Metallurgy Commons^™

Electrochemical Characterization Of Copper Deposited On Plasma And Thermally Modified Titanium Surfaces, K. S. Teng, J. L. Delplancke, Jiangfan Zhang, T. J. O'Keefe

Electrical and Computer Engineering Faculty Research & Creative Works

Thin oxide films were grown at temperatures from 373 to 1073 K in plasma and in air on commercially pure titanium substrates. It was determined that the color, thickness, composition, phase, and polarization behavior in a copper electrolyte varied with operating conditions: temperature, oxygen partial pressure, and plasma composition. High-temperature and high oxygen partial pressure plasma produced a thick oxide film. The surface film structure transformed from TiO2 (anatase) to TiO2 (rutile) at a temperature of 600 °C. A lower oxide of the form TinO2n-1, such as Ti2O3 (which may be porous) or possibly Ti3O5, was formed on a thermally …

Electrodeposition Of Copper On Thermally Oxidized 316 L Stainless Steel Substrates, Z. Zhou, Thomas J. O'Keefe

Materials Science and Engineering Faculty Research & Creative Works

The effect of thermal oxidation of 316 L stainless steel cathode blanks used in copper electrodeposition was studied. Current and potential step experiments were performed to evaluate electrochemical changes caused by the oxidation treatments. SEM and AES were used to characterize the stainless-steel substrates and the deposited copper films. Particular emphasis was given to the initial stages of copper nucleation and growth. The copper electro crystallization process was strongly influenced by the temperature employed in oxidizing the stainless steel. Dense, uniform and fine copper nuclei were obtained on the stainless-steel substrate oxidized in air at 200°C and 300°C for 3 …

Analysis Of The Value Of The Fe Examination For The Assessment Of Student Learning In Engineering And Science Topics, John L. Watson

Materials Science and Engineering Faculty Research & Creative Works

This paper presents the results of a project, which investigated the potential of fully using previously unreleased data from the nationally normed Fundamentals of Engineering (FE) examination to assess learning in key engineering and science topics. In the past, very limited information was released by the National Council of Examiners for Engineers and Surveyors (NCEES) for the eight hour FE examination, which is composed of 150-200 questions in ten morning and five afternoon topics. For the purposes of this project the NCEES agreed to release information to the University of Missouri-Rolla (UMR) to permit the value of the FE data …

Organically Deposited Metallic Films For Device Fabrication, Thomas J. O'Keefe, M. Stroder, Matthew O'Keefe

Materials Science and Engineering Faculty Research & Creative Works

Advances in integrated circuit density, speed and complexity are dependent on lower resistance, finer line width on-chip interconnections. Methods for incorporating copper interconnects into IC fabrication processes have been developed which accomplish this objective but most of these methods use some form of blanket metal deposition that requires mechanical and/or chemical removal of excess material. To date, investigations into the selective deposition of conductor materials for device fabrication have met with limited success. A new process for selectively depositing metallic conductors using inexpensive, organic-based chemical solutions could potentially force a paradigm shift in the deposition of metals for microelectronic applications. …

Maskless, Direct Deposition Of Copper Onto Aluminum Bond Pads For Flip Chip Applications, M. Fang, Thomas J. O'Keefe, M. Stroder, W. Shih, Matthew O'Keefe, R. Strawser, D. Via

Materials Science and Engineering Faculty Research & Creative Works

Flip chip interconnection of integrated circuits (IC) for packaging applications such as direct chip attachment use Pb-Sn solders as the connection between the die and the substrate. Under bump metallization is typically used to transition from the non-solderable Al bond pad on the IC to a solderable surface such as copper using traditional blanket metal deposition, photolithography and etching procedures. In this study, we report for the first time the use of a novel process for selectively depositing adherent copper directly onto aluminum thin films, eliminating the need for adhesion promoting transition layers and additional patterning steps. Utilizing copper bearing …

An Evaluation Of The Aws Entry Level Welder Training Program, John R. Rice

Dissertations and Theses @ UNI

The purpose of this study was to evaluate the effectiveness of a training program for Entry Level Welders and to provide this information to the American Welding Society (AWS), industry, and educators. The problem of this study was to evaluate the AWS Entry Level Welder Training Program (ELWTP) by obtaining the opinions of faculty members who taught the program and welders who had completed the program.

Two groups comprised the research population for this study. The first group consisted of faculty members who were actually involved in teaching the course at institutions accredited by the AWS to offer the curriculum. …

Strip Casting With Fluxing Agent Applied To Casting Roll, Robert S. Williams, Ronald J. O'Malley, Richard C. Sussman

Materials Science and Engineering Faculty Research & Creative Works

A strip caster (10) for producing a continuous strip (24) includes a tundish (12) for containing a melt (14), a pair of horizontally disposed water cooled casting rolls (22) and devices (29) for electrostatically coating the outer peripheral chill surfaces (44) of the casting rolls with a powder flux material (56). The casting rolls are juxtaposed relative to one another for forming a pouting basin (18) for receiving the melt through a teeming tube (16) thereby establishing a meniscus (20) between the rolls for forming the strip. The melt is protected from the outside air by a non-oxidizing gas passed …

Thickness Effects On A Cracked Aluminum Plate With Composite Patch Repair, Joel J. Schubbe

Theses and Dissertations

Post-repair fatigue crack growth was investigated in 3.175, 4.826, and 6.35 mm thick aluminum panels asymmetrically repaired with boron/epoxy composite patches bonded to the plates with FM73 sheet adhesive. Patches were uniaxial with patch to panel stiffness ratios ranging from 0.46 to 1.3. Experimental fatigue tests were carried out at 120 MPa, R=0.1, and 10 Hz (sinusoidal) to measure patched and unpatched face crack lengths, center crack opening displacements, and selected strains. Crack growth data was acquired using optical, eddy current, and post-test analysis methods. Crack growth rates were calculated using the incremental polynomial method. A three-layer Mindlin plate finite …

The Effect Of Casting Shape And Size On Solidification Time: A New Approach, Murat Tiryakioǧlu, Ergin Tiryakioǧlu, Donald R. Askeland

Materials Science and Engineering Faculty Research & Creative Works

The limitations of Chvorinov's Rule for predicting the solidification time of a casting are discussed and previous studies intended to modify Chvorinov's Rule in order to express the effect of the size and shape of castings on solidification time are reviewed. A new model that introduces a shape factor is presented that predicts the solidification times of castings as well as or better than Chvorinov's Rule, particularly for more complex shapes. The validity of the new model is compared with the conventional Chvorinov's Rule by a statistical analysis of twelve sets of data obtained from the literature.

Characterization Of Iron Oxides And Atmospheric Corrosion Of Steel, Sei Jin Oh

Physics Theses & Dissertations

The study of corrosion behavior was performed using three different analytical techniques, which provided information on the formation, development and layering of iron oxides on the corrosion products as a function of atmospheric conditions, exposure time and type of steel. In particular, the protective layer formed on weathering steel was investigated as a function of different amounts of alloying elements in the steel, atmospheric conditions and exposure times. Combined together, the results provided a better understanding of the atmospheric corrosion behavior of steel, and formed a part of database of the atmospheric corrosion characteristics.

Accurate characterization of the iron oxides …

Residual Strength And Fatigue Characterization Of Scs-6/Ti-6-4, Sang-Myung Lee

Theses and Dissertations

Metal matrix composite have potential in a variety of aerospace applications, but they should be better understood before they can be employed. Despite the many studies that have contributed to characterizing the fatigue response of titanium alloy MMCs, few have researched the residual strength. The purpose of this study was to investigate the residual strength and the frequency effects on the residual strength of an unidirectional laminate of SCS-6/Ti-6-4, a titanium alloy matrix based composite under tension-tension, load-controlled conditions at elevated temperatures and different frequencies. Specimens were fatigued at frequencies of 1 and 0.01Hz, and at maximum stress of 900MPa …

A Fluid Flow Analysis Of Aluminum 356.0 In The Vacuum Assisted Countergravity Method, John Launstein

Graduate Research Papers

The purpose of this study is to determine the fluid flow pattern obtained through the use of the countergravitaional process. The physical fluid flow model assists design engineers in their casting design of parts utilizing the LS-Vac technology thereby reducing tooling costs and time losses.

A Comparison Of Tool Life Of Two Coated Carbide Inserts Under Identical Conditions And At Different Cycle Times, Garold Zander

Graduate Research Papers

Coated hardmetals have brought tremendous increases in productivity since 1969, when they were first applied to cutting materials. These coatings are extremely hard and are very abrasion resistant. Typical coatings are alumina oxide, silicon nitride with metal oxides, titanium carbonnitrides with metal carbides, titanium nitride, titanium carbonitride, and zirconium oxide. This study examined two different coated cutting inserts to determine which would maximize performance for lathe operators.

The two chemical vapor deposition (CVD) coated indexible inserts examined were Carboloy CMNA 543 TP 100, and Carboloy CNMA 543 TP 10. Both cutting inserts were multi-coated with alumina (Al2O3 ), titanium nitride …

Mechanical Alloying Of Nitrogen Into Iron Powders, J. Rawers, D. Govier, D. C. Cook

Physics Faculty Publications

Mechanical alloying of nitrogen into bcc-fe powder is a very effective and efficient means of obtaining very high concentration of nitrogen in micron-size iron particles. Mechanical alloying increases the concentration of nitrogen in the iron powder far in excess of the bcc-Fe lattice low nitrogen solubility, however most of the infused nitrogen resides on the nano-size grain boundaries and in nano-size bct-fe that forms during mechanical alloying.

The Effects Of Post Inoculant Additions On Ductile Iron Fade, Travis James Frush

Dissertations and Theses @ UNI

This study involved the investigation of three specific, commercially available, post inoculants for ductile iron and their effect on the magnesium fading rate and chill reducing tendency in a low volume production environment. Although fading effects of ductile iron have been extensively investigated, in general, they apply to high volume production operations. Unfortunately, for the smaller foundry operations, many of the process solutions proposed for the prevention of the fading effects are not applicable or practical. In addition to the small production operations, new process technologies are also excluded from many of these process solutions. For this reason, a study …

An Investigation Into The Use Of Expanded Polystyrene Patterns With The Loose-Sand, Vacuum Assisted Counter Gravitational Casting Process, John B. Vandersall

Graduate Research Papers

"Considered for years as a metal casting renegade, Expendable Pattern Casting (EPC) is believed by some to be tomorrows long-term casting future. Others, however, see it as an unproven headache-ridden process that makes the simple art of metal casting unnecessarily complex." (Lessiter, 1994, p. 36). The complexity of this process has been largely due to the lack of knowledge surrounding the interaction of the metal front and the dissipating polystyrene pattern.

Since the discovery of EPS as a pattern material, numerous applied research projects have been performed to gain a better understanding of the thermal breakdown characteristics of the material. …

An Analysis Of The Disposition Of Used Foundry Sand With Thermal Reclamation, Douglas Miller

Graduate Research Papers

The purpose of this study was to identify the economic and environmental concerns for the disposal, reuse, or reclamation of used foundry sand and show how foundries have developed options to landfills. The sand type and the reclamation processes available are the factors to use in determining whether disposal, reuse, or reclamation is appropriate. The continued use of landfills for disposal of used sand strongly indicates that reclamation and reuse techniques were either not understood or not as economical as disposal. Public concerns and new environmental laws demand that alternate means of disposal for used foundry sand should be developed …

Identification And Characterization Of The Iron-Zinc Intermetallics Formed In Galvanneal Steel, Richard Frederick George Grant

Physics Theses & Dissertations

The demand to improve the corrosion resistance of steel sheet, particularly for use within the automotive industry, has led to a dramatic increase in the use of coated steels in place of cold-rolled sheet steel. Galvanneal steel results from the post annealing of the zinc-coated steel sheet, in which iron and zinc are interdiffused to form an iron-zinc alloy coating. Within this alloy coating, four main iron-zinc phases, Zeta, Delta, Gamma-1, and Gamma may be present. Manufacture of the most suitable coating requires identifying which phases form during the galvannealing process, an understanding of the properties of each phase and …

A Positron Annihilation Study Of Rotating Beam Fatigue Damage In The Superalloy Haynes 188, D. Hoeckelman, Hollis P. Leighly

Materials Science and Engineering Faculty Research & Creative Works

No abstract provided.

Effect Of Additives On Anomalous Deposition In Zinc-Cobalt Alloy Electrogalvanizing, H. M. Wang, Thomas J. O'Keefe

Materials Science and Engineering Faculty Research & Creative Works

Alloys of Zn-Co were deposited from sulphate electrolytes containing various additives to study their influence on the anomalous behavior of the reactions. The effects of antimony, germanium and arsenic on the Zn-Co alloy composition and structure were examined. The results showed that the composition and structure of Zn-Co alloys deposited could be dramatically changed by antimony, and to a lesser extent by germanium and arsenic. A concentration of Sb(III) as low as 5 mg dm-3 increased the cobalt content by a factor of approximately 3; however, the deposit morphology was very dendritic. Germanium additions nearly doubled the cobalt content and …

Solubility Of Red Phosphorous In Lead, Sean E. Walker

Opportunities for Undergraduate Research Experience Program (OURE)

The determination of the solubility of red phosphorus in lead can be used to produce a plot of the solubility with respect to temperature and pressure. The plot is produced with experimental data, activity determination from present thermodynamic data, and compilation of the two sets of data into the semi-regular solution format. A lead-phosphorus solubility diagram is necessary to determine the amount phosphorus that will be absorbed by lead and will remain unreacted in a given process.

Characterization Of Phase Transformation Behavior In Electrolytically Produced Indium-Thallium Shape Memory Alloy Films, Chong Ho Sonu, Thomas J. O'Keefe

Materials Science and Engineering Faculty Research & Creative Works

Indium-thallium alloys in the range 15-38 at. % Tl were electrodeposited from a sulfate electrolyte by using pulsed current. The relationship between composition and phase structure of the alloys deposited was investigated with regard to the shape memory effect. To date there have been no reported experimental studies describing the electrodeposition of InTl alloys capable of undergoing such transformations. Not only did the deposited alloys exhibit the shape memory effect, but the composition-phase relationship exhibited was shown to deviate from that reported for alloys in an equilibrium condition. The results show that the temperature and the temperature interval for the …

Positron Annihilation Determination Of Damage Caused By Fatigue Cycling In The Superalloy Haynes 188, D. Hoeckelman, Hollis P. Leighly

Materials Science and Engineering Faculty Research & Creative Works

No abstract provided.

Density Changes During Isothermal Annealing Of A Quenched Pb–7.45 At% Sn Alloy, Hollis P. Leighly, A. Belaidi

Materials Science and Engineering Faculty Research & Creative Works

The increase in density of a Pb–7.45 at% Sn alloy annealed at 150, 165, 180, and 195 °C and quenched at 20, 21.5, 23, 25, and 30 °C is measured isothermally. This increase in density accompanies the formation of the Sn‐rich phase precipitating as a function of time at the quenching temperature. The quenching is rapid enough to retain some vacancies at equilibrium at the annealing temperature. These vacancies accelerate the early stages of precipitation. The change in density versus time obeys the kinetic law allowing the determination of the reaction rate constant for several annealing and quenching conditions. Copyright …

The Corrosive Effects Of Salt Spray On Electrolytic Zinc Plated Mechanical Fasteners: The Case Of Clear Chromate And Yellow Dichromate Coatings On Medium Carbon Plated Bolts, Souleymane Boukari

Dissertations and Theses @ UNI

The purpose of this study was to evaluate the relationship between plating thickness and corrosion resistance of zinc coated medium carbon steel bolts under salt spray moisture conditions. Two types of zinc coatings were chosen for the study: the clear chromate zinc and the yellow dichromate zinc. One hundred and eighty 3/8-16 x 5 3/4 inch medium carbon steel bolts were selected for the test and divided into groups of 18. Two types of salt solution were used in the study: the low salt and the high salt. Bolts with various coatings tested with low salt concentration were composed of …

Investigation Of Tension-Compression Fatigue Behavior Of A Cross-Ply Metal Matrix Composite At Room And Elevated Temperatures, Elizabeth A. Boyum

Theses and Dissertations

This research, the first load-controlled tension-compression fatigue testing to be performed on a MMC, extends the existing knowledge of MMC fatigue damage mechanisms to include the tension compression loading condition. To accomplish this, a (0/90)2, SCS-6/Ti-15-3 laminate was subjected to tension- tension fatigue at room temperature, and tension-compression fatigue at both room temperature and 427°C. Stress and strain data was taken to evaluate the macro-mechanic behavior of the material. Microscopy and fractography were performed to characterize the damage on a micro-mechanic level. On a maximum applied stress basis, the room temperature tension-tension specimens had longer fatigue lives than the room …

Investigation Of Compressive Behavior For Metal Matrix Composites With A Circular Hole, Janet L. Gooder

Theses and Dissertations

This study investigated the notched and unnotched macromechanical response due to micromechanical behavior of [0/±45/90]_S SCS-6/β 21 S and [0/90] _2S Sigma/β 21S subjected to static compressive loads at room temperature. The stress-strain behavior and mechanical response in the presence of a circular hole was examined. A clear description of the progressive nature of damage, which ultimately resulted in failure, was provided. The effect of elevated temperature was shown for SCS-6/β 21S. The ultimate compressive strength and elastic modulus were reported for both MMCs. Sigma/β 21S and SCS-6/β 21S were mildly notch sensitive at room temperature. Notch sensitivity of …

Characterization Of Fatigue Damage In A Metal Matrix Composite (Scs-6/ Ti-15-3) At Elevated Temperature, Brian P. Sanders

Theses and Dissertations

The fatigue characteristics of a unidirectional titanium based metal matrix composite (MMC) were investigated at elevated temperature (427°C). A hybrid strain controlled loading mode was used to subject the 0° and 90° laminas to fatigue. Along with the fatigue tests, microscopy and analytical modeling ware also conducted. This combination of activities led to defining the initiation and progression of damage and deformation in the MMC. Hen loading was parallel to the fiber on, the fatigue behavior was initially dominated by creep deformation of the matrix. Then, depending on the maximum strain, specimen failure was the result either fiber fractures or …

A Technical Paper On Automated Pouring And The Selection Process Used By One North American Foundry, R. Stanley Weaver

Graduate Research Papers

This report on automated pouring focuses on the selection process used by one North American iron foundry. The problem facing this facility and any operation wishing to implement this technology lies in the number of variables which must be addressed in their quest for a suitable system.

A Study Of High Temperature Oxidation Resistance Of Plasma Treated Nb-Ti-Al Alloys, Roderick R. Rowland

Opportunities for Undergraduate Research Experience Program (OURE)

The effect of plasma treatment on the oxidation behavior of Ti-22Al-27Nb (atomic%) has been studied. The alloy, cast as an ingot by triple VAR and worked to a billet, was cut into smaller samples and oxidation plasma pre-treated. Oxidation plasma pre-treatments were conducted at four ambient temperatures: 25°C, 200°C, 400°C, and 500°C. Both the untreated and plasma pre-treated samples were oxidized at 700°C and 1000°C for one hour, in a muffle furnace. The oxidation behavior of the samples led us to do an extended oxidation of 100 hours at 700°C. The 200°C plasma pre-treated samples showed a definite leveling out …