Nanoscience and Nanotechnology Commons^™

Cationic Polymer-Grafted Magnetic Nanoparticles For Enhanced Removal Of Anionic Dyes From Wastewater, Joia A. Traver

Chemical Engineering Undergraduate Honors Theses

Water scarcity and pollution are escalating global challenges, with textile industry wastewater often enriched with toxic dyes posing significant risks to environmental and human health. These contaminants increase turbidity, reduce dissolved oxygen levels, and ultimately impair aquatic ecosystems. This thesis focuses on the remediation of dye-contaminated water using nanoscale polymeric adsorbents. Methyl orange, a common anionic dye widely used in textile and leather industries, was selected as the model contaminant due to its terminal sulfonate group, which enables strong electrostatic and hydrogen-bonding interactions with cationic functional materials.

In this work, magnetic nanoparticles grafted with cationic polymers were synthesized and evaluated …

Mechanisms Of Synergy Between Nanosecond Pulsed Electric Field (Nspef) And Cold Atmospheric Pressure Plasma Discharge (Cap) In Pancreatic Cancer: The Role Of Ros-Mediated Oxidative Stress And Apoptosis, Zobia Minhas

Biomedical Sciences Theses & Dissertations

Pancreatic ductal adenocarcinoma is a highly lethal malignancy characterized by poor prognosis and resistance to conventional therapies. Novel treatment strategies are needed to overcome this resistance. Non-thermal physical modalities, including nanosecond pulsed electric field (nsPEF) and cold atmospheric pressure plasma discharge (CAP), have emerged as potential anticancer approaches; however, the mechanisms underlying their combined effects remain unclear.

This study evaluated whether nsPEF enhances CAP-induced cytotoxicity and investigated the associated molecular mechanisms using the murine Pan02 pancreatic cancer cell line. Cell viability was assessed by WST-1 metabolic activity assays and electric cell–substrate impedance sensing (ECIS). Intracellular reactive oxygen species (ROS) were …

Molecular Catalysts For Electrochemical Nitrogen Activation Toward Sustainable Ammonia Synthesis, Jin-Xiu Han, Hao Xue, Xian-Biao Fu

Journal of Electrochemistry

Homogeneous electrocatalytic nitrogen reduction reaction (NRR) provides a powerful framework to interrogate molecular nitrogen-fixation pathways under mild conditions. By tuning the metal center, ligand architecture, and reaction medium, these systems enable capturing key intermediates and delivering mechanistic insight at the molecular-level resolution. Nevertheless, advances remain constrained by highly reduced operating potentials, intense competition from the hydrogen evolution reaction (HER), limited durability in turnover, and inadequate long-term stability.

In this review, we take electron delivery to the molecular active site as the guiding principle for organizing homogeneous electrochemical N₂ activation and transformation. We classify reported systems into direct electron transfer …

Water-Driven Solid Electrolyte Interphase Governs Continuous-Flow Ammonia Electrosynthesis, Peng-Bo Liu, Sheng-Liang Zhai, Ji Huang, Zhong-Shuo Zhang, Jie Zeng, Shao-Feng Li

Journal of Electrochemistry

Flow-cell architectures have emerged as a powerful platform for continuous and stable lithium-mediated nitrogen reduction (Li-NRR), enabling ambient-condition electrochemical ammonia synthesis and offering a promising alternative to Haber-Bosch processes. However, Li-NRR is exceptionally sensitive to trace water, and even minor variations in water content can profoundly alter interfacial chemistry. Here, we systematically investigate how initial water concentration affects Li-NRR performance in a continuous-flow cell. Excess water drives the formation of a thick solid electrolyte interphase (SEI) layer, which may impede nitrogen access to metallic lithium and hinder lithium-ion transport. As a result, the ammonia Faradaic efficiency collapses from ~61% to …

Insertion Of Noble Metal Free Cathodic Catalyst Layer With Fe-N-C Catalyst For Boosted Performance Of Pemfc, Shi Zhou, Muhammad Tariq, Asif Nadeem Tabish, Muhammad Salman, Fan-Di Ning, Muhammad Rayyan Tayyab, Ran-Ran Peng, Meng-Geng Hao, Wen-Mu Li, Xiao-Chun Zhou

Journal of Electrochemistry

Economical Fe-N-C catalysts are considered as promising alternatives to platinum group metal catalysts for proton exchange membrane fuel cells (PEMFCs). Despite exhibiting robust activity on rotating disk electrodes, their performance within membrane electrode assemblies often experiences limitations, such as decreased O₂ diffusion, high H₂O₂ formation, low proton conduction, and a lower electron transfer number. In this study, key factors, including proton transport, electron conduction, and gas diffusion within air-breathing PEMFCs, have been investigated by adjusting cathode catalyst layer (CCL) compositions. From the experimental results, the optimal peak power density was obtained when the loading of Fe-N-C …

Manufacturing Of Functional Surface Coatings In The Automotive Industry, Gulirano Saidakhmedova

Technical science and innovation

The development of environmentally sustainable technologies for material processing represents one of the most pressing scientific and technical challenges in modern industrial production. This issue is particularly relevant to the automotive industry, where growing demands for energy efficiency, durability, and environmental safety necessitate the adoption of advanced manufacturing methods. Special attention is given to developing vacuum-based, import-substituting equipment and technologies for producing functional coatings from composite materials with predefined physical, mechanical, and optical properties, including reflective and protective characteristics. Current requirements for mechanical engineering products and production technologies drive the need for innovative approaches to material processing and specialized technical …

Competitive Reaction Pathways In The Fully Green Synthesis And Surface Modification Of Silver Nanowires Under L-Ascorbic Acid-Limited Conditions, Finley Neal

Honors Theses

Silver nanowires (AgNWs) are critical building blocks for transparent conductive films (TCFs) in flexible electronics, yet their commercial viability is hindered by environmentally hazardous, energy-intensive synthesis methods and limited intrinsic chemical stability. This study investigated a fully green, room-temperature (25℃) batch synthesis of pristine AgNWs using tannic acid as a biodegradable dual reducing and capping agent under strict kinetic pH control (pH 1.25). To enhance oxidative resistance, a subsequent surface modification protocol was evaluated to deposit a protective palladium (Pd) shell using L-ascorbic acid (LAA) as a secondary reducing agent. The pristine green synthesis yielded one-dimensional Ag nanostructures with a …

Axial Sulfur-Coordination Engineering Boosting Fe–N–C Catalysts For High-Performance Proton Exchange Membrane Fuel Cells, Lin Lin, Xiu-Xuan Hou, Zhe-Chen Fan, Yi-Xuan Yin, Wei-Yi Zhao, Kai Wei, Yu-Die Zhou, Li-Na Hou, Ying Wang, Hao Wan, Jun-Jie Ge

Journal of Electrochemistry

Fe-N-C catalysts have long suffered from kinetically sluggish oxygen reduction reaction (ORR) due to excessive adsorption strength toward oxygen intermediates and low site utilization. Heteroatom doping effectively accelerates ORR reaction kinetics through electronic structure modulation of metal sites for optimal intermediate adsorption, while chemical vapor deposition (CVD) enhances the turnover frequency (TOF) of active sites. Herein, we developed an FeSNC catalyst featuring abundant FeS₁N₄ sites via a dual-precursor CVD strategy. Experimental and theoretical analyses revealed that S incorporation disrupts the symmetric coordination of active sites, which optimizes OH* adsorption energies from 0.212 eV to 1.194 eV. Moreover, …

Entropy Of Metal/Solution Interfaces: Thermodynamic Framework, Theoretical Models, And Roles Of Interfacial Water, Zeng-Ming Zhang, Zi-Xi Liang, Jun Huang

Journal of Electrochemistry

Entropy is a basic thermodynamic property of the electrical double layer (EDL) at metal/solution interfaces, yet, its definition, measurement, and theoretical treatment are dispersed in the literature, and, in some cases, ambiguous. In this paper, we revisit the thermodynamic theory of EDL, from which two variants of entropy, excess entropy and formation entropy, are obtained and compared. In terms of the formation entropy, two calculation routes are validated in the context of a primitive EDL model, namely, the Gouy-Chapman (GC) model. After clarifying the concepts and calculation routes, we investigate interfacial water effects on the EDL entropy, using a refined …

Deciphering The Role Of Binder Reaction Exothermicity In Thermal Runaway Of Lithium-Ion Cells, Wen Wen, Jing-Hong Zhou, Hao-Tian Lu, Xing-Gui Zhou

Journal of Electrochemistry

Thermal safety associated with lithium-ion cells as power sources remains a critical industry concern. A comprehensive understanding of how internal exothermic side reactions contribute to temperature rise is fundamental for accurately analyzing thermal runaway processes and predicting the thermal safety of lithium-ion cells. While various side-reactions, such as decomposition of solid electrolyte interphase layer, reaction between anode materials and electrolyte, reaction between cathode materials and electrolyte, and electrolyte decomposition, have been identified as heat generation sources in previous studies, the quantification of these reactions remains insufficiently standardized. Particularly, the impact of heat generation from binder decomposition (most commonly polyvinylidene difluoride) …

Sonochemically Synthesized Al-Doped Zno Nanorods-Based Flexible Piezoelectric Nanogenerators For Durable Energy Harvesting, Tiham Fayaz, Ahmed Hasnain Jalal, Fahmida Alam

Electrical and Computer Engineering Faculty Publications

This study presents a high-performance piezoelectric nanogenerator (PENG) based on aluminum-doped zinc oxide (Al:ZnO) nanorods synthesized via a novel sonochemical method. This rapid, cost-effective, and reproducible approach enables the synthesis of ZnO nanorods (ZnO NRs) under ambient conditions. The PENG, fabricated on a 177 µm flexible Indium Tin Oxide (ITO) coated polyethylene terephthalate (PET) substrate, benefits from optimized aluminum doping, enhancing the output voltage. Structural analyses conducted using atomic force microscopy (AFM), scanning electron microscopy (SEM), and X-ray diffraction (XRD) demonstrated that the synthesized ZnO nanorods possessed a high degree of crystallinity. The synthesis process was carefully fine-tuned to avoid …

Project Comet Verification Testing And Mbse, David Chiaravalle

Student Research Symposium (SRS)

Embry-Riddle’s Project COMET is developing a CubeSat mission to test mmWave communications technology in partnership with the University Nanosatellite Program (UNP). As the design continues to mature, the mission’s growing complexity has introduced challenges in defining and managing technical specifications across multiple subsystems. This Graduate Research Project (GRP) focuses on creating verification test plans at the component, subsystem, and system levels to ensure the spacecraft meets all mission requirements. To better understand and manage interactions between systems, a Model-Based Systems Engineering (MBSE) approach using MBSE software has been applied to provide a digital model representation of the spacecraft. This includes …

Dual-Modal Tumor Imaging Using Functionalized Iron-Oxide Nanoparticles For Mri And Fluorescence, Kevin Secades

USF Tampa Graduate Theses and Dissertations

Accurate tumor imaging is essential for early cancer detection and treatment monitoring [1]. Technetium-99m (Tc-99m) is a commonly used radioisotope for medical imaging, but its reliance on gamma-ray emission poses challenges related to safety, accessibility, and regulatory constraints[2-5]. This research proposes the development of a dual-modal imaging approach by functionalizing iron-oxide nanoparticles (IONPs) with the fluorescent chromophore Cy5, enabling both MRI contrast enhancement and optical imaging for improved tumor specificity. IONPs provide strong T2-weighted MRI contrast [6], while conjugated near-infrared (NIR) chromophores allow for high-resolution fluorescence imaging [7], making this proposed system adaptable for both in vitro and in vivo …

Sensing Negative-Cone Rotational Diffusion Of Dipole-Like Emitters, Yuanxin Qiu, Kaizhi A. Nie, Matthew D. Lew

Electrical & Systems Engineering Publications and Presentations

Fluorescence anisotropy and single-molecule orientation-localization microscopy (SMOLM) are powerful techniques that quantify the rotational diffusion of dipole-like emitters, which is important for sensing molecular interactions and chemical environments at the nanoscale. Numerous theoretical and experimental studies have thoroughly characterized single-molecule rotations even when those rotations are much faster than the detector integration time. Here, we extend the theory of measuring rotational diffusion to situations where a single dipole rotates uniformly everywhere outside of an isotropic cone of a certain size, termed a negative cone. This scenario corresponds to negative fluorescence anisotropy 𝑟 and has been observed in emitters exhibiting strong …

Emerging Design Paradigms And Microstructural Innovations In Refractory High-Entropy Alloys: A Critical Review, Deyu A. Jiang, Lai Chang Zhang, Kuaishe Wang, Mahmoud Ebrahimi, Wen Wang, Liqiang Wang, Weijie Lu, Di Zhang

Research outputs 2022 to 2026

Refractory high-entropy alloys (RHEAs) are being developed to meet mechanical, thermal and chemical requirements that exceed what current super-alloys can withstand. This review explains how composition design, processing routes and the resulting microstructures now combine to realize that potential. We first link phase selection in BCC-, FCC- and dual-phase RHEAs to atomic-size mismatch, mixing enthalpy and valence-electron concentration, and compare manufacturing paths ranging from arc melting to powder metallurgy, additive manufacturing and vapor deposition, showing how each reshapes grain structure and defect chemistry to improve high-temperature strength, corrosion resistance and irradiation tolerance. Computation-led tools—density-functional theory, calculation of phase diagrams and …

An Electrochemiluminescence-Based Arsenic (Iii) Sensor Using Luminol On Screen-Printed Gold Electrodes, Harmesa Harmesa, Isnaini Rahmawati, Andrea Fiorani, Yasuaki Einaga, Eny Kusrini, A’An Johan Wahyudi, Asep Saefumillah, Tribidasari A Ivandini

Journal of Electrochemistry

Electrochemiluminescence (ECL) of luminol has been studied on a screen-printed gold electrode for a simple and sensitive detection of arsenic ions (As(III)). Cyclic voltammetry (CV) was applied as the proposed technique to study luminol’s electrochemical behavior and to evaluate the arsenic’s effect in the ECL system, while hydrogen peroxide (H₂O₂) served as a co-reactant to enhance luminol’s light emission under alkaline conditions. To achieve optimal electrode performance, key parameters including pH, scan rate, and the concentrations of H₂O₂ and luminol were carefully optimized. The presence of As(III) induced a quenching effect on the …

Control Of Pore Nucleation And Rearrangement Kinetics During Aluminium Anodizing In Phosphoric Acid Electrolyte, Ilya V. Roslyakov, Nikita A. Shirin, Dmitry M. Tsymbarenko, Sergei N. Pavlov, Sergey E. Kushnir, Nikolay V. Lyskov, Kirill S. Napolskii

Journal of Electrochemistry

Anodic aluminium oxide (AAO) porous films with an interpore distance of several hundred nanometers are of great interest due to their unique interaction with visible and near-infrared light, and high thermal stability up to 1500 °C. These porous films are prepared by aluminium anodizing at high voltages in weak acids, leading to a slow kinetics of initial stages of porous structure formation. Here, we propose an approach to accelerate AAO formation in electrolytes based on weak acids such as phosphoric acid. Aluminium foils, pre-patterned using first anodizing under different conditions and subsequent selective dissolution of a sacrificial AAO layer, were …

Triphenylmethane-Derived Levelers For High-Speed Redistribution Layer Copper Electroplating Of Tailored Surface Morphologies, Zi-Hao Song, Wei-Bin Wang, Xiao-Hui Liu, Xiao-Min Han, Yi Zhou, Rui Huang, Yan-Xia Jiang, Zhe Li, Xiao-Wei Liu, Mei-Ling Xiao, Hong-Gang Liao, Wei-Lin Xu, Rong Sun

Journal of Electrochemistry

Redistribution Layer (RDL), composed of layered dielectrics and electroplated copper materials, is a basic structure to rearrange numerous I/O pads on the chip surface in wafer-level advanced packaging. As the key chemicals in electrolyte baths, electroplating additives have undergone continuous development to meet the industrial needs for high-speed and fine-line/fine-pitch applications. Meanwhile, the intricate relationships between additive chemical structures and electroplated copper properties are yet to be well understood. In this work, a pair of triphenylmethane-based dye molecules, i.e., gentian violet (GV) and methyl green (MG), was comparatively investigated as levelers for high-speed RDL copper electroplating. Compared to GV, significantly …

Nanoscale Opportunities In Extracellular Matrix Mimicry, L. Andrew Lyon, Abbygail Caine, Elif Narbay, E. Daniel Cárdenas-Vásquez

Engineering Faculty Articles and Research

We present an overview of the composition, function, energetics, and dynamics of extracellular matrix and its relation to nanoscale structures and phenomena. These concepts are then related to the development of synthetic and biosynthetic materials that aim to mimic the extracellular matrix for regenerative medicine and tissue engineering technologies. Notable successes and advancements towards the goal of biomimicry are outlined, while remaining challenges and knowledge gaps towards that goal are highlighted. Finally, we frame the remaining challenges in the field in terms of nanoscience-related research opportunities that if solved, might prove to be transformative steps forward in the discipline.

Metal-Free Nitrogen-Enriched Graphitic Carbon Nitride Architectures For Advanced Supercapacitor Energy Storage: Design, Synthesis, And Electrochemical Performance Optimization, Loujain Gamal Mohamed

Theses and Dissertations

Abstract

This thesis addresses the urgent global requirement for efficient energy storage materials by developing and characterizing advanced graphitic carbon nitride (g-C3N4)-based electrode materials for supercapacitors. A facile, low-cost thermal polymerization method produces 2D nitrogen-rich GCN nanosheets exhibiting excellent electrochemical stability and wide voltage windows, enabling symmetric devices with 19.33 Wh/kg energy density and remarkable cycling stability over 21,000 cycles. To overcome intrinsic limitations of pristine GCN, a 3D/2D metal free composite with bio-derived carbon (Bio-Cx) is synthesized, delivering high capacitance, wide potential windows, and ultrahigh energy density of 53.72 Wh/kg in asymmetric configurations paired with mesoporous nitrogen-doped carbon (MPNDC). …