Process Control and Systems Commons^™

Recent Advances In Bioethanol Production From Water Hyacinth: A Critical Review, Umuamina A. Matola, Mahir Mohammed Said, Olga-Ioanna Kalantzi, Abraham K. Temu

Tanzania Journal of Engineering and Technology (TJET)

Water hyacinth (WH) is a highly invasive tropical aquatic weed with high holocellulose and low lignin content, making it a promising lignocellulosic feedstock for second-generation bioethanol production. Producing bioethanol from WH offers a sustainable approach to simultaneously managing invasive biomass and producing renewable energy. This review critically evaluates recent advancements in bioethanol production from WH by examining pretreatment, hydrolysis, and fermentation technologies reported between 2014 and 2024. A PRISMA-guided literature search was conducted using the Scopus and Web of Science databases, and fifty-nine original research articles were selected for analysis. The reviewed studies were comparatively assessed based on pretreatment strategies, …

Physicochemical Properties And Chemical Compositions Of Cashew Nut Shell Liquid Extracted With Carbon Dioxide–Expanded Hexane, Neema Msuya, Joseph Yn Philip, Frank Jacob, Kando K. Janga

Tanzania Journal of Engineering and Technology (TJET)

Cashew nut shell liquid (CNSL) is a mixture of phenolic compounds that can effectively replace commercially available phenols in various applications. This study investigated the physicochemical properties and chemical composition of CNSL extracted using CO₂–expanded hexane (CXH) and compared to the traditional Soxhlet extraction method. Steamed cashew nut shells (sCNS) were used in both cases.  The CXH was carried under varying CO₂-mole fractions (0.468-0.892) and temperatures (20-36 °C) whereas Soxhlet extraction was performed at atmospheric pressure and hexane boiling point. Response Surface Methodology (RSM) with Central Composite Face-Centred Design (CCFD) was employed to evaluate the effect …

Optimization Of Renewable Energy-Based Alkaline Electrolysis Systems For Sustainable Hydrogen Production, Shokhrukhbek Kozimjon Ugli Bakhramov

Chemical Technology, Control and Management

This paper presents a comprehensive optimization study of hydrogen production systems through alkaline water electrolysis powered by photovoltaic energy sources, with a specific focus on Central Asian applications. The research systematically investigates critical operating parameters including KOH electrolyte concentration (25-30 wt%), temperature effects (25-80°C), current density optimization (100-500 mA/cm²), and electrode material performance using cost-effective 316L stainless steel. Experimental results demonstrate that optimized systems achieve solar-to-hydrogen efficiency of 13-15%, with hydrogen production costs ranging from $2-8/kg depending on system scale. The study reveals that maximum performance occurs at 30 wt% KOH concentration, 60-80°C operating temperature, and 200-400 mA/cm² current density. …

Production Of Potassium-Rich Biofertilizer From Composted Banana Peels And Watermelon Rinds, Neema O. Msuya

Tanzania Journal of Engineering and Technology (TJET)

This study investigated the production of biofertilizer from composted banana peels and watermelon rinds, focusing on the mineral content and its impact on plant growth. The process involved characterizing raw materials, producing biofertilizer, analyzing mineral concentrations (potassium, nitrogen and phosphorus), and evaluating its quality through Spiny Amaranth seed growth. A compost bin with three compartments was designed, testing three composting ratios of banana peels to watermelon rinds (2:1, 1:2 and 1:1). Composting was monitored on moisture content, pH, organic matter, and temperature for 37 days. The 1:1 ratio had the lowest temperature (33.45°C) and highest pH (7.08), while the 2:1 …

Effectiveness Of Natural Coagulants In Purification Of Industrial Wastewater: A Case Of Cactus Pads And Watermelon Seeds, Neema O. Msuya

Tanzania Journal of Engineering and Technology (TJET)

This study assessed the potential of cactus pads and watermelon seeds as natural coagulants in industrial wastewater treatment. The global characterization of the two coagulants was done by using the Fourier Transform Infrared (FTIR) to determine the specific functional groups and by zeta potential measurements. A full factorial design was used to design the experiment and analyze the effect of three factors: coagulant dosage, settling time and particle size with three levels each and one replicate on the turbidity removal. ANOVA analyses were used to determine the significance of the factors. Results show that the amino and hydroxyl groups in …

Membrane Reactor Modeling And Optimization For Hydrogen Production, Ayooluwa Tomiwa Akintola

Graduate Theses, Dissertations, and Problem Reports (ETD)

There has been an ongoing trend toward cleaner fuels for more environmentally benign forms of energy generation. Recently, hydrogen has been identified as a clean fuel for energy generation. However, the most established, efficient, and widely utilized technique for producing hydrogen remains the steam methane reforming (SMR) in the presence of catalyst. Unlike other fossil fuels, utilizing methane from natural gas in an SMR process to produce hydrogen emits less, but yet a notable sum of carbon dioxide. Furthermore, the endothermic nature of SMR reactions imply that there is a high energy requirement to obtain a substantial amount of hydrogen …

Modeling And Simulation Of A Process For Upcycling Of Low-Density Polyethylene Plastic Waste To Ethylene, Xiaoyan Wang

Graduate Theses, Dissertations, and Problem Reports (ETD)

Ethylene is one of the most widely produced petrochemicals, with an estimated global output of 180 million metric tons in 2022. Approximately 82 million metric tons of ethylene are used annually for plastic production, primarily for polyethylene (PE), as well as polypropylene (PP) and polyvinyl chloride (PVC). The CO₂ emissions associated with PE production were approximately 14 million metric tons in 2022. Globally, an estimated 70 million metric tons of PE are produced and consumed each year, with the majority (~79%) ending up in landfills or the environment.

This project proposes a novel process in which waste low-density polyethylene (LDPE) …

Investigation Of Heavy Metal Composition And Associated Health Risks From Selected Groundwater Wells In Temeke, Dar-Es-Salaam, Justin M. Jeremiah

Tanzania Journal of Engineering and Technology (TJET)

Water quality continues to be the challenge to residents in Dar es Salaam due to various anthropogenic activities in the city. This study was conducted to assess groundwater quality by determining concentrations of heavy metals. Both probability and Nonprobability sampling techniques were used to collect samples from 40 groundwater wells in 24 wards of Temeke municipal and analysed using Microwave Plasma Atomic Emission Spectrometer (Agilent 4210 MP-AES) at the Geochemistry Laboratory of the University of Dar es Salaam. Results indicated varying heavy metal concentrations ranging from 0.71 ± 0.08 to 6.64 ± 0.21 mg/l for As, 0.02 ± 0.01 to …

Thermogravimetric Analysis And Chemical Kinetics Of Waste Tires, Mahir Mohammed Said

Tanzania Journal of Engineering and Technology (TJET)

The focus of this paper is to analyse the pyrolysis reaction of waste tires. The pyrolysis was studied experimentally using thermal and chemical kinetics. The tires were pyrolyzed using thermogravimetry at a temperature range of 200 to 600°C, with heating rates of 10, 20, and 50°C/min. The activating energy was observed to increase with increased temperature. The highest activating energy was 101.02 kJ/mol at a heating rate of 50°C/min.

Sediment Characteristics And Hydrocarbon Composition Of Makukwa Seep In Southern Tanzania: Potential Implications For Subterranean Hydrocarbon Accumulation, Makungu M. Madirisha

Tanzania Journal of Engineering and Technology (TJET)

Exploring the interplay between natural seeps and nearby sediment and hydrocarbon properties is key to unlocking subsurface hydrocarbon potential. This study presents findings on the hydrocarbon composition and sediment characteristics of the Makukwa seep in southern Tanzania, providing insight into subterranean hydrocarbon accumulation. Sediment analysis across areas A and B, located approximately 20 m apart, showed a decrease in porosity with depth, indicative of typical sandstone formations. Area A, near the seeps, exhibited porosity ranging from 23% to 36%, whereas Area B, further away, showed porosity ranging from 22% to 38%. This suggests that a lower cretaceous sandstone layer may …

Design And Optimization Of An Azeotropic Distillation Pilot Plant For The Production Of Pure Ethanol, Samwel V. Manyele

Tanzania Journal of Engineering and Technology (TJET)

This study aimed to design an azeotropic distillation plant using Aspen Plus® V10 software and determine optimal process conditions for producing pure ethanol greater than 95% from pre-concentrated near-azeotropic ethanol-water solution. The non-random two-liquid Redlich-Kwong thermodynamic model was the base method for property analysis and performance prediction. Modelling and simulation of the converged process were conducted for fixed column variables (R = 5, N = 12 and p = 1 atm). Plant operating parameters were varied in the range of 0 to 1 for the pre-heater vapour fraction, 2 to 10 for the column feed plates (NFP), 2 to 6 …

Effect Of Zr And W Doping On Microstructures, Transition Temperature And Solar Transmittance Modulation Of Thermochromic W/Zr Co-Doped Vo2 Thin Films, Haji F. Haji

Tanzania Journal of Engineering and Technology (TJET)

Thermochromic W/Zr co-doped VO2-based thin films with different concentrations of Zr were successfully deposited on soda lime glass substrates by direct current (DC) magnetron sputtering of V(99)W(01) alloy and Zr targets at a substrate temperature of 425 °C. The films were characterized by x–ray diffraction (XRD), atomic force microscopy (AFM), Rutherford backscattering spectroscopy (RBS), two-point probe and UV/VIS/NIR spectroscopy. The film’s structural properties evolution was significantly influenced by Zr concentration in the films. The transition temperature and hysteresis loop widths of the films were found to decrease with increasing Zr concentration. For the Zr concentrations of 0.21 at.%, 0.23 at.% …

Study Of The Effects Of Thermal Aging Coupled With Shot-Peening Treatment Of Carbonitrided Din 1.6587 Low Alloy Steel On Retained Austenite And Residual Stresses, Richard J. Katemi

Tanzania Journal of Engineering and Technology (TJET)

This work investigated the effects of thermal aging and shot-peening of carbonitrided 1.6587 steel grade on retained austenite and residual stresses. After carbonitriding samples contained maximum of 0.87% carbon, 0.34% nitrogen and 50 mass. -% retained austenite. Thermal aging conditions investigated were -30°C, 90°C and 150°C while the aging period were 14, 96 and 720 hours. After thermal aging, some of the samples were subjected to shot-peening treatment using standard cut wire shots StD – G3 - 0.6 mm VDFI 8001 with intensity in the range of 0.25 to 0.30 mmA and coverage of 1.00 to 1.24 x 98%. It …

Study Of Reactive Distillation Equipment For Eterification Process, Abbos Elmanov, Abdulaziz Bakhtiyorov, Adham Norkobilov, Olimjon Maksudov, Zarif Oripov

CHEMISTRY AND CHEMICAL ENGINEERING

The purpose of this work is to study the chemical technological processes for eterification processes, and the reactive distillation unit, which carries out the reaction and separation process in one device, was chosen as the object of research. А reаctive distillаtion system is exаmined to produce for the production of Ethyl Acetate (EtAc) viа eterificаtion of acetic acid (HAc) with ethаnol. Optimizаtion methods using sensitivity analysis аre аlso conducted. Cаlculаtion of vаpor liquid equilibrium of the mixture system is done using UNIFАC model. Heat integration from the distillate stream of the column to the acid feed stream and from bottom …

Cfd Study On Two-Phase Flow Patterns In A Pipe With 90º Elbow In Different Operating Conditions, Hagar Alm-Eldin Bastawissi, Mohammed Ahmed Khafagy, E. A. El Shenawy Prof. Dr., Ahmed M. Salem Dr

Journal of Engineering Research

Recently, CFD has offered a technological solution for modelling multi-phase flow in which we can make endless simulations with reduced expenses and effort in high accuracy results; we shall also mention that experimental studies have limitations for safety considerations when experimenting with flow in high temperature or pressure values or medium nature as in nuclear or chemical flows.In this paper, we used the ANSYS FLUENT CFD program to simulate the two-phase flow in a pipe to study the effect of attaching a 90-degree elbow fitting to the piping system, seeking to find out the change in the pattern and resulting …

Schaeffler Icvd Coating Machine, Louis Mcgrath

Williams Honors College, Honors Research Projects

Chemical Vapor Deposition (CVD) is mutual technology used to deposit thin film through a gaseous phase by vaporizing the solid materials. This conventional process usually requires high thermal stability of the materials, which is not applicable for most of the polymeric materials. Therefore, a novel process, initiated Chemical Vapor Deposition (iCVD) is developed by introducing the gaseous monument and initiator to form the thin film in-situ. By adjusting the free-radical polymerization in the vapor phase, a variety of thin and uniform polymer films can be achieved. Depending on the chemistry, iCVD has many categories. This report explains the design …

Level And Temperature Controlled Vessel, Cameron Macesich

Williams Honors College, Honors Research Projects

Using two Arduino microcontrollers, level and temperature Proportional-Integral control systems for a continuously stirred tank reactor were designed and configured. Open-loop step tests were performed and fitted with First Order Plus Time Delay responses so that controller tuning parameters could be analytically derived. The effectiveness of the designed systems was evaluated by monitoring the response of closed-loop setpoint changes.

Optimization Of Styrene From Ethylbenzene Case Study, Jabria Daria Thompson

Honors Theses

The following pages detail the optimization process of styrene from ethylbenzene in the Styrene Production Plant, Unit 500. There were two parts of the assignment, each with slightly different end goals. The goal of the first part of the assignment, was to create a process that would effectively and efficiently increase the negative Net Present Value (NPV) of the production plant. Procedures taken in this process included developing a working kinetic process simulation model and optimizing this model through unit operations and heat integration, as well as developing an accurate economic model that will be used to evaluate the proposed …

Optimizing Virus Prefiltration For Biopharmaceutical Manufacturing, Solomon Isu

Graduate Theses and Dissertations

Virus filters are single-use devices that use a size-based separation process. In virus filters, contaminating virus particles are retained while the therapeutic molecules pass through the membrane pores. Virus filters are an essential component of the overall virus clearance strategy. Sections 1 and 2 of this dissertation provide an introduction and extensive review of monoclonal antibody (mAb) process development, where virus filtration is pivotal. In section 3, prefiltration studies were performed with an industrially relevant IgG1 type mAb using adsorptive and size-exclusion-based prefilters with different mechanisms of action. This mAb has an isoelectric point range of 7.1 to 8.0 and …

Microcystin-Lr Removal From Water Via Enzymatic Linearization And Ultrafiltration, Abelline Fionah, Cannon Hackett, Hazim Aljewari, Laura Brady, Faisal Alqhtani, Isabel C. Escobar, Audie K. Thompson

Chemical Engineering Faculty Publications and Presentations

Microcystin-LR (MC-LR) is a toxin produced by cyanobacteria that can bloom in freshwater supplies. This study describes a new strategy for remediation of MC-LR that combines linearization of the toxin using microcystinase A, MlrA, enzyme with rejection of linearized byproducts using membrane filtration. The MlrA enzyme was expressed in Escherichia coli (E. coli) and purified via a His-tag with 95% purity. Additionally, composite membranes made of 95% polysulfone and 5% sulfonated polyether ether ketone (SPEEK) were fabricated and used to filter a solution containing cyclic and linearized MC-LR. Tests were also performed to measure the adsorption and desorption of MC-LR …

Economic Feasibility Of A Methanol To Dimethyl Ether Production Process To Avoid Contract Failure Shortfalls From The Covid-19 Pandemic, Jacob Noll, Robert Wasson, Harrison Mckinnis

Honors Theses

Our team entered the 2021 AVEVA Academic Competition, where teams of undergraduate senior chemical engineering students competed across the country. The competition was composed of two parts: the base case design and the optimization of a chemical process. As part of the competition, our team is acting as the Engineering team for a fictional company that has given us this project. Due to COVID-19, our methanol producing company has lost a contract with a customer, leaving 23,000 tonnes/yr of unclaimed methanol. We have two choices with this methanol: either sell the methanol on the market at the spot price for …

Thermal Control Development Of A Proton Exchange Membrane Fuel Cell System, Ola Mohammed Taha Al-Shalash

Mechanical Engineering Theses

A fuel cell is an electrochemical energy conversion device that uses fuel to generate electricity. It basically converts the chemical energy of reactants directly into electricity without combustion. In a Proton Exchange Membrane Fuel Cell (PEMFC), the reactants, hydrogen and oxygen, are fed into the two electrodes, anode and cathode, respectively. A reaction takes place at each electrode and produces electricity, as well as water, and heat as the by-products. In order to maximize performance of a fuel cell, many factors can be considered for tuning and control. Temperature management is one of these factors.

A thermal-fluid model of a …

The Potentials Of Faecal Sludge Treatment Using Local Conditioners In Tanzania: A Review, Doglas Benjamin1

Tanzania Journal of Engineering and Technology (TJET)

Worldwide, every day human beings generate millions of tons of Faecal Sludge (FS), which is rich in water, nutrients, energy, and organic compounds. Yet FS is not being managed in a way that permits us to derive value from its reuse, while at the same time, millions of farmers struggle with depleted soils and lack of water. In most of the developing countries, energy for cooking is mainly derived from cutting of trees, either as wood or charcoal. Resource recovery and reuse from FS can create livelihoods, enhance food security, support green economies, reduce waste and contribute to cost recovery …

Design And Cost Analysis Of Acrylic Acid Plant, Adam Ferrier

Chemical Engineering Undergraduate Honors Theses

The purpose of this project was to model and design a plant to produce 75,000 tons per year of acrylic acid. Using the design in section B.9 of Richard Turton’s Analysis, Synthesis, and Design of Chemical Processes as a starting point, a plant was designed based around the partial oxidation of propylene to acrylic acid. The final plant design produces about 86,000 tons per year of acrylic acid. Using an interest rate of 10%, the plant has a discounted cash flow rate of return of 32% over 2 years of startup and 10 years of operation. Attached is an executive …

A Proposed Process And Economic Analysis For A Manufacturing Facility For Nylon 6,6, Perry Doles

Chemical Engineering Undergraduate Honors Theses

The global nylon market is a multi-billion-dollar industry that has been thriving in recent years due to advances in the process technology and its flexibility as a material. Nylon 6,6 is a versatile material with uses in many industries because of its ability manipulated into many forms. It is commonly used in applications that require heat resistance, chemical resistance, and high mechanical strength. It is commonly used in luggage, car parts, carpets, and many other plastic products that require the properties that nylon 6,6 exhibits. The versatility and demand for nylon 6,6 make it an attractive process for many potential …

Use Of Natural Ores As Oxygen Carriers In Chemical Looping Combustion: A Review, Michael J. Matzen, Jessica Pinkerton, Xiaomeng Wang, Yaşar Demirel

Department of Chemical and Biomolecular Engineering: Faculty Publications

Chemical looping combustion (CLC) has gained considerable ground in energy production due to its inherent carbon capture with a minimal energy penalty. The choice of metal oxide used as an oxygen carrier (OC) in CLC has a substantial weight on the overall efficiency of energy production as well as the ultimate cost per MW. While much work has gone into manufacturing synthetic OCs with high fuel conversions, harsh operating conditions and process limitations cause some unavoidable loss of the oxygen carrier. With low production costs and minimal conditioning required, natural ores have grown in interest as cheap alternative oxygen carriers. …

The Synthesis Of Solid Supported Palladium Nanoparticles: Effective Catalysts For Batch And Continuous Cross Coupling Reactions, Kendra W. Brinkley

Theses and Dissertations

Catalysis is one of the pillars of the chemical industry. While the use of catalyst is typically recognized in the automobile industry, their impact is more widespread as; catalysts are used in the synthesis of 80% of the US commercial chemicals. Despite the improved selectivity provided by catalyst, process inefficiencies still threaten the sustainability of a number of synthesis methods, especially in the pharmaceutical industry. Recyclable solid supported catalysts offer a unique opportunity to address these inefficiencies. Such systems coupled with continuous synthesis techniques, have the potential to significantly reduce the waste to desired product ratio (E-factor) of the production …

Applied Control Strategies At A Cogeneration Plant, Joseph William Burns

Master's Theses

The purpose of this paper is to demonstrate the effectiveness of “classical strategies for dynamic control” on authentic cogeneration processes. These strategies are applied to several processes at the University of Connecticut’s cogeneration plant. Case studies of their applications are presented in this paper. Strategies that are applied include the following:

1) The classical SISO feedback structure

2) The First Order Plus Dead Time (FOPDT) process model

3) The Internal Model Control (IMC) correlations for PI controller tuning

4) Static feed forward with feedback trim

5) Cascade Control

Socio-Economic Impacts Of Computer Viruses In Tanzania, M Victor

Tanzania Journal of Engineering and Technology (TJET)

This paper reports on a research project conducted with an objective of identifying and assessing various approaches used by different computer users (Management, System Administrators and end users) in Tanzania to combat computer viruses (CVs), and to assess users' awareness level on CVs. Specifically, the study aimed at assessing the awareness level on CVs to the Tanzanian business community; analyze the socio -economic impact caused by CVs in Tanzania and; assess existing methods, capacity and limitations on controlling CVs in Tanzania. Data was collected using both questionnaires and interview from financial institutions such as NBC and BOT, and telecommunications sector …

Review Of The Product Development Process And Information Flow In The Manufacturing Industry: Problems And A Possible Wav Forward, E Opiyo

Tanzania Journal of Engineering and Technology (TJET)

No abstract provided.