Metallurgy Commons^™

Fundamental And Applied Experimental Investigations Of Corrosion Of Steel By Lbe Under Controlled Conditions: Kinetics, Chemistry Morphology, And Surface Preparation, John Farley, Allen L. Johnson, Dale L. Perry

Transmutation Sciences Materials (TRP)

Advanced nuclear processes such as the transmutation of nuclear waste, fast reactors, liquid-metal-cooled reactors, and spallation neutron sources require advanced materials systems to contain them. The required structural materials must be stable in the presence of nonmoderating coolants. A prime candidate for such a coolant is Lead Bismuth Eutectic (LBE). Materials in these systems must be able to tolerate high neutron fluxes, high temperatures, and chemical corrosion. Unfortunately, LBE corrodes stainless steel.

The corrosive behaviors of structural materials in LBE are not well understood. The Russians have over 80 reactor-years experience with LBE coolant in their Alpha-class submarine reactors. The …

Theoretical Modeling Of Protective Oxide Layer Growth In Non-Isothermal Lead Alloy Coolant Systems, Yitung Chen, Jinsuo Zhang, Huajun Chen, Jichun Li

Transmutation Sciences Materials (TRP)

The goal of this research project is to provide a basic understanding of the protective oxide layer behaviors and to develop oxide layer growth models of steels in non-isothermal lead alloys (lead or lead-bismuth eutectic) coolant systems. Precise studies and simulations of all hydrodynamics with thermal conditions encountered in practical coolant loop systems by use of different flowing conditions in the laboratory are difficult and expensive, if not impossible. Therefore it is important and necessary to develop theoretical models to predict the protective oxide layer behaviors at the design stage of a practical lead-alloy coolant system, to properly interpret and …

Effect Of Welding Parameters On Properties Of 5052 Al Friction Stir Spot Welds, T. A. Freeney, S. R. Sharma, Rajiv S. Mishra

Materials Science and Engineering Faculty Research & Creative Works

Effect of process parameters on friction stir spot welding (FSSW) of 5052 Al alloy has been evaluated. a plunge type FSSW machine was used for this study. Sheet thicknesses of 1 and 1.6mm were used. the tool rotation rate was varied between 1000 and 3000 rpm. the tool plunge rate and dwell time was varied to give weld cycle of 1-4 seconds. Shear tests were performed in 2 sheet and 3 sheet configurations to determine the influence of processing parameters on the mechanical properties of lap joint FSSWs. Higher joint strengths were observed at lower tool rotation rates. Copyright © …

Cracking Of Martensitic Alloy Ep-823 Under Controlled Potential, Ajit K. Roy, M. K. Hossain

Mechanical Engineering Faculty Research

The susceptibility of martensitic Alloy EP-823 to stress corrosion cracking was evaluated with and without an applied cathodic potential using the slow-strain-rate (SSR) testing technique. The magnitude of the applied potential was based on the corrosion potential determined by cyclic polarization. The cracking susceptibility in an acidic environment at different temperatures was expressed in terms of the true failure stress (ơ_f), time to failure (TTF), and ductility parameters, including percent elongation (%El) and percent reduction in area (%RA). The data indicate that the magnitudes of ơ_r, TTF, %El, and %RA were reduced due to cathodic charging. …

Corrosion Mechanisms And Kinetics Of Steels In Lead-Bismuth Eutectic: Quaterly Report, Allen L. Johnson, John Farley

Transmutation Sciences Materials (TRP)

A large number of studies of corroded samples were conducted using SEM, XPS, probe, and the TEM. Samples from the DELTA loop at LANL and from other sources were examined. Also, the investigation of 316 class stainless steel in LBE is continuing.

Corroded samples of D-9 steel have been in the process of being studies, which is a variant of 316 stainless steel that is optimized for resistance to swelling. The D-9 samples are notable for the process in which a localized failure of the protective oxide layer becomes widespread corrosion. The research group is examining the D-9 samples using …

Effect Of Silicon Content On The Corrosion Resistance And Radiation- Induced Embrittlement Of Materials For Advanced Heavy Liquid Metal Nuclear Systems, Ajit K. Roy

Transmutation Sciences Materials (TRP)

This task is primarily focused on the evaluation of the effect of Si content on the susceptibility of modified 9Cr-1Mo-0.24V steel to stress corrosion cracking (SCC) and localized cracking in both molten lead-bismuth eutectic (LBE) and an aqueous solution of acidic pH.

Further, significant efforts are in progress to characterize the deformation mechanism of modified T91 grade steel as a function of temperature and strain rate. Simultaneously, surface analyses of the tested materials are ongoing using state-of-the-art techniques including scanning electron microscopy (SEM) and transmission electron microscopy (TEM).

Corrosion Barrier Development For Lbe Corrosion Resistance: Quarterly Report (April 2006), Biswajit Das

Transmutation Sciences Materials (TRP)

As reported in the last quarterly report, synthesis of Cr nanowires was found to be problematic in terms of uniform coverage. Hence Ni was identified as the alternative metal to form the nanowires. The purpose of the metal nanowires is to provide structural integrity to the nanoporous alumina, as well as a second defense mechanism against corrosion by oxidizing in case the top alumina layer is compromised. Nickel was selected due to its established electrochemical synthesis procedure. While Ni can provide very good structural integrity to the porous alumina, one potential problem is its higher dissolution rate in LBE. However, …

Development Of Nanostructure Based Corrosion-Barrier Coatings On Steel For Transmutation Applications, Biswajit Das

Transmutation Sciences Materials (TRP)

Advanced transmutation systems require structural materials that are able to withstand high neutron fluxes, high thermal cycling, and high resistance to chemical corrosion. The current candidate materials for such structures are ferritic and ferritic-martensitic steels due to their strong resistance to swelling, good microstructural stability under irradiation, and the retention of adequate ductility at typical reactor operating temperatures.

In parallel, lead bismuth eutectic (LBE) has emerged as a potential spallation target material for efficient production of neutrons, as well as a coolant in the accelerator system. While LBE has excellent properties as a nuclear coolant, it is also highly corrosive …

Interaction Between Metal Fission Products And Triso Coating Materials: A Study Of Chemical Bonding And Interdiffusion: 1st Quarterly Report, 2006, Clemens Heske

Fuels Campaign (TRP)

This project is devoted to an in-depth study of the chemical and electronic impact of metal fission products on the coating layers in TRISO nuclear fuel. In particular, there is a focus on the investigation of Pd, Cs, and Ag and their interface formation with SiC and carbon-based substrates. A variety of surface and near-surface bulk sensitive probes that investigate the occupied and unoccupied electronic states of the substrate and the metal overlayer have been utilized. By a controlled and stepwise deposition of the metal overlayer, it is possible to gain substantial insight into the formation of interfaces and their …

Interaction Between Metal Fission Products And Triso Coating Materials, Clemens Heske

Fuels Campaign (TRP)

In this project the chemical bonding and interface formation of metal fission products with the coating materials used in TRISO fuel particles is investigated. The interface formation of Pd, Cs, and Ag with SiC and pyrolytic carbon is studied in detail. Using the SiC single crystals and TRISO coating materials as substrates, interfaces are prepared under controlled conditions in an ultra-high vacuum environment and are studied with a photoelectron spectroscopy, Auger electron spectroscopy, Inverse Photoemission, X-ray emission spectroscopy, and X-ray absorption spectroscopy. Recent additions to the experimental approach include microscopic techniques (Transmission Electron Microscopy, Scanning Tunneling Microscopy, Atomic Force Microscopy) …

Synthesis Of Fuel Cell Membrane: Copolymerization Of Styrene On Etfe Film By Grafted Pre-Irradiation, Yohan Yohan, Rifai M. Nur, Lilik Hendrajaya, E. S. Siradj

Makara Journal of Technology

Synthesis of Fuel Cell Membrane: Copolymerization of Styrene on ETFE Film by Grafted pre-Irradiation. Preirradiation Grafting styrene monomer on ETFE film has been prepared. Research has been performed by γ-ray radiation at various total dose from 2.5 – 12.5 kGy and various dose rate from 1.3 – 1.9 kGy/hour. Irradiated copolymer is then grafted by styrene monomer in various solvent: ethanol, 2-propanol, and toluene, various concentration from 20 – 70% volume, various temperature from 50 – 90oC, and various grafting time from 2 – 12 hours. The results showed that percent of grafting is increase with increase of total dose …

Design Of Product Placement Layout In Retail Shop Using Market Basket Analysis, Isti Surjandari, Annury Citra Seruni

Makara Journal of Technology

Retailing is an industry with high level of competition. It is a customer-based industry which depends on how it could be aware of what the customers’ needs and requirements are. One technique most used in supermarkets is the mix merchandise. The purpose of this paper is to identify associated products, which then grouped in mix merchandise with the use of market basket analysis. This association between products then will be applied in the design layout of the product in the supermarket. The process of identifying the related products bought together in one transaction is done by using data mining technique. …

Production Hydrogen And Nanocarbon Via Methane Decomposition Using Ni-Based Catalysts. Effect Of Acidity And Catalyst Diameter, Widodo W. Purwanto, M. Nasikin, E. Saputra, L. Song

Makara Journal of Technology

Objectives of this research are mainly to study impacts of acidity strength (by varying amount of precipitant and loading Al-Si) and the effect of nickel particle size (by varying calcinations temperature) on decomposition reaction performances. In this research, high-nickel-loaded catalyst is prepared with two methods. Ni-Cu/Al catalysts were prepared with co-precipitation method. While the Ni-Cu/Al-Si catalyst were prepared by combined co-precipitation and sol-gel method. The direct cracking of methane was performed in 8mm quartz fixed bed reactor at atmospheric pressure and 500-700°C. The main results showed that the Al content of catalyst increases with the increasing amount of precipitant. The …

Design And Implementation Of 1-2 Ghz Stepped Frequency Gpr For Buried Metal Detection, Joko Suryana, Andriyan B. Suksmono, Tati R. Mengko

Makara Journal of Technology

Design and Implementation of 1-2 GHz Stepped Frequency GPR for Buried Metal Detection. In this paper, we describe the design and realization steps of 1 – 2 GHz SFGPR (Stepped Frequency Ground Penetrating Radar) transceiver for metal detection under the ground. Before using prototyped GPR for detecting the metal under the ground, several of calibration processes must be performed, namely phase calibration and monocycle pulse waveform calibration. After completing the calibrations, this prototyped GPR would be ready for detecting a hidden object such as a metal plate 5 cm under the ground in our small test range size 25 cm …

Simultaneous Treatment Of Organic (Phenol) And Heavy Metal (Cr6+ Or Pt4+) Wastes Over Tio2, Zno-Tio2 And Cds-Tio2 Photocatalysts, Slamet Slamet, R. Arbianti, Daryanto Daryanto

Makara Journal of Technology

Simultaneous Treatment of Organic (Phenol) and Heavy Metal (Cr6+ or Pt4+) Wastes over TiO2, ZnO-TiO2 and CdS-TiO2 Photocatalysts. Treatment of heavy metal (Cr6+ and Pt4+) and organic (phenol) wastes has been studied using the relatively new method, i.e. simultaneous photocatalytic process over TiO2 photocatalysts in the batch photoreactor. Following the photocatalytic reduction of the heavy metal wastes, recovery of Cr and Pt was carried out by precipitation and leaching method, respectively. The experimental results show that in the simultaneous photocatalytic system, there is a synergism effect between the photocatalytic reduction of heavy metal waste (Cr6+ or Pt4+) and the oxidation …

Design Of Generating Dual Frequency Operation For Triangular Microstrip Antenna Using Electromagnetic Coupling, Indra Surjati, Eko Tjipto Rahardjo, Djoko Hartanto

Makara Journal of Technology

Design of Generating Dual Frequency Operation for Triangular Microstrip Antenna Using Electromagnetic Coupling. A new design is proposed in this paper by applying a pair of slits using a microstrip feed line. Therefore the microstrip line feeding system is electromagnetically coupled to the patch. The antenna works at two different frequencies in the range from 2 GHz to 4 GHz (S band frequency). The results of the simulation shows that the dual frequency operation can be created when the slit width is 1 mm and the height of the slits ranges from 10 mm to 14 mm with inter slit …

Development Of Low Frequency Vibration Method Of Direct-Write Deposition Relevant To Layer Manufacturing Application, Susilo Adi Widyanto, Alva Edy Tontowi, Jamasri Jamasri, Heru Santosa Budi Rochardjo

Makara Journal of Technology

The research of deposition process is the first step in development process of multi materials selective laser sintering. The deposition process enables to settle multi materials powder in horizontal formation on one layer. In this research we use low frequency (70 - 200Hz) to vibrate a hopper nozzle in which powder is settled. The research method consists of two steps, the first step is to determine flow-ability parameters and the second is to join flow ability parameter with other parameters such that the line width can be controlled. The results show that the line width depends on uniformity of particle …

Sub-Surface Corrosion Research On Rock Bolt System, Perforated Ss Sheets And Steel Sets For The Yucca Mountain Repository — Quarterly Technical Report No. 5, Dhanesh Chandra, Jaak J.K. Daemen

Publications (YM)

This report encompasses the work done for this third quarter, 2005, in accordance to cooperative agreement of University of Nevada system for the Task 019 “Subsurface Corrosion Research on Rock Bolt System, Perforated SS Sheets and Steel Sets for the Yucca Mountain Repository”, the overall objective of which is to conduct corrosion research and predict the durability of rock-bolts and other underground metallic roof supports. We have started oxidation tests using Thermogravimetric Analyzer (TGA), and Potentiodynamic tests to determine the corrosion rates of rock bolts, other support materials including bench mark materials. In this quarter, we have also performed (1) …

Journal Of Materials Engineering And Performance: Editorial, C. Suryanarayana, Leon L. Shaw, Rajiv S. Mishra

Materials Science and Engineering Faculty Research & Creative Works

No abstract provided.

Modeling, Fabrication, And Optimization Of Niobium Cavities Final Phase: Final Report, Robert A. Schill Jr., Mohamed Trabia, William Culbreth

Transmutation Sciences Materials (TRP)

This final report provides the activities and accomplishments of Modeling, Fabrication, and Optimization of Niobium Cavities – Final Phase. The fluid flow experiments for the etching of the superconducting cavity walls and baffle designs of phase II of the three phases has been completed leading to a MS thesis in December of 2003. Designing the experimental setup of secondary electron emission was well underway in early summer of 2003 when funding was made available for this portion of the study. By March 2004, many of the components of the experimental study reached UNLV with some assembly accomplished. The first secondary …

Use Of Positron Annihilation Spectroscopy For Stress-Strain Measurements: Quarterly Progress Report (March – May 2005), Ajit K. Roy

Transmutation Sciences Materials (TRP)

Accomplishments:

● Analyses of defects (dislocations) in martensitic Alloy EP-823, cold-reduced to different levels, have been performed by using transmission electron microscopy. The dislocation density has been related to the degree of cold-reduction and residual stress in terms of a line-shape parameter determined by the positron annihilation spectroscopy (PAS).

● Additional PAS measurements are ongoing on tensile, welded and cold-worked specimens of Alloys EP-823 and HT-9 at the Idaho Accelerator Center of ISU. Both Subhra and Silpa are involved in these measurements.

● Silpa is performing neutron diffraction (ND) measurements at the Atomic Energy of Canada Limited (AECL), Chalk River …

Sub-Surface Corrosion Research On Rock Bolt System, Perforated Ss Sheets And Steel Sets For The Yucca Mountain Repository — Quarterly Technical Report No. 4, Dhanesh Chandra, Jaak J.K. Daemen

Publications (YM)

This report encompasses the work done for this third quarter, 2005, in accordance to cooperative agreement of University of Nevada system for the Task 019 “Subsurface Corrosion Research on Rock Bolt System, Perforated SS Sheets and Steel Sets for the Yucca Mountain Repository”, the overall objective of which is to conduct corrosion research and predict the durability of rock-bolts and other underground metallic roof supports. We have started oxidation tests using Thermogravimetric Analyzer (TGA), and Potentiodynamic tests to determine the corrosion rates of rock bolts, other support materials including bench mark materials. In this quarter, we have also performed hydrogen …

Effect Of Silicon Content On The Corrosion Resistance And Radiation-Induced Embrittlement Of Materials For Advanced Heavy Liquid Metal Nuclear Systems: Quarterly Progress Report (February – April 2005), Ajit K. Roy

Transmutation Sciences Materials (TRP)

This proposal is intended to study the effect of Si content not only on the corrosion resistance but also on the radiation-induced embrittlement of martensitic stainless steels. The susceptibility of these alloys with different Si content to stress corrosion cracking, general corrosion and localized corrosion will be evaluated in the molten LBE and aqueous environments of different pH values using state-of-the-art testing techniques. Testing in the aqueous media is intended to develop baseline data for comparison purpose. Radiation-induced embrittlement of these alloys will initially be studied by irradiating the test specimens with bremmstrahlung gamma radiation from 20-40 MeV electron beams …

Use Of Positron Annihilation Spectroscopy For Stress-Strain Measurements: Quarterly Progress Report (December 01, 2004 – February 28, 2005), Ajit K. Roy

Transmutation Sciences Materials (TRP)

The purpose of this collaborative research project involving the University of Nevada Las Vegas (UNLV), the Idaho State University (ISU), and the Los Alamos National Laboratory (LANL) is to evaluate the feasibility of determining residual stresses in cold-worked, plastically-deformed (bent), and welded materials using a nondestructive method based on positron annihilation spectroscopy (PAS). This technique uses γ-rays from a small MeV electron Linac to generate positrons inside the sample via pair production. This method is known to have capabilities of characterizing defects in thick specimens that could not be accomplished by conventional positron technique or other nondestructive methods. The data …

Effect Of Silicon Content On The Corrosion Resistance And Radiation-Induced Embrittlement Of Materials For Advanced Heavy Liquid Metal Nuclear Systems: Quarterly Progress Report (November 2004 – January 2005), Ajit K. Roy

Transmutation Sciences Materials (TRP)

This proposal is intended to study the effect of Si content not only on the corrosion resistance but also on the radiation-induced embrittlement of martensitic stainless steels. The susceptibility of these alloys with different Si content to stress corrosion cracking, general corrosion and localized corrosion will be evaluated in the molten LBE and aqueous environments of different pH values using state-of-the-art testing techniques. Testing in the aqueous media is intended to develop baseline data for comparison purpose. Radiation-induced embrittlement of these alloys will initially be studied by irradiating the test specimens with bremmstrahlung gamma radiation from 20-40 MeV electron beams …

Modeling, Fabrication, And Optimization Of Niobium Cavities: Phase Iii Fourth Quarterly Report, Robert A. Schill Jr., Mohamed Trabia, William Culbreth

Transmutation Sciences Materials (TRP)

Niobium cavities are important parts of the integrated NC/SC high-power linacs. Over the years, researchers in several countries have tested various cavity shapes. They concluded that elliptically shaped cells are the most appropriate shape for niobium superconducting cavities. The surface preparation can significantly affect the secondary electron emission yields. Such yields are used in design codes. Current codes use values obtained from niobium samples cleaned by a different means at temperatures other than the operating temperature. Secondary electron emission studies on LANL surface-cleaned niobium are conducted with preliminary data presented in this report at room temperature. Soon studies will be …

Sub-Surface Corrosion Research On Rock Bolt System, Perforated Ss Sheets And Steel Sets For The Yucca Mountain Repository — Quarterly Technical Report No. 3, Dhanesh Chandra, Jaak J.K. Daemen

Publications (YM)

This report encompasses the work done for third quarter in accordance to cooperative agreement of UCCSN for the Task 019 “Subsurface Corrosion Research on Rock Bolt System, Perforated SS Sheets and Steel Sets for the Yucca Mountain Repository”, the objective of which was proposed earlier, to conduct corrosion research and predict the durability of rockbolts and other underground metallic roof supports. We have recently started working on oxidation tests using Thermogravimetric Analyzer (TGA), stress corrosion cracking/hydrogen embrittlement studies on rock bolts, other support materials including bench mark materials. In this quarterly report we will discuss “Dry” oxidation of steels and …

3d Modelling With Linear Approaches Using Geometric Primitives, Mochammad Zuliansyah

Makara Journal of Technology

In this paper, we study linear approaches for 3D model acquisition from non-calibrated images. First, the intrinsic and extrinsic camera calibration is taken into consideration. In particular, we study the use of a specific calibration primitive: the parallelepiped. Parallelepipeds are frequently present in man-made environments and naturally encode the affine structure of the scene. Any information about their euclidean structure (angles or ratios of edge lengths), possibly combined with information about camera parameters is useful to obtain the euclidean reconstruction. We propose an elegant formalism to incorporate such information, in which camera parameters are dual to parallelepiped parameters, i.e. any …

Tensile Properties Of Martensitic Stainless Steels At Elevated Temperatures, Ajit K. Roy, Srinivasarao R. Kukatla, Bhagath Yarlagadda, V. N. Potluri, Martin Lewis, Brendan O'Toole

Mechanical Engineering Faculty Research

Tensile properties of quenched and tempered martensitic alloys EP-823, HT-9, and 422 were evaluated at temperatures ranging from ambient to 600 °C as a function of three different tempering times. The results indicated that the yield strength, ultimate tensile strength, and the failure strength were gradually reduced with increasing temperature. The ductility parameters were enhanced at elevated temperatures due to increased plastic flow. However, the tempering time did not significantly influence these properties. The evaluation of the fracture surfaces by scanning electron microscopy revealed reduced cracking and dimpled microstructures, indicating enhanced ductility at higher testing temperatures.

Residual Stress Characterization In Structural Materials By Destructive And Nondestructive Techniques, Ajit K. Roy, Anand Venkatesh, Vikram Marthandam, Satish Dronavalli, Douglas P. Wells, Ronald Rogge

Mechanical Engineering Faculty Research

Transmutation of nuclear waste is currently being considered to transform long-lived isotopes to species with relatively short half-lives and reduced radioactivity through capture and decay of minor actinides and fission products. This process is intended for geologic disposal of spent nuclear fuels for shorter durations in the proposed Yucca Mountain repository. The molten lead-bismuth-eutectic will be used as a target and coolant during transmutation, which will be contained in a subsystem vessel made from materials such as austenitic (304L) and martensitic (EP-823 and HT-9) stainless steels. The structural materials used in this vessel will be subjected to welding operations and …