Process Control and Systems Commons^™

Operation And Process Control Development For A Pilot-Scale Leaching And Solvent Extraction Circuit Recovering Rare Earth Elements From Coal-Based Sources, Douglas Kweku Addo

Theses and Dissertations--Mining Engineering

The US Department of Energy in 2010 has identified several rare earth elements as critical materials to enable clean technologies. As part of ongoing research in REEs (rare earth elements) recovery from coal sources, the University of Kentucky has designed, developed and is demonstrating a ¼ ton/hour pilot-scale processing plant to produce high-grade REEs from coal sources. Due to the need to control critical variables (e.g. pH, tank level, etc.), process control is required. To ensure adequate process control, a study was conducted on leaching and solvent extraction control to evaluate the potential of achieving low-cost REE recovery in addition …

Development Of A Sustainability Evaluation And Control Framework For Chemical Processes, Shuyun Li

Graduate Theses, Dissertations, and Problem Reports (ETD)

Industry, government, and society have begun to shift from economic stand-alone focus to the inclusion of sustainability in the decision-making process. This shift can be attributed to the growing environmental and social awareness that makes consumers and stakeholders not only care about product quality and cost, but also products and processes that minimize the environmental impact and conserve natural resources. As a result, some progress has been made in recognizing and understanding the challenges of sustainable development, which helps evaluating the sustainability performance of a specific process/product. In particular, sustainability assessment tools and methodologies have been developed to help the …

Design And Implementation Of Model Predictive Control Strategies For Improved Power Plant Cycling, Xin He

Graduate Theses, Dissertations, and Problem Reports (ETD)

Design and Implementation of Model Predictive Control Strategies for Improved Power Plant Cycling

Xin He

With the increasing focus on renewable energy sources, traditional power plants such as coal-fired power plants will have to cycle their load to accommodate the penetration of renewables into the power grid. Significant overshooting and oscillatory performance may occur during cycling operations if classical feedback control strategies are employed for plantwide control. To minimize the impact when power plants are operating away from their designed conditions, model-based optimal control strategies would need to be developed for improved power plant performance during cycling.

In this thesis, …

Online Model Predictive Control Of A Nonisothermal And Nonisobaric Membrane Reactor For Water-Gas Shift Reaction Applications, Jacob Martin Douglas

Graduate Theses, Dissertations, and Problem Reports (ETD)

Online Model Predictive Control of a Nonisothermal and Nonisobaric Membrane Reactor for Water-Gas Shift Reaction Applications Jacob M. Douglas Modern hydrogen production units are tasked with producing the most hydrogen possible while dealing with flow variations caused by changing power demands. Classical methods for hydrogen production employing the water-gas shift reaction are governed by equilibrium limitations that take effect at high temperatures and high concentrations of H2 (Georgis, et al., 2014). The implementation of a membrane reactor with temperature control enables the hydrogen concentration and temperature to reach an equilibrium at a higher concentration of H2. Another challenge that is …

Experimentation And Modeling Of The Effects Of Along-Wind Dispersion On Cloud Characteristics Of Finite-Duration Contaminant Releases In The Atmosphere, Jessica M. Morris

Graduate Theses and Dissertations

Along-wind dispersion, or stretching of the cloud in the direction of the wind, plays an important role in the concentration and modeling of contaminant releases in the atmosphere. Theoretical and empirical derivations were compared for appropriate parameterization of along-wind dispersion. Available field data were analyzed to evaluate and improve previous parameterizations of the along-wind dispersion coefficient, σ_x. An experimental test program was developed and executed in an ultra-low speed wind tunnel at the Chemical Hazards Research Center to determine the effects of the time distribution coefficient on true finite-duration releases from an original area source. Multiple wind speeds, release durations, …

Fluid Agitation Studies For Drug Product Containers Using Computational Fluid Dynamics, Matthew Hiroki Ichinose

Master's Theses

At Amgen, the Automated Vision Inspection (AVI) systems capture the movement of unwanted particles in Amgen's drug product containers. For quality inspection, the AVI system must detect these undesired particles using a high speed spin-stop agitation process. To better understand the fluid movements to swirl the particles away from the walls, Computational Fluid Dynamics (CFD) is used to analyze the nature of the two phase flow of air and a liquid solution.

Several 2-D and 3-D models were developed using Fluent to create simulations of Amgen's drug product containers for a 1 mL syringe, 2.25 mL syringe, and a 5 …

A Nonlinear Systems Framework For Cyberattack Prevention For Chemical Process Control Systems, Helen Durand

Chemical Engineering and Materials Science Faculty Research Publications

Recent cyberattacks against industrial control systems highlight the criticality of preventing future attacks from disrupting plants economically or, more critically, from impacting plant safety. This work develops a nonlinear systems framework for understanding cyberattack-resilience of process and control designs and indicates through an analysis of three control designs how control laws can be inspected for this property. A chemical process example illustrates that control approaches intended for cyberattack prevention which seem intuitive are not cyberattack-resilient unless they meet the requirements of a nonlinear systems description of this property.

Economic Model Predictive Control Design Via Nonlinear Model Identification, Laura Giuliani, Helen Durand

Chemical Engineering and Materials Science Faculty Research Publications

Increasing pushes toward next-generation/smart manufacturing motivate the development of economic model predictive control (EMPC) designs which can be practically deployed. For EMPC, the constraints, objective function, and accuracy of the state predictions would benefit from process models that describe the process physics. However, obtaining first- principles models of chemical process systems can be time-consuming or challenging such that it is preferable to develop physics-based process models automatically from process operating data. In this work, we take initial steps in this direction by suggesting that because experiments that are used to characterize first-principles models often target specific types of data, an …

State Measurement Spoofing Prevention Through Model Predictive Control Design, Helen Durand

Chemical Engineering and Materials Science Faculty Research Publications

Security of chemical process control systems against cyberattacks is critical due to the potential for injuries and loss of life when chemical process systems fail. A potential means by which process control systems may be attacked is through the manipulation of the measurements received by the controller. One approach for addressing this is to design controllers that make manipulating the measurements received by the controller in any meaningful fashion very difficult, making the controllers a less attractive target for a cyberattack of this type. In this work, we develop a model predictive control (MPC) implementation strategy that incorporates Lyapunov-based stability …

Data-Based Nonlinear Model Identification In Economic Model Predictive Control, Laura Giuliani, Helen Durand

Chemical Engineering and Materials Science Faculty Research Publications

Many chemical/petrochemical processes in industry are not completely modeled from a first-principles perspective because of the complexity of the underlying physico-chemical phenomena and the cost of obtaining more accurate, physically relevant models. System identification methods have been utilized successfully for developing empirical, though not necessarily physical, models for advanced model-based control designs such as model predictive control (MPC) for decades. However, a fairly recent development in MPC is economic model predictive control (EMPC), which is an MPC formulated with an economics-based objective function that may operate a process in a dynamic (i.e., off steady-state) fashion, in which case the details …

Process Intervention For Water Recovery In Food Manufacture, Christian Michael Wisniewski

Theses and Dissertations

A case study has been conducted for the recovery of water from complex wastewater at a soluble coffee manufacturing factory. The study has evaluated separation methods for process intervention based on environmental and economic assessments. Water recovery was identified in two possible wastewater streams at the factory: the overall plant effluent and an intermediate stream before it enters on-site pre-treatment. A novel vibratory field membrane separation was tested at the laboratory scale using real factory wastewater and scaled-up using appropriate design protocols. Recovery of water from the intermediate stream proved the most effective, both environmentally and economically. The full-scale vibratory …

Modeling Pharmaceutical Inhibition Of Glucose-Stimulated Renin-Angiotensin System In Kidneys, Ashlee N. Ford Versypt, Minu R. Pilvankar, Hui Ling Yong

Biology and Medicine Through Mathematics Conference

No abstract provided.

Pid Algorithm Design For Automation Of Eukaryote Fermentation, Madison Mann

Chemical Engineering Undergraduate Honors Theses

Single celled eukaryotic organisms are advantageous in the production of proteins for use in biopharmaceuticals due to their ease of cultivation and manipulation. Because of high cell density during fermentation and an ability to allow post-translational protein modifications, yeast is particularly well-suited. To maximize the specific formation rate of the desired proteins, an optimum specific growth rate of the yeast should be found and maintained. This rate is dependent upon pH, temperature, dissolved oxygen content, and carbon feed rate. Fermentation can be done in a fed batch reactor system, and it is possible to use a Buglab (online biomss) sensor …

A Proposed Process And Economic Analysis For A Manufacturing Facility For Nylon 6,6, Perry Doles

Chemical Engineering Undergraduate Honors Theses

The global nylon market is a multi-billion-dollar industry that has been thriving in recent years due to advances in the process technology and its flexibility as a material. Nylon 6,6 is a versatile material with uses in many industries because of its ability manipulated into many forms. It is commonly used in applications that require heat resistance, chemical resistance, and high mechanical strength. It is commonly used in luggage, car parts, carpets, and many other plastic products that require the properties that nylon 6,6 exhibits. The versatility and demand for nylon 6,6 make it an attractive process for many potential …

Some Insights Into The Migration Of Double Imaginary Roots Under Small Deviation Of Two Parameters, Dina Alina Irofti, Keqin Gu, Islam Boussaada, Silviu-Iulian Niculescu

SIUE Faculty Research, Scholarship, and Creative Activity

This paper studies the migration of double imaginary roots of the systems’ characteristic equation when two parameters are subjected to small deviations. The proposed approach covers a wide range of models. Under the least degeneracy assumptions, we found that the local stability crossing curve has a cusp at the point that corresponds to the double root, and it divides the neighborhood of this point into an S-sector and a G-sector. When the parameters move into the G-sector, one of the roots moves to the right halfplane, and the other moves to the left half-plane. When the parameters move into the …

Cfd/Fea Of A Steam Methane Reforming Tube, Matthew Wegener

Research Opportunities for Engineering Undergraduates (ROEU) Program 2017-18

Steam methane reforming is the primary method by which hydrogen is produced; increased efficiency in hydrogen production could enable hydrogen’s usage as an alternative fuel. The objectives of this project are to construct a robust CFD/FEA model of a steam methane reforming tube, and to perform CFD/FEA analysis in both steady and transient operational states, comparing thermal stresses/strains in the tube wall in the two states and relating tube stresses/strains to properties of the process controller.

Strong Stability Of A Class Of Difference Equations Of Continuous Time And Structured Singular Value Problem, Qian Ma, Keqin Gu, Narges Choubedar

SIUE Faculty Research, Scholarship, and Creative Activity

This article studies the strong stability of scalar difference equations of continuous time in which the delays are sums of a number of independent parameters tau_i, i = 1, 2, . . . ,K. The characteristic quasipolynomial of such an equation is a multilinear function of exp(-tau_i s). It is known that the characteristic quasipolynomial of any difference equation set in the form of one-delayper- scalar-channel (ODPSC) model is also in such a multilinear form. However, it is shown in this article that some multilinear forms of quasipolynomials are not characteristic quasipolynomials of any ODPSC difference equation set. The equivalence …

Strong Stability Of A Class Of Difference Equations Of Continuous Time And Structured Singular Value Problem, Qian Ma, Keqin Gu, Narges Choubedar

SIUE Faculty Research, Scholarship, and Creative Activity

This article studies the strong stability of scalar difference equations of continuous time in which the delays are sums of a number of independent parameters τi, i = 1, 2, . . . , K. The characteristic quasipolynomial of such an equation is a multilinear function of e−τis. It is known that the characteristic quasipolynomial of any difference equation set in the form of one-delay-per-scalar-channel (ODPSC) model is also in such a multilinear form. However, it is shown in this article that some multilinear forms of quasipolynomials are not characteristic quasipolynomials of any ODPSC difference equation set. The equivalence between …

Drawing And Twisting Of Graphene Fibers, Gregory T. Lane, Robert J. Sekerak, Isaias Diaz

Mechanical Engineering

The aim of this project was to develop a more automated process for drawing and twisting of graphene fibers than was currently in place. This was implemented by having two chemical baths with variable speed rollers at either end, and intermediate roller to spool fiber between stages, and a twisting cylinder with integral spool to twist the fiber as it is collected. The goal was to have this first iteration deliver a working prototype, however due to manufacturing delays and timing constraints, that will be missed. A second follow-on project would be able to continue the work presented here and …

Process Control Laboratory Skid Refurbishment, Danny Crowder

Williams Honors College, Honors Research Projects

This project evaluates a salvaged process control skid for potential refurbishment and educational re-use. In-lab work evaluated the existing skid. Several process control elements have been recommended for replacement, including the process tank (due to corrosion), the pressure transmitter (operability/corrosion), the flow meters (mechanical) and the control system (age). The control valves, temperature elements and transmitters, pump, holding tanks, and the electrical heat exchanger should be salvaged. An I/P converter and pressure relief valve should be added to the pneumatic feed. Enclosing of all electrical components should be prioritized. An electrical schematic for a new control system should be implemented. …

Use Of Natural Ores As Oxygen Carriers In Chemical Looping Combustion: A Review, Michael J. Matzen, Jessica Pinkerton, Xiaomeng Wang, Yaşar Demirel

Department of Chemical and Biomolecular Engineering: Faculty Publications

Chemical looping combustion (CLC) has gained considerable ground in energy production due to its inherent carbon capture with a minimal energy penalty. The choice of metal oxide used as an oxygen carrier (OC) in CLC has a substantial weight on the overall efficiency of energy production as well as the ultimate cost per MW. While much work has gone into manufacturing synthetic OCs with high fuel conversions, harsh operating conditions and process limitations cause some unavoidable loss of the oxygen carrier. With low production costs and minimal conditioning required, natural ores have grown in interest as cheap alternative oxygen carriers. …

Delay-Independent Stability Analysis Of Linear Time-Delay Systems Based On Frequency, Xianwei Li, Huijun Gao, Keqin Gu

SIUE Faculty Research, Scholarship, and Creative Activity

This paper studies strong delay-independent stability of linear time-invariant systems. It is known that delay-independent stability of time-delay systems is equivalent to some frequency-dependent linear matrix inequalities. To reduce or eliminate conservatism of stability criteria, the frequency domain is discretized into several sub-intervals, and piecewise constant Lyapunov matrices are employed to analyze the frequency-dependent stability condition. Applying the generalized Kalman–Yakubovich–Popov lemma, new necessary and sufficient criteria are then obtained for strong delay-independent stability of systems with a single delay. The effectiveness of the proposed method is illustrated by a numerical example.

Effect Of Packaging Material On Color Properties Of Catsup Tomato Sauce, Naser Kohan-Nia, Babak Pakbin, Razzagh Mahmoudi, Omid Fakhri

Journal of Applied Packaging Research

Catsup and tomato sauce products currently are one of the most popular and commercially available table sauces particularly consumed by young people and families around the world in recent decades. In this study colorimetric properties of catsup sauce samples including L*, a* and b* values in different packaging materials including PP, PE, PET, Glass and Sachet have been investigated during and after 180 days storage time at 22̊ C (environmental temperature). Hunter Lab system has been used to evaluate the color values of sauce samples. According to obtained results of experimental measurements and sensory evaluations, PP and PE packaging materials …

Pilot Scale Demonstration And Evaluation Of Innovative Non-Deslimed Non-Classified Gravity-Fed Hm Cyclone, Yumo Zhang

Theses and Dissertations--Mining Engineering

Coal preparation plants are required in some cases to produce a high-grade product using a low specific gravity cut-point. For these situations, a second higher gravity separation would be desirable to generate a mid-grade product that can be utilized for electricity generation thereby maximizing coal recovery. A study was conducted to evaluate the potential of achieving efficient separations at two different density cut-points in a single stage using a three-product dense medium cyclone. Variations in density cut-point and process efficiency values were quantified as a function of the feed medium density, feed medium-to-coal ratio, and feed pressure using a three-level …

Temperature Control Of An Emulsion Polymerization Process, Evan M. Arnold

Williams Honors College, Honors Research Projects

The project premise was to create a new temperature control scheme for an emulsion polymerization process at the pilot scale with intentions of implementing the system into a production facility in the near future. The data was collected using electronic instrumentation at a current emulsion polymerization pilot plant facility in real-time and saved in a Microsoft Excel format. The control scheme was based on three parameters: the rate of change, temperature dead band around the set point to determine heating or cooling, and a jacket fluid clamp temperature. After research and experimentation on actual emulsion polymerization batches it was determined …

Chemical Storage Of Wind Energy By Renewable Methanol Production: Feasibility Analysis Using A Multi-Criteria Decision Matrix, Michael J. Matzen, Mahdi H. Alhajji, Yaşar Demirel

Department of Chemical and Biomolecular Engineering: Faculty Publications

This study is for the technoeconomic analysis of an integral facility consisting of wind energy-based electrolytic hydrogen production, bioethanol-based carbon dioxide capture and compression, and direct methanol synthesis. ASPEN Plus was used to simulate the facility producing 97.01 mt (metric tons) methanol/day using 138.37 mt CO₂/day and 18.56 mt H₂/day. A discounted cash flow diagram for the integral facility is used for the economic analysis at various hydrogen production costs and methanol selling prices. The feasibility analysis is based on a multi-criteria decision matrix consisting of economic and sustainability indicators comparing renewable and non-renewable methanol productions. …

The Synthesis Of Solid Supported Palladium Nanoparticles: Effective Catalysts For Batch And Continuous Cross Coupling Reactions, Kendra W. Brinkley

Theses and Dissertations

Catalysis is one of the pillars of the chemical industry. While the use of catalyst is typically recognized in the automobile industry, their impact is more widespread as; catalysts are used in the synthesis of 80% of the US commercial chemicals. Despite the improved selectivity provided by catalyst, process inefficiencies still threaten the sustainability of a number of synthesis methods, especially in the pharmaceutical industry. Recyclable solid supported catalysts offer a unique opportunity to address these inefficiencies. Such systems coupled with continuous synthesis techniques, have the potential to significantly reduce the waste to desired product ratio (E-factor) of the production …

Water System For Developing Countries / Disaster Relief Made With Local Materials, Shumon Hasan

Chemistry & Biochemistry Undergraduate Honors Theses

The objective of this project was to design a water purification system that can be constructed from easily available materials, common to the particular country, and is capable of the complete water purification process.

Formulation And Solution Of Contingency Constrained Acopf Problem With Pyomo, Stefanus D. Winarto, Jianfeng Liu, Carl D. Laird

The Summer Undergraduate Research Fellowship (SURF) Symposium

Power grids scattered around the world bring great importance to society as they are challenged to provide economically efficient and reliable power market. With consideration of possible system contingency, which refers to multi-scenario optimization where each scenario considers an individual transmission element failure, the determination of optimal generators’ set points in the transmission network is becoming even more essential and challenging. A problem formulation is developed to solve the optimal allocation and minimize the total operating cost for the nominal case while including a large number of contingency scenarios. To achieve that goal, traditional ACOPF (AC optimal power flow model) …

Orientation-Dependent Pseudomorphic Growth Of Inas For Use In Lattice-Mismatched Mid-Infrared Photonic Structures, Gregory Edward Triplett, Charles Meyer, Emily Cheng

Electrical and Computer Engineering Publications

In this study, InAs was deposited on GaAs (100) and GaAs (111)B 2 degrees towardssubstrates for the purpose of differentiating the InAs growth mode stemming from strain and then analyzed using in-situ reflection high energy electron diffraction, scanning electron microscopy, Raman spectroscopy, reflectance spectroscopy, and atomic force microscopy. The procession of InAs deposition throughout a range of deposition conditions results in assorted forms of strain relief revealing that, despite lattice mismatch for InAs on GaAs (approximately 7%), InAs does not necessarily result in typical quantum dot/wire formation on (111) surfaces, but instead proceeds two-dimensionally due primarily to the surface orientation.