Geological Engineering Commons^™

Chemical Weathering And Mobility Of Inorganic Species In Dry Disposed Ash: An Insight From Geochemical Fractionation And Physicochemical Analysis, S.A. Akinyemi, W.M. Gitari, A. Akinlua, L.F. Petrik

Coal Combustion and Gasification Products Journal Archive

The burning of low-grade coal produces vast amounts of ash and other solid by-products. In South Africa, coal combustion by-products undergo disposal on land as dry heaps or slurried to dams. In this study, the geochemical partitioning, transport, and mobility of elements in dry disposed ash dumps were investigated using a modified sequential extraction scheme. The chemical and mineralogical compositions of 50 drilled core samples were investigated by X-ray fluorescence (XRF), X-ray diffraction (XRD), and inductively coupled plasma mass spectrometry. Ternary plots of major elements as determined by XRF showed that the 15-year-old and 2-week-old dry disposed ashes are sialic, …

Wolf Creek Dam: A Case Study Of Foundation Remediation For Dams Built On Karst Foundations, Kyla Justene Erich

Masters Theses

"Wolf Creek Dam was completed in 1952 as a 5,736-foot long and 258-foot high combination embankment-concrete gravity dam. Its storage capacity of 6 million acre feet makes it the ninth largest reservoir in the nation. The dam was built on a heavily karstified limestone foundation and began exhibiting signs of excess foundation seepage in late 1967. This led to extensive corrective work in the 1970s beneath the earthen core of the embankment to reduce underseepage. In 2006 an independent assessment by the Dam Safety Action Classification (DSAC) Peer Review Panel recommended that Wolf Creek Dam exhibited "Urgent and Compelling" foundation …

Characterization Of Rabinal, Guatemala Clay And Development Of An Engineered Surrogate For The Purpose Of Laboratory Study, Lara Anne Hubbel

Masters Theses

"Ceramic pot filters (CPFs) have been proven to be an effective, low cost household water treatment system that are commonly used in third world countries. They are made using local clay, burn out material and colloidal silver or silver nitrate. Challenges faced by researchers include difficulty in acquiring filters from their manufacturing facilities without incurring damage and the cost of shipping. Acquiring the clay material used to make the filters is also difficult due to the cost of shipping and permits necessary to import soil. There have been studies conducted that compared laboratory made CPFs made with native clay and …

Subsurface Discontinuity Analysis & Modeling For The Federal Waste Disposal Facility And Compact Waste Disposal Facility Landfills, Shuang Cao

Electronic Theses and Dissertations

This research considers discontinuities mapped by Waste Control Specialists LLC to support the site conditions and performance analysis of the Compact Waste Disposal Facility and the Federal Waste Disposal Facility excavations constructed near Andrews, Texas. Discontinuities observed in excavation walls contain a limited number of discontinuities shoevidence of previous fluid movement. While no networks of such discontinuities were observed in the field, the potential for such networks may exist. This research is significant in understanding the performance of these waste facilities by modeling multiple realizations of possible fracture configurations in three-dimensional spatial models of the type of discontinuities observed in …

A Modification Of Freeze-Core Technology For Collecting Granular Fluvial Sediment Samples, David Charles Smith

Masters Theses

"The presence of coarse grained sediment can potentially reduce the effectiveness of conventional sampling methods in recovering fluvial sediments. A modification to freeze-core technology was used to collect fine grained sediments for the purpose of characterizing the extent of heavy metal contamination in fluvial deposits that contain significant amounts of coarse-grained material such as cobbles and boulders. This material greatly reduces the effectiveness of conventional sampling methods. This method uses 2.5-cm and 2.9-cm diameter by 30-cm long finned samplers that were mechanically- and hand-driven into the ground. The sediment is frozen to the outside of the sampler by injecting liquid …

A Regional Study Of Landslide Hazards And Related Features In The Upper Indus River Basin, Northern Pakistan, Muhammad Farooq Ahmed

Doctoral Dissertations

"A spatial landslide inventory is a fundamental step preparatory to developing an understanding of regional landslide hazards. The techniques honed for this regional landslide mapping study began with compiling a stitched shaded topographic map of the Upper Indus River watershed; using remotely-sensed topographic maps from Russia combined with ASTER DEM 30m resolution data. Topographic recognition keys were then employed to aid in the visual identification and delineation of past landslides, rockslide avalanches, and landslide dam sites. The first order reconnaissance level inventory excerpted 2,254 landslides (mostly deep seated translational and complex slides) along the main stem of Indus River, land …

Regional Geomorphic Analysis And Gis Susceptibility Mapping Of Landslides In The Blue Nile And The Tekeze River Basins Of Ethiopia, Elamin Hassan Dai Ismail

Doctoral Dissertations

"The Plateau region of Ethiopia lies within a seismically active continental extensional regime, which is being rapidly incised by the Blue Nile and the Tekeze Rivers. Extremely large landslides pose serious hazards in this highly populated region (>27 million), which is in the process of developing its hydrologic resources. This research sought to develop cost-effective methods to compile regional landslide inventory and landslide susceptibility maps, using geomorphic tools and GIS technologies. This work also sought to evaluate the relationships between landslide dams and knickpoints, caused by channel bed incision from those caused by slope failures, by utilizing identified knickpoints …

Joint Diagonalization Applied To The Detection And Discrimination Of Unexploded Ordnance, Fridon Shubitidze, Juan Pablo Fernández, Irma Shamatava, Benjamin Barrowes, Kevin O’Neill

Dartmouth Scholarship

Efforts to discriminate buried unexploded ordnance from harmless surrounding clutter are often hampered by the uncertainty in the number of buried targets that produce a given detected signal. We present a technique that helps determine that number with no need for data inversion. The procedure is based on the joint diagonalization of a set of multistatic response (MSR) matrices measured at different time gates by a time-domain electromagnetic induction sensor. In particular, we consider the Naval Research Laboratory’s Time-Domain Electromagnetic Multisensor Towed Array Detection System (TEMTADS), which consists of a 5×5 square grid of concentric transmitter/receiver pairs. The diagonalization process …

Estimating Land Surface Temperature Using A Thermal Sharpening Technique, Yitong Jiang, Qihao Weng

Symposium 2012

No abstract provided.

Impacts Of Changes In Land Use And Land Cover On Atmospheric Chemistry And Air Quality Over The 21st Century, S. Wu, L. J. Mickley, J. O. Kaplan, D. J. Jacob

Michigan Tech Publications, Part 1

The effects of future land use and land cover change on the chemical composition of the atmosphere and air quality are largely unknown. To investigate the potential effects associated with future changes in vegetation driven by atmospheric CO 2 concentrations, climate, and anthropogenic land use over the 21st century, we performed a series of model experiments combining a general circulation model with a dynamic global vegetation model and an atmospheric chemical-transport model. Our results indicate that climate-and CO 2-induced changes in vegetation composition and density between 2100 and 2000 could lead to decreases in summer afternoon surface ozone of up …

Microstructural And Mineralogical Transformation Of Hydraulically Disposed Fly Ash—Implications To The Environment, Jabulani S. Mahlaba, Elsabe P. Kearsley, Richard A. Kruger

Coal Combustion and Gasification Products Journal Archive

Increasing amounts of coal are combusted annually to meet the ever-increasing energy demands. The inevitable by-products include fly ash and saline effluents, which require acceptable disposal. The aim of this article is to compare the effect of hydraulic disposal with dry ash dumping. The results indicate that the former carries more environmental benefits based on the physical, chemical, and mineralogical aspects that were investigated.

Cordyline Fruticosa Growth And Soil Microbial Quality With Topical Application Of Coal Combustion By-Products Aggregates, Sangchul Hwang, Isomar Latorre, Eileen Irizarry

Coal Combustion and Gasification Products Journal Archive

Coal combustion by-products aggregates (CCAs) are a solidified composite of fly and bottom ashes (2:1, by wt). Here, we assessed the feasibility of beneficial use of CCAs as a soil amendment or conditioner by conducting an outdoor experiment with Cordyline fruticosa (lucky plant) to determine its growth and soil microbial quality under the influence of topical CCA application (95 tons ha21). Enhanced growth of C. fruticosa with CCA application was noted, with respect to plant height, growth rate, leaf size, and leaf chlorophyll intensity. Soil dehydrogenase activity and total heterotrophic bacteria count were greater with topical CCA application, especially in …

Influence Of Activator Solution Formulation On Fresh And Hardened Properties Of Low-Calcium Fly Ash Geopolymer Concrete, Carlos Montes, Erez N. Allouche

Coal Combustion and Gasification Products Journal Archive

The effect of the composition of activator solutions on fresh and hardened properties of geopolymer concrete was investigated. Research variables included liquid sodium silicate product (DH, NH, and StarH), sodium hydroxide molar concentration (6, 10, and 14), and sodium silicate–to–sodium hydroxide ratio (1, 2, and 3). Response variables were compressive strength, corrosion resistance expressed as remaining compressive strength and mass loss, and flowability. Results were analyzed using Minitab statistical software. Findings suggest that activator solution formulation has a significant effect on the properties of the resulting geopolymer binder. The experimental design used was found effective in establishing the optimum activator …

Mineralogical Transformations In Coal Feedstocks During Carbon Conversion, Based On Packed-Bed Combustor Tests: Part 2. Behavior Of Individual Particles, Ratale H. Matjie, Colin R. Ward, Zhongsheng Li

Coal Combustion and Gasification Products Journal Archive

Handpicked carbon-rich particles (coal or char), mineral-rich particles (heated stones), and bonded stone aggregates (clinkers) from the upper and lower parts of a pilot-scale packed-bed combustor bed, designed to simulate conversion or combustion processes, were subjected to mineralogical and inorganic geochemical studies, in order to evaluate the reactions that may occur during carbon conversion at a particle-by-particle scale. The mineral matter of the carbon-rich particles was found to have higher proportions of carbonate minerals and kaolinite than the mineral-rich (stone) particles in the coal feedstocks used in the study, and to form phases such as anorthite, gehlenite, pyrrhotite, troilite, and …

Mineralogical Transformations In Coal Feedstocks During Carbon Conversion, Based On Packed-Bed Combustor Tests: Part 1. Bulk Coal And Ash Studies, Ratale H. Matjie, Colin R. Ward, Zhongsheng Li

Coal Combustion and Gasification Products Journal Archive

Mineralogical and inorganic geochemical studies have been carried out on composite samples of six different coarse-crushed (,120 mm) feed coals tested in a pilot-scale packed-bed combustor designed to simulate conversion and some fixed-bed combustion processes, and also on composite samples of the ashes produced. The mineral matter of the coals consisted mainly of quartz, kaolinite, and Ca-bearing carbonate minerals (calcite, dolomite, aragonite), with minor proportions of illite, pyrite, and several other phases, along with some Ca in an organically associated form. The base to acid ratio of the coal ashes ranged from 0.1 to 0.3, due mainly to variations in …

Potential Indoor Air Exposures And Health Risks From Mercury Off-Gassing Of Coal Combustion Products Used In Building Materials, Christopher M. Long, Sonja N. Sax, Ari S. Lewis

Coal Combustion and Gasification Products Journal Archive

Coal combustion products (CCPs), including coal fly ash (CFA) and flue gas desulfurization (FGD) gypsum, have gained accepted use as substitutes for traditional substances in building materials. Because of the presence of mercury (Hg) in CCP materials, some concerns have been raised regarding the potential for Hg to off-gas from building materials into indoor air. Risk assessment offers a well-accepted, objective framework in which to determine whether such off-gassing could result in humanexposures of health concern. We thus conducted a screening-level human health risk assessment to estimate worst-case inhalation risks from indoor air exposures to Hg for multiple CCP utilization …

Quantifying The Benefits Of Using Flue Gas Desulfurization Gypsum In Sustainable Wallboard Production, Jin Cheol Lee, Sabrina L. Bradshaw, Tuncer B. Edil, Craig H. Benson

Coal Combustion and Gasification Products Journal Archive

Electric utilities produce more than 11.2 Mt of flue gas desulfurization (FGD) gypsum annually. Approximately 7.5 Mt is used in wallboard production. This article examines the environmental and cost benefits associated with replacement of natural gypsum in wallboard with FGD gypsum. A life-cycle analysis program was used to quantify the benefits of using FGD gypsum from electric power production in wallboard construction. Comparisons were made between energy consumption, water use, and greenhouse gas (GHG) emissions associated with obtaining and processing virgin gypsum material and those with FGD gypsum. The added impact of disposing of the unused FGD gypsum in landfills …

Waste Classification Of Slag Generated In A Pilot-Scale Entrained-Flow Gasifier, Ashleigh Cousins, Robin W. Hughes, David J. Mccalden, Dennis Y. Lu, Edward J. Anthony

Coal Combustion and Gasification Products Journal Archive

Series of gasification tests have been completed in the pilot-scale entrained-flow slagging gasifier at CanmetENERGY using Canadian coals, oil-sand coke, and blends of these fuels to determine if the produced slags are nonhazardous in nature. Solid wastes generated during these tests were analyzed for their trace metals, crystallinity, and toxic constituent leaching tendency in an attempt to provide more insight into the possibility of disposal or by-product use of gasifier-produced solid waste. The gasification tests were performed at conditions representative of commercial gasifiers using a dry-fuel-feed configuration. The lower-volatility elements were found to partition between the slag and process-water solids …

Measuring The Orientations Of Hidden Subvertical Joints In Highways Rock Cuts Using Ground Penetrating Radar In Combination With Lidar, Adnan Mohammed Aqeel

Doctoral Dissertations

"Mapping discontinuities in rock cuts and measuring their orientations is crucial in assessing the stability of rock masses. This can be done usually using manual methods such as scanline or advanced techniques such as LIDAR. However, these methods are used only to map exposed discontinuities which may cause underestimation for slope stability. Accordingly, ground penetrating radar (GPR) has been recently used to detect such hidden discontinuities.

The used 400 MHz monostatic GPR antenna was significantly able to detect and map hidden subvertical joints within 4 m depths in five sandstone highways rock cuts and within 3 m depths in two …

Imaging The Subsurface In Karst Terrain Using Electrical Resistivity Tomography, Evgeniy V. Torgashov

Doctoral Dissertations

"Five electrical resistivity tomography (resistivity) case studies are presented. The first case study, entitled "Springfield Underground", includes ERT data acquired with the purpose of imaging the ceiling of an limestone aggregate mine following simultaneous localized roof failure. The interpretation of the ERT data indicates roof rock failure occurred at the intersection of two previously unmapped near-vertical solution-widened fractures.

At the "Chesterfield Dam" site, resistivity data were acquired to identify the zone of seepage through an earthfill dam. The seepage pathway beneath the dam is interpreted as through a solution-widened fracture, the top of which constituted a segment of the original …