bei Cao, Yin-Shun Wu, Hai Yang, Zheng-Rong Zhang

Journal of Electrochemistry

A self-made wedge-shaped simulated crevice apparatus was designed to investigate the solution chemistry in crevice of carbon steel and its anodic polarization behavior. For carbon steel with 3.5%(wt) NaCl, the change and the distribution of electrode potential, concentration of Cl^- and pH value of solution in the crevice, and the current density of metal in the crevice were measured respectively under various conditions of anodic polarization. The results showed that without polarization the metal about 2 cm away from the opening of the crevice was attacked preferentially because of its lowest free corrosion potential. The anodic polarization promoted the …

A Study On The Cathode Protection Potential Against Pitting Corrosion, Chun-Chun Xu, You-Ping Liu, Xiao-Bo Zhang, Xu-Hui Zhao

Journal of Electrochemistry

The methods have been developed to determine the protection potential against pitting corrosion. They are based on the theory that the pitting protection potential (E_p) is actually the transition potential of the direction of current between the occluded cell and the external surface (E_T). E_T lasts from -220 mV to -440 mV (SCE), the lowest of which can be considered as cathode protection potential. The E_p values determined with cyclic potentiodynamic polarization method is included in the E_T with above methods.

Zro2 And Zro2-Y2O3 Coatings Deposited By High Energy Pulse, Wei-Ping Yu, Ye-Dong He, Li-Na Zhang, De-Ren Wang

Journal of Electrochemistry

The basic rule and influence factors on deposition of ZrO₂ and ZrO₂-Y₂O₃ coatings by high energy pulse were studied. After the oxidizing experiment in air at 1 000 for 100 h, it was shown that the oxidation resistance of 18-8 stainless steel was marketly enhanced by depositing ZrO₂ and ZrO₂-Y₂O₃ coatings. The oxidation resistance was increased about 20 times and the oxide scale spallation resistance was increased about 100 times.

Study On The Microband Array Electrode-Based Glucose Microsensor, Neng-Qin Jia, Chui-Jue Sun, Lin Gao, Zong-Rang Zhang, Jian-Zhong Zhu, Guo-Xiong Zhang

Journal of Electrochemistry

The microband array electrode (MAE) consisting of 11 Pt microband of 5 m in wide, 2000 m long and 85 m gap was fabricated with a thin film techology. The MAE was characterized by means of cyclic voltammetry in a solution of K₃Fe(CN)₆ and H₂O₂. The results showed higher current density on MAE than on conventional Pt eletrode due to the strong edge effect of the former. A glucose microsensor was constructed with the substrate electrode of microband array. Microband array electrode was modified by Nafion followed by the immobilization of ferrocene onto …

In Situ Ftir Spectroelectrochemical Study Of Palladium Hexacyanoferrate Thin Film Deposited On Glassy Carbon Electrode, Ai-Li Bo, Xiang-Qin Lin

Journal of Electrochemistry

The electrochemically deposited Palladium hexacyanoferrate thin film on Glassy Carbon electrode (PdHCF|GC) has been studied in HCl, KCl and NaCl solutions by in-situ external reflection FTIR spectroelectrochemical technique. It is found that the behavior of the electroactive PdHCF film can be understood in terms of two states: Pd₂Fe(II)(CN)₆ formed in the inner layer and (M⁺)2Fe(II)(CN)₆ (M⁺: electrolyte cation) formed in the outer layer. The inner layer is oxidized at E_m=0.87 V in 1 mol/L KCl, while for the outer layer Em=0.77 V(vs. Ag/AgCl). In 1 mol/L NaCl or HCl solutions, …

Influence Of Ptfe And Nafion On The Utilization Efficiency Of Pt/C Catalyst In Pemfc, Xiao-Liang Cheng, Bao-Lian Yi, Jing-Xin Zhang, Ming Han, Ya-Guang Qiao

Journal of Electrochemistry

With cycling voltammetry curve(C-V), TEM and SEM photographs, the influence of PTFE and Nafion on the platinum utilization in catalyst layer of PEMFC was investigated. The results show that in gas diffusion electrode, the blocking effect of PTFE in the platinum utilization is not pronunced. In the thin-film catalyst layer, the electron conduct of the catalyst was blocked by the nafion solid and this caused the decrease of platinum utilization. With the increase of the nafion content in the catalyst layer, both platinum utilization and the electron conductivity decreased in the catalyst layer. Because the molecule size of nafion is …

Effect Of Inhibitor On Electrochemical Behavior Of 1cr18 Stainless Steel In Acidic Solution Under Friction, Jin-Ping Xiong

Journal of Electrochemistry

The electrochemical behavior of 1Cr18 stainless steel had been studied using a reciprocating triboelectrochemical equipment under friction in 0.2 mol/L H₂SO₄ solution with and without addition of thiourea, the frictionized surface of 1Cr18 stainless steel had been examined by the SEM, XPS and IR. The results showed that the loss rate of 1Cr18 stainless steel in the solution could be reduced by addition of thiourea. The adsorption of thiourea on the surface of 1Cr18 stainless steel prohibited the oxidization of Cr³⁺ to form Cr(Ⅵ) and formation of passive film consisting of CrO₄^2- or/and Cr(Ⅵ), …

The Behaviors Of Capacity Loss Of Limn2O4 Cathodeat Elevated Temperatures, Xiao-Hong Hu, Han-Xi Yang, Xin-Ping Ai, Sheng-Xian Li, Xin-Lin Hong

Journal of Electrochemistry

The capacity loss of spinel LiMn₂O₄ cathode at elevated temperatures was evaluated by constant current charge-discharge methods and it was found that serious capacity loss and cycleability decrease occured at above 50, especially for the charged cells. The mechanisms for this phenomena were examined by atomic emission and infrared spectrometry of the electrolyte, XRD measurment of the cycled elecrode and microelectrode voltammetry of LiMn₂O₄ at room and elevated temperatures. The results showed that with increasing temperature, Mn and Li ions tended to redistribute partly in the spinel framework due to the disproportion of Mn …

Z-Protected Glutamic Acid-Based Biodegradable Thermoplastic And Thermosetting Polyesters: Synthesis And Characterization, R. M. Tadros, Hossein Noureddini, Delmar C. Timm

Papers in Biomaterials

Biodegradable polymers were formed from N-benzyloxycarbonyl-L-glutamic acid with the comonomers ethylene glycol, diglycidyl ether of 1,4-butanediol, and diglycidyl ether of bisphenol A. The three polymers were a linear and a cross-linked heterochain polyester and a cross-linked polyester that contained aromatic units within its network chains. The thermoplastic resin and the soluble fractions for the thermosetting resins were characterized by gel permeation chromatography. Conversions for carboxylic acid were determined by titrations. A quality, 22,000 molecular weight thermoplastic resin was formed. The two thermosets were cured past their gel points. Gelation analysis revealed that the relative rate constants for the sequential oxirane/acid …

Method Of Coupling Ligands Onto Supports And Products Produced Therefrom , William H. Velander, Anuradha Subramanian

Department of Chemical and Biomolecular Engineering: Patents

A method is disclosed for coupling a ligand within a porous support. The method involves mixing ligand and porous support under conditions sufficient to suppress coupling conditions of the ligand to the porous support while enhancing the relative rate of diffusion, to the rate of reaction, of the ligand into and within the porous support, and then altering the conditions to enhance rapid coupling of the ligand within the porous support. The alteration from diffusion conditions to coupling conditions involves a change in the reaction solution of pH, ionic strength, temperature, coupling competitor, such that a relatively lower Thiele Modulus …

Method Of Coupling Ligands Onto Supports And Products Produced Therefrom , William H. Velander

Department of Chemical and Biomolecular Engineering: Patents

A method is disclosed for coupling a ligand within a porous support. The method involves mixing ligand and porous support under conditions sufficient to suppress coupling conditions of the ligand to the porous support while enhancing the relative rate of diffusion, to the rate of reaction, of the ligand into and within the porous support, and then altering the conditions to enhance rapid coupling of the ligand within the porous support. The alteration from diffusion conditions to coupling conditions involves a change in the reaction solution of pH, ionic strength, temperature, coupling competitor, such that a relatively lower Thiele Modulus …

Sensors Location Effect On The Dynamic Behaviour Of The Composite Structure With Flaw Detection, Eltahry Elghandour, Faysal Kolkailah, Abdel- Hamid I. Mourad

Aerospace Engineering

In this paper presents an experimental and numerical investigation ofthe natural frequency of composite material cantilever plates. The stacking sequence of tbe composite plate is Quasi-isotropic laminated plate is [2(0j/±45°/2(90°)]" The plate was subjected to incremental cuts and tests to determine changes in new modal properties. The study included white noise and sinusoidal dynamic testing techniques and a virtual instrument dynamic analyzer. In this study also, determining the resonant frequencies of the undamaged and damaged plate, and evaluating the capabilities of piezoelectric ceramics (PZT's) for fault detection based on their sensitivity and accuracy changes in modal parameters. Numerical results are …

Mixed Mode Stable Crack Extensions Through Stiffened Specimens, Abdel-Hamid I. Mourad, Eltahry Elghandour, Faysal A. Kolkailah

Aerospace Engineering

This study presents an experimental investigation of fracture mechanics for isotropic material, aluminum alloy D16AT. The problem of stable crack growth (SCG) has been addressed in this paper. Experimental results are presented for symmetrically stiffened and unstiffened three point bend specimens subjected to different modes, mode I and mixed mode. The stiffeners are doubly bonded to the fatigue pre-cracked specimens parallel to the length at a certain distance behind the crack tip using an adhesive Redux 410 NA. Results concerning load displacement variation, growth of plastic zones, instantaneous crack edge profiles, and tunneling are presented. There is evidence that the …

The Magnetic Excitation Spectrum And Thermodynamics Of High-Tc Superconductors, Pengcheng Dai, Herbert A. Mook, Stephen M. Hayden, Toby G. Perring, Gabriel Aeppli, Rodney Dale Hunt, Fatih Dogan

Materials Science and Engineering Faculty Research & Creative Works

Inelastic neutron scattering was used to study the wave vector– and frequency dependent magnetic fluctuations in single crystals of superconducting YBa₂Cu₃O_6+x. The spectra contain several important features, including a gap in the superconducting state, a pseudo gap in the normal state, and the much-discussed resonance peak. The appearance of the pseudo gap determined from transport and nuclear resonance coincides with formation of the resonance in the magnetic excitations. The exchange energy associated with the resonance has the temperature and doping dependences as well as the magnitude to describe approximately the electronic specific heat near …

The Magnetic Excitation Spectrum And Thermodynamics Of High-Tc Superconductors, Pengcheng Dai, Herbert A. Mook, Stephen M. Hayden, Gabriel Aeppli, Toby G. Perring, Rodney Dale Hunt, Fatih Dogan

Materials Science and Engineering Faculty Research & Creative Works

Inelastic neutron scattering was used to study the wave vector– and frequency dependent magnetic fluctuations in single crystals of superconducting YBa₂Cu₃O_6+x. The spectra contain several important features, including a gap in the superconducting state, a pseudo gap in the normal state, and the much-discussed resonance peak. The appearance of the pseudo gap determined from transport and nuclear resonance coincides with formation of the resonance in the magnetic excitations. The exchange energy associated with the resonance has the temperature and doping dependences as well as the magnitude to describe approximately the electronic specific heat near …

Membrane Process For Biological Treatment Of Contaminated Gas Streams, Sarina J. Ergas, Leslee Shumway, Mark W. Fitch, Jeffrey J. Neemann

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

A Hollow Fiber Membrane Bioreactor Was Investigated for Control of Air Emissions of Biodegradable Volatile Organic Compounds (VOCs). in the Membrane Bioreactor, Gases Containing VOCs Pass through the Lumen of Microporous Hydrophobic Hollow Fiber Membranes. Soluble Compounds Diffuse through the Membrane Pores and Partition into a VOC Degrading Biofilm. the Hollow Fiber Membranes Serve as a Support for the Microbial Population and Provide a Large Surface Area for VOC and Oxygen Mass Transfer. Experiments Were Performed to Investigate the Effects of Toluene Loading Rate, Gas Residence Time, and Liquid Phase Turbulence on Toluene Removal in a Laboratory-Scale Membrane Bioreactor. Initial …

Oxygen Permeation Through Composite Oxide-Ion And Electronic Conductors, Kevin Huang, Michael Schroeder, John B. Goodenough

Faculty Publications

Oxygen permeation through composites consisting of four well-known oxide-ion conductors and a noble metal, Pd or Ag, is reported. The oxides were Zr_0.9Y_0.1O_1.95 (YSZ), (Bi_1.75Y_0.25O₃)_0.95(CeO₂)_0.05 (BYC5), Ce_0.8Sm_0.2O_1.9 (SSC), and La_0.8Sr_0.2Ga_0.83Mg_0.17O_2.815 (LSGM). The results show that (BYC5 + Ag) yields the highest oxygen permeation flux, but the composite deteriorates with time. The composites (SSC + Pd), (LSGM + Pd), and (YSZ + Pd) give stable, but relatively lower oxygen permeation flux …

Modeling The High-Speed Switching Of Far-Infrared Radiation By Photoionization In A Semiconductor, Thomas E. Wilson

Physics Faculty Research

Data from an earlier study [T. Vogel et al., Appl. Opt. 31, 329 (1992)] on the subnanosecond switching of 119-μm radiation in high-resistivity silicon by pulsed UV laser radiation, is compared with a refined one-dimensional numerical multilayer model accounting for the generation, recombination, and diffusion of the free carriers on the resulting far-infrared optical properties of the silicon. The inclusion of recent measurements for carrier-density and temperature-dependent transport parameters leads to improved agreement between experiment and theory.

Anti-Blooming Nightvision: Extending Global Dynamic Range By Neural Network Image Fusion, Daniel L. Schuster

Dissertations and Theses

Sensor saturation in the presence of bright objects can create a non-restorable loss of image information as the spatial gradient tends to zero. Blooming is an attendant morphological corruption of image data that plagues quantum well sensors, and in particular, low-light Charge-Coupled Devices (CCD's) used for nightvision applications. A novel application of Radial Basis Function Neural Networks has shown promise as a means for patching gain/brightness adjusted short exposure frame detail into the bloomed regions of long exposure image frames. A computer-tethered CCD camera was used to capture robust target images, at different exposures, in a controlled light-box environment to …

Emerald & Orion Formation Flying Experiment, Robert J. Twiggs

Robert "Bob" Twiggs STEM Education Collection

A PowerPoint Presentation created by Professor Bob Twiggs titled "Emerald & Orion Formation Flying Experiment" from May 5, 1999.

The Testing And The Automation Of Dark Current, Photoresponse And Responsivity Measurements For On-Wafer Metal Semiconductor Metal (W-Msm) Photodetectors, Tiffany Evette Monroe

Electronic Dissertations and Theses

This paper presents the testing and the automation of dark current, photoresponse, and responsivity measurements for W-MSM photodetectors. The testing phase of this particular photodetector is performed in order to compare manual measurement results with automated measurement results done in Lab VIEW. The automation phase is performed in order to take measurements quickly and efficiently using Lab VIEW programs which imitate the functions of actual instruments used to take dark current, photoresponse, and responsivity measurements. So far, only the dark current measurements can be automated. However, in the future, Lab VIEW programs will be written in order to automate the …

Santa Clara Magazine, Volume 41 Number 1, May 1999, Santa Clara University

Santa Clara Magazine

8 - A BRIDGE BETWEEN WORLDS By President PaulL. Locatelli, S.J. 'Go. President Locatelli examines the value of service learning for students, the University, and America's social fabric.

12 - A GIANT ARTIST By Ann Granning Bennett. Auguste Rodin's sculptures are now on view at the de Saisset Museum. The question is: How do high-profile art shows like this one come about?

18 - ARIZONA'S DIPLOMATIC TOP COP By Tamara Straus. Janet Napolitano ' 79 , Arizona's newly elected attorney general , discusses the challenges of public office as well as politics, ethics, and fighting crime.

Resonant Tank Motor Model For Voltage Reflection Simulations With Pwm Drives, Davia W. Schlegel, Glenn T. Wrate, Russ Kerkman, Gary Skibinski

Conference Papers in Published Proceedings

Reflected wave transient voltages that are impressed on drive output cables and low voltage AC induction motors are normally simulated with steep fronted dv/dt pulse waveforms from PWM voltage source inverters. System simulation arises from a need to correlate reflected wave peak voltage and risetime with the dielectric insulation capability of both the motor and cable. To obtain reasonable results, accurate models of each component must be employed. This investigation concentrates on parameter identification for a high frequency resonant tank motor model from fractional to several hundred horsepower.

Variable Angle Of Incidence Analysis Of Magneto-Optic Multilayers, William A. Mcgahan, Liang-Yao Chen, John A. Woollam

Department of Electrical and Computer Engineering: Faculty Publications

We have applied the technique of variable angle of incidence spectroscopic ellipsometry (VASE) to the analysis of multilayered magneto-optic structures. With this instrument we measure the complete pseudodielectric tensor (diagonal and off-diagonal elements) for the sample of interest at variable angles of incidence. We have also developed computer software to perform a best-fit analysis of the measured data, providing optical constants, Voigt parameters, and layer thicknesses for the individual layers in the sample. Additionally, given an estimate of the material parameters, this software will provide an estimate of the optimum spectral range and angles of incidence for accurate characterization of …

Chu Spaces - A New Approach To Diagnostic Information Fusion, Hung T. Nguyen, Vladik Kreinovich, Berlin Wu

Departmental Technical Reports (CS)

This paper is rather theoretical. Its aim is to describe a general algebraic framework, known as Chu spaces, in which different type of information can be transformed into the same form, so that fusion procedures can be investigated in a single general framework.

Weber Basin Water Quality Optimization, P. Wayne Hale Ii, Elizabeth Hales, Kade Moncur, Jonathan Oldham

Undergraduate Honors Capstone Projects

Salt Lake City, after evaluating its projected water needs for the next 25 years, has proposed to route 300 MGD of water via pipeline from the Bear River to Salt Lake's culinary water system. According to Weber Basin Water Conservancy District officials, this water will be available between October and March (the irrigation off-season). En route to the system, the water will pass through an area known as the "Slaterville Diversion" subsequent to water treatment at a new plant. The Diversion is currently the mixing point for several water sources. These waters need to be managed and mixed appropriately with …

Water Resource Potential Of The Rio-Grande River Basin In Bolivia, José Luis Chávez Egüez

All Graduate Plan B and other Reports, Spring 1920 to Spring 2023

The exploiting of water resources in developing countries is fundamental for stabilizing population growth, and promoting efficient agriculture. The development of water resources allows the utilization of modern irrigation systems and methodologies.

Recently developed methods to predict runoff from rainfall data are applied to a Bolivian watershed. A study in Honduras yielded a good response to the method that utilizes Moisture Availability Index (MAI) to predict runoff, but the coefficients of that relation could not be related to MAI or to the difference between average weather station elevation and average basin elevation in the Rio Grande Upper Basin in Bolivia. …

Acuta Enews May 1999, Vol. 28, No. 5

ACUTA Newsletters

In This Issue

Board Approves Slate of Nominees

Moderators & Monitors Needed in Nashville!

Board Report

Who Pays for Cellular Calls?

DC at a Glance

Positions Available

Welcome New Members

Directivity Patterns Of Acoustic Radiation From Bowed Violins, Lily M. Wang, Courtney B. Burroughs

Durham School of Architectural Engineering and Construction: Faculty Publications

Directivity patterns of acoustic radiation have been measured in the far-field of a violin, excited with an open-frame mechanical bowing machine. Analysis of the directivity patterns confirms that, at frequencies below 600 Hz, the violin radiates omnidirectionally, while above 600 Hz, certain trends are apparent as the patterns become increasingly complex. It is noted that when different strings are excited, the far-field radiation patterns observed at nearly the same frequency are similar, even in higher frequency ranges where modal overlap is high. When the difference in frequency between two directivity patterns exceeds some fraction of a semitone, though, the measured …