University of South Florida
Purdue University
University of Nebraska-Lincoln
College of Chemistry, Sichuan University, Chengdu 610065, P. R. China
Syracuse University
Thermally-Driven Equiaxation Of Columnar Grains And Α″ Nanoparticles Enabling Isotropic Β-Ti Alloys With Strength–Ductility Synergy Manufactured By Laser Powder Bed Fusion,
2026
Edith Cowan University
Thermally-Driven Equiaxation Of Columnar Grains And Α″ Nanoparticles Enabling Isotropic Β-Ti Alloys With Strength–Ductility Synergy Manufactured By Laser Powder Bed Fusion, Lei Qin, Shengfeng Zhou, Jianbo Jin, Huan Yang, Kunmao Li, Cheng Deng, Yujie Yuan, Lai-Chang Zhang
Research outputs 2022 to 2026
The transient thermal cycling characteristics during laser powder bed fusion (LPBF) induce elemental segregation and columnar growth, resulting in significant mechanical anisotropy and strength–ductility trade-off in titanium alloys. In order to break through this bottleneck, this work proposes a strategy of inducing equiaxation of columnar grains through recrystallization and regulating the morphology of the α″ phase (from an acicular shape to nanoparticles) to synergistically optimize the uniformity, strength and ductility of LPBF-fabricated Ti-35Nb-5Cu-xMo (Ti355x, x = 0, 1, 2, 4 wt%) alloys. The results demonstrate that LPBF-fabricated Ti355x alloys display equiaxed/columnar microstructures with significant mechanical anisotropy and strength–ductility trade-off. After …
Electrochemical Behavior Of Passive Film On Electron Beam Powder Bed Fusion Fabricated Ti-6al-4v Alloy Under Uniaxial Tensile Stress,
2026
Edith Cowan University
Electrochemical Behavior Of Passive Film On Electron Beam Powder Bed Fusion Fabricated Ti-6al-4v Alloy Under Uniaxial Tensile Stress, Hongyu Zheng, Mengdi Yan, Yun Bai, Qian Wang, Lai-Chang Zhang, Jin Xu, Hao Wang, Yingjie Ma, Shujun Li, Rui Yang
Research outputs 2022 to 2026
As medical titanium alloys inevitably undergo synergistic actions of stress and corrosion in human body, a comprehensive investigation of their relevant properties is deemed essential for ensuring their safe application. This work investigates the uniaxial tensile stress electrochemical behaviour of Ti-6Al-4V alloy fabricated by electron beam powder bed fusion under simulated implantation conditions. The results indicate that tensile stress facilitates rapid formation of a dense passive film, which contains a high proportion of high-valent oxides. As the passivation process proceeds, applied stress promotes more defects accumulation in the passive film, compromising its barrier function and reducing corrosion resistance. Under sustained …
Nanoparticle-Enabled Superplasticity In Extruded Az91 Magnesium Alloy With Elongation Exceeding 600%,
2026
Edith Cowan University
Nanoparticle-Enabled Superplasticity In Extruded Az91 Magnesium Alloy With Elongation Exceeding 600%, Bai Xin Dong, Hong Yu Yang, Xin Zhang, Feng Qiu, Qi Chuan Jiang, Lai Chang Zhang
Research outputs 2022 to 2026
No abstract provided.
Size-Tunable Tellurium Quantum Dots By Glancing Angle Deposition,
2026
University of Arkansas at Little Rock
Size-Tunable Tellurium Quantum Dots By Glancing Angle Deposition, S. M. Sayem, Salim Hussain, Fernando Maia De Oliveira, Ranjitha Kumarapuram Hariharalakshmanan, Gregory Guisbiers, Tansel Karabacak
Faculty Scholarship
Tellurium has a unique helical crystal arrangement and pronounced anisotropy that influence its electronic and optical properties at the nanoscale. This study reports the synthesis of pure tellurium quantum dots (Te QDs) on silicon wafer using glancing angle deposition (GLAD). Quasi-hemispherical dots with lateral sizes ranging from 9 to 28 nm and vertical dimensions of 6 to 10 nm were produced as a function of the deposition duration. A comparison of the dot sizes with the Bohr radii of the charge carriers indicated a regime of strong to intermediate confinement. Structural analyses confirmed the polycrystalline nature and trigonal phase of …
Decoding Surface Chemistry Effects On Polystyrene Nanoplastic Fouling In Plasma-Grafted Pes Membranes With Distinct Functional Groups,
2026
Edith Cowan University
Decoding Surface Chemistry Effects On Polystyrene Nanoplastic Fouling In Plasma-Grafted Pes Membranes With Distinct Functional Groups, Mohadeseh Najafi, Javad Farahbakhsh, Ebrahim Mahmoudi, Michael Johns, Masoumeh Zargar
Research outputs 2022 to 2026
Nanoplastic (NP) fouling remains a key challenge for ultrafiltration (UF) membranes, yet systematic, controlled comparisons of how membrane functional groups govern NP-membrane interactions are still limited. Here, the role of membrane surface chemistry was systematically investigated using a controlled comparative framework based on plasma-grafted polyethersulfone (PES) UF membranes tailored with structurally comparable methacrylate monomers bearing distinct terminal functionalities, including mono-2-(methacryloyloxy)ethyl succinate (MMES, -COOH), N-[3-(dimethylamino)propyl] methacrylamide (DMAPMA, -N(CH3)2), and [2-(methacryloyloxy)ethyl]dimethyl-(3-sulfopropyl)ammonium hydroxide (SBMA, zwitterionic). Comprehensive characterisations supported successful surface grafting while preserving the membrane substructure. Fouling and separation were assessed using polystyrene (PS) NPs having different surface chemistries, i.e., PS, PS-COOH and …
Biosensor Development In East Africa: A Systematic Review Of Technologies, Applications, Challenges, And Future Directions,
2026
Department of Molecular Biology and Biotechnology, College of Natural and Applied Sciences, University of Dar es Salaam, P.O. Box 35179, Dar es Salaam, Tanzania.
Biosensor Development In East Africa: A Systematic Review Of Technologies, Applications, Challenges, And Future Directions, Ally Mahadhy
Tanzania Journal of Science
Biosensors integrate biological recognition elements with signal transduction systems to generate quantitative or semi-quantitative analytical information and have applications across healthcare, food safety, agriculture, environmental monitoring, and wildlife health. Despite substantial global advances, biosensor development in East Africa remains poorly characterized. This systematic review, conducted according to PRISMA 2020 guidelines, evaluated published evidence from 1995 to 2025 within a predefined East African Community geographical scope. Eligibility was based on IUPAC-aligned operational criteria requiring an integrated biological recognition element, transduction mechanism, and quantitative or semi-quantitative signal output. Three locally developed biosensors met the criteria: an electrochemical nano-biosensor for schistosomiasis diagnosis in …
Efficient Acidic H2O2 Electrosynthesis Over Co Atoms Anchored On Nitrogen-Doped Hierarchical Porous Carbon,
2026
State Key Laboratory of Green and Efficient Development of Phosphorus Resources, School of Chemistry and Environmental Engineering, Wuhan Institute of Technology, Wuhan 430205, China; Hubei Key Laboratory of Processing and Application of Catalytic Materials, College of Chemistry and Chemical Engineering, Huanggang Normal University, Huanggang 438000, China
Efficient Acidic H2O2 Electrosynthesis Over Co Atoms Anchored On Nitrogen-Doped Hierarchical Porous Carbon, Xiao Huang, Zi-Hao Zhan, Hao-Xu Niu, Guan-Yu Luo, Jin-Tao Huang, Bo-Xuan Jin, De-Li Wang
Journal of Electrochemistry
The two-electron oxygen reduction reaction (2e− ORR) presents a promising route for the on-site production of hydrogen peroxide (H2O2), offering a green alternative to energy-consuming anthraquinone process. However, the high selectivity toward the competing 4e− ORR over the desired 2e− pathway leads to low Faradaic efficiency for H2O2, posing a critical challenge in catalyst design. In this work, a nitrogen-doped hollow hierarchical porous carbon with anchored Co atoms (CoN/HPC) was constructed for high-performance H2O2 production. The as-prepared Co-N/HPC catalyst showed excellent 2e− ORR performance, achieving …
Engineering Small-Sized Cations With Strong Solvation For High-Voltage Supercapacitors,
2026
College of Materials Science and Engineering, Tianjin Key Laboratory of Advanced Fibers and Energy Storage, Tiangong University, Tianjin 300387, China
Engineering Small-Sized Cations With Strong Solvation For High-Voltage Supercapacitors, Tong Huo, Pan Liu, Hao Chen, Peng Zhang, Zhen-Lei Chen, Guo-Fu Sun, Zhi-Qiang Shi, Jing Wang
Journal of Electrochemistry
Supercapacitors (SCs) have attracted much attention in the field of energy storage due to their high power density and long cycle life. However, their relatively low energy density limits their application in a wider range of fields. Methods to increase energy density include enhancing specific capacitance and extending operating voltage window. Herein, we report a novel electrolyte salt, tetramethylammonium bis(fluorosulfonyl)imide (TMA-FSI), the resulting electrolyte formed with propylene carbonate (PC), designated as TMF, exhibited a wide electrochemical stability window (ESW) of 5.09 V. On the one hand, we found that the small size of TMA+ enables it to enter the …
Dense Platinum Nanoparticles Confined In Mn-N-C Nanocages For Robust Heavy-Duty Pemfcs,
2026
School of Materials and Energy, University of Electronic Science and Technology of China, Chengdu 611731, P.R. China; School of Materials and Environmental Engineering, Chengdu Technological University, Chengdu 611730, P.R. China
Dense Platinum Nanoparticles Confined In Mn-N-C Nanocages For Robust Heavy-Duty Pemfcs, Lei Zhao, Zhen-Min Cao, Jia-Yu Zuo, Ming-Liang Yang, Hong-Yan Qiao, Jun-Song Chen, Rui Wu
Journal of Electrochemistry
High-loading Pt cathodes are essential for heavy-duty proton exchange membrane fuel cells but suffer from a critical tradeoff between ionomer sulfonate poisoning and nanoparticle instability. Herein, we report a spatial confinement strategy to encapsulate dense Pt nanoparticles (~51.8 wt%) within Mn/N-co-doped mesoporous carbon nanocages (denoted as Pt-MnNC). This architecture excludes bulky ionomers to create an ionomer-shielded environment against sulfonate poisoning, while Mn-Nx-mediated strong metal-support interactions anchor the Pt nanoparticles to prevent agglomeration and further boost durability. In the 5 × 5 cm2 membrane electrode assembly tests, the Pt-MnNC catalyst delivers an exceptional power density of 1.26 W·cm …
In Situ Electrochemical Characterization Techniques For Active Hydrogen In Electrocatalytic Nitrate Reduction To Ammonia,
2026
College of Chemistry, Sichuan University, Chengdu 610065, P. R. China
In Situ Electrochemical Characterization Techniques For Active Hydrogen In Electrocatalytic Nitrate Reduction To Ammonia, Hong-Mei Li, Mei Yi, Zhao-Yu Jin, Ming-Hao Xie, Khalid M. Omer, Yong Guo, Pan-Pan Li
Journal of Electrochemistry
Electrocatalytic nitrate reduction to ammonia (NitRR) represents a sustainable pathway that integrates environmental remediation with the production of high-value ammonia. However, the activity and selectivity of this process are limited by the generation, consumption, and dynamic equilibrium of the key transient intermediate—active hydrogen (*H). Precise modulation of *H necessitates a comprehensive understanding of its behavior, which relies fundamentally on advanced in situ electrochemical characterization techniques. However, a systematic review dedicated to the rational selection and application of in situ electrochemical techniques for the specific characterization of *H in NitRR, with clear definitions of each technique's "detectable targets, quantitative accuracy, and …
Neural Network Driven By Electrochemical Performance Data For Predicting The Discharge Termination Time Of Seawater Electrolyte-Based Metal-Air Batteries,
2026
State Key Laboratory of Tropic Ocean Engineering Materials and Materials Evaluation, School of Information and Communication Engineering, School of Electronic Science and Technology, Hainan University, Haikou 570228, Hainan, China
Neural Network Driven By Electrochemical Performance Data For Predicting The Discharge Termination Time Of Seawater Electrolyte-Based Metal-Air Batteries, Peng-Peng Shen, Yi-Chi Pan, Yu-Rong Liu, Lu-Dan Zhang, Ning Niu, Guan-Jun Wang, De-Kun Yang, Xin-Long Tian, Peng Rao
Journal of Electrochemistry
Seawater electrolyte-based metal-air batteries exhibit great promise for marine energy supply systems. However, conventional statistical analysis methods, though applicable to seawater metal-air battery lifetime prediction, have inherent limitations of insufficient prediction accuracy and large error. Herein, a deep time-series regression framework based on InceptionTime and incorporating prior-biased attention pooling is proposed to construct a nonlinear mapping between electrochemical performance sequences and the discharge termination time of catalysts. Specifically, chronoamperometric profiles are employed to extract long-term stability features, while prior knowledge derived from linear sweep voltammetry is introduced to strengthen the attention weighting over critical potential regions. Under a nested leave-one-catalyst-out …
Microwave-Assisted Synthesis Of Core-Shell Structured Pd@Pdptcufe Recessed Truncated Octahedral Nanocrystals For Multifunctional Electrocatalysis,
2026
New Energy Research Institute, School of Environment and Energy, South China University of Technology, Guangzhou 510006, Guangdong, China
Microwave-Assisted Synthesis Of Core-Shell Structured Pd@Pdptcufe Recessed Truncated Octahedral Nanocrystals For Multifunctional Electrocatalysis, De-Zhong Hu, Wen-Dan Jiang, Wei Keat Ng, Jun Yang, Xiong-Wu Kang
Journal of Electrochemistry
Developing cost-efficient and durable multifunctional electrocatalysts of hydrogen evolution reaction, oxygen reduction reaction and oxygen evolution reaction is crucial for improving energy conversion efficiency in electrolytic water splitting electrolyzer and advancing rechargeable zinc-air batteries. Polyhedral shaped nanocrystals with well-defined crystal facets represent a type of model catalysts that enables the exploration of structure-activity relationships. However, it is still very challenging to prepare alloy nanocrystals with multiple metal components due to their complicated redox potentials and mixing enthalpy. Herein, we report a rapid microwave-assisted polyol reduction method for syntheses of core-shell Pd@PdPtCu, Pd@PdPtCuNi, Pd@PdPtCuCo and Pd@PdPtCuZn octahedral nanocrystals, and recessed truncated-octahedral …
Experimental Investigation Of The Discharge Modes Of Nanosecond Pulsed Plasmas At Atmospheric Pressure,
2026
Old Dominion University
Experimental Investigation Of The Discharge Modes Of Nanosecond Pulsed Plasmas At Atmospheric Pressure, Md Ziaur Rahman
Electrical & Computer Engineering Theses & Dissertations
The generation of repeatable and stable nanosecond pulsed atmospheric pressure plasmas is important to non-thermal plasma applications in various fields including medicine, material processing, food processing, and plasma ignition for combustion. This dissertation investigates the atmospheric pressure plasma initiation and formation under 10 – 200 ns pulsed power for electrode configurations applicable for transient plasma ignition (TPI) for combustion. The impacts of pulsed power parameters, gas condition, and electrode geometry on the discharge initiation and modes (i.e., streamer, transient spark and spark) are systematically evaluated for applying TPI for combustion. We evaluated the discharge modes driven by both longer and …
Reinforcement Learning For Cathode Material Design Through Sequential Decision-Making Frameworks,
2026
Edith Cowan University
Reinforcement Learning For Cathode Material Design Through Sequential Decision-Making Frameworks, Taimoor Muzaffar Gondal, Muhammad Qasim, Yasir Arafat
Research outputs 2022 to 2026
The cathode material design is a persistent challenge in the development of next-generation rechargeable batteries. The cathode performance is critically influenced by certain key parameters, i.e., composition, crystal structures, ion transport, and degradation behaviour. Moreover, techno-economic and sustainable considerations also play a pivotal role in the viable cathode material design. In recent years, the integration of static machine learning models with conventional experimental techniques has significantly enhanced the cathode material design. However, the sequential nature of cathode discovery has not been fully captured by these techniques as they do not update their decision strategy based on prior outcomes. In this …
Validated Near-Infrared Spectroscopy And Chemometric Modelling For Rapid Quantification Of Essential Oil Yield And Α/Β-Santalol In Santalum Album L.,
2026
Edith Cowan University
Validated Near-Infrared Spectroscopy And Chemometric Modelling For Rapid Quantification Of Essential Oil Yield And Α/Β-Santalol In Santalum Album L., Muhammad Hassnain, Muhammad Rizwan Azhar
Research outputs 2022 to 2026
The sandalwood industry remains constrained by destructive, time-intensive assays for essential oil (EO) yield, composition, moisture content, and wood fraction, which limit real-time decision-making. We report a unified near-infrared spectroscopy-artificial intelligence (NIRS-AI) platform for non-destructive analytics across the Santalum album L. value chain. Reflectance and transmittance spectra from solid matrices (disks, logs, chips, and powders), oils, ethanol extracts, and CID-derived emulsions were acquired using benchtop (400–2500 nm) and portable (900–1700 nm) spectrometers and calibrated against hydrodistillation, gas chromatography, extraction, and moisture assays. Advanced chemometric modelling using AI-based machine learning techniques, including regularised regression, ensemble learning, boosting algorithms, and neural networks, …
Atomic-Scale Investigation Of Functional Molecular Systems And Graphene Nanoribbons Using Scanning Probe Microscopy,
2026
Old Dominion University
Atomic-Scale Investigation Of Functional Molecular Systems And Graphene Nanoribbons Using Scanning Probe Microscopy, A.M. Shashika D. Wijerathna
Physics Theses & Dissertations
Emerging molecular electronics, molecular devices, and carbon-based nanotechnologies increasingly rely on the precise control of molecular structures and interfaces at the atomic scale. Advancing these systems requires experimental techniques capable of resolving atomic structures, quantifying molecular behavior, and revealing the mechanisms governing nanoscale assembly. Scanning probe microscopy uniquely provides these capabilities by combining atomic-resolution imaging with local spectroscopy and manipulation. This dissertation employs ultra-high-vacuum low-temperature scanning tunneling microscopy (UHV-LT-STM) and qPlus atomic force microscopy (qPlus AFM) to address three complementary challenges: (i) atomic-scale characterization of complex supramolecular architectures, (ii) quantitative investigation of mechanically induced conformational switching of individual molecules, and …
Nanostructured Negative Electron Affinity Gallium Arsenide Photocathodes With Enhanced Quantum Efficiency And Extended Charge Lifetime For Advanced Photoinjectors,
2026
Old Dominion University
Nanostructured Negative Electron Affinity Gallium Arsenide Photocathodes With Enhanced Quantum Efficiency And Extended Charge Lifetime For Advanced Photoinjectors, Md Aziz Ar Rahman
Physics Theses & Dissertations
This dissertation presents a comprehensive experimental and computational investigation of nanostructured negative electron affinity (NEA) gallium arsenide (GaAs) photocathodes. This work was undertaken to achieve higher quantum efficiency (QE) and longer charge lifetime than conventional flat NEA GaAs electron sources commonly used in photoinjectors. Finite-Difference Time-Domain and charge-transport simulations of three types of nanostructure geometries reveal substantial QE enhancement over flat GaAs via Mie resonance mode excitation. Consequently, the truncated nanocone array (TNCA) photocathodes with heights of 400, 700, and 1000 nm were fabricated and NEA activated via Cs-NF₃ deposition. In a low-voltage ultra-high vacuum chamber with a base pressure …
Dynamic Reconstruction Engineering Of Anti-Corrosion Ni-Based Anodes For Alkaline Seawater Electrolysis,
2026
Faculty of Maritime and Transportation, Ningbo University, Ningbo, 315211; Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Advanced Fuel Cells and Electrolyzers Technology, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, 315201
Dynamic Reconstruction Engineering Of Anti-Corrosion Ni-Based Anodes For Alkaline Seawater Electrolysis, Yi-Gang Zhang, Wen-Wen Xu, Tian-Yu Zhang, Zhi-Yi Lu
Journal of Electrochemistry
Green hydrogen production via alkaline seawater electrolysis offers an environmentally sustainable and potentially cost-effective route to address both energy and climate challenges. Achieving long-term anode stability under complex ionic environments and industrial current densities remains a central bottleneck. Specifically, Ni-based anodes exhibit intense surface reconstruction during the oxygen evolution reaction, necessitating dynamic anti-corrosion strategies. This mini review systematically summarizes reconstruction engineering approaches to develop anti-corrosion Ni-based anodes of alkaline seawater electrolysis across increasingly complex ionic environments from simulated seawater to real seawater: (i) Cl– dominated; (ii) Cl– with co-existing oxyanions, and (iii) Cl– with co-existing Br– …
In Situ Stm Visualization Of Molecular Structural Evolution During Electrochemical Oxidation Coupling Of Para-Aminothiophenol On Au(111),
2026
State Key Laboratory of Physical Chemistry of Solid Surface, and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, PR China
In Situ Stm Visualization Of Molecular Structural Evolution During Electrochemical Oxidation Coupling Of Para-Aminothiophenol On Au(111), Zi-Wei Ma, Tai-Rui Wu, An-Ni Zheng, Lai-Ke Chen, Yuan-Hui Xiao, Zhao-Bin Chen, Qing-Na Zheng, Jian-Zhang Zhou, Jia-Wei Yan, De-Yin Wu
Journal of Electrochemistry
Para-aminothiophenol (PATP) is not only a widely-used probe molecule in the field of surface-enhanced Raman spectroscopy (SERS), but also an important model molecule for interfacial reactions, exhibiting distinct photo- and electro-oxidation pathways, so that PATP is selectively activated under different external fields. The evolution of products and intermediates during electrochemical oxidative coupling remains unknown. In this study, we have investigated the dynamic electrochemical oxidation process of PATP on the Au(111) surface using cyclic voltammetry, electrochemical (EC)-SERS, and in situ electrochemical scanning tunneling microscopy (EC-STM). The results showed that PATP forms an unsaturated adsorption coverage on Au(111) in an acidic solution. …
Harnessing Tio2-Based Nanofilaments: A Pathway To Enhanced Optoelectronic Performance In Dye-Sensitized And Perovskite Light Harvesters,
2026
The British University in Egypt
Harnessing Tio2-Based Nanofilaments: A Pathway To Enhanced Optoelectronic Performance In Dye-Sensitized And Perovskite Light Harvesters, Zahraa Ismail, Tarek A. Elmelegy, Hassan Nageh, Sameh Abdellatif
Mechanical Engineering
This study explores the integration of TiO2-based nanofilaments into dye-sensitized solar cells (DSSCs) and perovskite solar cells (PSCs) to enhance their optoelectronic performance. Despite the advancements in one-dimensional lepidocrocite TiO2 nanofilaments, there remains a significant gap in understanding their optical scattering mechanisms and dual applicability in both types of solar cells. We synthesized TiO2 nanofilaments and compared their performance to conventional P25 TiO2 in terms of morphology, electrical, and optical properties. The results indicate that the DSSC utilizing nanofilaments achieved a short-circuit current density of 8.2 mA/cm² and a power conversion efficiency (PCE) of 6.9%, compared to 7.1 mA/cm² and …
