Engineering Science and Materials Commons^™

External Direct Sum Invariant Subspace And Decomposition Of Coupled Differential-Difference Equations, Keqin Gu, Huan Phan-Van

SIUE Faculty Research, Scholarship, and Creative Activity

This article discusses the invariant subspaces that are restricted to be external direct sums. Some existence conditions are presented that facilitate finding such invariant subspaces. This problem is related to the decomposition of coupled differential-difference equations, leading to the possibility of lowering the dimensions of coupled differential-difference equations. As has been well documented, lowering the dimension of coupled differential-difference equations can drastically reduce the computational time needed in stability analysis when a complete quadratic Lyapunov-Krasovskii functional is used. Most known ad hoc methods of reducing the order are special cases of this formulation.

Materials Of Lightweight Concrete Research, Meganne Chapman, Kathryn Burns, John Grubb

Williams Honors College, Honors Research Projects

The objectives for this research project are to explore options for innovative and sustainable materials in lightweight concrete. Various materials including granite powder, hydrated lime, latex, and recycled glass beads will be used in the concrete testing for this project. The question the team wants to answer is how these additives affect the concrete’s mechanical properties. Weekly mix designs will be performed, and control cylinders will be compared to experimental cylinders. Compression and tensile testing will also be performed to further aid the research. The motivation for performing this research is to aid mix development for the University of Akron …

Reducing Food Scarcity: The Benefits Of Urban Farming, S.A. Claudell, Emilio Mejia

Journal of Nonprofit Innovation

Urban farming can enhance the lives of communities and help reduce food scarcity. This paper presents a conceptual prototype of an efficient urban farming community that can be scaled for a single apartment building or an entire community across all global geoeconomics regions, including densely populated cities and rural, developing towns and communities. When deployed in coordination with smart crop choices, local farm support, and efficient transportation then the result isn’t just sustainability, but also increasing fresh produce accessibility, optimizing nutritional value, eliminating the use of ‘forever chemicals’, reducing transportation costs, and fostering global environmental benefits.

Imagine Doris, who is …

Multi-Mode Regulation Of The Drying Process Of Industrial Gas, Isamidin Xakimovich Sidikov Pr, Nashvandova Gulruxsor Murot Qizi Phd

Technical science and innovation

Currently, much attention is paid to the issue of energy efficiency of gas processing enterprises. The continuous growth of world prices for energy resources requires constant improvement of the management system, providing the most optimal conditions for the flow of technological processes. A conceptual model of the heat-mass transfer process occurring in the absorber as an object of research has been developed, which characterizes the relationship of the variables involved in the drying process of natural gas, control, measurable and immeasurable, as well as controlled parameters have been selected, which are used to develop and study a mathematical model of …

Nitrogen-Doped Graphite Felt On The Performance Of Aqueous Quinone-Based Redox Flow Batteries, Heng Zhang, Li-Xing Xia, Shan Jiang, Fu-Zhi Wang, Zhan-Ao Tan

Journal of Electrochemistry

Modification of electrode is vitally important for achieving high energy efficiency in aqueous quinone-based redox flow batteries (AQRFBs). The modification of graphite felt (GF) was carried out by means of urea hydrothermal reaction, and simultaneously, the effects of hydrothermal reaction time on the functional groups and surface structure of nitrogen-doped graphite felt were studied. The surface morphology and defect, element content and surface chemical state of the modified electrode were characterized by scanning electron microscopy (SEM), Brunauer-Emmett-Teller (BET) test, Raman spectroscopy, and X-ray photoelectron spectroscopy (XPS). The electrochemical performance of the modified electrodes was evaluated by cyclic voltammetry, electrochemical impedance …

An In-Situ Raman Spectroscopic Study On The Interfacial Process Of Carbonate-Based Electrolyte On Nanostructured Silver Electrode, Yu Gu, Yuan-Fei Hu, Wei-Wei Wang, En-Ming You, Shuai Tang, Jian-Jia Su, Jun Yi, Jia-Wei Yan, Zhong-Qun Tian, Bing-Wei Mao

Journal of Electrochemistry

The solid-electrolyte interphase (SEI) plays a key role in anodes for rechargeable lithium-based battery technologies. However, a thorough understanding in the mechanisms of SEI formation and evolution remains a major challenge, hindering the rapid development and wide applications of Li-based batteries. Here, we devise a borrowing surface-enhanced Raman scattering (SERS) activity strategy by utilizing a size optimized Ag nanosubstrate to in-situ monitor the formation and evolution of SEI, as well as its structure and chemistry in an ethylene carbonate-based electrolyte. To ensure a reliable in-situ SERS investigation, we designed a strict air-tight Raman cell with a three-electrode configuration. Based on …

Electrochemical Performance Of Porous Ceramic Supported Tubular Solid Oxide Electrolysis Cell, Heng-Ji Wang, Wen-Guo Chen, Zhou-Yi Quan, Kai Zhao, Yi-Fei Sun, Min Chen, Ogenko Volodymyr

Journal of Electrochemistry

Solid oxide electrolysis cell (SOEC) is an efficient and clean energy conversion technology that can utilize electricity obtained from renewable resources, such as solar, wind, and geothermal energy to electrolyze water and produce hydrogen. The conversion of abundant intermittent energy to hydrogen energy would facilitate the efficient utilization of energy resources. SOEC is an all-ceramic electrochemical cell that operates in the intermediate to high temperature range of 500–750 ℃. Compared with traditional low temperature electrolysis technology (e.g., alkaline or proton exchange membrane cells operating at ~100 ℃), the high-temperature SOEC can increase the electrolysis efficiency from 80% to ~100%, providing …

Robust Gasification Trial Results For A Variety Of Difficult-To-Recycle Packaging-Related Materials, Bruce A. Welt

Journal of Applied Packaging Research

Currently, recycling requires nearly absolute sorting of materials to accommodate the limited capabilities of existing recycling infrastructure. Whether a material is “recyclable” depends more on the method of recycling than the material itself. Our dependence upon sorting has limited success of recycling and has stifled our ability to achieve circular economy sustainability with plastic packaging materials. Our dependence upon sorting is rooted in our material-specific recycling processes. However, newer robust recycling processes are commercially available that reduce or eliminate the need to sort waste, and can convert mixed waste into primary feedstock chemicals, such as methanol for subsequent manufacture of …

Analyzing The Effects Of Ultrafast Laser Processing On Mechanical Properties Of 3d-Printed Pla Parts, Darshan Pramodbhai Yadav

Theses and Dissertations

Recent advances in additive manufacturing technologies have already led to wide-scale adoption of 3D-printed parts in various industries. The expansion in choice of materials that can be processed, particularly using Fused Deposition Modeling (FDM), and the steady advancements in dimensional accuracy control have extended the range of applications far beyond rapid prototyping. However, additive manufacturing still has considerable limitations compared to traditional and subtractive manufacturing processes. This work addresses limitations associated with the as-deposited surface roughness of 3D-printed parts. The effects of roughness-induced stress concentrations were studied on ultimate tensile strength and fatigue life. The samples were manufactured using a …

Initiation Criteria For The Onset Of Geomagnetic Substorms Based On Auroral Observations And Electrojet Current Signatures, Mayowa Michael Kayode-Adeoye

Theses and Dissertations

In recent years, several substorm onset criteria have been developed, either from auroral observations (many authors) or from auroral electrojet properties such as those described by (Forsyth et al., 2015; Maimaiti et al., 2019; Newell & Gjerloev, 2011; Partamies et al., 2011) The different criteria are being investigated using a low order physics model of the magnetosphere called WINDMI (Spencer et al., 2009) and inferences are being made in line with the WINDMI model. The model variables will be compared with the criteria for substorm onset proposed by examining the SML index.

The WINDMI model uses solar wind and IMF …

Upcyclying Of Polyethylene Terephtalate By Addition Of Thermoplastic Elastomer, Diego Francisco Bermudez

Open Access Theses & Dissertations

Continual overconsumption of single-use plastics has generated challenges of solid waste management across the United States. Common plastic waste management solutions, such as landfill, have caused the migration of contaminants into the environment consequently affecting not only the health of wildlife, but also that of human beings. Alternative strategies for the handling of single-use plastic such as polyethylene terephthalate (PET), used in the food packaging industry, can ultimately help mitigate the noxious consequences of single-use plastics affecting entire ecosystems. This study demonstrates a potential avenue of materials upcycling by studying the effects of coupling PET with the thermoplastic elastomer styrene-ethylene-butylene-styrene …

Effect Of Multiple Machine Configurations And Wall Thickness On Microstructure And Microhardness Of Laser Powder Bed Fusion (L-Pbf) Additively Manufactured Heat-Treated Inconel 718 Products, Anannya Doris

Open Access Theses & Dissertations

This research examined thin section prototypes having seven nominal thicknesses ranging from 0.1 to 2.0 mm, composing a series of geometric feature build plates manufactured by multiple laser powder bed fusion (L-PBF) machine configurations. The build plates and thin section feature prototypes underwent a full heat treatment cycle per established standards: anneal at 1066°C, SR+HIP at 1163°C, and fully treat-treated by combining SR+HIP+solution treatment at 1066°C and double aging treatment at 760°C and 680°C, respectively. The fully heat-treated (FHT) Inconel 718 wall specimens were sectioned from 16 distinct geometric feature build plates constructed on 15 different L-PBF machines. The thin …

Development Of A 3d Printed Conductive Biopolymer For Cardiac Tissue Engineering, Britanny Lizeth Stark

Open Access Theses & Dissertations

Cardiovascular disease (CVD) is the leading cause of death in the US, with approximately 859,000 deaths each year. The major contributor to CVD is Acute Myocardial Infarction (AMI), which causes the death of approximately 25% of the cardiomyocytes present in the left ventricle of the heart. After AMI, the adult human heart has a very limited regenerative capacity. Moreover, the electrical propagation of the myocardium is severely disrupted, making the heart more susceptible to failure and patient death. However, current pharmacological treatments do not address the loss of cardiomyocytes and the disruption of electrical propagation in the heart. Tissue engineering …

Ultrasonic Non-Destructive Evaluation Of Additively Manufactured Polymer-Ceramic Composites, Christian Alexander Ruiz

Open Access Theses & Dissertations

Digital light processing (DLP) is an attractive additive manufacturing technique due to its ability to create ceramic parts with complex geometries. DLP uses ultraviolet light to polymerize a slurry comprised of ceramic powder and photosensitive resin in layers to create solid parts. Printing parameters such as light intensity and exposure time are critical when producing these parts. Improper parameters can lead to over or under-curing, adversely impacting print quality and strength. Samples were printed at varying layer exposure times and then tested using ultrasonics to determine the degree of conversion. Additionally, ultrasonics were used as a non-destructive technique to obtain …

Characterization Of Fcc Al-Cu-Ni-Mn-Ag High Entropy Alloy, Gina Zavala Alvarado

Open Access Theses & Dissertations

The effect of Ag on the microstructure developed in Al-Cu-Ni-Mn alloy has been determined. The modified Al-Cu-Ni-Mn alloy by Ag addition shows the presence of three microconstituents consisting of phases rich in (1) Cu, (2) Ni, and (3) Ag. The foregoing alloys heated for 24 hours from 600 to 1000 °C show excellent oxidation resistance. Oxide formation and microstructural changes of the alloy have been characterized by elemental mapping and X-ray diffraction (XRD). Results show that the elements of Al and Mn preferentially oxidize while Cu and Ni provide oxidation resistance to the alloy. Hardness was taken on the alloy …

Preparation And Lithium Storage Properties Of Carbon Confined Li3Vo4 Nano Materials, Jia-Qi Fan, Huan-Qiao Song, Jia-Ying An, Amantai A-Yi-Da-Na, Mo Chen

Journal of Electrochemistry

Li₃VO₄, as a promising anode material for lithium ion batteries, has been widely studied because of its low and safe voltage, and large capacity. However, its poor electronic conductivity impedes the practical application of Li₃VO₄ particularly at high rates. In this paper, carbon confined Li₃VO₄ nano materials (Li₃VO₄/C) were synthesized by hydrothermal and solid-phase method, and for comparison, the Li₃VO₄ (N) nano materials without carbon confinement and Li3VO4 (B) materials were also synthesized by pure solid-phase method. The composition, structure, morphology and specific …

Lif-Sn Composite Modification Layer To Modify Garnet/Lithium Metal Interface, Wu Yang, Xue-Fan Zheng, Yu-Qi Wu, Zheng-Liang Gong

Journal of Electrochemistry

The growing demands for electric vehicles and consumer electronics; as well as the expanding renewable energy storage market; have promoted extensive research on energy storage technologies with low costhigh energy density and safety. Lithium (Li) metal and solid-state electrolytes are considered as important components for next-generation batteries because of their great potential for improvements in energy density and safety performance. Inorganic garnet-type solid electrolytes with high Li-ion conductivity (about 10^-3 S·cm^-1) and high shear modulus (55 GPa) are considered to be ideal solid-state electrolytes; however; the issue of Li dendrite growth still obstructs their practical application. Herein; …

Constructing Carbon-Encapsulated Nifev-Based Electrocatalysts By Alkoxide-Based Self-Template Method For Oxygen Evolution Reaction, En-Hui Ma, Xu-Po Liu, Tao Shen, De-Li Wang

Journal of Electrochemistry

The development of green and sustainable water-splitting hydrogen production technology is beneficial to reducing the over-reliance on fossil fuels and realizing the strategic goal of "carbon neutral". As one of the half reactions for water splitting, oxygen evolution reaction has suffered the problems of sluggish four-electron transfer process and relatively slow reaction kinetics. Therefore, exploring efficient and stable catalysts for oxygen evolution reaction is of critical importance for water-splitting technology. Metal alkoxides are a series of compounds formed by the coordination function of metal ions with alcohol molecules. Metal alkoxides possess the double advantages of organic materials and inorganic materials, …

Peg-Water Electrolyte For High-Performance Zinc Iodine Dual-Ion Batteries, Xiao-Feng Qu, Yu-Ting Tang, Xin-Cheng He, Jia-Sheng Zhou, Zi-Heng Tang, Wen-Hua Feng, Jun Liu

Journal of Electrochemistry

Thanks to abundant resource and rapid redox reaction kinetics, iodine is regarded as promising positive materials inthe batteries. However, the shuttling effect due to the high solubility of iodine in the electrolyte makes the performance of battery poor. In this paper, polyethylene glycol (PEG400) and potassium iodide were added into zinc-ion aqueous electrolyte. PEG400 could complex with iodine to reduce the dissolution of iodine, therefore alleviating the formation of soluble triiodide (I₃^–) from iodine and iodide ions. Furthermore, this electrolyte was used in the battery with double carbon cloths as the current collectors, double separators and zinc …

Meta-Analysis Of Insulated Concrete Wall Panel Design Methods For Shear And Flexure Behavior, Maryam Al-Bayati

Durham School of Architectural Engineering and Construction: Dissertations, Thesis, and Student Research

Insulated Concrete wall panels have been designed and constructed since the early 1950s with various shear ties, dimensions, and methods; nonetheless, thermal bridging and rational design are still a concern. Many companies have recently developed plastic connectors that have gradually replaced solid concrete sections and steel connectors due to their superior thermal efficiency and strength. However, there is no generally accepted method for predicting the behavior of sandwich wall panels in structural engineering practice or codes, but many methods have been used since the early 1920. This study aims to evaluate the accuracy of current methods for predicting the flexural …