Embedded State Estimation For Optimization Of Cislunar Space Domain Awareness Constellation Design, Thomas Henry Clareson

Graduate Theses, Dissertations, and Problem Reports (ETD)

The traffic in cislunar space is expected to increase over the coming years, leading to a higher likelihood of conjunction events among active satellites, orbital debris, and non-cooperative satellites. This increase necessitates enhanced space domain awareness (SDA) capabilities that include state estimation for targets of interest. Both Earth surface-based and space-based observation platforms in geosynchronous orbit or below face challenges such as range, exclusion, and occlusion that hinder observation. Motivated by the need to place space-based observers in the cislunar space regime to overcome these challenges, this paper proposes a cislunar SDA constellation design and analysis framework that integrates state …

Development Of Probabilistic Dynamic Model Building And Bayesian Machine Learning Approaches, Samuel Oladayo Adeyemo

Graduate Theses, Dissertations, and Problem Reports (ETD)

Abstract

Development of Probabilistic Dynamic Model Building and Bayesian Machine Learning Approaches

Samuel Adeyemo

The recent years have seen a tremendous increase in the use of artificial intelligence (AI) and machine learning (ML) for the development of data-driven mathematical models needed for performing real-time optimization, model-based control, performance optimization, dynamic data reconciliation, and process performance monitoring. However, the development of data-driven models is faced with some challenges including lack of model interpretability, sensitivity of algorithm to noise in training data, limited extrapolation capabilities and violation of conservation laws. Drawing motivation from these existing gaps, this work aims to develop robust …

Modeling And Techno-Economic Optimization Of Microwave Assisted Ammonia Synthesis Processes, Opeyemi Aduragbemi Ogunniyan

Graduate Theses, Dissertations, and Problem Reports (ETD)

Ammonia, which plays a crucial role in agriculture, chemical production, and energy storage applications, has traditionally been produced using the Haber-Bosch (HB) process. However, this well-established technology has significant drawbacks. The HB process requires extremely high pressures (up to 300 bar) and temperatures (400-500°C), making it feasible only for large-scale operations with substantial capital investment. Additionally, the high energy consumption of the HB process contributes significantly to greenhouse gas emissions, raising concerns about its environmental sustainability. This dissertation extensively explores a new low-pressure microwave-assisted process for synthesizing ammonia, demonstrating its economic viability and potential cost-effectiveness compared to the traditional method, …

Development Of Dynamic Mass-Energy-Thermodynamics Constrained Hybrid Neural Network Models For Process Systems Applications, Angan Mukherjee

Graduate Theses, Dissertations, and Problem Reports (ETD)

First-principles models can provide very good predictions even for cases when there are no data at all, or data are limited in certain range of operating conditions, or for cases where data collection is infeasible. However, the development of accurate first-principles models for complex nonlinear dynamic systems can be time consuming, computationally expensive, and may be infeasible for certain systems due to lack of sufficient knowledge (information). It is also challenging to adapt first-principles models for time-varying systems. Furthermore, it can be difficult, if not impossible, to develop accurate models for some complex phenomena that are poorly understood. On the …

State Estimation And Economic Analysis For Electrochemical Sensor-Based Corrosion Monitoring, Chandra Sekhar Somayajula

Graduate Theses, Dissertations, and Problem Reports (ETD)

Coal is currently the third-largest source of electricity production in the U.S. However, renewables are projected to be the primary source of electricity production in the future. Though coal-fired power plants (CFPPs) are rapidly retiring in the U.S., many CFPPs worldwide are expected to stay operational for a while due to factors like easy and cheap access to comparatively inexpensive coal. Therefore, non-renewable sources like coal are still expected to be prevalent and be used to ensure the stability of the electric grid in the foreseeable future. The existing coal-fired power plants generally designed to operate at base-loaded conditions are …

An Approach For Robotic Pollination That Utilizes Imitation Learning, Ronald Michael Butts Ii

Graduate Theses, Dissertations, and Problem Reports (ETD)

The global decline in pollinator populations poses a significant threat to agriculture, motivating the development of robotic pollination systems. Previous works demonstrated successful robotic pollination of bramble flowers using visual servoing; however, pollination was limited to specific flower orientations. As such, the objective of this work is to develop a robotic pollination system that is capable of pollinating a wider range of orientations.

This research introduces an imitation learning-based framework for robotic pollination that positions the manipulator to view chosen flowers in specific orientations. The developed model leverages object detection (YOLOv8) to identify individual flowers and a convolutional neural network …

Autonomous Object Search Planning In Large-Scale Environments, Matthew A. Collins

Graduate Theses, Dissertations, and Problem Reports (ETD)

The advancement of autonomous search holds significant promise for applications ranging from emergency response to planetary exploration. This thesis investigates strategies to enhance autonomous search performance in large-scale environments. The main contribution of this work is its practical application in real-world scenarios, where efficient search methods are essential for managing vast amounts of data, particularly in large environments. Effective search planning requires navigating complexities such as limited prior information and managing large state spaces, necessitating advanced strategies to plan with this limited information. Additionally, balancing exploration and exploitation is crucial for optimizing the search process, as it ensures thorough coverage …

Cellular Level Changes Induced In Cancer Cells Due To Microgravity, Sai Deepika Reddy Yaram

Graduate Theses, Dissertations, and Problem Reports (ETD)

The increase in human activity in space has revealed several kinds of physiological challenges brought on by the absence of Earth's gravitational pull. NASA observed that during spaceflight, astronauts experience a 1-1.5% monthly loss in the mineral density of weight-bearing bones, with rehabilitation efforts on Earth often proving ineffective. This issue extends to muscles, the neuro vestibular system, the cardiovascular system, and vision. Cancer has emerged as a significant cause of mortality among astronauts, with studies up to 2017 showing that 41.3% of natural cause deaths among U.S. astronauts were due to cancer, primarily due to space radiation exposure. Cancer …

Enhancing Robotic Exploration Through Semantically-Guided Sampling Strategies, Christopher Alexander Arend Tatsch

Graduate Theses, Dissertations, and Problem Reports (ETD)

From space and deep-sea exploration to disaster response and environmental monitoring, autonomous robots are essential for advancing science, improving safety, and addressing critical challenges. This dissertation introduces a novel open-source strategy for autonomous robotic exploration: the Semantically-Guided Exploration (SGE) framework. Designed for ground vehicles, SGE integrates semantic understanding into the autonomous exploration process, improving decision-making in complex environments. Specifically, the proposed sampling-based approach uses the information from the semantic segmentation of RGB images and depth images to guide the robot's selection of exploration goals. This method enables the robot to steer away from potential dangers such as large rocks and …

Processing, Stability, And High-Temperature Properties Of Doped Lacro3-Based Refractory Ceramics And Composites For Harsh Environments Sensing Applications, Javier A. Mena

Graduate Theses, Dissertations, and Problem Reports (ETD)

In order to test and monitor the operational stability and conditions of various energy, transportation, and manufacturing systems and their components, accurate sensors capable of operating at temperatures over 1000 °C in various environments for long durations are required. In addition, many of these harsh environmental systems do not permit sensors to be directly inserted into the environment, so the sensors need to be embedded into the surrounding support or thermal protective materials. Some technological and industrial applications that require the use of harsh environment conditions sensing include nuclear and chemical reactors, jet engines, heavyduty gas turbines, rotating bearings in …

Investigating Critical Mineral Recovery And Carbon Mineralization Potential In Coal Fly Ash, Syabilla Cardosh

Graduate Theses, Dissertations, and Problem Reports (ETD)

Coal fly ash (CFA), a byproduct of coal combustion, represents an innovative opportunity to address the rising demand for critical minerals and the need to reduce CO2 emissions due to its significant concentrations of calcium and magnesium. By providing insights and preliminary data, this study aims to contribute to the foundational understanding necessary for future development.

A multidisciplinary approach was employed to assess CFA’s potential, including detailed chemical and mineralogical characterization using X-ray fluorescence (XRF), inductively coupled plasma mass spectrometry (ICP-MS), X-ray diffraction (XRD), and scanning electron microscopy (SEM). XRD analysis revealed crystalline phases in the CFA samples. At the …

Foraging Economies: A Market Based Methodology For Robotic Swarm Foraging, John A. Little

Graduate Theses, Dissertations, and Problem Reports (ETD)

Swarm robotics involves coordinating large groups of autonomous agents to accomplish complex tasks through decentralized, adaptive behaviors, providing a robust and scalable approach suited to dynamic and unpredictable environments. While traditional swarm models frequently draw inspiration from biological systems such as ant colonies or bee foraging, other approaches use techniques from physics, control theory, and economics to achieve effective coordination. This study distinguishes itself by applying economic principles—specifically, market-driven mechanisms like auctions, utility functions based on opportunity cost, and supply-demand dynamics based on fluctuating resource values at a central base—to improve task allocation within a swarm foraging context. This approach …

Bridging Evolutionary And Bayesian Optimization For Enhanced Safety Verification In Control Systems, Joshua M. Yancosek

Graduate Theses, Dissertations, and Problem Reports (ETD)

The rigorous safety verification of control systems in critical applications is essential, given their in creasing complexity and integration into everyday life. Simulation-based falsification approaches play a pivotal role in the safety verification of control systems, particularly within critical applications. These methods systematically explore the operational space of systems to identify configurations that result in violations of safety specifications. However, the effectiveness of traditional simulation based falsification is frequently limited by the high dimensionality of the search space and the sub stantial computational resources required for exhaustive exploration. This thesis presents Bayesian Evolutionary Approach for COuNterexample, or BEACON, a novel …

4d Epr Oximetry Imaging For 4d Bioprinting And Tissue Engineering, Sajad Sarvari

Graduate Theses, Dissertations, and Problem Reports (ETD)

Bioprinting, akin to 3D printing, employs cell-laden hydrogels such as GelMA (Gelatine Methacrylate) and Alginate instead of plastic or resin to create biological structures. The printing process followed by subsequent tissue maturation is known as 4D bioprinting, where the fourth dimension is time. Ensuring adequate and consistent oxygen, O2, supply within 3D bioprint volume over the entire maturation period process is crucial, as even transient hypoxia can impact cellular behavior and phenotypes. However, printing of fully developed vasculature remains an unresolved technical challenge. Several approaches to chemically (peroxides) or biologically (photosynthesis) generate oxygen during bioprint maturation have been proposed. However, …

Life Cycle Cost Model For Transit Bus Fleets, Connor Andrew Jack

Graduate Theses, Dissertations, and Problem Reports (ETD)

Abstract

Life Cycle Cost Model for Transit Buses

Connor Jack

Transit agencies battle with reducing emissions while trying to be cost effective. In 2009, the Transit Cooperative Research Program Report (TCRP) 132 presented a life cycle cost model to aid in procurement evaluation [1]. The model is a life cycle cost analysis tool to estimate the overall costs of procurement and compare alternative technologies [2]. The model concentrates on pre-2007 conventional diesel, diesel hybrid with first generation diesel particulate filters, gasoline hybrid, and compressed natural gas transit buses.

The objectives of this work are to implement battery electric technology into …

Characterization And Evaluation Of Various Biochar Types As Green Adsorbents For Rare Earth Element Recovery From Aqueous Solutions, Oluwaseun Victor Famobuwa

Graduate Theses, Dissertations, and Problem Reports (ETD)

Rare earth elements (REEs) are members of the lanthanide family (atomic number 57 – 71). They are significantly important to the global economy due to their applications in renewable energy, defense, and medical industries. REEs are primarily derived from bastnaesite and monazite but may also be present in xenotime, cerite, alanite, and many other types of mineralization in lesser amounts. Due to the increasing demand for REEs and their criticality in the supply chain, the need to explore secondary sources of REEs has gained tremendous importance.

Secondary sources of REEs include but are not limited to acid mine drainage (AMD), …

Effect Of Resin Bleed Out On Compaction Behavior Of The Fiber Tow Gap Region During Automated Fiber Placement Manufacturing, Von Clyde Jamora, Virginia Rauch, Sergii G. Kravchenko, Oleksandr G. Kravchenko

Mechanical & Aerospace Engineering Faculty Publications

Automated fiber placement is a state-of-the-art manufacturing method which allows for precise control over layup design. However, AFP results in irregular morphology due to fiber tow deposition induced features such as tow gaps and overlaps. Factors such as the squeeze flow and resin bleed out, combined with large non-linear deformation, lead to morphological variability. To understand these complex interacting phenomena, a coupled multiphysics finite element framework was developed to simulate the compaction behavior around fiber tow gap regions, which consists of coupled chemo-rheological and flow-compaction analysis. The compaction analysis incorporated a visco-hyperelastic constitutive model with anisotropic tensorial prepreg viscosity, which …

Parametric Optimization Of Friction Stir Welding Of Aa6061-T6 Samples Using The Copper Donor Stir-Assisted Material Method, Aiman H. Al-Allaq, Joseph Maniscalco, Srinivasa Naik Bhukya, Zhenhua Wu, Abdelmageed Elmustafa

Mechanical & Aerospace Engineering Faculty Publications

This study presents an optimization of the process parameters for the effect of copper (Cu) donor material percentage on the friction stir welding (FSW) of AA6061-T6 alloy. Extensive factorial experiments were conducted to determine the significance of the rotational speed (ω), the transverse speed (v), the interface coefficient of friction (μ), and the Cu donor material percentage in the plunge, left, right, and downstream zones. Design Expert 13 software was used to identify the number of simulation experiments to be conducted using the Abaqus simulation software. From Design Expert 13, which is a thorough multi-objective optimization analysis software, we were …

Effect Of Post-Cured Through Thickness Reinforcement On Disbonding Behavior In Skin-Stringer Configuration, Jimesh D. Bhagatji, Christopher Morris, Yogaraja Sridhar, Bodhisatwa Bhattacharjee, Krishnanand N. Kaipa, Oleksandr G. Kravchenko

Mechanical & Aerospace Engineering Faculty Publications

An experimental investigation of interlaminar toughness for post-cured through-thickness reinforcement (PTTR) skin-stringer sub-element is presented. The improvement in the crack resistance capability of skin-stringer samples was shown through experimental testing and finite element analysis (FEA) modeling. The performance of PTTR was evaluated on a pristine and initial-disbond of the skin-stringer specimen. A macro-scale pin-spring modeling approach was employed in FEA using a non-linear spring to capture the pin failure under the mixed-mode load. The experimental results showed a 15.5% and 20.9% increase in strength for the pristine-PTTR and initial-disbond PTTR specimens, respectively. The modeling approach accurately represents the overall structural …

A New Cache Replacement Policy In Named Data Network Based On Fib Table Information, Mehran Hosseinzadeh, Neda Moghim, Samira Taheri, Nasrin Gholami

VMASC Publications

Named Data Network (NDN) is proposed for the Internet as an information-centric architecture. Content storing in the router’s cache plays a significant role in NDN. When a router’s cache becomes full, a cache replacement policy determines which content should be discarded for the new content storage. This paper proposes a new cache replacement policy called Discard of Fast Retrievable Content (DFRC). In DFRC, the retrieval time of the content is evaluated using the FIB table information, and the content with less retrieval time receives more discard priority. An impact weight is also used to involve both the grade of retrieval …

Type-B Energetic Processes: Introduction And Invitation To Special Issue Of Energies, James Weifu Lee, Daniel P. Sheehan

Chemistry & Biochemistry Faculty Publications

[First paragraph] Currently, there is substantial scientific evidence for the existence of Type-B energetic processes on Earth, such as the naturally occurring transmembrane-electrostatically localized protons (TELP) thermotrophic properties in life [1]. A number of groundbreaking human-made Type-B energetic processes, including (but not limited to) “asymmetric function-gated isothermal electricity production” [2], “epicatalysis generating a temperature difference between catalysis-asymmetric filaments” [3], “artificially made asymmetric membrane concentration cell” [4,5], “Fu’s experiment on heat–electric conversion using surface electron emission under a static magnetic field” [6], and the “dynamic processes in superconductors indicating Type-B energetic process” [7,8,9] have been invented and/or experimentally demonstrated. The innovative …

Synthetic Approaches Of Carbohydrate Based Self-Assembling Systems, Guijun Wang, Anji Chen, Pramod Aryal, Jonathan Bietsch

Chemistry & Biochemistry Faculty Publications

Carbohydrate-based self-assembling systems are essential for the formation of advanced biocompatible materials via a bottom-up approach. The self-assembling of sugar-based small molecules has applications encompassing many research fields and has been studied extensively. In this focused review, we will discuss the synthetic approaches for carbohydrate-based self-assembling (SA) systems, the mechanisms of the assembly, as well as the main properties and applications. This review will mainly cover recent publications in the last four years from January 2020 to December 2023. We will essentially focus on small molecule self-assembly, excluding polymer-based systems, which include various derivatives of monosaccharides, disaccharides, and oligosaccharides. Glycolipids, …

Photoluminescence Switching In Quantum Dots Connected With Carboxylic Acid And Thiocarboxylic Acid End-Group Diarylethene Molecules, Ephraiem S. Sarabamoun, Pramod Aryal, Jonathan M. Bietsch, Maurice Curran, Sugandha Verma, Grayson Johnson, Lucy U. Yoon, Amelia G. Reid, Esther H. R. Tsai, Charles W. Machan, Christopher Paolucci, Guijun Wang, Joshua J. Choi

Chemistry & Biochemistry Faculty Publications

We contrast the switching of photoluminescence (PL) of PbS quantum dots (QDs) cross-linked with photochromic diarylethene molecules with different end groups, 4,4′-(1-cyclopentene-1,2-diyl)bis[5-methyl-2-thiophenecarboxylic acid] (1C) and 4,4′-(1-cyclopentene-1,2-diyl)bis[5-methyl-2-thiophenethiocarboxylic acid] (2T). Our results show that the QDs cross-linked with the carboxylic acid end group molecules (1C) exhibit a greater amount of switching in photoluminescence intensity compared to QDs cross-linked with the thiocarboxylic acid end group (2T). We also demonstrate that regardless of the molecule used, greater switching amounts are observed for smaller quantum dots. Varying these parameters allows for the fabrication of photoswitches with tunable PL change. We relate these observations to the …

Polarizable Amoeba Force Field Predicts Thin And Dense Hydration Layer Around Monosaccharides, Luke A. Newman, Mackenzie G. Patton, Breyanna A. Rodriguez, Ethan W. Summer, Valerie Vaissier Welbourn

Chemistry & Biochemistry Faculty Publications

Polarizable force fields crucially enhance the modeling of macromolecules in polar media. Here, we present new parameters to model six common monosaccharides with the polarizable AMOEBA force field. These parameters yield a thinner, but denser, hydration layer than that previously reported. This denser hydration layer results in eliminating non-physical aggregation of glucose in water-an issue that has plagued molecular dynamics simulations of carbohydrates for decades.

Small-Strain Site Response Of Soft Soils In The Sacramento-San Joaquin Delta Region Of California Conditioned On Vₛ₃₀ And Mhvsr, Tristan E. Buckreis, Jonathan P. Stewart, Scott J. Brandenberg, Pengfei Wang

Civil & Environmental Engineering Faculty Publications

Sites located in the Sacramento-San Joaquin Delta region of California typically have peaty-organic soils near the ground surface, which are characteristically soft, with shear wave velocities as low as 30 m/s. These unusually soft geotechnical conditions, which are outside the range of applicability of existing ergodic site amplification models, can be anticipated to produce significant site effects during earthquake shaking. We evaluate site response for 36 seismic stations in the Delta region using non-ergodic methods with low-amplitude ground motion data. We model first-order site effects using a period-dependent relation conditioned on the 30 m time-averaged shear wave velocity (V …

A Review On Biochar As An Adsorbent For Pb(Ii) Removal From Water, Pushpita Kumkum, Sandeep Kumar

Civil & Environmental Engineering Faculty Publications

Heavy metal contamination in drinking water is a growing concern due to its severe health effects on humans. Among the many metals, lead (Pb), which is a toxic and harmful element, has the most widespread global distribution. Pb pollution is a major problem of water pollution in developing countries and nations. The most common sources of lead in drinking water are lead pipes, faucets, and plumbing fixtures. Adsorption is the most efficient method for metal removal, and activated carbon has been used widely in many applications as an effective adsorbent, but its high production costs have created the necessity for …

A General Framework For Modeling Subregional Path Effects, T. E. Buckreis, P. Wang, S. J. Brandenberg, J. P. Stewart

Civil & Environmental Engineering Faculty Publications

Next Generation Attenuation (NGA) West2 ground motion models (GMMs) include regional path adjustments for broad jurisdictional regions, which necessarily averages spatially variable path effects within those regions. We extend that framework to account for systematic variations in attenuation within subregions defined in consideration of geologic differences. In recent years, cell-based methods which systematically account for spatial variations by summing the attenuation effects over a fine discretization of uniform-rectangular cells (e.g., Dawood and Rodriquez-Marek 2013; Kuehn et al. 2019) have been shown to be an effective alternative to regionalization and a step towards modelling non-ergodic path effects. The main drawbacks of …

Reliability Of Low Frequency Mhvsr Ordinates, F. J. Ornelas, C. C. Nweke, C. A. De La Torre, P. Wang, T. D. Mai, B. R. Cox, S. J. Brandenberg, J. P. Stewart

Civil & Environmental Engineering Faculty Publications

Microtremor horizontal-to-vertical spectral ratios (mHVSR) are frequency-dependent ratios of Fourier amplitude spectra of the horizontal to vertical components of a 3-component recording of ambient ground motions from microtremors. Results from mHVSR tests can identify the frequencies associated with site resonances at sites with large impedance contrasts, and hence have potential to provide useful parameters for predicting seismic site response. Site measurements are made by recording ground vibrations either from a temporarily deployed seismometer, typically recording for a relatively short period of time (~1-2 hrs.), or from a permanently-installed broadband seismometer. In this paper, we discuss ongoing work investigating the reliability …

User-Interaction With A Web-Served Global Ground Motion Relational Database, T. E. Buckreis, C. C. Nweke, P. Wang, S. J. Brandenberg, R. Shams, M. E. Ramos-Sepulveda, R. Pretell, S. Mazzoni

Civil & Environmental Engineering Faculty Publications

We present an application programming interface (API) which facilitates public access to a global relational database of earthquake ground motion intensity measures, associated metadata, and time-series data. Next Generation Attenuation (NGA)-East and NGA-West2 project spreadsheets have been adapted into a relational database format composed of multiple tables through a series of primary and foreign keys. The combined dataset has been expanded to include contributions from earthquakes, generally with magnitudes greater than M3.9, that have occurred since the conclusion of the data synthesis component of both projects in 2011. Currently the database includes 62,449 ground motions recorded at 9,092 stations for …

Modeling Coupled Driving Behavior During Lane Change: A Multi-Agent Transformer Reinforcement Learning Approach, Hongyu Guo, Mehdi Keyvan-Ekbatani, Kun Xie

Civil & Environmental Engineering Faculty Publications

In a lane change (LC) scenario, the lane change vehicle interacts with surrounding vehicles. The interactions not only affect their driving behaviors but also influence the traffic flow. This study aims to model the coupled behavior of the lane changer and the follower in the target lane during LC. Large-scale real-world connected vehicle (CV) data from the Safety Pilot Model Deployment (SPMD) program are used to extract LCs and study vehicle interactions. A multi-agent Transformer-based deep deterministic policy gradient (MA-TDDPG) method is proposed to model the coupled behaviors during LC. The multi-agent framework can handle the multiple agents’ behaviors with …