Metallurgy Commons^™

Isolation Of Methyl Laurate From Coconut Oil As Raw Material For Fatty Alcohol Sulfate, Rita Arbianti, Tania Surya Utami, Astri Nugroho

Makara Journal of Technology

Isolation of Methyl Laurate from Coconut Oil as Raw Material for Fatty Alcohol Sulfate. Methyl laurate is a raw or base material for many industries, including surfactant industries. In this research, coconut oil (VCO) is transesterified with methanol to produce methyl ester, using NaOH as the catalyst. Methyl laurate is then separated by method based on the difference in melting point. This research focuses at determining the effects of some variables in transesterification on the concentration of produced methyl laurate. The variables are temperature (40 oC, 50 oC, 60 oC, 80 oC), time of transesterification reaction (0,5 hour, 1 hour, …

Two Element Microstrip Antenna Array With Defected Ground Structure, Fitri Yuli Zulkifli, Eko Tjipto Rahardjo, Muhamad Asvial, Djoko Hartanto

Makara Journal of Technology

Two Element Microstrip Antenna Array with Defected Ground Structure. This paper presents a two element microstrip antenna array using trapezium shape defected ground structure (DGS). The DGS is inserted in the ground plane between two elements of antenna array. Insertion of the DGS is intended to suppress the mutual coupling effect produced by antenna array. Simulation and measurement results were taken and compared between antenna array with and without DGS. Measurement results show that the antenna with DGS compared to antenna without DGS can suppress mutual coupling effect to 7.9 dB, improve the return loss to 33.29% from -30.188 dB …

Physical Characteristics And Utilization Oft The Karst Beaches In Kabupaten Gunungkidul, Astrid Damayanti, Ranum Ayuningtyas

Makara Journal of Technology

Physical Characteristics and Utilization oft the Karst Beaches in Kabupaten Gunungkidul. Karsts beaches at Gunungkidul Regency (Baron, Kukup, Sepanjang, Drini, Krakal, Ngandong, and Sundak), located in south of Daerah Istimewa Yogyakarta Province, have economic potential. Even they have similarity in geological condition (genesis and morphological processes), but they have different physical characteristics. Based on result of observation environment on morphological conditions and spatial analysis method, we found the proper utilization of the beaches.

Spectral Response Surfaces And The Ringing Response Of Offshore Structures, I Ketut Suastika

Makara Journal of Technology

A method, called spectral response surface method, is proposed for the study of the ringing phenomenon of offshore structures. Newman’s results for diffraction force on a column were reformulated in terms of the frequency components of the ocean surface and their Hilbert transforms. Using a first-order reliability method together with a dynamic model for the structural response, it is straightforward to calculate the ocean surface history most likely to generate an extreme ringing response and the ringing response history.

Neutron Irradiation On Ss316 Material For Radioactive Endovascular Stent Production, Rohadi Awaludin, Abidin Abidin, Sriyono Sriyono

Makara Journal of Technology

Neutron Irradiation on SS316 Material for Radioactive Endovascular Stent Production. It was reported that restenosis could be prevented by radioactive endovascular stent. SS316 material of endovascular stent has been irradiated at pneumatic rabbit system of G.A. Siwabessy reactor for 5 minutes for producing radioactive stent by neutron activation. After 10 days of decay, the irradiated SS316 was measured by gamma spectrometer. The radioisotopes of 51Cr, 59Fe and 60Co were detected in the irradiated SS316 with radioactivity of 5990, 107 and 109 Bq/mg respectively. The Calculation results showed that radioisotopes of 51Cr, 59Fe and 55Fe were produced by neutron activation. The …

Phase Unwrapping Insar Image Using Local Energy Minimization Approach, Kusworo Adi, Tati L.R. Mengko, Andriyan B. Suksmono, Hendra Gunawan

Makara Journal of Technology

Phase Unwrapping InSAR Image Using Local Energy Minimization Approach. Reconstruction process of phase data from its cover is called Phase Unwrapping (PU). Ideally, without any noise phrase, singularity, and aliasing problems, the phase information can be unwrapped easily. However, in fact, the phase data actually always get noise disturbance and discontinuity. The PU process becomes more complicated and needs a better PU algorithm to address the problems properly. In this research, the local PU algorithm is developed using minimization of close related firstorder pixels energy approach. In this method, the energy difference between four close related pixels is counted, followed …

Hydrogen Absorption In Weldments Of Overlaid Claded Pressure Vessel, Ronnie Higuchi Rusli

Makara Journal of Technology

Cracks was found in type 347 stainless steel internal attachment welds of a reactor for a high temperature, and high pressure hydrogen service. One of the possible causes of cracking is low cycle fatigue cracking induced by repetition of thermal stress to embrittled weld metal. Type 347 weld metal loses its ductility by presence of sigma phase and hydrogen.

The Decompositioning Of Volatile-Matter Of Tanjung Enim Coal By Using Thermogravimetry Analyzer (Tga), Nukman Nukman

Makara Journal of Technology

The Decompositioning of Volatile-Matter of Tanjung Enim Coal by using Thermogravimetry Analyzer (TGA). Coal is a nature material which a kind of energy source. The decompotition of coal could analyze by heat treated using thermogravimetry analyzer. The decomposition of the volatile matter for three kinds of Tanjung Enim coal could be known. The value of activation energy that be found diference, then for Semi Anthracite, Bitumonius and Sub Bituminous Coal, the initial temperatures are 60.8 oC, 70.7 oC, 97.8oC, and the last temperatures are 893.8 oC, 832 oC, 584.6oC.

Gtaw ايجادشده با روش جوشکاری Tini-Tic و Tini بررسی ريزساختاری پوشش, Masoud Harooni, Morteza Shamanian, Alireza Fadaei Tehrani

Masoud Harooni

هدف از انجام اين پژوهش بهبود سختي سطحي و ريزساختار فولاد ساده کربنی از نوع 52 و مقايسه ريز ساختار اين دو با هم GTAW ايجاد شده به روش جوشکاری TiNi-TiC و TiNi پوششی از بترتيب با نسبت استوکيومتری مساوي و نسبت ۲۰ Ti-Ni-C و Ti-Ni است. بدين منظور مخلوط پودری به طور جداگانه توسط روش فعال سازی مکانيکی فعال شد و سپس بر سطح TiC درصد تقويت کننده به ضخامت ۱ ميليمتر پيش نشانده شده با استفاده از روش جوشکاری قوسی St نمونه های فولادی 52 تنگستن- گاز ذوب و با فلز پايه امتزاج يافته است. جهت بررسي نوع …

Ocena Wielkości Emisji Do Powietrza Z Arcelormittal Poland S.A. Oddział W Krakowie W Odniesieniu Do Standardów Unii Europejskiej, Marian Mazur, Marek Bogacki, Robert Oleniacz

Robert Oleniacz

The work presents emission factors of main air pollutants for installations of ArcelorMittal Poland S.A. Unit in Krakow (Poland) in comparison with analogous characteristic emissions for iron and steel industry in West Europe. In the comparison four installations (to coke, sinter, pig iron and steel production) were taken into consideration. The emission rates from ArcelorMittal Poland S.A. Unit in Krakow were estimated on the basis of the emission levels and production data from 2004, when took place the most significant production of liquid steel during last several years. As a result of the analysis, most the emission factors (with the …

Environmental Effects On Corrosion Properties Of Alloy 22, Mano Misra

Publications (YM)

This document presents detailed technical report for four Subtasks that were conducted independently. All four Subtasks investigated environmental effects on corrosion properties of Alloy 22. The four Subtasks that were investigated are as follows: Subtask 1: Experimental Determination of Parameters for the General Corrosion Model. Subtask 2: Corrosion under Dust Deposits Containing Hygroscopic Salts. Subtask 3: Heated Electrode Approach for the Study of Corrosion Under Aggressive Conditions. Subtask 4: Effect of Hydrogen Permeation on the Stability of the Passive Film of Alloy 22.

The Role Of Silicon Content On Environmental Degradations Of T91 Steels, Ajit K. Roy, D. Maitra, Pankaj Kumar

Mechanical Engineering Faculty Research

T91 grade steels showed a gradual enhancement in tensile ductility at ambient temperature due to an increase in Si content from 0.5 to 2.0 weight percent (wt.%). However, the ultimate tensile strength was reduced only above 1.5 wt.% Si. The corrosion potential became more active in an acidic solution with increasing temperature. The cracking susceptibility in a similar environment under a slow-strain-rate (SSR) condition was enhanced at higher temperatures showing reduced ductility, time to failure, and true failure stress. Cathodic potentials applied to the test specimens in SSR testing caused an enhanced cracking tendency at 30 and 60°C, suggesting hydrogen …

Tensile Deformation Of A Nickel-Base Alloy At Elevated Temperatures, Ajit K. Roy, Anand Venkatesh, Vikram Marthandam

Mechanical Engineering Faculty Research

The results of tensile testing involving Waspaloy indicate that the failure strain was gradually reduced at temperatures ranging between ambient and 300 °C. Further, serrations were observed in the engineering stress versus strain diagrams in the temperature range of 300-600 °C. The reduced failure strain and the formation of serrations in these temperature regimes could be the result of dynamic strain aging of this alloy. The extent of work hardening due to plastic deformation was reduced at temperatures above 300 °C. A combination of ductile and intergranular brittle failures was seen at temperatures above 600 °C. γ′ was detected at …

The Effect Of Ozone And Zeolite Concentration To The Performance Of The Treatment Of Wastewater Containing Heavy Metal Using Flotation Process, Eva Fathul Karamah, Setijo Bismo, Hotdi M. Simbolon

Makara Journal of Technology

The Effect of Ozone and Zeolite Concentration to the Performance of the Treatment of Wastewater Containing Heavy Metal Using Flotation Process. Industrial wastewater which contains heavy metal cannot be disposed to the environment directly, due to its toxicity. In this research, separation of metal from wastewater was conducted by sorptive flotation method, using Lampung natural zeolite as bonding agent. The most common diffuser used in the flotation process is air or oxygen. In this research, ozone is used as diffuser because it is a stronger oxidant and more dissolvable in water than oxygen. Besides, ozone is a coagulant aid and …

The Development Of Inverter Fuzzy Logic Control For Induction Motor Control By Vector Control Method In Electric Vehicle, Era Purwanto, Mohammad Ashary, Subagio Subagio, Mauridhi Heri Purnomo

Makara Journal of Technology

The development of Inverter Fuzzy Logic Control for Induction Motor Control by Vector Control Method in Electric Vehicle. In response to concerns about energy cost, energy dependence, and environmental damage, a rekindling of interest in electric vehicles (EV’s) has been obvious. Thus, the development of power electronics technology for EV’s will take an accelerated pace to fulfill the market needs, regarding with the problem in this paper is presented development of fuzzy logic inverter in induction motor control for electric vehicle propulsion. The Fuzzy logic inverter is developed in this system to directed toward developing an improved propulsion system for …

Ad Hoc On-Demand Distance Vector (Aodv) Routing Protocol Performance Evaluation On Hybrid Ad Hoc Network: Comparison Of Result Of Ns-2 Simulation And Implementation On Testbed Using Pda, Riri Fitri Sari, Abdusy Syarif, Bagio Budiardjo

Makara Journal of Technology

Ad Hoc on-Demand Distance Vector (AODV) Routing Protocol Performance Evaluation on Hybrid Ad Hoc Network: Comparison of Result of Ns-2 Simulation and Implementation on Testbed using PDA. In Mobile Ad hoc NETwork (MANET), node supplemented with wireless equipment has the capacity to manage and organise autonomously, without the presence of network infrastructures. Hybrid ad hoc network, enable several nodes to move freely (mobile) to create instant communication. Independent from infrastructure. They could access the Local Area Network (LAN) or the Internet. Functionalities of ad hoc network very much dependent on the routing protocol that determines the routing around node. Ad …

Internet Congestion Control System, Pranoto Hidaya Rusmin, Carmadi Machbub, Agung Harsoyo, Hendrawan Hendrawan

Makara Journal of Technology

Internet Congestion Control System. Internet congestion occurs when resource demands exceeds the network capacity. But, it is not the only reason. Congestion can happen on some users because some others user has higher sending rate. Then some users with lower sending rate will experience congestion. This partial congestion is caused by inexactly feedback. At this moment congestion are solved by the involvement of two controlling mechanisms. These mechanisms are flow/congestion control in the TCP source and Active Queue Management (AQM) in the router. AQM will provide feedback to the source a kind of indication for the occurrence of the congestion …

The Role Of 1 And 9 Wt.% Zn In Precipitation Hardening Of Aa319 Aluminium, Bondan Tiara Sofyan, Sari Susanti, Ridwan R. Yusfranto

Makara Journal of Technology

The Role of 1 and 9 wt.% Zn in Precipitation Hardening of AA319 Aluminium. Aluminium alloys are widely used for automotive application due to its low density and high corrosion resistance. For economic reason, casting of automotive products always uses aluminium scrap as charging materials that may result in fluctuation of content of alloying element, such as Zn. This research studies the role of Zn in precipitation hardening of AA319 aluminium alloys. Hardness and tensile testing were conducted to study the mechanical properties of the alloys, while ageing response was followed by hardness measurements. Evolution of microstructures was observed by …

A Study Of Co2 Absorption Using Jet Bubble Column, Setiadi Setiadi, Nita Tania Hadiyani, Hantizen Hantizen, Dijan Supramono

Makara Journal of Technology

A Study of CO2 Absorption Using Jet Bubble Column. The phenomenon of plunging jet gas-liquid contact occurs quite often in nature, it's momentum carries small air bubbles with it into the reactor medium. The momentum of the liquid stream can be sufficient to carry small bubbles completely to the bottom of the vessel. A stream of liquid falling toward a level surface of that liquid will pull the surrounding air along with it. It will indent the surface of the liquid to form a trumpet-like shape. If the velocity of the stream is high enough, air bubbles will be pulled …

Building Fire Safety Audit At Faculty X, University Of Indonesia, Year 2006, Fatma Lestari, Rm. Yodan Amaral Panindrus

Makara Journal of Technology

Building Fire Safety Audit at Faculty X, University of Indonesia, Year 2006. Fire may cause loss of life, material and valuable assets. The objective of this study is to conduct audit for fire safety and emergency response in the building at Faculty X, University of Indonesia, Depok. The audit results on the building fire safety facilities including emergency response and preparedness are then compared to the Building Code Australia (BCA) and Indonesian regulation on the building fire safety (Kep.MenPU.No 10 and 11/KPTS/2000). The building selected are Building A, B, C, D, F and G. Building classification for A, B, D, …

Substrates Preparation From Woody Tropical Waste Biomass For Biohydrogen Production, Dwi Susilaningsih, Theresia Umi Harwati, Khairul Anam, Yopi Yopi

Makara Journal of Technology

Substrates Preparation from Woody Tropical Waste Biomass for Biohydrogen Production. Addressing to the global warming problem, energy crisis and pollution, hydrogen production by micro-organisms using biotechnological approach should be considered, since it fulfils the recent society requirement to safely produce, renewable and environmental friendly energy. Hydrogen is one of the most promising green energy sources, because it is easily converted to electricity and cleanly combustible. There are three types of micro-organisms for hydrogen production, the first is cyanobacteria through the photosynthesis process, the second is anaerobic bacteria, which use organic substances as electron donor and energy and convert them to …

Biomass Production Chlorella Vulgaris Buitenzorg Using Series Of Bubble Column Photo Bioreactor With A Periodic Illumination, Anondho Wijanarko, Dianursanti Dianursanti, Muryanto Muryanto, Josia Simanjuntak, Praswasti Pembangun Dyah Kencana Wulan, Heri Hermansyah, Misri Gozan, Roekmijati Widaningroem Soemantojo

Makara Journal of Technology

Chlorella vulgaris Buitenzorg cultivation using three bubble column photo bioreactors arranged in series with a volume of 200 mL for 130 hours shows an increase of biomass production of Chlorella vulgaris Buitenzorg up to 1.20 times and a decrease of the ability of CO2 fixation compared to single reactor at a periodic sun illumination cycle. The operation conditions on cultivation are as following: T, 29.0oC; P,1 atm.; UG, 2.40 m/h; CO2, 10%; Benneck medium; and illumination source by Phillip Halogen Lamp 20W /12V/ 50Hz. Other research parameters such as microbial carbon dioxide transferred rate (qco2), CO2 transferred rate (CTR), energy …

Sub-Surface Corrosion Research On Rock Bolt System, Perforated Ss Sheets And Steel Sets For The Yucca Mountain Repository — Quarterly Technical Report No. 14, Dhanesh Chandra, Jaak J.K. Daemen

Publications (YM)

This report shows the work done for this period in accordance to cooperative agreement of University of Nevada system for the Task 019 “Subsurface Corrosion Research on Rock Bolt System, Perforated SS Sheets and Steel Sets for the Yucca Mountain Repository”, the overall objective of which is to conduct corrosion research and predict the durability of rock-bolts and other underground metallic roof supports. We are performing oxidation tests using Thermogravimetric Analyzer (TGA), and Potentiodynamic and immersion tests to determine the corrosion rates of rock bolts.

In this quarter specifically we have accomplished the following:

Potentiodynamic tests were performed to determine …

Linking The Structure And Mechanical Behavior Of Nanoporous Gold, Ye Sun

University of Kentucky Doctoral Dissertations

The structure of nanoporous gold (np-Au) provides a very limited volume for deformation to occur, and thus offers an opportunity to study the role of defects such as dislocations in nanoscale metal volumes. A practical goal is to understand mechanical properties of np-Au so that it can be can produced in stable form, for use in applications that require some mechanical integrity. Bulk and thin film np-Au have been fabricated and studied here.

Bulk np-Au was prepared by electrochemically dealloying Au-Ag alloys with 25 and 30 at.% Au. In the lower Au content material, cracks always formed during dealloying. When …

Structural Characteristics Of Some Ternary Ag-In-Sn Alloys, Zeljko J. Kamberovic

Zeljko J Kamberovic

The Ag-In-Sn system, as one of potential lead-free solder materials, was studied in this paper. The investigated alloys were chosen from two sections, with molar ratio of In:Sn equal to 1:4; 1:2. DTA, XRD, SEM and microhardness investigations were used in order to determine structural characteristics of chosen Ag-In-Sn ternary alloys.

Fundamental And Applied Experimental Investigations Of Corrosion Of Steel By Lbe Under Controlled Conditions: Kinetics, Chemistry Morphology, And Surface Preparation, John Farley, Allen L. Johnson

Transmutation Sciences Materials (TRP)

Advanced nuclear processes and facilities (e.g., transmutation of nuclear waste, fast reactors, and spallation neutron sources) impose special demands on materials, which must withstand high temperatures, high radiation fields, and chemical corrosion. Proposed schemes for transmuting nuclear waste require a nonmoderating coolant such as lead-bismuth eutectic (LBE) or liquid sodium. While LBE corrodes most steels, small amounts of oxygen in the LBE greatly reduces the corrosion rate, and could ideally re-grow a damaged oxide layer in situ. The protective oxide layer would thus be self-healing. However, a fundamental understanding of the role of oxygen and passivating oxide layers is presently …

Effect Of Silicon Content On The Corrosion Resistance And Radiation-Induced Embrittlement Of Materials For Advanced Heavy Liquid Metal Nuclear Systems, Ajit K. Roy

Transmutation Sciences Materials (TRP)

The beneficial effects of Si on both the metallurgical and corrosion properties of Cr-Mo steels have previously been demonstrated at UNLV. Therefore, additions of Si ranging from 0.5-2.0 weight percent (wt%) was attempted in this investigation to explore Si effect on both the high temperature tensile properties and corrosion behavior of T91 grade steel. Corrosion studies in the presence of molten LBE could not be performed due to a lack of proper experimental facilities at UNLV. Therefore, detailed corrosion studies involving Si-containing T91 grade steels were performed in an aggressive aqueous solution of acidic pH. Further, significant efforts have been …

Theoretical Modeling Of Protective Oxide Layer Growth In Non-Isothermal Lead Alloy Coolant Systems, Yitung Chen, Taide Tan, Jinsuo Zhang, Jichun Li

Transmutation Sciences Materials (TRP)

In advanced nuclear energy systems, lead alloys emerge as strong candidates for transmutation and advanced reactor systems as nuclear coolants and spallation neutron targets. However, it is widely recognized that corrosion of materials caused by lead alloys presents a critical barrier to their industrial use. A few experimental research and development projects have been set up by different groups such as at Los Alamos National Laboratory to study the corrosion phenomena in their test facilities and to develop mitigation techniques and materials. One of the central or main techniques under development is to use active control of oxygen thermodynamic activity …

Development Of Nanostructure Based Corrosion-Barrier Coatings On Steel For Transmutation Applications, Biswajit Das

Transmutation Sciences Materials (TRP)

Advanced transmutation systems require structural materials that are able to withstand high neutron fluxes, high thermal cycling, and high resistance to chemical corrosion. The current candidate materials for such structures are ferritic and ferritic-martensitic steels due to their strong resistance to swelling, good microstructural stability under irradiation, and the retention of adequate ductility at typical reactor operating temperatures.

In parallel, lead-bismuth eutectic (LBE) has emerged as a potential spallation target material for efficient production of neutrons, as well as a coolant in the accelerator system. While LBE has excellent properties as a nuclear coolant, it is also highly corrosive to …

Interaction Between Metal Fission Products And Triso Coating Materials, Clemens Heske

Fuels Campaign (TRP)

This project focuses on the chemical bonding and interface formation of metal fission products with the coating materials used in tri-isotropic (TRISO) fuel particles for gas-cooled reactors. By combining surface- and bulk-sensitive spectroscopic and microscopic methods, intermediate chemical phases at the interface, intermixing/diffusion behavior, and the electronic interface structure for different coating materials and metals are examined.

In detail, the project studies the interface formation of Pd, Cs, and Ag with SiC and pyrolytic carbon. Using SiC single crystals and highly-ordered pyrolytic carbon (HOPG) as substrates, interfaces are prepared under controlled conditions in an ultra-high vacuum environment and are studied …