Chemical Engineering Commons^™

Investigating Ph And Other Electrical Properties Of Potassium Salt Solutions, Li Shu, Xi Lu, Veeriah Jegatheesan, Leonardo Jegatheesan

Research outputs 2022 to 2026

A recent study of ours reported that pH of common salts varies with concentration at room temperature. It can either increase in case of basic salts or decrease in case of acidic salts. In this study, pH values of four kind of potassium salts were investigated and their pH values increased with salt concentrations. It was reasoned that the concentration of hydrogen ions equalled the concentration of positive charges/protons in a solution, so a relationship between the activity of hydrogen ions and charge activity was developed. Further, the well-established equations for pH with hydrogen-ion activity and electrostatic/cell potential were extended …

Improving Lignin Recovery From Paper Mill And Biorefinery Waste Streams Via Liquid-Phase Splitting, Carter Fitzgerald

All Dissertations

Lignin is an abundant biopolymer with significant promise due to its aromaticity. It has been targeted as a replacement for a number of petroleum-based products including adhesives, coatings, polyurethane foams, activated carbon, and carbon fibers. However, commercially available bulk lignins are too polydisperse, and contain too many residual metals from the pulping process that are detrimental to the properties of the final product.

The Sequential Liquid-lignin Recovery and Purification (SLRP) process was developed by Michael Lake and John Blackburn, in collaboration with Clemson, with the intention of creating a continuous method for recovering lignin from paper-mill black liquors. Thies and …

Mil-53(Fe) Derived Magnetic Cufe2o4/Fe2o3 Composite For Catalytic Oxidation Of Sulfamethoxazole Via Peroxymonsulfate Activation, Abdul H. Asif, Nasir Rafique, Rajan A. K. Hirani, Lei Shi, Yantao Wang, Xiaoguang Duan, Yu Yin, Hongqi Sun

Research outputs 2022 to 2026

Design of metal–organic framework (MOF) derived metal oxides is an effective approach for environmental remediation. The current study describes the fabrication of MIL-53-derived perforated CuFe2O4/Fe2O3 using a facile, one-step, post-thermal solid-state approach by varying Cu/Fe ratios. Herein, the release of CO2 and H2O during the thermal treatment facilitates the incorporation of Cu2+ onto the Fe2O3 structure, forming a perforated hollow CuFe2O4/Fe2O3 composite via an in-situ ion-exchange mechanism. The optimised catalyst CF-0.5 displays a high degradation efficiency for the removal of sulfamethoxazole (SMX) by heterogeneous activation of peroxymonsulfate (PMS), ascribing to the better textural, morphological, and elemental properties of the novel …

The Effect Of Heat Treatment And Chemical Treatment On Natural Fibre To The Durability Of Wood Plastic Composites – A Review, Nuratiqah Asyiqin Mohd Nasharudin, Nur Fatihah Sulaiman, Nurul Aziemah Mohammad, Wan Nor Raihan Wan Jaafar, Falah Abu Dr., Siti Norasmah Surip

Journal of Materials Exploration and Findings (JMEF)

The application of WPC is not only limited to indoor applications but has been extended to exterior applications where properties of WPC could compromise during service life. WPC was derived from wood fiber of various sizes to reinforce polymers. Wood fiber has the advantage of a cheaper price, being abundantly available, and ease of processing, however, the critical factor is its hydrophilic nature, where moisture absorption is likely to occur. Thus, treatments for reducing the hydrophilicity of wood fibers are applied. By treatment of wood fiber, the surface impurities were removed, leaving the roughened surface of fibers, thus providing a …

The Plastics Collection Reference Packet, Special Collections Research Center

Special Collections Research Center

This reference packet is an informational tool to support further research into the history of plastics—whether interested in companies, individuals within the plastics industry's history, historical plastics materials, essays, and more. All content featured within this packet was previously published on the former plastics.syr.edu website as part of a Syracuse University Libraries and Special Collections Research Center (SCRC) partnership established in 2007 with the Plastics Pioneers Association (PPA)—an association of plastics industry professionals interested in preserving the plastics industry's past.

Impact Of Microplastics On Organic Fouling Of Hollow Fiber Membranes, Sahar Ghasemi, Bin Yan, Masoumeh Zargar, Nicholas N.A. Ling, Einar O. Fridjonsson, Michael L. Johns

Research outputs 2022 to 2026

Given the potential hazards of microplastics (MPs), it is desirable to efficiently remove them during wastewater treatment processes. To this end, ultrafiltration (UF) membranes can significantly increase the removal of MPs, however the fouling of such membrane modules can also be impacted by the presence of MPs. Magnetic Resonance Imaging (MRI) was used here to non-invasively quantify the effect of polyethylene (PE) MPs accumulation in a 3D UF hollow fiber (HF) membrane module containing 400 fibers, via direct non-invasive velocity imaging of the flow distribution between individual fibers during module operation. The co-effect of MPs and alginate (a common organic …

Modeling And Dynamic Correction Of The Thermal Radiation Fluxes Measuring System, Olexander Alekseevich Sytnik, Fatima Mirazizovna Sagatova

Chemical Technology, Control and Management

Temperature measurements are currently an integral part of modern production, in particular, energy, aviation, instrumentation, etc. Therefore, the need to improve the accuracy of measurement, control and regulation of temperature largely determines the technical and economic efficiency of production. The development of reliable methods for temperature control under various conditions and the creation of specific devices is one of the most important tasks of modern instrumentation. The article deals with the issues of solving the problems of modeling and correcting the dynamic characteristics of a system for measuring thermal radiation fluxes using the integral method of signal recovery. For computer …

Intellectualization Of The Process Of Monitoring Of Complex Technological Productions, Dmitry Semenovich Karpovich, Umidjon Abdimajitovich Ruziev

Chemical Technology, Control and Management

The article deals with the creation of intelligent monitoring systems for complex technological processes. The methods and models of the intellectualization of information processing systems are analyzed. The advantages of using intelligent measuring instruments in monitoring systems are given, which allow obtaining reliable information necessary for the effective control of complex technological processes. The issues of using intelligent measuring instruments in monitoring systems are considered. A block diagram of intelligent monitoring of signal processing of complex production processes has been proposed. An algorithm for parametric correction of intelligent measuring instruments in monitoring systems has been developed. A model of a …

Investigation Of Magnetic Circuits Of Differential Transformer Displacement Sensors, Sulton Fayzullaevich Amirov, Absaid Khurramovich Sulliev, Shukhrat Azamatovich Sharapov

Chemical Technology, Control and Management

The article examines the magnetic circuits of both existing and developed differential transformer displacement sensors for large linear displacements. These circuits are characterized by a specific distribution structure of magnetic resistance parameters in long ferromagnetic cores and the magnetic capacitance between them. It is shown that in the existing sensor, the distribution of working magnetic flux along the length of the ferromagnetic cores has a nonlinear nature, resulting in a nonlinear relationship between the output signal in the form of electromotive force and the input linear displacement of the sensor. It has been established that by selecting the law of …

Current Issues Of The Use Of Artificial Intelligence In The Activities Of Customs Authorities, Jasur Usmonovich Sevinov, Gayrat Rustamovich Khamroev

Chemical Technology, Control and Management

Presents effective methods and solutions to eliminate errors caused by the “human factor” (fatigue, neglect, etc.) as a result of the creation and improvement of automated systems based on artificial intelligence, distinguishing features such as commodity group, weight, dimensions, etc. in relation to goods under customs control. The use of artificial intelligence in customs activities allows: to increase the speed of performing tasks set before customs authorities by increasing productivity, without attracting additional personnel; to eliminate errors caused by the “human factor” (fatigue, neglect, etc.); to free employees from everyday activities and transfer it to solving mainly analytical tasks; to …

Prediction Using Fire Data Based On Machine Learning Algorithms, Oybek Zokirovich Koraboshev

Chemical Technology, Control and Management

In this article, the process of real-time prediction of the dynamics of fire development in non-stationary and gas-fired areas is carried out by developing a real-time prediction method based on artificial intelligence and deep machine learning (Deep Machine Learning) algorithms. The most commonly used KNN algorithm, CVM algorithm, Random Forest algorithm and Naive Bayes algorithm were used for prediction fire situations.

Synthesis Of Control Systems With Multilayer Neural Networks Based On Velocity Gradient Methods, Oxunjon Boborayimov, Okyay Kaynak

Chemical Technology, Control and Management

In this manuscripts, the synthesis of control systems with multilayer neural networks based on the speed gradient methods is given. For adjusting the weight coefficients of the base processor element, the gradient method of minimizing the learning criterion is used. A procedure for the synthesis of neural network control systems based on the velocity gradient methods has been developed. This guarantees the stabilization of the system under external limited disturbances that are inaccessible to direct measurement. Taking into account the state vector of the control object in the network learning function ensures the consistency of the processes of setting the …

Topological Interpolation Method For Modeling Dynamic Systems, Isamiddin Xakimovich Siddikov, Dilnoza Maxamadjanovna Umurzakova

Chemical Technology, Control and Management

The method of simulation structural-complex continuous-discrete control systems is discussed. For simulation and calculation of dynamic processes in continuous-discrete systems topological interpolation method is proposed, based on application of hybrid methods of space of state variables and interpolation of signals. The essence of the method is that the dynamics of the investigated system, considered at the final interval, is broken down into subintervals, on each of which the processes are described by linear ordinary system differential equations. The computational efficiency of the proposed method was evaluated by comparison with standard methods such as the Runge-Kutta-Merson method. The use of this …

Intelligen Superpro Designer Files For Economic Simulation Of Batch And Continuous Aqueous Two-Phase Purification For Viral Products, Natalie Nold, Eric Pearson, Caryn L. Heldt

Michigan Tech Research Data

Vaccine manufacturing strategies that lower capital and production costs could improve vaccine access by reducing the cost per dose and encouraging localized manufacturing. Continuous processing is increasingly utilized to drive lower costs in biological manufacturing by requiring fewer capital and operating resources. Aqueous two-phase systems (ATPS) are a liquid-liquid extraction technique that enables continuous processing for viral vectors. To date, no economic comparison between viral vector purifications using traditional methods and ATPS has been published. In this work, economic simulations of traditional chromatography-based virus manufacturing were compared to simulations of ATPS-based virus manufacturing for the same product output in both …

Exploring Underground Hydrogen Storage Options In North Dakota: A Review, Aimen Laalam, Olusegun Stanley Tomomewo

Petroleum Engineering Posters and Presentations

As the world shifts towards a low-carbon future, the demand for efficient, safe, and cost-effective energy storage solutions has become increasingly critical. Hydrogen has emerged as a promising energy carrier with numerous advantages, such as high energy density, zero emission combustion, and versatile applications. Nevertheless, the challenge of effective hydrogen storage remains. This study examines the potential of underground hydrogen storage (UHS) in North Dakota, assessing its opportunities and challenges in supporting the region's renewable energy objectives. North Dakota's unique geological features, abundant renewable energy resources, and growing energy demands make it an ideal location for UHS implementation. This review …

Reasons Why Oil Reserves Remain Unproductive-A Case Study, Mohamed Al-Saho

Journal of the Arab American University مجلة الجامعة العربية الامريكية للبحوث

By studying the production plans of some wells of Al Furat Petroleum Company, the researcher noticed that the rate of production increases to reach a peak and then falls back sharply. The deformation of the area around the well due to the decrease in the formation pressure (after production for a certain period) may have caused a change in the storage properties (porosity, permeability) and thus lower production rate. However, from the point of view of the geomechanics of the oil formation, which includes the study of the stress situation and its effect on the rock tissue, we will notice …

Advancing Our Understanding Of Non-Linear Flow Behavior In X-Crossing Fractures Through 3d Printing Technology, Ghoulem Ifrene, Sven Egenhoff, Doina Irofti, Nicholas Bittner, Tyler Newman

Petroleum Engineering Posters and Presentations

Fractured reservoir systems play a critical role in the efficient management of hydrocarbon resources, CO2 storage, and geothermal energy extraction. Understanding the behavior and characteristics of these systems is essential for optimizing recovery, reducing carbon footprint, and increasing efficiency. However, fractures within reservoir systems create complex geometries and can make fluid flow behavior complex and difficult to predict. Replicating these complex geometries in the laboratory has been challenging, but advancements in 3D printing technology have made it possible to create accurate models of rough-walled fracture geometries. In this study, the impact of geometric characteristics on fluid flow behavior in connected …

Ultra-Thin Zro2 Overcoating On Cuo-Zno-Al2o3 Catalyst By Atomic Layer Deposition For Improved Catalytic Performance Of Co2 Hydrogenation To Dimethyl Ether, Xiao Fan, Baitang Jin, Xiaoqing He, Shiguang Li, Xinhua Liang

Chemical and Biochemical Engineering Faculty Research & Creative Works

An Ultra-Thin overcoating of Zirconium Oxide (ZrO₂) Film on CuO-ZnO-Al₂O₃ (CZA) Catalysts by Atomic Layer Deposition (ALD) Was Proved to Enhance the Catalytic Performance of CZA/HZSM-5 (H Form of Zeolite Socony Mobil-5) Bifunctional Catalysts for Hydrogenation of CO₂ to Dimethyl Ether (DME). under Optimal Reaction Conditions (I.e. 240 °C and 2.8 MPa), the Yield of Product DME Increased from 17.22% for the Bare CZA/HZSM-5 Catalysts, to 18.40% for the CZA Catalyst after 5 Cycles of ZrO₂ ALD with HZSM-5 Catalyst. All the Catalysts Modified by ZrO₂ ALD Displayed Significantly Improved Catalytic Stability …

Performance Enhancement Of Photovoltaic-Thermal Modules Using A New Environmentally Friendly Paraffin Wax And Red Wine-Rgo/H2o Nanofluid, Hossein Nabi, Mosayeb Gholinia, Mehdi Khiadani, Abdellah Shafieian

Research outputs 2022 to 2026

Photovoltaic/thermal systems are one of the most efficient types of solar collectors because they absorb solar radiation and generate electricity and heat simultaneously. For the first time, this paper presents an investigation into the impact of red wine-rGO/H2O nanofluid and paraffin wax on the thermohydraulic properties of a photovoltaic/thermal system. The study focuses on three innovative nonlinear arrangements of the serpentine tubes. The effects of these materials and configurations are analyzed through numerical simulations. To improve the performance, environmentally friendly materials, including red wine-rGO/H2O nanofluid and paraffin wax, have been used. Various performative parameters such as electrical and thermal efficiency …

Saudi Arabian Basalt/Co2/Brine Wettability: Implications For Co2 Geo-Storage, Muhammad Ali, Nurudeen Yekeen, Amer Alanazi, Alireza Keshavarz, Stefan Iglauer, Thomas Finkbeiner, Hussein Hoteit

Research outputs 2022 to 2026

The geological sequestration of carbon dioxide, including mineralization in basaltic formations, has been identified as a promising method of attaining a low-carbon economy. However, successful CO₂ storage depends on both the CO₂ wettability of the basaltic rocks and the basalt rock-fluid interfacial interactions. The contact angles of brine/CO^₂ systems for Western Australian (WA) and Iceland basalts have been recently reported in the literature. However, contact angle datasets for evaluating the CO₂ wettability of Saudi Arabian (SA) basalt have not been previously reported. Moreover, there is limited information on the impact of organic acids on the wettability …