Chemical Engineering Commons^™

Investigating Ph And Other Electrical Properties Of Potassium Salt Solutions, Li Shu, Xi Lu, Veeriah Jegatheesan, Leonardo Jegatheesan

Research outputs 2022 to 2026

A recent study of ours reported that pH of common salts varies with concentration at room temperature. It can either increase in case of basic salts or decrease in case of acidic salts. In this study, pH values of four kind of potassium salts were investigated and their pH values increased with salt concentrations. It was reasoned that the concentration of hydrogen ions equalled the concentration of positive charges/protons in a solution, so a relationship between the activity of hydrogen ions and charge activity was developed. Further, the well-established equations for pH with hydrogen-ion activity and electrostatic/cell potential were extended …

Improving Lignin Recovery From Paper Mill And Biorefinery Waste Streams Via Liquid-Phase Splitting, Carter Fitzgerald

All Dissertations

Lignin is an abundant biopolymer with significant promise due to its aromaticity. It has been targeted as a replacement for a number of petroleum-based products including adhesives, coatings, polyurethane foams, activated carbon, and carbon fibers. However, commercially available bulk lignins are too polydisperse, and contain too many residual metals from the pulping process that are detrimental to the properties of the final product.

The Sequential Liquid-lignin Recovery and Purification (SLRP) process was developed by Michael Lake and John Blackburn, in collaboration with Clemson, with the intention of creating a continuous method for recovering lignin from paper-mill black liquors. Thies and …

The Effect Of Heat Treatment And Chemical Treatment On Natural Fibre To The Durability Of Wood Plastic Composites – A Review, Nuratiqah Asyiqin Mohd Nasharudin, Nur Fatihah Sulaiman, Nurul Aziemah Mohammad, Wan Nor Raihan Wan Jaafar, Falah Abu Dr., Siti Norasmah Surip

Journal of Materials Exploration and Findings (JMEF)

The application of WPC is not only limited to indoor applications but has been extended to exterior applications where properties of WPC could compromise during service life. WPC was derived from wood fiber of various sizes to reinforce polymers. Wood fiber has the advantage of a cheaper price, being abundantly available, and ease of processing, however, the critical factor is its hydrophilic nature, where moisture absorption is likely to occur. Thus, treatments for reducing the hydrophilicity of wood fibers are applied. By treatment of wood fiber, the surface impurities were removed, leaving the roughened surface of fibers, thus providing a …

Impact Of Microplastics On Organic Fouling Of Hollow Fiber Membranes, Sahar Ghasemi, Bin Yan, Masoumeh Zargar, Nicholas N.A. Ling, Einar O. Fridjonsson, Michael L. Johns

Research outputs 2022 to 2026

Given the potential hazards of microplastics (MPs), it is desirable to efficiently remove them during wastewater treatment processes. To this end, ultrafiltration (UF) membranes can significantly increase the removal of MPs, however the fouling of such membrane modules can also be impacted by the presence of MPs. Magnetic Resonance Imaging (MRI) was used here to non-invasively quantify the effect of polyethylene (PE) MPs accumulation in a 3D UF hollow fiber (HF) membrane module containing 400 fibers, via direct non-invasive velocity imaging of the flow distribution between individual fibers during module operation. The co-effect of MPs and alginate (a common organic …

Intelligen Superpro Designer Files For Economic Simulation Of Batch And Continuous Aqueous Two-Phase Purification For Viral Products, Natalie Nold, Eric Pearson, Caryn L. Heldt

Michigan Tech Research Data

Vaccine manufacturing strategies that lower capital and production costs could improve vaccine access by reducing the cost per dose and encouraging localized manufacturing. Continuous processing is increasingly utilized to drive lower costs in biological manufacturing by requiring fewer capital and operating resources. Aqueous two-phase systems (ATPS) are a liquid-liquid extraction technique that enables continuous processing for viral vectors. To date, no economic comparison between viral vector purifications using traditional methods and ATPS has been published. In this work, economic simulations of traditional chromatography-based virus manufacturing were compared to simulations of ATPS-based virus manufacturing for the same product output in both …

Exploring Underground Hydrogen Storage Options In North Dakota: A Review, Aimen Laalam, Olusegun Stanley Tomomewo

Petroleum Engineering Posters and Presentations

As the world shifts towards a low-carbon future, the demand for efficient, safe, and cost-effective energy storage solutions has become increasingly critical. Hydrogen has emerged as a promising energy carrier with numerous advantages, such as high energy density, zero emission combustion, and versatile applications. Nevertheless, the challenge of effective hydrogen storage remains. This study examines the potential of underground hydrogen storage (UHS) in North Dakota, assessing its opportunities and challenges in supporting the region's renewable energy objectives. North Dakota's unique geological features, abundant renewable energy resources, and growing energy demands make it an ideal location for UHS implementation. This review …

Reasons Why Oil Reserves Remain Unproductive-A Case Study, Mohamed Al-Saho

Journal of the Arab American University مجلة الجامعة العربية الامريكية للبحوث

By studying the production plans of some wells of Al Furat Petroleum Company, the researcher noticed that the rate of production increases to reach a peak and then falls back sharply. The deformation of the area around the well due to the decrease in the formation pressure (after production for a certain period) may have caused a change in the storage properties (porosity, permeability) and thus lower production rate. However, from the point of view of the geomechanics of the oil formation, which includes the study of the stress situation and its effect on the rock tissue, we will notice …

Ultra-Thin Zro2 Overcoating On Cuo-Zno-Al2o3 Catalyst By Atomic Layer Deposition For Improved Catalytic Performance Of Co2 Hydrogenation To Dimethyl Ether, Xiao Fan, Baitang Jin, Xiaoqing He, Shiguang Li, Xinhua Liang

Chemical and Biochemical Engineering Faculty Research & Creative Works

An Ultra-Thin overcoating of Zirconium Oxide (ZrO₂) Film on CuO-ZnO-Al₂O₃ (CZA) Catalysts by Atomic Layer Deposition (ALD) Was Proved to Enhance the Catalytic Performance of CZA/HZSM-5 (H Form of Zeolite Socony Mobil-5) Bifunctional Catalysts for Hydrogenation of CO₂ to Dimethyl Ether (DME). under Optimal Reaction Conditions (I.e. 240 °C and 2.8 MPa), the Yield of Product DME Increased from 17.22% for the Bare CZA/HZSM-5 Catalysts, to 18.40% for the CZA Catalyst after 5 Cycles of ZrO₂ ALD with HZSM-5 Catalyst. All the Catalysts Modified by ZrO₂ ALD Displayed Significantly Improved Catalytic Stability …

Deconstructed Plastic Substrate Preferences Of Microbial Populations From The Natural Environment, Lindsay I. Putman, Laura G. Schaerer, Ruochen Wu, Daniel G. Kulas, Ali Zolghadr, Rebecca Ong, David Shonnard, Stephen Techtmann

Michigan Tech Publications

Over half of the world's plastic waste is landfilled, where it is estimated to take hundreds of years to degrade. Given the continued use and disposal of plastic products, it is vital that we develop fast and effective ways to utilize plastic waste. Here, we explore the potential of tandem chemical and biological processing to process various plastics quickly and effectively. Four samples of compost or sediment were used to set up enrichment cultures grown on mixtures of compounds, including disodium terephthalate and terephthalic acid (monomers of polyethylene terephthalate), compounds derived from the chemical deconstruction of polycarbonate, and pyrolysis oil …

Saudi Arabian Basalt/Co2/Brine Wettability: Implications For Co2 Geo-Storage, Muhammad Ali, Nurudeen Yekeen, Amer Alanazi, Alireza Keshavarz, Stefan Iglauer, Thomas Finkbeiner, Hussein Hoteit

Research outputs 2022 to 2026

The geological sequestration of carbon dioxide, including mineralization in basaltic formations, has been identified as a promising method of attaining a low-carbon economy. However, successful CO₂ storage depends on both the CO₂ wettability of the basaltic rocks and the basalt rock-fluid interfacial interactions. The contact angles of brine/CO^₂ systems for Western Australian (WA) and Iceland basalts have been recently reported in the literature. However, contact angle datasets for evaluating the CO₂ wettability of Saudi Arabian (SA) basalt have not been previously reported. Moreover, there is limited information on the impact of organic acids on the wettability …

Exploring Senior Chemical Engineering Students’ Approach To Process Safety Decision Making, Jeffrey Saunders Stransky

Theses and Dissertations

Despite investments in chemical process safety education, evidence suggests that engineers’ decision making may contribute to process safety incidents. Currently, limited educational endeavors in process safety decision making exist, raising the need for a better understanding of how to prepare chemical engineering students for industry decisions. This dissertation fortifies current process safety education through three studies involving senior chemical engineering students. Study One developed the Engineering Process Safety Research Instrument (EPSRI) through exploratory and confirmatory factor analyses. Educators may use the EPSRI to evaluate their students’ moral development. Study Two evaluated a digital process safety game, Contents Under Pressure, on …

Hydrothermal Liquefaction (Htl) Of Lignocellulosic Biomass For Biocrude Production: Reaction Kinetics And Corrosion-Resistance Performance Of Candidate Alloys For Reactors, Haoyu Wang

Electronic Thesis and Dissertation Repository

In recent years, the rapid increase in the demand for clean energy and green chemicals as well as concerns over the supply and environmental impacts associated with fossil. resources have stimulated intensive research on conversion of bioresources, such as lignocellulosic biomass and biowaste, into energy, fuels, chemicals, and materials.

Hydrothermal liquefaction (HTL) is a unique thermochemical conversion process, particularly applicable for the conversion of wet biomass and biowaste feedstocks. Most of the biomass HTL studies are conducted in batch reactor and focus on the effects of catalysts, reaction temperature and time on production efficiency and chemical properties of the products. …

Vitreoscilla Globin Promoter Cloning And Testing In Escherichia Coli, Lauren J. Coffey

Rose-Hulman Undergraduate Research Publications

No abstract provided.

Method Of Evanescently Coupling Whispering Gallery Mode Optical Resonators Using Liquids [U.S. Patent Us11650370b2], Hengky Chandrahalim, Kyle T. Bodily

Faculty Publications

The present invention relates to evanescently coupling whispering gallery mode optical resonators having a liquid coupling as well as methods of making and using same. The aforementioned evanescently coupling whispering gallery mode optical resonators having a liquid couplings provide increased tunability and sensing selectivity over current same. The aforementioned. Applicants’ method of making evanescent-wave coupled optical resonators can be achieved while having coupling gap dimensions that can be fabricated using standard photolithography. Thus economic, rapid, and mass production of coupled WGM resonators-based lasers, sensors, and signal processors for a broad range of applications can be realized.

The Biological Activity Of Dual-Responsive Glycopolymers For Intracellular Codelivery Of Antigen And Lipophilic Adjuvant, Micaela Shields

Honors Theses

Subunit vaccines present themselves as an attractive alternative to traditional approaches to vaccines, which utilizes whole organisms to trigger an immune response. While these traditional approaches have proven themselves reliable within the history of vaccinations, they generally deliver subpar robust cellular-mediated immunity and pose many safety risks. Composed of proteins and /or peptides, subunit vaccines are safer and more precise alternatives to traditional approaches. However, the pharmacokinetic properties of the macromolecules that make up these vaccines hinder the subunit vaccine’s level of immunogenicity [d1] Examples of this hindrance include but are not limited to aggregation at the injection site and …

Optimization Of A Fluidized Bed Reactor For The Production Of Acetone From Isopropyl Alcohol, Andrew Rawls Wasson

Honors Theses

For the optimization of the isopropyl alcohol to acetone process, Unit 1100, the Net Present Value (NPV) was used as the objective function to observe the economic impact of each of the optimization factors being tested. During the optimization process, it is not only important to optimize the process’s profitability but also to ensure that the process operates efficiently and meets product specifications. The goal of this optimization was to alter variables from the base case calculations of Unit 1100 to maximize the NPV of the unit. AVEVA ProII software was used to simulate the process and make changes to …

An Analysis Of The Production Of Pharmaceutical-Grade Acetone Via The Dehydrogenation Of Isopropanol (Ipa), Jordan Desplas

Honors Theses

The production of 99.9 wt% acetone from isopropanol in Unit 1100 is designed to start up in 2025 and operate for 12 years after startup. The engineering team was tasked with designing the process, creating an economic model, and optimizing the net present value (NPV). The process was simulated in AVEVA PRO/II Simulation for the design process, and the economic analysis was estimated in Microsoft Excel. Parametric and topological optimization was performed linearly on the unit operations in the process. The NPV was improved by $14M from a base case of $122M to an optimized case of $136M. The project …

Monitoring Pm2.5 Pollution In The North End Of Hartford, Ct, Jocelyn Phung, Kristina Wagstrom

Honors Scholar Theses

Particulate matter (PM) or particle pollution is one of the six criteria air pollutants that can cause harm to human health and the environment; yet, there is a lack of data in many areas of the United States. Particulate matter is a mixture of solid particles and liquid droplets suspended in the air (EPA). Exposure to PM2.5 has been linked to respiratory and cardiovascular conditions. People who live in urban areas are more likely to be exposed to particulate matter as many urban areas are known to have poor air quality. Our goal is to determine how particulate matter levels …

The Design Estimate Of A Warehouse Refrigeration System, Jackson Dear

Honors Theses

The intention of this project was to provide a design and cost estimate for the refrigeration systems within an industrial cold storage distribution center for Magnolia Country Frozen Foods, Inc. in East Rutherford, NJ. The facility includes eighteen 300,000 ft3 units (200 ft x 100 ft x 15 ft). These units require 200 tons of refrigeration at a maintained temperature of 0oF. This project's scope included choosing an optimal refrigeration system, selecting a refrigerant for use within the system, and providing a cost estimate for the purchase of the refrigeration system equipment and for the yearly cost associated with running …

The Effects Of Pre Coating Layers On Barrier Layer Performance, Kritee Pokharel

Electronic Theses and Dissertations

Layers of cellulose nanofibrils (CNF) on paper have been demonstrated to be an effective barrier against oxygen and grease and have been shown to improve the barrier performance of dispersion-based barrier coatings. The potential to produce paper grades that have good oxygen, grease, and moisture barrier properties is clear, but a good understanding of the synergies between CNF, other coating layers, and water-borne barrier coatings (WBBC) is not clear. Different coat weights of a WBBC were applied to papers that have a range of different qualities and amounts of the CNF layer on them. The same WBBC was also applied …