Nanoscience and Nanotechnology Commons^™

Molecular Dynamics Simulations Of Self-Assemblies In Nature And Nanotechnology, Phu Khanh Tang

Dissertations, Theses, and Capstone Projects

Nature usually divides complex systems into smaller building blocks specializing in a few tasks since one entity cannot achieve everything. Therefore, self-assembly is a robust tool exploited by Nature to build hierarchical systems that accomplish unique functions. The cell membrane distinguishes itself as an example of Nature’s self-assembly, defining and protecting the cell. By mimicking Nature’s designs using synthetically designed self-assemblies, researchers with advanced nanotechnological comprehension can manipulate these synthetic self-assemblies to improve many aspects of modern medicine and materials science. Understanding the competing underlying molecular interactions in self-assembly is always of interest to the academic scientific community and industry. …

Atomistic Simulation Of Desalination, Ian David Durr

Symposium of Student Scholars

Atomistic Simulation of Desalination

Ian Durr, Matheus Prates, and Jungkyu Park

Kennesaw State University

In this research, we investigate the desalination capacity of three-dimensional (3D) carbon nanostructures using molecular dynamics simulations. 3D carbon nanostructures proposed here will filter seawater efficiently because of their multiple layers with holes of tunable sizes. The structure is designed to be flexible, allowing mechanical deformation during daily use. The 3D carbon nanostructure will still possess high thermal conductivity, enabling easy recycle through a simple heating process. Here, we employ LAMMPS, Large-scale Atomic/MolecularMassively Parallel Simulator distributed by Sandia National Laboratories to measure salt ion flux through …

Colloidal Quantum Dot (Cqd) Based Mid-Wavelength Infrared Optoelectronics, Shihab Bin Hafiz

Dissertations

Colloidal quantum dot (CQD) photodetectors are a rapidly emerging technology with a potential to significantly impact today’s infrared sensing and imaging technologies. To date, CQD photodetector research is primarily focused on lead-chalcogenide semiconductor CQDs which have spectral response fundamentally limited by the bulk bandgap of the constituent material, confining their applications to near-infrared (NIR, 0.7-1.0 um) and short-wavelength infrared (SWIR, 1-2.5 um) spectral regions. The overall goal of this dissertation is to investigate a new generation of CQD materials and devices that advances the current CQD photodetector research toward the technologically important thermal infrared region of 3-5 ?m, known as …

Feedstock Powders For Reactive Structural Materials, Daniel Hastings

Dissertations

Metals as fuels have higher energy density per unit mass or volume compared to any hydrocarbon. At the same time, metals are common structural materials. Exploring metals as reactive structural materials may combine their high energy density with attractive mechanical properties. Preparing such materials, however, is challenging. Requirements that need to be met for applications include density, strength, and stability enabling the component to sustain the structure during its desired operation; added requirements are the amount and rate of the energy release upon impact or shock. Powder technology and additive manufacturing are approaches considered for design of reactive structural materials. …

Contact Angle Measurement Using A Hele-Shaw Cell: A Proof-Of-Concept Study, Haipeng Zhang, Jacob Gottberg, Sangjin Ryu

Department of Mechanical and Materials Engineering: Faculty Publications

Contact angle is an important property to quantify the wettability of a solid surface with a liquid, which characterizes interactions of the solid-liquid pair. Generally, to measure contact angle, special instruments such as a goniometer are necessary, but they are not readily available in certain research settings. In this study, an alternative method to measure contact angle based on a Hele-Shaw cell, microscopy imaging, and image processing is suggested. In this method, a liquid drop is injected into a transparent Hele-Shaw cell, the meniscus of the drop is captured in the top or bottom view using a brightfield microscope, and …

Preparation And Electrochemical Evaluation Of Mos2/Graphene Quantum Dots As A Catalyst For Hydrogen Evolution In Microbial Electrolysis Cell, Hong-Yan Dai, Hui-Min Yang, Xian Liu, Xiu-Li Song, Zhen-Hai Liang

Journal of Electrochemistry

Microbial electrolysis cell (MEC) is a relatively new bioelectrochemical technology that produces H₂ and meanwhile treats organic wastewater. Cathode hydrogen evolution catalyst plays a key role in MEC. The doping of Graphene Quantum Dots (GQDs) into MoS₂ nanosheets can improve the catalytic activity of MoS₂ by creating abundant defect sites both in the edge plane and the basal plane, as well as enhancing the electrical conductivity. In this paper, using Na₂MoO₄ , cysteine and GQDs as raw materials, a series of MoS₂/GQDs composites were firstly synthesized via hydrothermal method, and then loaded …

Storage Performance And Mechanism Of Mose2 Nanospheres In Lithium And Magnesium Ion Batteries, Yi Peng, Wei Zhang, Fang-Zhen Zuo, Hao-Ying Lv, Kai-Jun Hong

Journal of Electrochemistry

Molybdenum diselenide (MoSe₂) is a two-dimensional (2D) transition metal dichalcogenide (TMD) material, attracting wide attention in lithium ion battery (LIB) and exhibiting great potential in next-generation magnesium ion battery (MIB) due to its unique layered structure with fast ion mobility and weak van der Waals interlayer interaction. However, the reported literatures related to MoSe₂ mainly focus on the enhancement of performance in LIB without deep storage mechanisms investigations. Meanwhile,the magnesium storage capacity and mechanisms have not been explored. In this work, MoSe₂ nanospheres were synthesized via wet chemical route and followed by annealing treatment. When used …

Molecular Interfaces And Heterogeneous Bubble Nucleation From Heated Surfaces At Nanoscale, Manish Gupta

Dissertations - ALL

Heat transfer from a solid surface to fluid occurs in numerous applications, such as boilers, refrigerators, power electronics, etc., and include various underlying phenomena of thin-film evaporation, boiling, condensation, surface wetting, and droplet evaporation. Several studies show that heat transfer can be enhanced significantly by incorporating micro and nanoscale features onto surfaces. Phase change heat transfer plays an important role in dissipating energy from hot surfaces and distributing it to bulk liquid due to high latent heat of liquids. Boiling, a phase change heat transfer phenomenon, happens when the surface is heated to a temperature above the saturation temperature of …

Design And Development Of 2d Functional Semiconductor Nanocrystals, Andrew Hunter Davis

Dissertations - ALL

Anisotropic nanocrystals (NCs) have become of keen interest in recent years, especially for applications in optoelectronic devices due to their directionally oriented emissions, narrow emission spectra, and suitable morphologies for device integration. Of the desired anisotropic NCs, two-dimensional (2D) NCs are of profound interest, due to their impressive optical and electronic properties as well as their prospective advantages towards applications in layered optoelectronic devices, such as solar cells. However, 2D NCs face many challenges, including limited synthetic derivation, as well as decreased stability and optical response, due to their large surface-to-volume ratio and reactive planar surface increasing surface defect state …

Contact Angle Measurement Using A Hele-Shaw Cell: A Proof-Of-Concept Study, Haipeng Zhang, Jacob Gottberg, Sangjin Ryu

Department of Mechanical and Materials Engineering: Faculty Publications

Contact angle is an important property to quantify the wettability of a solid surface with a liquid, which characterizes interactions of the solid-liquid pair. Generally, to measure contact angle, special instruments such as a goniometer are necessary, but they are not readily available in certain research settings. In this study, an alternative method to measure contact angle based on a Hele-Shaw cell, microscopy imaging, and image processing is suggested. In this method, a liquid drop is injected into a transparent Hele-Shaw cell, the meniscus of the drop is captured in the top or bottom view using a brightfield microscope, and …

Vortex-Oriented Ferroelectric Domains In Snte/Pbte Monolayer Lateral Heterostructures, Kai Chang, John W. D. Villanova, Jing-Rong Ji, Souvik Das, Felix Kuster, Salvador Barraza-Lopez, Paolo Sessi, Stuart S. P. Parkin

Physics Faculty Publications and Presentations

Heterostructures formed from interfaces between materials with complementary properties often display unconventional physics. Of especial interest are heterostructures formed with ferroelectric materials. These are mostly formed by combining thin layers in vertical stacks. Here the first in situ molecular beam epitaxial growth and scanning tunneling microscopy characterization of atomically sharp lateral heterostructures between a ferroelectric SnTe monolayer and a paraelectric PbTe monolayer are reported. The bias voltage dependence of the apparent heights of SnTe and PbTe monolayers, which are closely related to the type-II band alignment of the heterostructure, is investigated. Remarkably, it is discovered that the ferroelectric domains in …

Converting Parylene C Into A Thin Film Piezoelectric Material, Murali Manohar Duggina

Nanoscience and Microsystems ETDs

Thin-film piezoelectric materials are increasing in demand, but most materials are stiff ceramic materials. Polyvinylidene fluoride (PVDF) is a common polymer piezoelectric material, but it has limitations such as it requires post-processing steps to promote appropriate β-phase and it has a low operating and Curie Temperature, which limits its use in traditional microfabrication processing. The toxicity of PZT makes it incompatible with biomedical applications. Therefore, there is a need to develop a new class of polymer piezoelectric films that are compatible with current microfabrication methods. Parylene C (PA-C) is a chemical vapor deposited semi-crystalline polymer material with a nonsymmetric polymer …

Methods , Systems , And Devices Relating To Surgical End Effectors, Shane M. Farritor, Thomas Frederick, Joe Bartels

Department of Mechanical and Materials Engineering: Faculty Publications

The embodiments disclosed herein relate to various medical device components , including components that can be incorporated into robotic and / or in vivo medical devices, and more specifically including end effectors that can be incorporated into such devices. Certain end effector embodiments include various vessel cautery devices that have rotational movement as well as cautery and cutting functions while maintaining a relatively compact structure. Other end effector embodiments include various end effector devices that have more than one end effector.

Simulation Of Light Propagation Captured By Photoemission Electron Microscopy (Peem), Nabila Islam

Dissertations and Theses

The Photoemission electron microscopes (PEEM) is a powerful tool capable of synchronously imaging wave nature of light manifested by interference patterns as well as its particle nature through the energy exchange between the incident photons and the photoemitted imaging electrons. PEEM offers a non-invasive high-resolution approach for studying light propagation and interaction phenomena within a nanophotonic waveguide [7,8]. The electric field intensity variation of the interference pattern yielded by the interaction between the incident light and the guided mode coupled into the waveguide produces varying photoemission yields creating contrast in PEEM image. The guided modes cannot be excited simply by …

Robotic Surgical Devices , Systems , And Related Methods, Shane Farritor, Erik Mumm, Philip Chu, Nishant Kumar, Jason Dumpert, Yutaka Tsutano

Department of Mechanical and Materials Engineering: Faculty Publications

The embodiments disclosed herein relate to various medical device components, including components that can be incorporated into robotic and / or in vivo medical devices. Certain embodiments include various modular medical devices for in vivo medical procedures.

In Vivo Printing Of Growth Factor-Eluting Adhesive Scaffolds Improves Wound Healing, Kristo Nuutila, Mohamadmahdi Samandari, Yori Endo, Yuteng Zhang, Jacob Quint, Tannin A. Schmidt, Ali Tamayol, Indranil Sinha

Department of Mechanical and Materials Engineering: Faculty Publications

Acute and chronic wounds affect millions of people around the world, imposing a growing financial burden on patients and hospitals. Despite the application of current wound management strategies, the physiological healing process is disrupted in many cases, resulting in impaired wound healing. Therefore, more efficient and easy-to-use treatment modalities are needed. In this study, we demonstrate the benefit of in vivo printed, growth factor-eluting adhesive scaffolds for the treatment of full-thickness wounds in a porcine model. A custom-made handheld printer is implemented to finely print gelatin-methacryloyl (GelMA) hydrogel containing vascular endothelial growth factor (VEGF) into the wounds. In vitro and …

Investigation Of Iron-Nickel Based Nanoparticles As Catalysts For Oxygen Evolution Reaction (Oer), Prashant Acharya

Graduate Theses and Dissertations

Hydrogen fuel is increasingly seen as an appealing alternative by both the scientific and the industrial communities in the drive towards a clean energy future. Hydrogen, unlike fossil-based fuels, does not release carbon dioxide, a chief component of greenhouse gases, upon combustion. However, more than 95% of the hydrogen in the world is still produced by burning fossil fuels as this method is currently the only economically feasible option at a large industrial scale.

Water electrolysis shows a lot of potential in both hydrogen generation and in the storage of energy from renewable sources such as wind and sunlight. Likewise, …

Molecular Dynamics Simulations Of Ion Transport Through Electrically Stressed Biological Membranes, Federica Castellani

Biomedical Engineering Theses & Dissertations

The cell membrane is a selectively permeable barrier that controls the transport of ions, molecules, and other materials into and out of a cell. The manipulation of the cell membrane permeability is the basis for several biotechnological and biomedical applications, including electroporation. Electroporation (or electropermeabilization) occurs when the application of an external electric pulse causes water intrusion into the membrane interior and the formation of conductive transmembrane electropores. These electropores allow drugs, genetic material, and other normally impermeant molecules to enter a cell. Despite years of study, the complex mechanisms underlying this process are still not well understood. Molecular dynamics …

The Impact Of Nanopulse Treatment On The Tumor Microenvironment In Breast Cancer: Overturning The Treg Immunosuppressive Dominance, Anthony Nanajian

Biomedical Sciences Theses & Dissertations

Nanopulse treatment (NPT) is a high-power electric engineering modality that has been shown to be an effective local tumor treatment approach in multiple cancer models. Our previous studies on the orthotopic 4T1-luc breast cancer model demonstrated that NPT ablated local tumors. The treatment consequently conferred protection against a second live tumor challenge and minimized spontaneous metastasis. This study aims to understand how NPT mounts a potent immune response in a predominantly immunosuppressive tumor.

NPT changed the local and systemic dynamics of immunosuppressive cells by significantly reducing the numbers of regulatory T cells (Tregs), myeloid-derived suppressor cells (MDSCs), and tumor-associated macrophages …

Fabrication And Characterization Of Photodetector Devices Based On Nanostructured Materials: Graphene And Colloidal Nanocrystals, Wafaa Gebril

Graduate Theses and Dissertations

Photodetectors are devices that capture light signals and convert them into electrical signals. High performance photodetectors are in demand in a variety of applications, such as optical communication, security, and environmental monitoring. Among many appealing nanomaterials for novel photodetection devices, graphene and semiconductor colloidal nanocrystals are promising candidates because of their desirable and unique properties compared to conventional materials.

Photodetector devices based on different types of nanostructured materials including graphene and colloidal nanocrystals were investigated. First, graphene layers were mechanically exfoliated and characterized for device fabrication. Self-powered few layers graphene phototransistors were studied. At zero drain voltage bias and room …