Nanoscience and Nanotechnology Commons^™

Surface Enhanced Raman Spectroscopy Analysis Of Thin-Smear-Contamination On Hdd Read-Write Head, Charin Seesomdee

Chulalongkorn University Theses and Dissertations (Chula ETD)

Surface-enhanced Raman spectroscopy (SERS) is one of the most powerful analytical techniques for the identification of molecules in microelectronics industry for failure analysis protocol. In this work, a dry-processed gold nanoclusters were prepared by magnetron sputtering deposition to promote the enhancement of the Raman signal for the best intensity gain from selected common polymers found in hard disk drive as surface contamination. The optimized sputtering conditions was applied for SERS on polycarbonate (PC), polyethylene terephthalate (PET), polypropylene (PP), and high-density polyethylene (HDPE). The Raman spectrum showed the average Raman signal intensity gain at about 114%, 78%, 254%, and 226% respectively. …

Inventions Of Scientists, Engineers And Specialists From Different Countries In The Area Of Nanotechnologies. Part V, Leonid A. Ivanov, Li D. Xu, Konstantin E. Razumeev, Valentina M. Feoktistova, Petr S. Prokopiev

Information Technology & Decision Sciences Faculty Publications

Introduction. Advanced technologies impress people's imagination demonstrating the latest achievements (materials, methods, systems, technologies, devices etc.) that dramatically change the world. This, first of all, concerns nanotechnological inventions designed by scientists, engineers and specialists from different countries. Main part. The article provides an abstract overview of inventions of scientists, engineers and specialists from different countries: Russia, USA, China, Belarus, Italy. The results of the creative activity of scientists, engineers and specialists, including inventions in the field of nanotechnology and nanomaterials allow, when introduced to industry, achieving a significant effect in construction, housing and communal services, and related sectors of the …

Generation Of Excited Species In A Streamer Discharge, Shirshak K. Dhali

Electrical & Computer Engineering Faculty Publications

At or near atmospheric pressure, most transient discharges, particularly in molecular gases or gas mixture containing molecular gases, result in a space charge dominated transport called a streamer discharge. The excited species generation in such discharges forms the basis for plasma chemistry in most technological applications. In this paper, we simulate the propagation of streamers in atmospheric pressure N₂ to understand the energy partitioning in the formation of various excited species and compare the results to a uniform Townsend discharge. The model is fully two-dimensional with azimuthal symmetry. The results show a significantly larger fraction of the energy goes …

Multi-Level Analysis Of Atomic Layer Deposition Barrier Coatings On Additively Manufactured Plastics For High Vacuum Applications, Nupur Bihari

Dissertations, Master's Theses and Master's Reports

While hardware innovations in micro/nano electronics and photonics are heavily patented, the rise of the open-source movement has significantly shifted focus to the importance of obtaining low-cost, functional and easily modifiable research equipment. This thesis provides a foundation of open source development of equipment to aid in the micro/nano electronics and photonics fields.

First, the massive acceptance of the open source Arduino microcontroller has aided in the development of control systems with a wide variety of uses. Here it is used for the development of an open-source dual axis gimbal system. This system is used to characterize optoelectronic properties of …

Nondestructive Evaluation Of Aluminium Foam Panels Subjected To Impact Loading, Gabriella Epasto, Fabio Distefano, Hozhabar Mozafari, Emanoil Linul, Vincenzo Crupi

Department of Mechanical and Materials Engineering: Faculty Publications

Aluminium foam sandwich structures have excellent energy absorption capacity, combined with good mechanical properties and low density. Some of the authors of this paper proposed an innovative Metallic Foam Shell protective device against flying ballast impact damage in railway axles. A closed-cell aluminium foam was chosen for the Metallic Foam Shell device. The main goal of this study was the experimental investigation of the impact responses of aluminium foam panels. Low velocity impact tests were carried out at different energies on different types of aluminium foam panels in order to investigate the effects of some parameters, such as core thickness, …

Surface Strengthening Of Single-Crystal Alumina By High-Temperature Laser Shock Peening, Fei Wang, X. L. Yan, Lei Liu, Michael Nastasi, Yongfeng Lu, Bai Cui

Department of Mechanical and Materials Engineering: Faculty Publications

This manuscript reports a novel process of high-temperature laser shock peening (HTLSP) for surface strengthening of single-crystal ceramics such as sapphire and reveals its fundamental mechanisms. HTLSP at 1200°C can induce a high compressive residual stress on the surface of sapphire while minimize the damage of laser-driven shock waves. Transmission electron microscopy characteriza- tions revealed high dislocation densities near the surface, suggesting that plastic deformation at an ultrahigh strain rate was generated by the high shock wave pressure. The HTLSP-induced compres- sive residual stress can significantly improve the hardness and fracture toughness of sapphire, while maintain its outstanding optical transmittance.

The Role Of Microenvironmental Cues And Mechanical Loading Milieus In Breast Cancer Cell Progression And Metastasis, Brandon D. Riehl, Eunju Kim, Tasneem Bouzid, Jung Yul Lim

Department of Mechanical and Materials Engineering: Faculty Publications

Cancer can disrupt the microenvironments and mechanical homeostatic actions in multiple scales from large tissue modification to altered cellular signaling pathway in mechanotransduction. In this review, we highlight recent progresses in breast cancer cell mechanobiology focusing on cell-microenvironment interaction and mechanical loading regulation of cells. First, the effects of microenvironmental cues on breast cancer cell progression and metastasis will be reviewed with respect to substrate stiffness, chemical/topographic substrate patterning, and 2D vs. 3D cultures. Then, the role of mechanical loading situations such as tensile stretch, compression, and flow-induced shear will be discussed in relation to breast cancer cell mechanobiology and …

Ligand Assisted Growth Of Perovskite Single Crystals With Low Defect Density, Ye Liu, Xiaopeng Zheng, Yanjun Fang, Ying Zhou, Zhenyi Ni, Xun Xiao, Shangshang Chen, Jinsong Huang

Department of Mechanical and Materials Engineering: Faculty Publications

A low defect density in metal halide perovskite single crystals is critical to achieve high performance optoelectronic devices. Here we show the reduction of defect density in per[1]ovskite single crystals grown by a ligand-assisted solution process with 3‐(decyldimethy[1]lammonio)‐propane‐sulfonate inner salt (DPSI) as an additive. DPSI ligands anchoring with lead ions on perovskite crystal surfaces not only suppress nucleation in solution, but also regulate the addition of proper ions to the growing surface, which greatly enhances the crystal quality. The grown CH₃NH₃PbI₃ crystals show better crystallinity and a 23-fold smaller trap density of 7 × 10 …

Social Connectedness And Negative Affect Uniquely Explain Individual Differences In Response To Emotional Ambiguity, Maital Neta, Rebecca L. Brock

Department of Mechanical and Materials Engineering: Faculty Publications

Negativity bias is not only central to mood and anxiety disorders, but can powerfully impact our decision-making across domains (e.g., financial, medical, social). This project builds on previous work examining negativity bias using dual-valence ambiguity. Specifically, although some facial expressions have a relatively clear negative (angry) or positive valence (happy), surprised expressions are interpreted negatively by some and positively by others, providing insight into one’s valence bias. Here, we examine putative sources of variability that distinguish individuals with a more negative versus positive valence bias using structural equation modeling. Our model reveals that one’s propensity toward negativity (operationalized as temperamental …

Direct Numerical Simulation Of A Pulsatile Flow In A Stenotic Channel Using Immersed Boundary Method, Siamak Mirfendereski, Jae Sung Park

Department of Mechanical and Materials Engineering: Faculty Publications

A three-dimensional direct numerical simulation model coupled with the immersed boundary method has been developed to simulate a pulsatile flow in a planar channel with single and double one-sided semicircular constrictions. For relevance to blood flow in large arteries, simulations have been performed at Reynolds numbers of 750 and 1000. Flow physics and resultant wall shear stress (WSS)-based hemodynamic parameters are presented. The instantaneous vortex dynamics, mean flow characteristics, and turbulent energy spectra are evaluated for flow physics. Subsequently, three WSS-based parameters, namely the time-averaged WSS, oscillatory shear index, and relative residence time, are calculated over the stenotic wall and …

Large-Scale Synthesis Of Compressible And Re-Expandable Three-Dimensional Nanofiber Matrices, Alec Mccarthy, Lorenzo Saldana, Daniel Mcgoldrick, Johnson V. John, Mitchell Kuss, Shixuan Chen, Bin Duan, Mark A. Carlson, Jingwei Xie

Department of Mechanical and Materials Engineering: Faculty Publications

Due to their biomimetic properties, electrospun nanofibers have shown great potential in many biomedical fields. However, traditionally-produced nanofibers are typically two-dimensional (2D) membranes limiting their applications. Herein, we report a large-scale synthesis of compressible and reexpandable three-dimensional (3D) nanofiber matrices for potential biomedical applications. The reproducible mass production of such matrices is achieved using a multiple-emitter electrospinning machine with a controlled environment (e.g., temperature, humidity, and air flow rate) followed by an innovative gas-foaming expansion. The modified 20-emitter circular array with 3D-printed needle caps is capable of maintaining stable Taylor cones under extremely high flow rates. The introduction of such …

Assembly Of Close-Packed Ferroelectric Polymer Nanowires Via Interface-Epitaxy With Res2, Dawei Li, Shuo Sun, Kun Wang, Zahra Ahmadi, Jeffrey E. Shield, Stephen Ducharme, Xia Hong

Department of Mechanical and Materials Engineering: Faculty Publications

The flexible, transparent, and low-weight nature of ferroelectric polymers makes them promising for wearable electronic and optical applications. To reach the full potential of the polarization-enabled device functionalities, large-scale fabrication of polymer thin films with well-controlled polar directions is called for, which remains a central challenge. The widely exploited Langmuir–Blodgett, spin-coating, and electrospinning methods only yield polymorphous or polycrystalline films, where the net polarization is compromised. Here, an easily scalable approach is reported to achieve poly(vinylidene fluoride-trifluoroethylene) P(VDF-TrFE) thin films composed of close-packed crystalline nanowires via interface-epitaxy with 1T′-ReS₂. Upon controlled thermal treatment, uniform P(VDF-TrFE) films restructure into …

Reducing Corrosion Of Additive Manufactured Magnesium Alloys By Interlayer Ultrasonic Peening, M. P. Sealy, R. Karunakaran, S. Ortgies, G. Madireddy, A. P. Malshe, K. P. Rajurkar

Department of Mechanical and Materials Engineering: Faculty Publications

Additive manufad (AM) magn alloys corrode rapidly due to tensile stress and coarse microstructures. Cyclically combining (hybridizing) additive manufacturing with interlayer ultrasonic peening was proposed as a solution to improve corrosion resistance of additive manufactured magnesium WE43 alloy through strengthening mechanisms and compressive residual stress. Applying interlayer peening work hardened discrete layers and formed a glocal integrity of regional grain refinement and subsurface compressive residual stress barriers. Tensile residual stress that typically accelerates corrosion decreased 90%. Results showed time-resolved control over corrosion was attainable by interlayer peening, and local corrosion within print cells decreased 57% with respect to as-printed WE43.

Ultra-Fast Charging In Aluminum-Ion Batteries: Electric Double Layers On Active Anode, Xuejing Shen, Tao Sun, Lei Yang, Alexey Krasnoslobodtsev, Renat F. Sabirianov, Michael P. Sealy, Wai-Ning Mei, Zhanjun Wu, Li Tan

Department of Mechanical and Materials Engineering: Faculty Publications

With the rapid iteration of portable electronics and electric vehicles, developing high-capacity batteries with ultra-fast charging capability has become a holy grail. Here we report rechargeable aluminum-ion batteries capable of reaching a high specific capacity of 200 mAh g^−1. When liquid metal is further used to lower the energy barrier from the anode, fastest charging rate of 10⁴ C (duration of 0.35 s to reach a full capacity) and 500% more specific capacity under high-rate conditions are achieved. Phase boundaries from the active anode are believed to encourage a high-flux charge transfer through the electric double layers. As …

Twinning-Assisted Dynamic Adjustment Of Grain Boundary Mobility, Qishan Huang, Qi Zhu, Yingbin Chen, Mingyu Gong, Jixue Li, Ze Zhang, Wei Yang, Jian Wang, Haofei Zhou, Jiangwei Wang

Department of Mechanical and Materials Engineering: Faculty Publications

Grain boundary (GB) plasticity dominates the mechanical behaviours of nanocrystalline materials. Under mechanical loading, GB configuration and its local deformation geometry change dynamically with the deformation; the dynamic variation of GB deformability, however, remains largely elusive, especially regarding its relation with the frequently-observed GB-associated deformation twins in nanocrystalline materials. Attention here is focused on the GB dynamics in metallic nanocrystals, by means of well-designed in situ nanomechanical testing integrated with molecular dynamics simulations. GBs with low mobility are found to dynamically adjust their configurations and local deformation geometries via crystallographic twinning, which instantly changes the GB dynamics and enhances the …

Electron Microscopy Observation Of Electric Field-Assisted Sintering Of Stainless Steel Nanoparticles, Fei Wang, Qin Zhou, Xing-Zhong Li, Yongchul Yoo, Michael Nastasi, Bai Cui

Department of Mechanical and Materials Engineering: Faculty Publications

The intrinsic role of electrical current on the electric field-assisted sintering (EFAS) process of stainless steel 316L nanoparticles has been revealed by both ex situ and in situ experiments. A novel device on the Si chip has been designed and fabricated to fit into the sample holder of a transmission electron microscope for these experiments. The evolution of nanoparticle morphology and microstructures during the EFAS process has been studied using scanning electron microscopy and transmission electron microscopy, which has been combined with the simultaneous measurement of the electric voltage and current changes. A preliminary four-stage mechanism for the EFAS process …

Development Of Light Actuated Chemical Delivery Platform On A 2-D Array Of Micropore Structure, Hojjat Rostami Azmand, Hojjat Rostami Azmand

Dissertations and Theses

Localized chemical delivery plays an essential role in the fundamental information transfers within biological systems. Thus, the ability to mimic the natural chemical signal modulation would provide significant contributions to understand the functional signaling pathway of biological cells and develop new prosthetic devices for neurological disorders. In this paper, we demonstrate a light-controlled hydrogel platform that can be used for localized chemical delivery in a high spatial resolution. By utilizing the photothermal behavior of graphene-hydrogel composites confined within micron-sized fluidic channels, patterned light illumination creates the parallel and independent actuation of chemical release in a group of fluidic ports. The …

Ultrafast Thermal Modification Of Strong Coupling In An Organic Microcavity, Bin Liu, Vinod M. Menon, Matthew Y. Sfeir

Publications and Research

There is growing interest in using strongly coupled organic microcavities to tune molecular dynamics, including the electronic and vibrational properties of molecules. However, very little attention has been paid to the utility of cavity polaritons as sensors for out-of-equilibrium phenomena, including thermal excitations. Here, we demonstrate that non-resonant infrared excitation of an organic microcavity system induces a transient response in the visible spectral range near the cavity polariton resonances. We show how these optical responses can be understood in terms of ultrafast heating of electrons in the metal cavity mirror, which modifies the effective refractive index and subsequently the strong …

Detection Of Subsurface, Nanometer-Scale Crystallographic Defects By Nonlinear Light Scattering And Localization, Farbod Shafiei, Tommaso Orzali, Alexey Vert, Mohammad-Ali Miri, Pui Yee Hung, Man Hoi Wong, Andrea Alù, Gennadi Bersuker, Michael C. Downer

Publications and Research

Heteroepitaxial crystalline films underlie many electronic and optical technologies but are prone to forming defects at their heterointerfaces. Atomic-scale defects such as threading dislocations that propagate into a film impede the flow of charge carriers and light degrading electrical/optical performance of devices. Diagnosis of subsurface defects traditionally requires time-consuming invasive techniques such as cross-sectional transmission electron microscopy. Using III–V films grown on Si, noninvasive, bench-top diagnosis of subsurface defects have been demonstrated by optical second-harmonic scanning probe microscope. A high-contrast pattern is observed of subwavelength “hot spots” caused by scattering and localization of fundamental light by defect scattering sites. Size …

Perovskite Thin Films Annealed In Supercritical Fluids For Efficient Solar Cells, Gilbert Annohene

Theses and Dissertations

In the field of photovoltaics, scientists and researchers are working fervently to produce a combination of efficient, stable, low cost and scalable devices. Methylammonium lead trihalide perovskite has attracted intense interest due to its high photovoltaic performance, low cost, and ease of manufacture. Their high absorption coefficient, tunable bandgap, low-temperature processing, and abundant elemental constituent provide innumerable advantages over other thin film absorber materials. Since the perovskite film is the most important in the device, morphology, crystallization, compositional and interface engineering have been explored to boost its performance and stability. High temperatures necessary for crystallization of organic-inorganic hybrid perovskite films …