Metallurgy Commons^™

The Use Of 2d Plastic Grating For Surface Profile And Dimension Manufacture Product Measurements By Using Ndt Moiré Technique, Retno Wigajatri P., Dini Andiani

Makara Journal of Technology

The Use of 2D Plastic Grating for Surface Profile and Dimension Manufacture Product Measurements by Using NDT Moiré Technique. Research of measuring the shape and dimension of object using the moiré technique have been done. Measurement have been made by observing the moiré space as a result of interaction between grating and its shadow casted on the object’s surface caused by the projector lamp with CCD camera. The acquired data was further processed by way of off-line. By successive phase shifts that is π/2, π dan 3π/2 towards the table tennis ball at the distance of 48 cm from the …

Investigation Of The Corrosion Of Steel By Lead-Bismuth Eutectic (Lbe) Using Scanning Electron Microscopy And X-Ray Photoelectron Spectroscopy, Daniel Koury

UNLV Theses, Dissertations, Professional Papers, and Capstones

Lead Bismuth Eutectic (LBE) has been proposed for use in programs for accelerator transmutation of waste. LBE is the leading candidate material as a spallation target and an option for the sub-critical blanket coolant. The corrosion of 316 and 316L stainless steels by LBE has been studied using UNLV's facilities for Scanning Electron Microscopy (SEM) and X-ray Photoelectron Spectroscopy (XPS). We have compared exposed and unexposed samples and studied the differences. Some amount of surface contamination is present on the samples and has been removed by ionbeam etching. The unexposed samples reveal typical stainless steel characteristics: a chromium oxide passivation …

Segmented Roll For Casting Metal Strip, James R. Sauer, Ronald J. O'Malley, Robert S. Williams

Materials Science and Engineering Faculty Research & Creative Works

Casting molten metal using a segmented roll for casting continuous metal strip. A strip caster (10) for producing a continuous strip (18) includes a tundish for containing a melt and a pair of horizontally disposed water cooled composite casting rolls (84). The casting rolls are juxtaposed relative to one another for forming a pouring basin (16) for receiving molten metal. The composite rolls are formed from a plurality of annular segments (45). Each segment preferably includes at least a pair of coolant openings (34) and means for aligning the coolant openings, such as a pair of alignment openings (26). The …

Corrosion Of Steel By Lead Bismuth Eutectic: Quarterly Report August September October 2002, John Farley

Transmutation Sciences Materials (TRP)

We continued with sputter depth profiling of 316 and 316L steel samples that have been exposed to LBE. We also calibrated the sputter depth profiling using a sample of SiO₂ on Si, and the SEM. This is a valuable independent determination of the thickness of oxide layers.

In the laboratory, progress continues using the XPS machine. Experiments have been performed on steel samples using Argon ions to mill away the surface of the sample, thereby making measurements as a function of depth. This "ion beam milling" proceeds slowly through the oxide layer that covers the steel sample. We are …

Development Of A Mechanistic Understanding Of High-Temperature Deformation Of Alloy Ep-823 For Transmutation Applications: Annual Progress Report (September 2001 – August 2002), Ajit K. Roy, Brendan O'Toole

Transmutation Sciences Materials (TRP)

The purpose of this project is to evaluate the elevated temperature tensile properties of Alloy EP-823, a leading target material for accelerator-driven waste transmutation applications. This alloy has been proven to be an excellent structural material to contain the lead-bismuth-eutectic (LBE) nuclear coolant needed for fast spectrum operations. Very little data exist in the open literature on the tensile properties of this alloy. The test material will be thermally treated prior to the evaluation of its tensile properties at temperatures relevant to the transmutation applications. The deformation characteristics of tensile specimens, upon completion of testing, will be evaluated by surface …

Modeling, Fabrication, And Optimization Of Niobium Cavities: Phase Ii Quarterly Report, Robert A. Schill Jr., Mohamed Trabia

Transmutation Sciences Materials (TRP)

Multipacting is one of the major loss mechanisms in rf superconductivity cavities for accelerators. This loss mechanism limits the maximum amount of energy/power supported by the cavities. Optimal designs have been identified in others’ studies. In practice, these designs are not easily manufactured. Chemical etching processes used to polish the cavity walls result in a nonuniform surface etch. A nonuniform surface etch will leave some unclean areas with contaminants and micron size particles. These significantly affect mutipacting. Further, a nonuniform etch will leave areas with damaged grain structure, which is not good for superconducting properties. Typically, the depth of chemical …

Hydrogen-Induced Embrittlement Of Candidate Target Materials For Applications In Spallation-Neutron-Target Systems: Quarterly Progress Report (June 01 – August 31, 2002), Ajit K. Roy, Brendan O'Toole

Transmutation Sciences Materials (TRP)

The primary objective of this task is to evaluate the effect of hydrogen on environment-assisted cracking of candidate target materials for applications in spallation-neutron-target (SNT) systems such as accelerator production of tritium (APT) and accelerator transmutation of waste (ATW). The materials selected for evaluation and characterization are martensitic stainless steels including Alloy HT-9, Alloy EP 823 and Type 422 stainless steel. The susceptibility to stress corrosion cracking (SCC) and hydrogen embrittlement (HE) of these materials are being evaluated in environments of interest using tensile specimens under constant load and slow-strain-rate (SSR) conditions. Further, the localized corrosion behavior of these alloys …

Use Of Positron Annihilation Spectroscopy For Stress-Strain Measurements: Quarterly Progress Report (June 1 – August 31, 2002), Ajit K. Roy

Transmutation Sciences Materials (TRP)

The purpose of this collaborative research project involving the University of Nevada Las Vegas (UNLV), the Idaho State University (ISU), and the Los Alamos National Laboratory (LANL) is to evaluate the feasibility of determining residual stresses in cold-worked, plastically-deformed, and welded materials using a nondestructive method based on positron annihilation spectroscopy. This technique uses γ-rays from a small MeV electron Linac to generate positrons inside the sample via pair production. This method is known to have capabilities of characterizing defects in thick specimens, that could not be accomplished by conventional positron technique or other nondestructive methods. The generated data will …

Modeling Corrosion In Oxygen Controlled Lbe Systems With Coupling Of Chemical Kinetics And Hydrodynamics-Task V: Final Report -Phase I 09/01/2001-08/30/2002, Samir Moujaes, Yitung Chen

Transmutation Sciences Materials (TRP)

The Lead-Bismuth eutectic (LBE) has been determined from previous experimental studies by the Russians and the European scientific community to be a potential material that can be used as a spallation target and coolant for the AAA proposed application. Properly controlling the oxygen content in LBE can drastically reduce the LBE corrosion to structural steels. However, existing knowledge of material corrosion performance was obtained from point-wise testing with only very sparse experimental data. Scientists have noticed that the concentration of oxygen dissolved in the liquid alloy could control the corrosion rate of steels exposed to Pb or Pb-Bi. At high …

Design And Analysis For Melt Casting Metallic Fuel Pins Incorporating Volatile Actinides: Quarterly Progress Report 5/16/02- 8/15/02, Yitung Chen, Randy Clarksean, Darrell Pepper

Fuels Campaign (TRP)

An important aspect of the Advanced Accelerator Applications (AAA) program is the development of a casting process by which volatile actinide element (i.e., americium) can be incorporated into metallic alloy fuel pins. The traditional metal fuel casting process uses an inductively heated crucible.

This process works well for the fabrication of metal fuel pins traditionally composed of alloys of uranium and plutonium, but does not work well when highly volatile actinides are included in the melt. The problem occurs both during the extended time period required to superheat the alloy melt as well as when the chamber must be evacuated. …

The Effects Of Corrosive Chemicals On Corrosion Rate Of Steel Reinforcement Bars: I. Swamp Water, Sulistyoweni Widanarko, Henki W. Ashadi, Andri Krisnadi Wicaksono

Makara Journal of Technology

Most of infrastructures using steel concrete to reinforce the strength of concrete. Steel concrete is so vulnerable to chemical compounds that can cause corrosion. It can happen due to the presence of chemical compounds in acid environment in low pH level. These chemical compounds are SO4 2-, Cl-, NO3 -. There are many swamp area in Indonesia. The acid contents and the concentration of ion sulphate, chlorides, and nitrate are higher in the swamp water than in the ground water .The objective of this research was to find out the influence of corrosive chemicals in the swamp water to the …

The Effects Of Corrosive Chemicals On Corrosion Rate Of Steel Reinforcement Bars: Ii. Swamp Sludges, Henki W. Ashadi, Sulistyoweni Widanarko, Irma Gusniani

Makara Journal of Technology

A polluted environment will influence the building age. The objective of this research was to find out the influence of corrosive chemicals within the sludge swamp area with the corrosion rate of steel concrete. Corrosion in steel concrete usually occur in acid area which contain of SO4 2-, Cl- and NO3 -. The research treatment used by emerging ST 37 and ST 60 within 60 days in ‘polluted’ sludge swamp area. Three variation of ‘polluted’ swamp sludge were made by increasing the concentration a corrosive unsure up to 1X, 5X and 10X. The corrosion rate measured by using an Immersion …

The Effect Of Ca Content On Cao-Zeolite On Nitrogen Adsorption Capacity, Mohammad Nasikin, Tania Surya Utami, Agustina Tp Siahaan

Makara Journal of Technology

In industry, Ca zeolite is used as nitrogen selective adsorbent with the use of PSA (Pressure Swing Adsorption)/VSA (Vacuum Swing Adsorption) methods. Natural zeolite modified to be Cao-zeolite by ion exchange process using Ca(OH)2. Adsorption test was done on CaO-zeolite with different Ca concentration to understand how it’s adsorption phenomena on oxygen and nitrogen. Adsorption test has been done for CaO-zeolite with Ca concentration = 0,682%, 0,849% and 1,244% to oxygen and nitrogen with equal concentration seperately. Pressure variation has being done three times (5 minutes long each time) adsorption time to analyze the connection between adsorption time and how …

Cetane Number Booster Additive For Diesel Fuel Synthesized From Coconut Oil, Mohammad Nasikin, Rita Arbianti, Abdul Azis

Makara Journal of Technology

To reduce NOx, SOx, HC, and particulates that produce because of using diesel fuel, can be done by increasing cetane number. One of methods is adding an additive to diesel fuel. 2-Ethyl Hexyl Nitrate (2-EHN) is a commercial additive that an organic nitrate. Making an additive in this research is used palm oil by nitration reaction that used HNO3 and H2SO4. Result of this reaction is methyl ester nitrate that has a structure looks like 2-EHN. IR spectra from research show that methyl ester nitrate is indicated by spectrum NO2 at 1635 cm-1. This result show that methyl ester nitrate …

Analogy Method Development For Cost Estimation Of Software Design, Riyanarto Sarno, Joko Lianto Buliali, Siti Maimunah

Makara Journal of Technology

The important aspect of planning and managing software development project is to estimate the cost of a project. There are several methods for estimating the cost of a software development project, and the Analogy method is a method which gives relatively better estimates. This paper shows that the modified Analogy method selects a closer project reference, estimates more accurate project effort and cost. This study enhances the cost estimate technique by including valid and complete cost parameters, therefore the estimate of a project cost is better than the result of the standard Analogy method.

The Role Of Si3n4 Amorphous Phase In Nc-Tin/A-Si3n4 Nanocomposites In Increases The Hardness And Thermal Stability, Keba Moto

Makara Journal of Technology

The role of Si3N4 amorphous phase in nc-TiN/a-Si3N4 nanocomposites will be shown and compared with polycrystalline ZrN/Ni which has no such amorphous phase (non-composites). The presence of amorphous phase Si3N4 increases the hardness of film as well as the toughness of the bulk nanocomposites under indentation load. It has been observed that nc-TiN/a-Si3N4 nanocomposites films has higher thermal stability than ZrN/Ni polycrystalline films.

Biodiesel's Characteristics Preparation From Palm Oil, Tilani Hamid. S, Rachman Yusuf

Makara Journal of Technology

Biodiesel’s characteristics preparation from palm oil. Using vegetable oils directly as an alternative diesel fuel has presented engine problems. The problems have been attributed to high viscosity of vegetable oil that causes the poor atomization of fuel in the injector system and pruduces uncomplete combustion. Therefore, it is necessary to convert the vegetable oil into ester (metil ester) by tranesterification process to decrease its viscosity. In this research has made biodiesel by reaction of palm oil and methanol using lye (NaOH) as catalyst with operation conditions: constant temperature at 60 oC in atmosferic pressure, palm oil : methanol volume ratio …

Development Of Hardness Measurement Procedure For Nanocomposite Nc-Tin/A-Si3n4, Keba Moto

Makara Journal of Technology

Hardness of nc-TiN/a-Si3N4 nanocomposites which was determined by using two methods of measurements i. e. depth sensing method and remaining plastic indentation area that were magnified by using SEM (Scanning Electron Microscope) lie in the good agreement. The hardness value is not influenced by the biaxial and residual compressive stress. The measurement of the biaxial stress on the substrate shows a very small value of biaxial stress as well as the constant hardness and crystallite size against annealing temperature. Therefore, the reported hardness value here is the intrinsic value that depend on its microstructure properties.

Corrosion Of Steel By Lead Bismuth Eutectic: Quarterly Report For May-June-July 2002, John Farley

Transmutation Sciences Materials (TRP)

The goal of this project is to understand the basic science of corrosion in the steel/LBE system.

We are taking more data, typically using the newly installed X-ray Photoelectron Spectrometry (XPS) apparatus, and analyzing our existing data. Undergraduate students Denise Parsons and Julia Manzerova have helped a great deal in the analysis of the data. We can obtain the elemental composition as a function of position within the sample. This gives clues to the migration of materials, the composition of the protective oxide layer, and the basic science of the corrosion process. We found dramatic differences between the exposed and …

Design And Analysis For Melt Casting Metallic Fuel Pins Incorporating Volatile Actinides, Xiaolong Wu

UNLV Theses, Dissertations, Professional Papers, and Capstones

Fundamental issues related to the selection of a metallic fuel casting furnace design are presented and discussed including heating mechanisms, casting issues, crucible design, and issues related to the mass transport of americium. The process of evaluating all of these different criteria is undertaken to select a concept that would have the greatest chance of success for casting americium in a metallic fuel rod. Based on this evaluation process, a concept for the casting of metallic fuel pins containing high vapor pressure materials is selected and discussed. The important physics of this concept include mass transport of americium from the …

Hydrogen-Induced Embrittlement Of Candidate Target Materials For Applications In Spallation-Neutron-Target Systems: Annual Progress Report (May 2001 – May 2002), Ajit K. Roy, Brendan O'Toole

Transmutation Sciences Materials (TRP)

The primary objective of this task is to evaluate the effect of hydrogen on environment-assisted cracking of candidate target materials for applications in spallation-neutron-target (SNT) systems such as accelerator production of tritium (APT) and accelerator transmutation of waste (ATW). The materials selected for evaluation and characterization are martensitic stainless steels including Alloy HT-9, Alloy EP 823 and Type 422 stainless steel. The susceptibility to stress corrosion cracking (SCC) and hydrogen embrittlement (HE) of these materials are being evaluated in environments of interest using tensile specimens under constant load and slow-strain-rate (SSR) conditions. Further, the localized corrosion behavior of these alloys …

Development Of A Mechanistic Understanding Of High-Temperature Deformation Of Alloy Ep-823: Aaa Task-10 Quarterly (03/01, 2002 –05/31, 2002) Report, Ajit K. Roy, Brendan O'Toole

Transmutation Sciences Materials (TRP)

The objective of this task is to evaluate the elevated temperature tensile properties of Alloy EP-823, a leading target material for accelerator-driven waste transmutation applications. The test material will be thermally treated prior to evaluation of its tensile properties at temperatures relevant to the transmutation applications. The deformation characteristics of tensile specimens, upon completion of testing, will be evaluated by surface analytical techniques including scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The overall results are expected to provide a mechanistic understanding of high-temperature deformation behavior of Alloy EP-823 as a function of heat treatment.

Highlights of Accomplishment

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Modeling Corrosion In Oxygen Controlled Lbe Systems With Coupling Of Chemical Kinetics And Hydrodynamics: Quarterly Progress Report 03/16/02- 06/15/02, Samir Moujaes, Yitung Chen

Transmutation Sciences Materials (TRP)

The Lead-Bismuth eutectic (LBE) has been determined from previous experimental studies by the Russians and the European scientific community to be a potential material that can be used as a spallation target and coolant for the AAA proposed application. Properly controlling the oxygen content in LBE can drastically reduce the LBE corrosion to structural steels. However, existing knowledge of material corrosion performance was obtained from point-wise testing with very limited density. Scientists have noticed that the concentration of oxygen dissolved in the liquid alloy could control the corrosion rate of steels exposed to Pb or Pb-Bi. At high oxygen concentration, …

Modeling Corrosion In Oxygen Controlled Lbe Systems With Coupling Of Chemical Kinetics And Hydrodynamics-Phase Two, Samir Moujaes, Yitung Chen

Transmutation Sciences Materials (TRP)

The proposed work will combine chemical kinetics and hydrodynamics in target and test-loop lead-bismuth eutectic (LBE) systems to model system corrosion effects. This approach will result in a predicative tool that can be validated with corrosion test data, used to systematically design tests and interpret the results, and provide guidance for optimization in LBE system designs. The task includes two subtasks. The first subtask is to try to develop the necessary predictive tools to be able to predict the levels of oxygen and corrosion products close to the boundary layer through the use of Computational Fluid Dynamics (CFD) modeling. The …

Development Of A Mechanistic Understanding Of High-Temperature Deformation Of Alloy Ep-823 For Transmutation Applications, Ajit K. Roy, Brendan O'Toole

Transmutation Sciences Materials (TRP)

The purpose of this project is to evaluate the elevated temperature tensile properties of Alloy EP-823, a leading target material for accelerator-driven waste transmutation applications. This alloy has been proven to be an excellent structural material to contain the lead-bismuth-eutectic (LBE) nuclear coolant needed for fast spectrum operations. However, very little data exist in the open literature on the tensile properties of this alloy. The selection of Alloy EP-823 as the test material in the proposed task is based on the recommendation of our collaborator at the Los Alamos National Laboratory (LANL). The test material will be thermally treated prior …

Humidity And Temperature Boundaries For Biofilm Formation In Yucca Mountain, Terry Ann Else, Penny S. Amy, James Jay, Amy J. Smiecinski

Publications (YM)

To determine the long-term success of the recommended Yucca Mountain high-level nuclear waste repository, studies of bacterial colonization and biofilm development are needed. Bacteria involved in microbially-influenced corrosion and degradation are known to form biofilms with the potential to impact the integrity of repository packaging and structural materials. Temperature and humidity are environmental factors that can greatly affect biofilm formation. Therefore, it is necessary to determine the temperature and humidity conditions that affect biofilm formation. Microcosms, which simulated the repository environment of Yucca Mountain, were placed at temperatures ranging from 30° C to 70° C and in relative humidities ranging …

Evaluation Of Lead Anode Reactions In Acid Sulfate Electrolytes: Ii. Manganese Reactions, Pu Yu, Thomas J. O'Keefe

Materials Science and Engineering Faculty Research & Creative Works

Lead alloys containing calcium-tin, silver, or similar combinations are the primary insoluble anodes used for copper and zinc electrowinning. One potential concern with these anodes is the detrimental effect on cathode purity from incorporation of lead corrosion products. Other factors which are important to process economics are the reaction potential and overpotential required for oxygen evolution. In addition to the inherent overpotential, impurities in the electrolyte can have a significant polarization impact, such as the films that may form when manganese is present. In order to gain a better understanding of the fundamental behavior of various concentrations of manganese ions …

Design And Analysis Of A Process For Melt Casting Metallic Fuel Pins Incorporating Volatile Actinides, Yitung Chen, Darrell Pepper, Randy Clarksean

Fuels Campaign (TRP)

UNLV has developed and will continue to develop process models for the analysis of melt casting processes. This work will continue to be performed under the guidance of Argonne National Laboratory (ANL) engineers to ensure that their knowledge and experience benefits the project. The research to be conducted during the second year will center on performing detailed analyses on a conceptual design of an inductively heated skull-crucible casting furnace. Processing conditions will be analyzed, basic models utilized, and detailed heat and mass transfer models will be developed to analyze the most promising processes. The goal of this second year is …

Modeling, Fabrication, And Optimization Of Niobium Cavities: Phase Ii, Robert A. Schill Jr., Mohamed Trabia

Transmutation Sciences Materials (TRP)

Niobium cavities are important parts of the integrated NC/SC high-power linacs. Over the years, researchers in several countries have tested various cavity shapes. They concluded that elliptically shaped cells are the most appropriate shape for superconducting cavities. The need for very clean surfaces led to the use of a buffered chemical polishing procedure for surface cleaning to get good performance of the cavities. This proposal discusses the second phase of research in the second year of the project.

The first phase (starting Summer 2001) has resulted in improving the basic understanding of multipacting and the process of chemical etching. Based …

Use Of Positron Annihilation Spectroscopy For Stress-Strain Measurements, Ajit K. Roy

Transmutation Sciences Materials (TRP)

The purpose of this collaborative research project involving the University of Nevada, Las Vegas (UNLV) and Idaho State University (ISU) is to evaluate the feasibility of determining residual stresses of welded (after pre-straining) engineering materials using a new nondestructive technique based on positron annihilation spectroscopy. The proposed technique is to use γ-rays 2 from a small MeV electron Linac to generate positrons inside the sample via pair production. This method can be used for materials characterization and investigation of defects in thick samples that could not be accomplished by conventional positron techniques or other nondestructive methods. The data generated will …