Nanoscience and Nanotechnology Commons^™

Study Of Immobilizing Cadmium Selenide Quantum Dots In Selected Polymers For Application In Peroxyoxalate Chemiluminescence Flow Injection Analysis, Christopher S. Moore

Electronic Theses and Dissertations

Two batches of CdSe QDs with different sizes were synthesized for immobilizing in polyisoprene (PI), polymethylmethacrylate (PMMA), and low-density polyethylene (LDPE). The combinations of QDs and polymer substrates were evaluated for their analytical fit-for-use in applicable immunoassays. Hydrogen peroxide standards were injected into the flow injection analyzer (FIA) constructed to simulate enzyme-generated hydrogen peroxide reacting with bis-(2,4,6-trichlorophenyl) oxalate.

Linear correlations between hydrogen peroxide and chemilumenscent intensities yielded regression values greater than 0.9750 for hydrogen peroxide concentrations between 1.0 x 10^-4 M and 1.0 x 10^-1 M. The developed technique’s LOD was approximately 10 ppm. Variability of the prepared …

Metal Oxide Nanocomposite Nanoliter Reaction Chamber Fabrication And Applications For Harsh Environment Gas Sensing, Michael C. Briggs

Nanoscale Science & Engineering (discontinued with class year 2014)

In order to perform research at the College of Nanoscale Science and Engineering, funding for the desired research is required. Undergraduates get around that by working under a graduate student or professor who is currently funded. For those who seek funding, they receive it by submitting a grant proposal stating the motivation for research, the background, and previous research done to support this new endeavor, as well as future research plans that will be possible with funding. These grant proposals follow certain formats depending on where the principal investigator is seeking funding. As part of the honors requirement for the …

Advancements Towards Single Site Information Storage And Processing Using Hfo2 Resistive Random Access Memory (Reram), Michael Quinlan Hovish

Nanoscale Science & Engineering (discontinued with class year 2014)

Resistive Random Access Memory (ReRAM) has attracted much attention among researchers due to its fast switching speeds, lower switching voltages, and feasible integration into industry compatible CMOS processing. These characteristics make ReRAM a viable candidate for next-generation Non- Volatile Memory. Transition-Metal-Oxides have been proven to be excellent materials for ReRAM applications. This work investigates the effect of various, post-deposition anneals (PDA) on the switching parameters of Ni/Cu/HfO2/TiN Resistive Memory Devices (RMD). Results are presented in the form of a Small Business Innovation Research (SBIR) grant proposal. The use of the SBIR format emphasizes understanding of the experimental design, commercial viability, …

High Element Gold Nanorod Plasmonic Sensing Array For Harsh Environment Gas Detection Grant Proposal, Brian Janiszweski

Nanoscale Science & Engineering (discontinued with class year 2014)

In order to acquire funding for scientific endeavors very specific grant proposal documents must be written and submitted. The following is an example of that. This project was very useful because my peers and I will undoubtedly have to write a grant of some type or another in our future careers. This specific proposal is a mock grant requesting money from the National Science Foundation to fund research into a gas sensor that utilizes gold nanostructures as sensing mechanism. The research done behind this project was performed over three semesters in the lab of Dr. Michael Carpenter form the College …

Generation Of Saws In Ghz Range For Nanoscale Particle Removal, Leigh Kent Lydecker Iv

Nanoscale Science & Engineering (discontinued with class year 2014)

In order to do research at CNSE, funding is required. Funding is achieved by submitting a grant proposal stating the background of the problem one hopes to address, a proposed solution, and sufficient information to prove success is achievable. These grant proposals follow a very particular format, which is extremely valuable to be familiar with in the scientific field of study. Therefore, learning to write a grant proposal for some of the work I have done during my undergraduate studies was proved a valuable learning experience. The following grant proposal is based on the work I have done during the …

Neoadjuvant Therapy For Ovarian Cancer Using Bioglycogentm Nanoparticles Sbir Grant Proposal, Alexander E. Talamo

Nanoscale Science & Engineering (discontinued with class year 2014)

Project Summary Technical Abstract This Small Business Innovation Research Phase I project, presented by Talamo Inc., is to test an ovarian cancer therapeutic delivery system, comprised of a nanoscale biocompatible vesicle that carries a bioactive small interfering RNA molecule (siRNA), in vivio in mice. The siRNA has shown to reduce the expression of an enzyme (Sod2) that is highly expressed in multiple ovarian cancer types. The reduced expression of Sod2 will allow the tumor to become increasingly susceptible to chemotherapy agents, while simultaneously diminishing tumor progression. Research has proved that the nanoscale vesicle is non-toxic and in combination with siRNA …

Electrical Characterization Of Gold Functionalized Dna Origami Nanotubes, Christopher Vinhtroung Buu

Boise State University Theses and Dissertations

Conductivity types (i.e., insulator, semiconductor, and conductor) can be tuned by varying the size of metallic nanoparticles. DNA origami, a molecular self-assembly technique, has promise to programmatically self-assemble nanoparticles (NPs) with nanometer precision. The work presented here demonstrates the programmatic self-assembly of AuNPs on DNA origami nanotubes (NTs). DNA origami NTs were also functionalized with positively charged Au clusters. DNA origami NTs, both bare and functionalized with Au, were electrically characterized using DC current-voltage (DC-IV) measurements. The measurements showed that bare, undecorated DNA NTs behaved as an insulator, whereas linear, ohmic conductivity was observed for Au enhanced Au decorated NTs. …

New Effects Of Aging And Lattice Intercalation On Surface Properties Of Titanate Nanobelts, Roger Williams

Graduate Theses and Dissertations

Titanate nanobelts (NBs) have structural characteristics beyond that of clays. Due to a negatively charged lattice matrix of edge-shared TiO6-octahedra, the location of intercalated cations within the interlayer space may dictate the charge-conductions. This environment may in turn govern the lattice-framework's stability and surface properties, based upon our preliminary

data.

On that basis, these nanomaterials have been found in our lab to possess superb biological compatibility that is closely related to the types of the intercalated cations. In addition, a prolonged agitation was proven to enable us to manipulate the titanate NBs' length. In a parallel study, a ripening was …

Directed Percolation And The Abstract Tile Assembly Model, Tyler Garrett Moore

Graduate Theses and Dissertations

Self-assembly is a process by which simple components build complex structures through local interactions. Directed percolation is a statistical physical model for describing competitive spreading processes on lattices. The author describes an algorithm which can transform a tile assembly system in the abstract Tile Assembly Model into a directed percolation problem, and then shows simulations of the aTAM which support this algorithm. The author also investigates two new constructs designed for Erik Winfree's abstract Tile Assembly Model called the NULL tile and temperature 1.5. These constructs aid the translation between self-assembly and directed percolation and may assist self-assembly researchers in …

Synthesis And Characterization Of Iron Pyrite Nanocrystals For Photovoltaic Devices, Scott Curtis Mangham

Graduate Theses and Dissertations

Iron pyrite nanocrystals have been synthesized using a hot-injection method with a variety of amines and characterized with properties necessary for photovoltaic devices. The iron pyrite nanocrystals were characterized using X-ray diffraction, scanning electron microscopy, transmission electron microscopy, optical absorption, micro-Raman, and micro-Photoluminescence. The optical absorbance spectra showed the large absorption in the visible and near infrared spectral range for the nanocrystals as well as to show the band gap. The face-centered cubic crystal structure of the iron pyrite nanocrystals was shown by matching the measured X-ray diffraction pattern to a face-centered cubic iron pyrite reference pattern. Using Bragg's law …

Iii-V Bismide Optoelectronic Devices, Dongsheng Fan

Graduate Theses and Dissertations

This dissertation explores modeling, molecular beam epitaxy growth, and fabrication of III-V bismide optoelectronic devices, which are of great importance in modern applications of telecommunication, gas sensing, environment monitoring, etc. In the current room-temperature continuous-wave operational GaSb-based type-I InGaAsSb/AlGaInAsSb quantum well laser diodes in 3-4 um mid-wavelength range, the lasing wavelength and performance of the devices are limited due to the lack of hole confinement in the active regions. In this dissertation, a novel GaSb-based GaInAsSbBi material is proposed to replace the conventional InGaAsSb material in the quantum well region, which enables the laser diodes achieve up to 4 µm …

Design And Fabrication Of Nanofluidic Systems With Integrated Sensing Electrodes For Rapid Biomolecule Characterization, Taylor Bradley Busch

Graduate Theses and Dissertations

A transparent nanofluidic system with embedded sensing electrodes was designed and fabricated by integrating Atomic Force Microscopy (AFM) nanolithography, Focused Ion Beam (FIB) milling and metal deposition, and standard microfabrication processing. The fabrication process started with the evaporation of chrome/gold (Cr/Au) onto a Pyrex 7740 wafer followed by photolithography and wet etching of the microchannels. The wafer was patterned a second time to form Au microelectrodes with 15-45 micrometer separation gaps in the nanochannel region. Sensing electrodes (up to one micron wide) were then deposited using FIB to bridge the gaps. The nanochannels were realized through both AFM nanolithography and …

The Geometry And Sensitivity Of Ion-Beam Sculpted Nanopores For Single Molecule Dna Analysis, Ryan Connor Rollings

Graduate Theses and Dissertations

In this dissertation, the relationship between the geometry of ion-beam sculpted solid-state nanopores and their ability to analyze single DNA molecules using resistive pulse sensing is investigated. To accomplish this, the three dimensional shape of the nanopore is determined using energy filtered and tomographic transmission electron microscopy. It is shown that this information enables the prediction of the ionic current passing through a voltage biased nanopore and improves the prediction of the magnitude of current drop signals when the nanopore interacts with single DNA molecules. The dimensional stability of nanopores in solution is monitored using this information and is improved …

Design And Fundamental Understanding Of Minimum Quantity Lubrication (Mql) Assisted Grinding Using Advanced Nanolubricants, Parash Kalita

Graduate Theses and Dissertations

Abrasive grinding is widely used across manufacturing industry for finishing parts and components requiring smooth superficial textures and precise dimensional tolerances and accuracy. Unlike any other machining operations, the complex thermo-mechanical processes during grinding produce excessive friction-induced energy consumption, heat, and intense contact seizures. Lubrication and cooling from grinding fluids is crucial in minimizing the deleterious effects of friction and heat to maximize the output part quality and process efficiency. The conventional flood grinding approach of an uneconomical application of large quantities of chemically active fluids has been found ineffective to provide sufficient lubrication and produces waste streams and pollutants …

Plasmonic Nanostructures For The Absorption Enhancement Of Silicon Solar Cells, Nathan Matthias Burford

Graduate Theses and Dissertations

In this work, computational investigation of plasmonic nanostructures was conducted using the commercial finite element electromagnetics solver Ansys® HFSS. Arrays of silver toroid nanoparticles located on the surface of an amorphous silicon thin-film absorbing layer were studied for particle sizes ranging from 20 nm to 200 nm in outer diameter. Parametric optimization by calculating an approximation of the photocurrent enhancement due to the nanoparticles was performed to determine optimal surface coverage of the nanoparticles. A comparison was made between these optimized nanotoroid arrays and optimized nanosphere arrays based on spectral absorption enhancement and potential photocurrent enhancement in an amorphous silicon …

Quantum Criticality Analysis By Finite-Size Scaling And Exponential Basis Sets, Fahhad H. Alberbi, Sabre Kais

Birck and NCN Publications

We combine the finite-size scaling method with the mesh-free spectral method to calculate quantum critical parameters for a given Hamiltonian. The basic idea is to expand the exact wave function in a finite exponential basis set and extrapolate the information about system criticality from a finite basis to the infinite basis set limit. The used exponential basis set, though chosen intuitively, allows handling a very wide range of exponential decay rates and calculating multiple eigenvalues simultaneously. As a benchmark system to illustrate the combined approach, we choose the Hulthen potential. The results show that the method is very accurate and …

Broadband Enhancement Of Spontaneous Emission From Nitrogen-Vacancy Centers In Nanodiamonds By Hyperbolic Metamaterials, Mikhail Y. Shalaginov, Satoshi Ishii, J. Liu, Joseph Irudayaraj, A. Lagutchev, Alexander V. Kildishev, Vladimir M. Shalaev

Birck and NCN Publications

We experimentally demonstrate a broadband enhancement of emission from nitrogen-vacancy centers in nanodiamonds. The enhancement is achieved by using a multilayer metamaterial with hyperbolic dispersion. The metamaterial is fabricated as a stack of alternating gold and alumina layers. Our approach paves the way towards the construction of efficient single-photon sources as planar on-chip devices. (C) 2013 AIP Publishing LLC.

Pre-Breakdown Evaluation Of Gas Discharge Mechanisms In Microgaps, Abbas Semnani, Ayyaswamy Venkattraman, Alina A. Alexeenko, Dimitrios Peroulis

Birck and NCN Publications

The individual contributions of various gas discharge mechanisms to total pre-breakdown current in microgaps are quantified numerically. The variation of contributions of field emission and secondary electron emission with increasing electric field shows contrasting behavior even for a given gap size. The total current near breakdown decreases rapidly with gap size indicating that microscale discharges operate in a high-current, low-voltage regime. This study provides the first such analysis of breakdown mechanisms and aids in the formulation of physics-based theories for microscale breakdown. (C) 2013 AIP Publishing LLC

An Electrochemical Impedance Spectroscopic Study Of Cuf2/Moo3/C Cathode Composites, Yue-Li Shi, Nan Wu, Ming-Fang Shen, Jia-Qun Dong, Quang-Chao Zhuang, Li Jiang

Journal of Electrochemistry

Composite electrode of CuF₂/MoO₃/C was fabricated through high energy mechanical milling. The properties of CuF₂/MoO₃/C were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), high resolution transmission electron microscopy (TEM), galvanostatic charge-discharge measurements, cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The results showed that the grain sizes of CuF₂ and MoO₃ after milling were 200 ~ 300 nm, and the initial discharge capacity of CuF₂/MoO₃/C was 647 mAh·g^-1 at room temperature and at a current density of 10 mA·g^-1. However, the …

Preparation And Catalytic Properties Of Feco Alloy Nanocatalyst, Ming-Xuan Li, Jie-Lian Ou, Sheng-Pei Chen, Peng Wang, Bin-Bin Xu, Shi-Gang Sun

Journal of Electrochemistry

The FeCo alloy nanoparticles were electrodeposited on glassy carbon electrode by chronoamperometry and were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The results showed that the shapes of FeCo nanoparticles were cubes with an average size of 65 nm. The atom ratio of Fe and Co is 1:1. As indicated from the pattern of selected area electron diffraction (SAED), the FeCo cubic nanoparticles were single crystal which belonged to body-centered cubic with an interval of 0.201 nm referring to the (110) facets of FeCo alloy. The FeCo cubic nanoparticles exhibited the enhanced electrocatalytic …