Nanoscience and Nanotechnology Commons^™

Investigation Of Electromigration Stresses Of Advanced Node Conductors Through Pulsed Power Behavior, Mohd Mueen Ul Islam Mattoo

Electronic Theses & Dissertations (2024 - present)

The microelectronics industry continues to put a heavy focus on preventing electromigration (EM) failures at advanced node conductors. The continuous scaling coupled with higher operating current densities further accentuate the problem. Most of the electromigration testing in the industry is performed with DC currents to evaluate the electromigration reliability of metal interconnects. However, most of the real-world applications operate using a pulsed current rather than a constant direct current. EM testing with pulsed direct current (PDC) show interesting results with how the current induced stress gradient evolves in absence of the electromigration driving force. It is generally assumed that the …

Novel Silicon Anodes For Improved Lithium Ion Battery, Amir Hegazy

Electronic Theses & Dissertations (2024 - present)

Li-ion battery (LIB) have been dominating the development of electronics shaping our daily life owing to their good specific and volumetric energy densities. However, the technological advancement calls for higher energy, safer, lower cost, and large-scale manufacturing batteries.

Silicon is considered an excellent candidate for anode material for higher energy LIB. This thesis examines the potential of silicon as an anode in high-capacity LIBs where the role of silicon is studied at the frontside (FS) and the backside (BS) of the anode. At the frontside, the effect of deposition of silicon on graphite on the battery performance was studied. Graphite …

A Potentially Fruitful Path Toward A Cleaner And Safer Environment: Mxenes Uses In Environmental Remediation, Ali Mohammad Amani, Milad Abbasi, Atena Najdian, Farzaneh Mohamadpour, Seyed Reza Kasaee, Hesam Kamyab, Shreeshivadasan Chelliapan, Hanieh Ardeshiri, Lobat Tayebi, Ehsan Vafa, Sarah Mosleh-Shirazi, Alireza Jahanbin, Saravanan Rajendran, Daniel Simancas-Racines

Electrical & Computer Engineering Faculty Publications

The rapid industrialization of the world has resulted in severe environmental pollution, necessitating the development of new materials such as pollution remediation. Two-dimensional (2D) MXenes have emerged as a promising family of materials due to their unique physicochemical properties, making them ideal for environmental remediation. The article sheds light on the new opportunities of MXenes in the removal of organic and inorganic contaminants, including organic dyes, pharmaceuticals, heavy metals, radionuclides, and gas pollutants. MXenes also show excellent performance in photocatalytic degradation, adsorption, and microbial inactivation with environmental safety. Moreover, their application in recovering valuable elements from waste streams is also …

Multifunctional Nanoscale Pigments: Emerging Risks And Circular Strategies For A Sustainable Future, Ajay Vikram Singh, Preeti Bhardwaj, Vimal Kishore, Sunil Choudhary, Akihiko Hirose, Neha Gupta, Madleen Busse, Swarn Lata Singh, Christopher J. Osgood

Biological Sciences Faculty Publications

The substantial penetration of nanoscale pigments into a range of sectors has changed the dynamics of industries such as medical, material science, and many more. Nonetheless, their persistence in the environment and probable adverse impacts on health require that an assessment of such risks be formulated considering the One Health perspective. This viewpoint considers the crossing of boundaries of progress in the nanotechnology of nanoscale pigments with environmental, animal, and human health and emphasizes the significance of collaborative activity. Traditional perspectives explain the distribution of pigment history, while the nanotechnology of today's accessibility poses problems regarding utilization, toxicities, and interactions …

Cellax Nanoparticles: Taxane Nanoformulations For Solid Tumor Targeting, Lobat Tayebi, Mehran Alavi

Electrical & Computer Engineering Faculty Publications

Nanoparticles (NPs), specifically polymer-modified NPs, have illustrated unique therapeutic advantages compared to bulk materials. Cellax NPs have provided a promising approach to cancer therapy by improving drug delivery, targeting the tumor microenvironment, and potentially overcoming drug resistance, all while reducing overall toxicity compared to traditional taxane treatment. By the flash nanoprecipitation (FNP) method, docetaxel and cabazitaxel have been formulated with polyethylene glycol (PEG) modified-acetylated carboxymethylcellulose (CMC) polymer to increase biocompatibility, bioavailability, specific targeting, and modulate the tumor microenvironment. However, there are some challenges and clinical limitations related to this formulation, encompassing optimum targeted delivery to tumors, overcoming biological barriers, such …

Advancing 4h-Silicon Carbide Power Device Technology Through Improved Device Design, Performance And Reliability, Stephen A. Mancini

Electronic Theses & Dissertations (2024 - present)

The work presented in this document focuses on advancing the overall design, performance, and reliability of 4H-SiC power devices through various design architectures and processing strategies. Power devices serve as an efficient way to control the flow of power and thus are utilized throughout a vast number of different systems. These systems accommodate various current and voltage ratings to support applications such as personal electronics, electric vehicle components, fast chargers, renewable energy solutions, and energy storage systems. As the demand for these applications grows alongside global electrification and sustainability efforts, minimizing power losses becomes increasingly important. Therefore, developing efficient and …

Al(X)In(Y)Ga(1−X−Y)N-Based Monolithically Integrated Ir Detector-Visible Emitter Device, Alireza Lanjani

Electronic Theses & Dissertations (2024 - present)

III-Nitride material system has been widely used in electronic, sensing, optoelectronic, and power device applications. Owing to the wide and tunable bandgap of this material system and the realization of relatively high conductivity p-type Mg-doped GaN films, considerable research over the past few decades has focused on applications based on wide bandgaps, such as blue and ultraviolet (UV) light-emitting diodes (LEDs), laser diodes, visible-blind and solar-blind photodetectors. The other side of the spectrum, infrared (IR) has remained considerably less explored.

To exploit III-Nitrides for IR detection applications, the quantum well infrared photodetector (QWIP) design is employed. In the QWIP …

Advancing 4h-Silicon Carbide Power Mosfets Through Three-Dimensional Technology Computer Aided Design Optimization, Skylar A. Deboer

Electronic Theses & Dissertations (2024 - present)

This research contributes to the advancement of 1.2 kV 4H-Silicon Carbide (SiC) Metal-Oxide-Semiconductor Field-Effect Transistors (MOSFETs) through the development and implementation of sophisticated three-dimensional Technology Computer-Aided Design (3D TCAD) methodologies. These advanced simulation techniques enable comprehensive evaluation of innovative unit cell architectures that remain inaccessible to conventional two-dimensional (2D) TCAD approaches. By leveraging these 3D simulation capabilities, this work facilitates significant improvements in both the performance and reliability of next-generation wide-bandgap power devices.

Power devices convert electrical energy between different forms throughout the power grid making them essential in applications ranging from personal electronics, electric vehicles, renewable energy systems, industrial …

Flexible Hybrid Self-Powered Piezo-Triboelectric Nanogenerator Based On Bto-Pvdf/Pdms Nanocomposites For Human Machine Interaction, Wentao Dong, Mengyun Li, Chang Chen, Kun Xie, Jinhua Hong, Lin Yang

Civil & Environmental Engineering Faculty Publications

As flexible and wearable electronics play more and more important role in smart watches, smart glass and virtual reality, and the power supply to the wearable electronics have been revealed more attentions for long-term usage and continuous healthy monitoring. To overcome the challenge, flexible self-powered BTO-PVDF/PDMS piezoelectric-triboelectric electric hybrid generators (BPP-HNG) are developed to human gesture monitoring and human machine interaction (HMI) application without external power supply. BPP-HNG based on BTO-PVDF and PDMS films are prepared by sol-gel and spin-coating method. When the BTO content is 20 wt.%, BPP-HNG exhibits better electrical performance with an output voltage of 20.51 V. …

All-Solid-State Sodium-Ion Batteries: A Leading Contender In The Next-Generation Battery Race, Rui-Jie Zhu, Ze-Chen Li, Wei Zhang, Akira Nasu, Hiroaki Kobayashi, Masaki Matsui

Journal of Electrochemistry

All-solid-state lithium-ion batteries (LIBs) using ceramic electrolytes are considered the ideal form of rechargeable batteries due to their high energy density and safety. However, in the pursuit of all-solid-state LIBs, the issue of lithium resource availability is selectively overlooked. Considering that the amount of lithium required for all-solid-state LIBs is not sustainable with current lithium resources, another system that also offers the dual advantages of high energy density and safety— all-solid-state sodium-ion batteries (SIBs) —holds significant sustainable advantages and is likely to be the strong contender in the competition for developing next-generation high-energy-density batteries. This article briefly introduces the research …

Contributions To Journal Of Electrochemistry, The Flagship Journal Of Chinese Chemical Society Electrochemical Committee, Will Be Listed As A New Recommendation Policy For China Youth Awards Of Electrochemist, Editorial Office Of J.Electrochem.

Journal of Electrochemistry

No abstract provided.

Dendrite-Free Strategies For Aqueous Zinc-Ion Batteries: Structure, Electrolyte, And Separator, Gang Wu, Wu-Hai Yang, Yang Yang, Hui-Jun Yang

Journal of Electrochemistry

Continued growth in energy demand and increased environmental pollution constitute major challenges that need to be addressed urgently. The development and utilization of renewable, sustainable, and clean energy sources, such as wind and solar, are crucial. However, the instability of these intermittent energy sources makes the need for energy storage systems increasingly urgent. Aqueous zinc-ion batteries (AZIBs) have received widespread attention due to their unique advantages, such as high energy density, cost-effectiveness, environmental friendliness, and safety. However, AZIBs face significant challenges, mainly the formation of zinc dendrites that seriously affect the stability and lifetime of the batteries, leading to battery …

Electrochemical-Method-Induced Strong Metal-Support Interaction In Pt-Cnt@Sno2 For Co-Tolerant Hydrogen Oxidation Reaction, Shen-Zhou Li, Zi-Jie Lin, Qi-An Chen, Zhao Cai, Qing Li

Journal of Electrochemistry

Inducing the classic strong metal-support interaction (SMSI) is an effective approach to enhance the performance of supported metal catalysts by encapsulating the metal nanoparticles (NPs) with supports. Conventional thermal reduction method for inducing SMSI processes is often accompanied by undesirable structural evolution of metal NPs. In this study, a mild electrochemical method has been developed as a new approach to induce SMSI, using the cable structured core@shell CNT@SnO₂ loaded Pt NPs as a proof of concept. The induced SnO_x encapsulation layer on the surface of Pt NPs can protect Pt NPs from the poisoned of CO impurity in …

Synthesis Of Activated Carbon From Coconut Shell And Recycled Styrofoam Nanofiber For Water Filtration, Rahma Dani, Ismet Ismet, Leni Marlina, Rona Alisya, Muhamad Abel Kirana Aldi, Anggi Ludiansyah, Lintang Auliya Kurdiati, Meutia Kamilatun Nuha Ap Idjan, Agung Mataram, Muhammad Rama Almafie, Ida Sriyanti

Makara Journal of Science

Water pollution affects life sustainability; hence, several efforts have been exerted to overcome this problem. For ex-ample, nanofiber membrane technology is introduced to retain solutes while allowing only water molecules to pass through the system. Therefore, this study aimed to maximize the technology for water filtration using the electrospin-ning method by combining Styrofoam waste-based polymer with activated carbon from coconut shell waste (ACCS). The nanofiber diameter produced ranged from 590 nm to 610 nm with porous characteristics and without beads. The carbon content varied from 68.04% to 69.84%, according to the energy dispersive X-ray measurement, demonstrating the composite’s effectiveness. The …

A Mechanistic Study Of Silicon Nanocrystal Formation Via Solid State Synthesis, Katherine Mccarthy Weinfurter

Dissertations and Theses

Silicon nanocrystals (SiNCs) show promising physiochemical properties that could be used in industrial applications. The production of SiNCs through solid-state synthesis is ideal due to relatively low cost of equipment and chemical reagents, as well as the ability to scale-up production. A widely known and commonly used precursor previously used in solid-state synthesis for SiNCs, hydrogen silsesquioxane (HSiO_1.5), was discontinued in chemical manufacturing, which has led to researching alternative precursors (or starting materials). We have identified that there is a gap of knowledge related to producing these precursors, as well as the mechanistic understanding of the chemical reactions …

Ge/Sige Quantum Wells: Material For The Post-Moore Era, Troy Alexander Hutchins-Delgado

Optical Science and Engineering ETDs

This dissertation demonstrates high-quality germanium quantum wells on a 200 mm silicon wafer platform, enabling novel device possibilities. Partnering with a commercial silicon-germanium epitaxy supplier, we obtained shallow, undoped germanium quantum wells with high-crystalline quality, confirmed through x-ray diffraction, secondary ion mass spectroscopy, high-resolution scanning transmission electron microscopy, and energy dispersive x-ray spectroscopy. Hall bar devices fabricated on single quantum wells revealed that surface preparation can tune transport properties while maintaining peak mobilities around 10⁵ cm²V⁻¹s⁻¹. Manganese-germanide spintronic contacts were integrated via solid-state reaction, with contact quality assessed through Schottky diodes, transfer length …

Magnetic Resonance Imaging Trackable Pathology-Triggered Polymersomes Toward Enzyme Replacement Theranostics For Gm1 Gangliosidosis, Dorian Foster

All Dissertations

This dissertation investigates the development and optimization of pathology-responsive polymersomes for simultaneous enhanced magnetic resonance imaging (MRI) and enzyme replacement therapy (ERT) in the treatment of GM1 gangliosidosis (GM1). While therapeutic strategies exist for similar, non-neuropathic lysosomal storage disorders, implementation towards GM1 faces significant challenges due to the blood-brain barrier.

Herein, we developed and characterized a range of low molecular weight hyaluronic acid-b-polylactic acid (HA-PLA) polymersomes (PSs) capable of encapsulating therapeutic enzymes in their hydrophilic core. These polymersomes exhibit pathophysiology-triggered responsiveness, degrading in the presence of acidic conditions, which is characteristic of lysosomes, and enzymes such as hexosaminidase A, which …

Understanding Defect Dynamics In Black Phosphorene Under Noble Gas Ion Irradiation., Saransh Gupta

Electronic Theses and Dissertations

Controlled introduction of defects in phosphorene using high-energy ion beams offers a promising route to design novel high-performance materials for energy technologies. However, this potential remains underexplored due to a lack of fundamental understanding of the atomic-scale mechanisms governing the production, accumulation, and temporal evolution of defects during ion irradiation. Here, we employ a combination of classical and ab initio molecular dynamics simulations to elucidate the effects of ion energy, angle of incidence, noble gas ion size/mass, and fluence on (a) defect generation (i.e., point defects, topological imperfections, voids), (b) atomic-scale mechanisms of defect formation and re-arrangement, and (c) defect …

Neodymium Doped Zinc Oxide Based Advanced Flexible Piezoelectric Energy Harvester And Self-Powered Biomotion Sensor, Muhtasim Ul Karim Sadaf, Abu Musa Abdullah, Haimanti Majumder, Sk Shamim Hasan Abir, Mariana Torres, Karen Lozano, Md. Wasikur Rahman, M. Jasim Uddin

Mechanical Engineering Faculty Publications

Flexible piezoelectric devices have garnered a lot of attention for their potential as energy harvesters and transducers. In this work, Neodymium (Nd) doped Zinc Oxide (ZnO) based flexible piezoelectric energy harvester and sensory device has been developed. Nd-doped ZnO has been synthesized using wet chemical co-precipitation and incorporated in Polyvinylidene Difluoride (PVDF) polymer matrix along with Multiwalled Carbon Nanotubes (MWCNT) to produce flexible piezoelectric films. The piezoelectric output of the device is tested at variable tapping frequency (60 to 240 BPM) and pressure (10 to 40 psi). The device has also been tested with conventional electronics like bridge rectifiers, capacitors, …

Fabrication And Charcaterization Of Pullulan-Collagen Nanofibers Via Forcespinning, Valeria Leon Leal

Theses and Dissertations

Extensive research on collagen has spurred advancements in tissue engineering and biomaterial development, given collagen´s pivotal role in regulating various tissue structures across diverse organisms. This study delves into fabricating nanocomposites utilizing collagen, along with silver nanoparticles, chondroitin sulfate and pullulan, for potential applications in antibacterial medical devices, and cell regeneration. Collagen, abundant in the extracellular matrix, provides essential structural support, while silver nanoparticles and chondroitin confer antimicrobial properties, crucial for combating infections. Pullulan, a polysaccharide polymer, serves as a biocompatible carrier for silver nanoparticles whilst being the starting nanofiber forming material. Utilizing Forcespinning® technology, composite nanofibers were successfully synthesized. …