Development Of A Digestion Procedure Using Fe2+ Ions For Electrochemical Detection Of Mno2 Particles In Drinking Water,
2025
Department of Chemistry, Queen’s University, 90 Bader Lane, Kingston, ON K7L 3N6, Canada; Beaty Water Research Centre, Queen’s University, 69 Union St., Kingston, ON K7L 3N6, Canada
Development Of A Digestion Procedure Using Fe2+ Ions For Electrochemical Detection Of Mno2 Particles In Drinking Water, Kayla Elliott, Sarah Jane Payne, Zhe She
Journal of Electrochemistry
Developing methods for detection contaminants in drinking water is essential to ensuring that safe and acceptable quality drinking water is delivered to consumers. While manganese (Mn) was previously known only as a mere aesthetic issue, recent epidemiological data has shown to have negative neurological effects on humans, especially on children, prompting new health-based guidelines by Health Canada and the World Health Organization. In drinking water, Mn exists predominantly as Mn(II) and Mn(IV), and is regulated based on total Mn levels. Interestingly, measurement of Mn particulate using electroanalytical methods has not yet been reported in the literature. Herein, a digestion procedure …
Regulating Lithium Metal Nucleation And Growth For Dendrite Suppression: From Liquid-Electrolyte To Solid-State Batteries,
2025
Tianjin Key Laboratory of Advanced Carbon and Electrochemical Energy Storage, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, P. R. China
Regulating Lithium Metal Nucleation And Growth For Dendrite Suppression: From Liquid-Electrolyte To Solid-State Batteries, Ao Du, Juan Zhang, Pan Xu, Ya-Jie Li, Kang-Yu Yi, Zhen-Zhen Shen, Hui-Lin Ge, Guang-Wen Zhang, Chao-Hui Zhang, Yu-Hao Wang, Chen-Zi Zhao, Meng-Yang Xu, Yu-Lin Jie, Rui Wen, Shu-Hong Jiao, Si-Qi Shi, Qiang Zhang, Chun-Peng Yang, Yu-Guo Guo
Journal of Electrochemistry
Lithium metal anodes, with a theoretical capacity of up to 3860 mAh·g−1, are regarded as the cornerstone for developing next-generation high-energy-density batteries. However, several key challenges hinder their practical applications, including dendrite formation, unstable solid electrolyte interphase (SEI), side reactions with electrolytes, and associated safety risks. This review systematically explores the mechanisms of lithium nucleation, growth, and stripping in both liquid and solid-state battery systems, analyzing critical theoretical concepts like heterogeneous nucleation thermodynamics, surface diffusion kinetics, space charge effects, and SEI-induced nucleation, which are crucial for understanding the genesis of dendrite growth. Additionally, the review discusses the electrochemical-mechanical …
Biocompatible And Antibacterial Pcl-Tio2@Ag/Γ-Cd Mof Nanocomposite Coating For Corrosion Resistance Of Magnesium Alloy In Simulated Body Fluid,
2025
Department of Chemistry, Yazd University, Yazd, 89195-741, Iran
Biocompatible And Antibacterial Pcl-Tio2@Ag/Γ-Cd Mof Nanocomposite Coating For Corrosion Resistance Of Magnesium Alloy In Simulated Body Fluid, Sara Dehghan-Chenar, Hamid R. Zare, Zahra Mohammadpour, Maryam Sadat Mirbagheri-Firoozabad
Journal of Electrochemistry
Magnesium alloys are promising candidates for bio-implant applications due to their biodegradability and biocompatibility. However, their rapid corrosion remains a critical limitation. This study presents the development of a multifunctional nanocomposite coating designed to enhance the corrosion resistance and antibacterial properties of magnesium alloy implants. The coating comprised γ-cyclodextrin metal-organic frameworks (γ-CD MOFs) decorated with TiO2@Ag core-shell nanoparticles, embedded in a polycaprolactone (PCL) matrix. Immersion tests in a simulated body fluid (SBF) revealed an initially higher corrosion rate for the PCL-TiO2@Ag/γ-CD MOF coating compared to the coating without TiO2@Ag nanoparticles; however, it demonstrated significant …
Mechanisms Of Correlated Neuronal Activity In The Globus Pallidus,
2025
University of Denver
Mechanisms Of Correlated Neuronal Activity In The Globus Pallidus, Hamza Albawaliz
Electronic Theses and Dissertations
This thesis investigates the mechanisms of correlated neuronal activity in the globus pallidus externus (GPe), a key structure in the basal ganglia. Neuronal activity in the GPe is reportedly decorrelated in healthy subjects but can become highly correlated in Parkinson’s disease. However, high-density neuronal recordings in the GPe of healthy rats reveal a surprising degree of correlated activity. This raises the question of whether intrinsic properties or network connectivity alone can account for such patterns. To explore this, a computational model was developed in which GPe neurons are represented as coupled phase oscillators influenced by experimentally derived phase-response curves and …
Advanced Plant Growth Using Halloysite Nanotubes (Hnts) And Waste Extraction For Medical Applications,
2025
Louisiana Tech University
Advanced Plant Growth Using Halloysite Nanotubes (Hnts) And Waste Extraction For Medical Applications, Zeinab Jabbari Velisdeh
Doctoral Dissertations
This dissertation presents an integrated research framework that bridges nanotechnology, green chemistry, and sustainable agriculture, aiming to address two critical global challenges: enhancing plant growth under resource-limited conditions and valorizing agricultural waste for bioactive compound extraction. The study is divided into three major projects that together highlight the innovative application of magnesium oxide-coated halloysite nanotubes (MgO-HNTs) and the development of environmentally conscious extraction methods for high-value phytochemicals. The first component of this work investigates the design, fabrication, and functional evaluation of MgO-HNTs as advanced nanocarriers for promoting seed germination and early root development in tomato plants. MgO-HNTs were synthesized via …
Strategies For Obtaining High-Performance Li-Ion Solid-State Electrolytes For Solid-State Batteries,
2025
Hubei Key Laboratory of Electrochemical Power Sources, College of Chemistry & Molecular Science, Wuhan University, Wuhan, Hubei 430072, P. R. China
Strategies For Obtaining High-Performance Li-Ion Solid-State Electrolytes For Solid-State Batteries, Yi-Cheng Deng, Zi-Chang You, Geng-Zhong Lin, Guo Tang, Jing-Hua Wu, Zhi-Min Zhou, Xiang-Chun Zhuang, Li-Xuan Yang, Zhen-Jie Zhang, Zhao-Yin Wen, Xia-Yin Yao, Chang-Hong Wang, Qian Zhou, Guang-Lei Cui, Ping He, Hui Li, Xin-Ping Ai
Journal of Electrochemistry
With the widespread adoption of lithium-ion batteries (LIBs), safety concerns associated with flammable organic electrolytes have become increasingly critical. Solid-state lithium batteries (SSLBs), with enhanced safety and higher energy density potential, are regarded as a promising next-generation energy storage technology. However, the practical application of solid-state electrolytes (SSEs) remains hindered by several challenges, including low Li+ ion conductivity, poor interfacial compatibility with electrodes, unfavorable mechanical properties and difficulties in scalable manufacturing. This review systematically examines recent progress in SSEs, including inorganic types (oxides, sulfides, halides), organic types (polymers, plastic crystals, poly(ionic liquids) (PILs)), and the emerging class of soft …
High-Voltage Solid-State Lithium Batteries: A Review Of Electrolyte Design, Interface Engineering, And Future Perspectives,
2025
School of Energy and Power Engineering, Nanjing University of Science and Technology, Nanjing 210094, P. R. China
High-Voltage Solid-State Lithium Batteries: A Review Of Electrolyte Design, Interface Engineering, And Future Perspectives, Cheng Yang, Zi-Xin Liang, Ming-Yun Zhang, Ming-Zhe Chen, Kai Zhang, Li-Min Zhou
Journal of Electrochemistry
Solid-state lithium batteries have become a research hotspot in the field of large-scale energy storage due to their excellent safety performance. The development of high-voltage positive electrode materials matched with lithium metal anode have advanced the energy density of solid-state lithium batteries close to or even exceeding that of lithium batteries based on a liquid electrolyte, which is expected to be commercialized in the future. However, in high voltage conditions (> 4.3 V), the decomposition of electrolyte components, structural degradation, and interface side reactions significantly reduce battery performance and hinder its further development. This review summarizes the latest research progress …
Development Trends And Priority Research Fields Of Electrochemical Discipline In The 15th Five Year Plan Period,
2025
College of Chemistry and Molecular Sciences, Wuhan University, Wuhan, 430072, P. R. China
Development Trends And Priority Research Fields Of Electrochemical Discipline In The 15th Five Year Plan Period, Lin Zhuang, Wen-Bin Cai, Heng-Xing Ji, Qing Li, Gong-Wei Wang, Sen Xin, Qing Zhao, Fang-Yi Cheng, Yu-Guo Guo, Lan-Qun Mao, Yang Tian, Fei Wu, Li-Min Zhang, Yan Xiang, Jin-Song Hu, Rui Cao, Li Xiao, Hua-Bing Tao, Wei Xing, Dong-Ping Zhan, Hong-Gang Liao, Mei-Ling Xiao, Bin Ren, Zhang-Quan Peng, Rui Wen, Xiang Wang, Yue-Feng Song, Hou-Fu Lv, Bao-Yu Xia, Guo-Xiong Wang, Jun Cheng, Zhi-Pan Liu, Min Zhou, Bing Huang, Cun-Pu Li, Yu-Qin Zou, Shuang-Yin Wang, Hai-Bo Lin, Zi-Dong Wei
Journal of Electrochemistry
In fulfillment of the national science-and-technology development agenda, the Department of Chemical Sciences of the National Natural Science Foundation of China (NSFC) convened the Strategic Symposium on the Fifteenth Five-Year (2026–2030) Development Plan for Electrochemistry held in Xiamen on 29 August, 2025—the culminating year of the Fourteenth Five-Year (2021–2025) Development Plan. More than forty leading experts in the field of electrochemistry participated with spanning nine thematic fronts: Interfacial Electrocatalysis, Interfacial Electrochemistry for Energy Storage, Bioelectrochemistry, Electrochemistry of Hydrogen Energy, Electrochemical Micro-/Nano-Manufacturing, Operando Electrochemical Characterization, Electro-Thermal Coupling Catalysis, Theoretical and Computational Electrochemistry, and Electrochemical Synthesis. The forum assembled China’s foremost electrochemical …
Melamine-Based Polymer Nanofibers For Supercapacitors,
2025
The British University in Egypt
Melamine-Based Polymer Nanofibers For Supercapacitors, Samar A. Salim, Hani Nasser Abdelhamid
Nanotechnology Research Centre
This investigation describes the synthesis, electrospinning, and characterization of melamine-glutaraldehyde (MAGA) polymer composites with polymethyl methacrylate (PMMA) for supercapacitors applications. Electrospun fibers are generated by combining the MAGA polymer with PMMA at varying concentrations (2.5 %, 5 %, and 10 wt%). The synthesis of the polymer, its morphological attributes, and structural features are validated by characterization methods e.g., XRD, TEM, SEM, and FT-IR. In a three-electrode configuration, the electrochemical performances of the prepared electrodes are assessed using cyclic voltammetry (CV), galvanostatic charge-discharge (GCDC), and linear sweep voltammetry (LSV). The results suggest that the 5 % MAGA-PMMA composite has a specific …
Formulation And Characterization Of Albumin Nanoparticles For Nsclc Photochemotherapy,
2025
University of South Florida
Formulation And Characterization Of Albumin Nanoparticles For Nsclc Photochemotherapy, Faisal Mohammad Shamim Khan
USF Tampa Graduate Theses and Dissertations
Non-small Cell Lung Cancer (NSCLC) is the most common type of lung cancer and is a leading cause of worldwide cancer-related death, which is a strong motivation to develop more efficacious approaches to its treatment. This thesis outlines the construction of folate-targeted bovine serum albumin (FA-BSA) nanoparticles co-loading Chlorin e6 (Ce6), a photodynamic therapy photosensitizer, and Evofosfamide (EVO), a hypoxia-activated prodrug, to enable synergistic photochemotherapy. The 1-Ethyl-3-(3-dimethylaminopropyl)carbodiimide (EDC) is a water-soluble carbodiimide coupling reagent and used for amide bonds between carboxylic acid and amines. FA-BSA nanoparticles were prepared through a desolvation approach and stabilized through crosslinking by the carbodiimide reagent …
Developing A Low-Temperature Pathway For The Synthesis Of Two-Dimensional Ws2 Nanosheets,
2025
University Of Connecticut
Developing A Low-Temperature Pathway For The Synthesis Of Two-Dimensional Ws2 Nanosheets, Akhil Potdar
Holster Scholar Projects
Since their discovery in 2004, two-dimensional (2D) materials have attracted great attention due to their unique mechanical, electrical, and chemical properties. However, their integration into devices is limited by the high temperatures required for crystalline growth, which prevents the use of flexible and biocompatible substrates like polymers for biomedical and next-generation electronic devices. This project aims to therefore develop a low-temperature synthesis process for two-dimensional tungsten disulfide (WS₂), a material particularly promising due to its tunable bandgap and biocompatibility. We propose that by first depositing an intermediate tungsten oxide film (WOx) via Hollow Cathode Plasma-Assisted Atomic Layer Deposition (HCP-ALD) and …
Plasmonic Nanoparticle Integration On Fiber Optic: Role Of Organic Linker And Functionalization Length In Refractive Index Sensing,
2025
Research Center for Photonics, National Research and Innovation Agency, B.J. Habibie Science and Technology Park, South Tangerang 15314, Indonesia
Plasmonic Nanoparticle Integration On Fiber Optic: Role Of Organic Linker And Functionalization Length In Refractive Index Sensing, Shela Ilmiyah, Mohamad Syahadi, Muflikhah Muflikhah, Yuwana Pradana, Zainul Arifin Iman Supardi, Iwan Darmadi, Lia Aprilia
Makara Journal of Science
Nanoplasmonic fiber optic sensors leverage the optical fiber’s inherent compactness and surface sensitivity via evanescent-field interactions with the localized surface plasmon resonance of the metallic nanoparticles. One of the popular approaches is self-assembly owing to its relatively low cost. Despite its low cost, the self-assembly technique has low reproducibility and exhibits low sensitivity because of low nanoplasmonic coverage on the fiber optic surface. In this study, several fabrication techniques were explored to assess the refractive index sensitivity by comparing three common organosilanes, i.e., (3-Aminopropyl)triethoxysilane (APTES), (3-Aminopropyl)trimethoxysilane, and (3-Mercaptopropyl)trimethoxysilane. Comparative analyses assessed the anchoring efficiency of the three silanes, sensor reproducibility, …
Series Reports From Professor Wei’S Group Of Chongqing University: Advancements In Electrochemical Energy Conversions (2/4): Report 2: High-Performance Water Splitting Electrocatalysts,
2025
National Key Laboratory of Special Power Supplies, National-Municipal Joint Engineering Laboratory for Chemical Process Intensification and Reaction, School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044, China
Series Reports From Professor Wei’S Group Of Chongqing University: Advancements In Electrochemical Energy Conversions (2/4): Report 2: High-Performance Water Splitting Electrocatalysts, Ling Zhang, Wang-Yang Wu, Qiu-Yue Hu, Shi-Dan Yang, Li Li, Rui-Jin Liao, Zi-Dong Wei
Journal of Electrochemistry
The unavailability of high-performance and cost-effective electrocatalysts has impeded the large-scale deployment of alkaline water electrolyzers. Professor Zidong Wei’s group has focused on resolving critical challenges in industrial alkaline electrolysis, particularly elucidating hydrogen and oxygen evolution reaction (HER/OER) mechanisms while addressing the persistent activity-stability trade-off. This review summarizes their decade-long progress in developing advanced electrodes, analyzing the origins of sluggish alkaline HER kinetics and OER stability limitations. Professor Wei proposes a unifying “12345 Principle” as an optimization framework. For HER electrocatalysts, they have identified that metal/metal oxide interfaces create synergistic “chimney effect” and “local electric field enhancement effect”, enhancing selective …
Local Electric Fields Coupled With Cl− Fixation Strategy For Improving Seawater Oxygen Reduction Reaction Performance,
2025
School of Marine Science and Engineering, Hainan University, Haikou 570228, Hainan, China
Local Electric Fields Coupled With Cl− Fixation Strategy For Improving Seawater Oxygen Reduction Reaction Performance, Yu-Rong Liu, Miao Zhang, Yan-Hui Yu, Ya-Lin Liu, Jing Li, Xiao-Dong Shi, Zhen-Ye Kang, Dao-Xiong Wu, Peng Rao, Ying Liang, Xin-Long Tian
Journal of Electrochemistry
Development of robust electrocatalyst for oxygen reduction reaction (ORR) in a seawater electrolyte is the key to realize seawater electrolyte-based zinc-air batteries (SZABs). Herein, constructing a local electric field coupled with chloride ions (Cl−) fixation strategy in dual single-atom catalysts (DSACs) was proposed, and the resultant catalyst delivered considerable ORR performance in a seawater electrolyte, with a high half-wave potential (E1/2) of 0.868 V and a good maximum power density (Pmax) of 182 mW·cm−2 in the assembled SZABs, much higher than those of the Pt/C catalyst (E1/2: 0.846 V; Pmax: 150 mW·cm−2 …
Bridging Materials And Energy Storage Mechanisms In Zn-I2 Batteries,
2025
Key Laboratory for Colloid and Interface Chemistry Ministry of Education, School of Chemistry and Chemical Engineering Department, Shandong University, Jinan 250100, China
Bridging Materials And Energy Storage Mechanisms In Zn-I2 Batteries, Rong-Qi Liu, Wen-Shuo Shang, Jin-Tao Zhang
Journal of Electrochemistry
Zinc-iodine (Zn-I2) batteries have emerged as a compelling candidate for large-scale energy storage, driven by the growing demand for safe, cost-effective, and sustainable alternatives to conventional systems. Benefiting from the inherent advantages of aqueous electrolytes and zinc metal anodes, including high ionic conductivity, low flammability, natural abundance, and high volumetric capacity, Zn-I2 batteries offer significant potential for grid-level deployment. This review provides a comprehensive overview of recent progress in three critical domains: positive-electrode engineering, zinc anode stabilization, and in situ characterization methods. On the cathode side, anchoring iodine to conductive matrices effectively mitigates polyiodide shuttling and enhances …
Significantly Enhanced Oxygen Reduction Reaction Activity In Co-N-C Catalysts Through Synergistic Boron Doping,
2025
Laboratory of Advanced Power Source, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, China; School of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei, 230026, China; Jilin Province Key Laboratory of Low Carbon Chemical Power Sources, Changchun 130022, China; State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese, Academy of Sciences, Changchun 130022, China
Significantly Enhanced Oxygen Reduction Reaction Activity In Co-N-C Catalysts Through Synergistic Boron Doping, Chang Lan, Jing-Sen Bai, Xin Guan, Shuo Wang, Nan-Shu Zhang, Yu-Qing Cheng, Jin-Jing Tao, Yu-Yi Chu, Mei-Ling Xiao, Chang-Peng Liu, Wei Xing
Journal of Electrochemistry
The weak adsorption energy of oxygen-containing intermediates on Co center leads to a considerable performance disparity between Co-N-C and costly Pt benchmark in catalyzing oxygen reduction reaction (ORR). In this work, we strategically engineer the active site structure of Co-N-C via B substitution, which is accomplished by the pyrolysis of ammonium borate. During this process, the in-situ generated NH3 gas plays a critical role in creating surface defects and boron atoms substituting nitrogen atoms in the carbon structure. The well-designed CoB1N3 active site endows Co with higher charge density and stronger adsorption energy toward oxygen species, …
Antibacterial Activity Of Zno/Geopolymer Composite Granules And Their Potential Application In Water Treatment,
2025
Department of Chemistry, Faculty of Mathematics and Natural Sciences, IPB University, Bogor 16680, Indonesia
Antibacterial Activity Of Zno/Geopolymer Composite Granules And Their Potential Application In Water Treatment, Ziyan Tirta Maulitia, Putri Nur Angelina, Pipit Erlita Sari, Sri Sugiarti, Irma Isnafia Arief, Zaenal Abidin
Makara Journal of Science
Water pollution has become a major global concern owing to its complexity and widespread impact. Staphylococcus aureus (S. aureus) and Escherichia coli (E. coli) are the most common bacterial contaminants in water sources, which pose significant threats to public health. To mitigate water contamination by these pathogenic microorganisms, developing and implementing effective water treatment technologies are essential. A promising approach involves using antibacterial water filtration systems. Herein, zinc oxide (ZnO) nanoparticles were synthesized via hydrothermal and precipitation methods as antibacterial agents for water treatment. These preparation methods required considerably low synthesis time. A capping agent was …
Eng- Semicon: Understanding Nanoscale Heat Transport In Wide- And Ultrawide Bandgap Semiconductors Using Novel Deep Ultraviolet Tools,
2025
Utah State University
Eng- Semicon: Understanding Nanoscale Heat Transport In Wide- And Ultrawide Bandgap Semiconductors Using Novel Deep Ultraviolet Tools, Joshua Lee Knobloch
Funded Research Records
No abstract provided.
Click-Ready Gold Nanoparticles From Aqueous Mechanochemistry: 2-Propynylamine As A Reducing Agent And Surface Ligand,
2025
The University of Texas Rio Grande Valley
Click-Ready Gold Nanoparticles From Aqueous Mechanochemistry: 2-Propynylamine As A Reducing Agent And Surface Ligand, Amber L. Garcia, Brian S. Mitchell, Amanda Reusch, Mark J. Fink, Juan P. Hinestroza, Yelin Ko, Julie P. Vanegas
Physics & Astronomy Faculty Publications
We report a rapid aqueous method for synthesizing monodisperse gold nanoparticles (AuNPs), employing 2-propynylamine as both an intrinsic reducing agent and a surface-stabilizing ligand. This self-mediated process—achieved in a single step—yields spherical AuNPs with an average diameter of 4.0 ± 1.0 nm and a well-defined localized surface plasmon resonance band centered at 520 nm. Acting as a bifunctional molecule, 2-propynylamine simultaneously reduces HAuCl4·3H2O to elemental gold and passivates the nanoparticle surface through coordination via the amine group, while preserving a terminal alkyne (–C≡CH) functionality. This reactive moiety remains exposed and chemically accessible, enabling post-synthetic modification through Cu(I)-catalyzed azide–alkyne cycloaddition. Control …
Nanostructured Zinc Stannate Perovskite Films Synthesized Via Molten Salt Modified-Solvothermal Method For Enhanced Piezoelectric Properties,
2025
The University of Texas Rio Grande Valley
Nanostructured Zinc Stannate Perovskite Films Synthesized Via Molten Salt Modified-Solvothermal Method For Enhanced Piezoelectric Properties, Christopher Munoz, Alyssah Fuentes, Christian Alaniz, Tarik Dickens, Mohammed Jasim Uddin
School of Integrative Biological & Chemical Sciences Faculty Publications
Three dimensional (3D) piezoelectric zinc stannate (ZnSnO3) nanoweb arrays are synthesized using a molten salt modified solvothermal method and deposited in PDMS films for electrochemical analysis of its piezoelectric response. This work is a preliminary assessment of comparative piezoelectric efficacy influenced by changes in synthesis, effecting dimension and particle size. Advantages of hydrothermal, molten salt, and solvothermal synthesis methods were leveraged to facilitate several chemical and surface engineering techniques to enhance piezoelectric properties by increasing the surface area of zinc stannate nanoparticles. The combination of these treatments reduce the size of zinc stannate to approximately ∼40nm-80nm weblike networks. Scanning …
