Nanoscience and Nanotechnology Commons^™

Carbon Composite Fe3O4 Nanoparticles Based Electrochemical Sensor For Hydrogen Peroxide Detection, Si-Yu Zhang, Hui-Juan Wang, Shu-Fang Li, Jian-Ying Qu

Journal of Electrochemistry

In this work, a novel hydrogen peroxide electrochemical sensor was constructed with ferroferric oxide (Fe₃O₄) magnetic nanoparticles, which demonstrated good electrocatalytic activity for hydrogen peroxide. There existed a good linear relationship between the concentration of hydrogen peroxide and the oxidation peak current in the range of 1.00 × 10^-6 ~ 1.00 × 10^-3 mol·L^-1 (R = 0.9980) with the detection limit of 6.60 × 10-7 mol·L^-1. The sensor exhibited good anti-interference ability, high reproducibility and stability.

Lead Modified Nanoporous Platinum Electro-Catalysts For Formic Acid Oxidation, Yuan-Yuan Zhang, Qing-Feng Yi, Ge-Kun-Kun Zuo, Tao Zou, Xiao-Ping Liu, Xiu-Lin Zhou

Journal of Electrochemistry

Platinum (Pt) catalysts modified by other suitable metals significantly enhance their electrochemical activities for formic acid oxidation. In this work, a titanium-supported nanoporous network platinum (nanoPt/Ti) electrode was prepared using a hydrothermal method. The as-prepared nanoPt/Ti electrode was modified with a certain amount of lead by using cyclic voltammetry for different scan cycle numbers (n), namely, n = 10, 15, 20 and 30, to synthesize the novel lead-modified nanoporous Pt (nanoPb_(n)-Pt/Ti) electrodes. Electro-oxidation of formic acid on these electrodes was studied with cyclic voltammetry (CV), chronoamperometry and chronopotentiometry in sulfuric acid solution. CV curves showed that both nanoPt/Ti …

Distribution And Localization Of Novel Iodine Nanoparticles In The Human Glioma 1242 Growing In The Brains Of Mice, Benjamin Billings

Honors Scholar Theses

Observing and designing the in vivo distribution and localization of therapeutic nanoparticles is an essential aspect of developing and understanding novel nanoparticle- based medical treatments. This study investigates novel PEGylated Iodine-based nanoparticles (INPs), an alternate composition to the more widely researched gold nanoparticles (AuNPs), which may help avoid adverse effects associated with AuNPs, such as potential toxicity and skin discoloration, when used in similar applications. Determining the localization of the novel INPs within murine brains containing human glioma U-1242MG cells is critical in assisting the development of radiation dose enhancement therapy for this aggressive cancer. Radiation dose enhancement utilizes the …

Oxidation Of N-Doped Multiwalled Carbon Nanotubes And Formation Of Discontinuous Spiraled Carbon Nanoribbons, Aman Preet Kaur, Mark S. Meier, Rodney Andrews, Dali Qian

Chemistry Faculty Publications

The effects of five commonly used wet chemical oxidations were studied for the extent of oxidation of graphitized nitrogen-doped multiwalled carbon nanotubes (N-MWCNTs). KMnO₄/ H₂SO₄ was the most potent oxidant, as it produced the highest fraction of oxygen-containing functional groups. Electron microscopy studies showed that the treatment of annealed N-MWCNTs (G-N-MWCNTs) with H₂SO₄/HNO₃ and H₂SO₄/KMnO₄ mixtures leads to interesting spiraled ribbon textures. A structural model, involving the stacking of coiled subunits to form a discontinuous carbon nanoribbon rather than a continuous ribbon is proposed to …

Nanoparticle-Mediated Therapeutic Agent Delivery For Treating Metastatic Breast Cancer—Challenges And Opportunities, Yunfei Li, Brock Humphries, Chengfeng Yang, Zhishan Wang

Toxicology and Cancer Biology Faculty Publications

Breast cancer (BC) is the second leading cause of cancer-related death in American women and more than 90% of BC-related death is caused by metastatic BC (MBC). This review stresses the limited success of traditional therapies as well as the use of nanomedicine for treating MBC. Understanding the biological barriers of MBC that nanoparticle in vivo trafficking must overcome could provide valuable new insights for translating nanomedicine from the bench side to the bedside. A view about nanomedicine applied in BC therapy has been summarized with their present status, which is gaining attention in the clinically-applied landscape. The progressions of …

Binder Free Graphene Hybridized Fe3O4 Nanoparticles For Supercapacitor Applications, Nathan D. Jansen

Maseeh Summer Undergraduate Research Experience

In a world with increasing energy demands, the need for safe and mobile energy storage grows. There are a number of renewable energy sources that can be harvested, however peak demand and peak production times tend to not overlap. As the capabilities of collecting the energy grows so does the need to store the energy for later consumption. The two promising methods of storing energy are batteries or supercapacitors. Both technologies employ an electrode consisting of an active material bound to a current collector. This material participates in a redox reaction, storing charge electrochemically to later be used as energy, …

System And Method For Controlling Operations Of Air - Conditioning System, Mouhacine Benosman, Petros Boufounos, Boris Kramer, Piyush Grover

Department of Mechanical and Materials Engineering: Faculty Publications

A method controls an operation of an air - conditioning system generating airflow in a conditioned environment . The method updates a model of airflow dynamics connecting values of flow and temperature of air conditioned during the operation of the air - conditioning system . The model is updated interactively iteratively to reduce an error between values of the airflow determined according to the model and values of the airflow measured during the operation . Next , the method models the airflow using the updated model and controls the operation of the air - conditioning system using the model .

Soft-Microrobotics: The Manipulation Of Alginate Artificial Cells, Samuel Sheckman

Mechanical Engineering Research Theses and Dissertations

In this work, the approach to the manipulation of alginate artificial cell soft-microrobots, both individually and in swarms is shown. Fabrication of these artificial cells were completed through centrifugation, producing large volumes of artificial cells, encapsulated with superparamagnetic iron oxide nanoparticles; these artificial cells can be then externally stimulated by an applied magnetic field. The construction of a Permeant Magnet Stage (PMS) was produced to manipulate the artificial cells individually and in swarms. The stage functionalizes the permanent magnet in the 2D xy-plane. Once the PMS was completed, Parallel self-assembly (Object Particle Computation) using swarms of artificial cells in complex …

Voltage-Controlled Deposition Of Nanoparticles For Next Generation Electronic Materials, Subhodip Maulik

LSU Doctoral Dissertations

This work presents both a feasibility study and an investigation into the voltage-controlled spray deposition of different nanoparticles, namely, carbon nanotubes (CNTs), as well as molybdenum disulfide (MoS₂) and tungsten disulfide (WS₂) from the transition metal dichalcogenides (TMDCs) family of materials. The study considers five different types of substrates as per their potential application to next-generation device electronics. The substrates selected for this research were: 1) aluminum as a conducting substrate, 2) silicon as a semiconducting substrate, 3) glass, silicon dioxide (SiO₂), and syndiotactic poly methyl methacrylate (syndiotactic PMMA) as insulating substrates.

Since the …

Increasing Ph In Cancer: Enabling A New Therapeutic Paradigm Using Novel Carbonate Nanoparticles, Avik Som

McKelvey School of Engineering Graduate Student Theses & Dissertations

Enormous progress has been made to treat cancer, and yet the mortality rate of cancer remains unacceptably high. High clinical resistance to molecularly targeted therapeutics has pushed interest again towards inhibiting universal biochemical hallmarks of cancer. Recent evidence suggests that malignant tumors acidify the local extracellular environment to activate proteases for degrading the tumor matrix, which facilitates metastasis, and explains why more aggressive tumors are more acidic. Current therapies have only focused on using the low pH for enhancing drug release in tumors, thereby still relying on the traditional paradigm of intracellular inhibition of pathways, a method that continues to …

A Study Of Light-Matter Interaction In Nanopatterned Arrays And Biosensing Applications, Mohammad Waliullah

Student Theses and Dissertations

Food fraud and adulteration issue is persistent everywhere in today’s world. Identification of the seafood and meat species correctly, swiftly and economically is a necessity to fight this issue. Every species has its unique DNA. Therefore, identification of DNA will lead to identification of species. Before identification, DNA must be amplified to facilitate analysis. The traditional methods for both amplification and identification of DNA require sophisticated laboratory, trained personnel, high cost and long time. In case of amplification, choosing Recombinase Polymerase Amplification (RPA) method over traditional barcoding method can reduce these problems. In case of identification, fabrication of a novel …

Mesoscale Computational Studies Of Thin-Film Bijels, Joseph M. Carmack

Graduate Theses and Dissertations

Bijels are a relatively new class of soft materials that have many potential applications in the technology areas of energy, medicine, and environmental sustainability. They are formed by the arrest of binary liquid spinodal decomposition by a dispersion of solid colloidal nanoparticles. This dissertation presents an in-depth simulation study of Bijels constrained to thin-film geometries and in the presence of electric fields. We validate the computational model by comparing simulation results with previous computational modeling and experimental research. In the absence of suspended particles, we demonstrate that the model accurately captures the rich kinetics associated with diffusion-based surface-directed spinodal decomposition. …

A Nanoindentation Study Of The Fatigue Properties Of Al/A-Si Core-Shell Nanostructures, Jason Steck

Mechanical Engineering Undergraduate Honors Theses

Nanostructure-textured surfaces can reduce friction and increase the reliability of micro- and nanoelectromechanical systems (NEMS/MEMS). For MEMS incorporating moving parts, the fatigue properties of nanostructures pose a challenge to their reliability in long-term applications. In this study, the fatigue behavior of hemispherical Al/a-Si core-shell nanostructures (CSNs), bare hemispherical Al nanodots, and a flat Al/a-Si layered thin film have been studied using nanoindentation and nano-scale dynamic mechanical analysis (nano-DMA) techniques. Fatigue testing with nano-DMA shows that the deformation resistance of CSNs persists through 5.0 × 10⁴ loading cycles at estimated contact pressures greater than 15 GPa. When the a-Si shell …

Design, Fabrication, And Characterization Of All-Inorganic Quantum Dot Light Emitting Diodes, Ramesh Vasan

Graduate Theses and Dissertations

Quantum dot light emitting diodes are investigated as a replacement to the existing organic light emitting diodes that are commonly used for thin film lighting and display applications. In this, all-inorganic quantum dot light emitting diodes with inorganic quantum dot emissive layer and inorganic charge transport layers are designed, fabricated, and characterized. Inorganic materials are more environmentally stable and can handle higher current densities than organic materials. The device consists of CdSe/ZnS alloyed core/shell quantum dots as the emissive layer and metal oxide charge transport layer. The charge transport in these devices is found to occur through resonant energy transfer …

Glucose Level Estimation Based On Invasive Electrochemical, And Non-Invasive Optical Sensing Methods, Sanghamitra Mandal

Graduate Theses and Dissertations

The purpose of this research is to design and fabricate sensors for glucose detection using inexpensive approaches. My first research approach is the fabrication of an amperometric electrochemical glucose sensor, by exploiting the optical properties of semiconductors and structural properties of nanostructures, to enhance the sensor sensitivity and response time. Enzymatic electrochemical sensors are fabricated using two different mechanisms: (1) the low-temperature hydrothermal synthesis of zinc oxide nanorods, and (2) the rapid metal-assisted chemical etching of silicon (Si) to synthesize Si nanowires. The concept of gold nano-electrode ensembles is then employed to the sensors in order to boost the current …

Non-Covalent Functionalization Of Graphene Films For Uniform Nanoparticle Deposition Via Atoic Layer Deposition, Ty Seiwert

Mechanical Engineering Undergraduate Honors Theses

Graphene functionalized with platinum (Pt) and palladium (Pd) has proven to be highly effective as a hydrogen sensor. Deposition methods such as Atomic layer deposition (ALD) can be further enhanced by pretreating the graphene with a non-covalent surfactant prior to nanoparticle deposition. In this study, graphene-based sensing devices will be fabricated by ALD deposition. The graphene will be non-covalently functionalized using sodium dodecyl sulfate (SDS) anionic surfactant prior to ALD deposition. The aim of this study is to test the deposition pattern achieved by varying the amount of time that graphene is treated with the SDS surfactant. Initially, ALD deposition …

Improving The Selectivity And Reducing The Leakage Of Dna Strand Displacement Systems, Shohei Kotani

Boise State University Theses and Dissertations

Because of the elegance of Watson-Crick base pairing and the programmability of toehold-mediated strand displacement, DNA is a model material for designing, building, and testing molecular assemblies. DNA assemblies are categorized as structural when they are at thermodynamic equilibrium and dynamic when they are not. Through programmed perturbations, metastable assemblies perform physical, chemical, and computational work. When integrated into a diagnostic package, disease-specific nucleic acid sequences can be identified, amplified, and analyzed via standard DNA nanotechnology rules. In order for these rules to make an impact, two critical challenges in the field have been undertaken in this dissertation. First, the …

Concomitant Crystallization In Propylene/Ethylene Random Copolymer With Strong Flow At Elevated Temperatures, Lirong Zheng, Lucia Fernandez-Ballester, Gerrit W. M. Peters, Zhe Ma

Department of Mechanical and Materials Engineering: Faculty Publications

Flow-induced crystallization of α- and γ-phases was studied for a propylene/ethylene random copolymer with 3.4 mol % ethylene at two high temperatures of 132 and 142 °C by combining a pressure-driven slit flow device with real-time synchrotron wide-angle X-ray diffraction. At 132 °C, it was found that both α- and γ-phases were generated at shear stresses ranging from 0.091 to 0.110 MPa and that the γ-phase always appeared later than the α-phase. However, for 142 °C and the same stresses, only the α-phase formed. Only upon cooling the partially crystallized copolymer did the γ-phase emerge. The lack of γ-crystals obtained …

Surface Area And Electrocatalytic Properties Of Feni Nanoparticles For The Oxygen Evolution Reaction (Oer), James Burrow

Chemical Engineering Undergraduate Honors Theses

Iron-nickel bimetallic electrocatalysts have recently emerged as some of the best candidates for the oxygen evolution reaction (OER) in alkaline electrolyte. Understanding the effects of composition and morphology of iron-nickel nanoparticles is crucial for optimization and enhanced electrocatalyst performance. Both physical surface area and electrochemical surface area (ECSA) are functions of morphology. In this study, four different iron-nickel nanoparticle catalysts were synthesized. The catalysts were varied based on morphology (alloy versus core-shell) and composition (low, medium, and high stabilizer concentration). Brunauer-Emmett-Teller (BET) surface area analysis was conducted on three of the synthesized iron-nickel nanoparticles using a physisorption analyzer while electrochemical …

Degradation Of Orange G Through Persulfate Activated Nanoscale Zerovalent Iron Composites And Boron-Doped Diamond Electrodes, Suzana Ivandic

Chemical Engineering Undergraduate Honors Theses

Properly treated wastewater is necessary for water reuse and to avoid unnecessary impacts on the environment. The poultry industry utilizes large amounts of water for poultry processing. The need for innovative ways to treat organic contaminants in the poultry wastewater industry is especially necessary due to increased poultry consumption. The U.S. Department of Agriculture projected Americans would consume approximately 92 pounds of chicken per person in 2017.¹ Dissolved air flotation (DAF) is currently used in poultry wastewater treatment, but DAF does not remove organic contaminants efficiently per effluent standards. Implementation of processes that degrade contaminants directly would benefit the …