Nanoscience and Nanotechnology Commons^™

2024 World Fuel Cell Conference Held In Ningbo, Zhejiang, Editorial Office Of J.Electrochem.

Journal of Electrochemistry

No abstract provided.

Upcoming Meeting-The 1St Young Investigator Symposium On Electrosynthesis, Chinese Chemical Society, Chinese Society Of Electrochemistry (Cse)

Journal of Electrochemistry

No abstract provided.

Advancing Electrochemical Microsensors For Multiplexed Neurotransmitters And Environmental Toxins Detection, Sanjeev Billa

Doctoral Dissertations

Electrochemical sensors have emerged as a promising solution for monitoring neurotransmitters and heavy metals, which could ensure good health and safety in the environment. This dissertation focuses on advancement in the field of electrochemical microsensors by improving the electrode properties and sensor metrics such as rapid response time, multiplexing, high sensitivity, high selectivity, and accuracy for the real-time monitoring of neurotransmitters (glutamate and GABA) and heavy metals (cadmium and lead). In this dissertation, a novel silicon (Si) multifunctional biosensor probe with four platinum ultramicroelectrodes (UMEs) and an on-demand in situ calibration (ODIC) microfluidic channel was optimized for sub-second simultaneous real-time …

Micropatterning Of Biologically Derived Surfaces With Functional Clay Nanotubes, Nisha Lama

Doctoral Dissertations

In this study, we have generalized an assembly of 50 nm diameter clay nanotubes on larger 20-50 μm diameter biological microfibers such as human hair (protein), cotton (cellulose) and synthetic polyethylene terephthalate- PET. We developed a common set of parameters and nanoclay coating techniques on these naturally different microfibers. We exploited and optimized the electrostatic interaction of the components through strategic adjustments in the solvent pH, employing polycation treatment, as well as selectively modifying the halloysite nanotubes with silanes. For 5 mins, a 5 wt% aqueous dispersion of halloysite nanotubes were applied to get approximately 1-2 μm thick fiber coating …

Green Synthesis Of Carbonized Chitosan-Fe3o4-Sio2 Nano-Composite For Adsorption Of Heavy Metals From Aqueous Solutions, Dalia A. Ali Eng, Rinad Galal Ali Eng.

Chemical Engineering

Water pollution with heavy metals owing to industrial and agricultural activities have become a critical dilemma to humans, plants as well as the marine environment. Therefore, it is of great importance that the carcinogenic heavy metals present in wastewater to be eliminated through designing treatment technologies that can remove multiple pollutants. A novel green magnetic nano-composite called (Carbonized Chitosan-Fe3O4-SiO2) was synthesized using Co-precipitation method to adsorb a mixture of heavy metal ions included; cobalt (Co2+), nickel (Ni2+) and copper (Cu2+) ions from aqueous solutions. The novelty of this study was the synthesis of a new

nano-composite which was green with …

Understanding And Tuning Magnetism In Van Der Waals-Type Metal Thiophosphates, Rabindra Basnet, Jin Hu

Physics Faculty Publications and Presentations

Over the past two decades, significant progress in two-dimensional (2D) materials has invigorated research in condensed matter and material physics in low dimensions. While traditionally studied in three-dimensional systems, magnetism has now been extended to the 2D realm. Recent breakthroughs in 2D magnetism have attracted substantial interest from the scientific community, owing to the stable magnetic order achievable in atomically thin layers of the van der Waals (vdW)-type layered magnetic materials. These advances offer an exciting platform for investigating related phenomena in low dimensions and hold promise for spintronic applications. Consequently, vdW magnetic materials with tunable magnetism have attracted significant …

Validation, Optimization, And Experimentation Of Electro-Centrifugal Spinning, Carlos Alberto Delgado

Theses and Dissertations

The aim of this study is to understand the behavior of polymeric solutions, when exposed to both electric fields and centrifugal forces through the electro-centrifugal fiber creation method, observing both effects of various parameter variations on the resulting nanofibers. The elemental deposition on electrospun fibers through in-situ processes is studied and optimized. The morphology, crystallinity, thermal properties, and elemental composition of the nanofibers were characterized. The purpose of these nanofibers is for future applications such as energy harvesting, filtration, and biomedical applications.

Attachment Of 2d Nanomaterials Onto 1d Nanofibers For Separation And Sensing Applications, Elmmer A. Vera Alvarado

Theses and Dissertations

Advancing materials for water desalination and sensing is essential for tackling global issues related to clean water and efficient energy systems. This thesis explores the application of 2D nanomaterials, specifically graphene, integrated onto 1D poly(vinylidene fluoride) (PVDF) nanofibers to enhance their effectiveness in these areas. Utilizing innovative techniques such as Forcespinning® and plasma treatment, PVDF nanofibers were strengthened with graphene and conductive polymers like poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT: PSS). The research involved thorough assessments using direct contact membrane distillation (DCMD) systems, oil-water separation tests, and various mechanical and electromechanical evaluations. Heat-pressed membranes consistently delivered a flux of 0.33 kg/m²/hr and …

Enhanced Optical And Infrared Activity Of Nanosphere Dimers Attributed To Dimer Geometry, D. Keith Roper, Jin-Woo Kim, Ricardo R. Romo, Joseph Batta-Mpouma

Biological and Agricultural Engineering Faculty Publications and Presentations

Enhanced optical and infrared activity of subwavelength metal nanoparticles is key to their use in optoelectronics, spectroscopy, and sensing. The present work compared spectra of nanosphere dimers merged by centrifuging gold nanospheres with corresponding simulated nanoscale dimers. Geometric features of the nanosphere dimers were related to corresponding optical and near-infrared activity through simulation. Differences in optical and infrared activity of the nanosphere dimers were largely attributable to changes in the radius of the nanosphere and the radius of the conductive junction between merged nanospheres. The features observed in the experimental spectra were attributed to a select number of dimers exhibiting …

Nanoparticle-Based Approaches To Brain Injury And Studies For Improved Detectability Toward Better Delivery Characterization, Hunter A. Miller

Dissertations and Doctoral Documents, University of Nebraska-Lincoln, 2023–

The clinical translation of nanoparticle (NP) therapeutics for brain injury has been slow despite preclinical promise. The causes of disconnect between preclinical and clinical outcomes is multifactorial, but insufficient delivery is noteworthy. Preclinical delivery characterization often lacks, obscuring mechanisms of failure, slowing development. Multimodal imaging is a promising strategy to improve delivery characterization, combining the strengths of various modalities. Magnetic resonance imaging (MRI) and luminescence imaging are a suitable combination for multimodal imaging, expanding the spatial and temporal resolution of either alone, but further material development is needed to enhance detectability. One problem is the interference of cellular autofluorescence in …

Fabrication And Characterization Of A Monolithic Photonic Integrated Circuit With High-Aspect Ratio Photonic Device Structures, Sami A. Nazib

Optical Science and Engineering ETDs

The focus of this work was to create a process to fabricate an InP-based Photonic Integrated Circuit (PIC). The design of the PIC required the photonic components of this device to be created by deep etching of an epitaxially-grown multilayer structure. Therefore, a novel dry etching process was developed to produce very high aspect- ratio (HAR) features. This process not only involved the development of dry etch chemistry but also the engineering of a metal mask structure. The next step of the challenge was to use a polymer-based material that would have two functions: cladding for the etched photonic components …

Professor Yong Yang, The Editorial Board Member Of Journal Of Electrochemistry, Is Elected As A Fellow Of The Electrochemical Society, Editorial Office Of J.Electrochem.

Journal of Electrochemistry

No abstract provided.

Series Reports From Professor Wei’S Group Of Chongqing University: Advancements In Electrochemical Energy Conversions (1/4): Report 1: High-Performance Oxygen Reduction Catalysts For Fuel Cells, Fa-Dong Chen, Zhuo-Yang Xie, Meng-Ting Li, Si-Guo Chen, Wei Ding, Li Li, Jing Li, Zi-Dong Wei

Journal of Electrochemistry

Two major challenges, high cost and short lifespan, have been hindering the commercialization process of low-temperature fuel cells. Professor Wei’s group has been focusing on decreasing cathode Pt loadings without losses of activity and durability, and their research advances in this area over the past three decades are briefly reviewed herein. Regarding the Pt-based catalysts and the low Pt usage, they have firstly tried to clarify the degradation mechanism of Pt/C catalysts, and then demonstrated that the activity and stability could be improved by three strategies: regulating the nanostructures of the active sites, enhancing the effects of support materials, and …

Data-Driven Viewpoint For Developing Next-Generation Mg-Ion Solid-State Electrolytes, Fang-Ling Yang, Ryuhei Sato, Eric Jian-Feng Cheng, Kazuaki Kisu, Qian Wang, Xue Jia, Shin-Ichi Orimo, Hao Li

Journal of Electrochemistry

Magnesium (Mg) is a promising alternative to lithium (Li) in solid-state batteries due to its abundance and high theoretical volumetric capacity. However, the sluggish Mg-ion conduction in the lattice of solid-state electrolytes (SSEs) is one of the key challenges that hamper the development of Mg-ion solid-state batteries. Though various Mg-ion SSEs have been reported in recent years, key insights are hard to be derived from a single literature report. Besides, the structure-performance relationships of Mg-ion SSEs need to be further unraveled to provide a more precise design guideline for SSEs. In this Viewpoints article, we analyze the structural characteristics of …

Kai Wu, The Editorial Board Member Of Journal Of Electrochemistry And Chief Scientist Of Catl, Receives The National Science And Technology Progress Award, Editorial Office Of J.Electrochem.

Journal of Electrochemistry

No abstract provided.

First Announcement Of 76th Annual Meeting Of The International Society Of Electrochemistry, International Society Of Electrochemistry (Ise)

Journal of Electrochemistry

No abstract provided.

Exploring Co2-Eor Miscibility Flooding Potential For Horus Oil Field, Western Desert, Egypt: A Simulation-Based Investigation, Attia Attia, Adel Salem Prof., Rehab El-Maghraby, Mohamed Youssef Prof.

Petroleum Engineering and Gas

Carbon dioxide (CO2) miscible flooding is becoming increasingly vital in enhanced oil recovery (EOR) not only for residual oil extraction but also for holding a potential for environmental protection, given its association with global warming. This paper explores the impact of EOR using miscible continuous gas injection on enhancing the oil productivity of the aging Horus oil field in Egypt's Western Desert. Horus field faces declining production rates and a significant water cut, with only eight wells out of 24 wells actively producing. Currently, the field maintains a stabilized oil production plateau of 1050 barrels per day, accompanied by a …

Gene Expression Analysis Reveals Dysregulation In Traumatic Brain Injury Leading To Tauopathy, Kristina M. Tosi

USF Tampa Graduate Theses and Dissertations

Traumatic Brain Injury (TBI) causes a cascade of detrimental events within neurons, contributing to a host of neurological diseases relating to dementia. In this study we have performed a meta-analysis comparing differentially expressed genes (DEG) in specific cell types such as neurons and microglia revealing inflammation as a common driver of neurological deficiencies post TBI. Inflammation and hypoxia are well characterized features of TBI; however, the molecular mechanisms causing tau hyperphosphorylation by tauopathy associated genes (TAG) post-TBI are currently poorly understood. Furthermore, there are limited in-vitro neuroinflammatory models that mimic primary and secondary TBI. We hypothesize that inducing hypoxia and …

Chemical And Physical Properties Of Fine Fractions From A Village Proximate To A Uranium Mine: Insights About Soil Health, Mary P. Haley

Nanoscience and Microsystems ETDs

Thousands of abandoned uranium mines (AUM) in Native American tribal lands have not been fully remediated, leaving uranium mine wastes exposed and accessible for potential erosion and transport by wind. Analyzing the metal and organic content of the fine-grained fractions in soils could uncover the impact of mine legacy on the soil health in communities that live in proximity to AUM. This study investigates the physical and chemical properties of the fine-grained fraction (μm) of soils to quantify the effect of heavy metal-bearing particulates on the soil health in the village of Paguate and within the Jackpile-Paguate AUM located on …

Development And Characterization Of Automated Screen Mesh-Based Microfluidic Device To Perform Continuous Countercurrent Liquid-Liquid Extraction, Quinn Mcculloch

Nanoscience and Microsystems ETDs

Continuous Countercurrent Microfluidic Liquid-Liquid Extraction (CC-MLLE) shows tremendous potential to generate large numbers of equilibrium stages of separation in a small footprint, with a minimum of pumping, valving, and phase separation steps. However, CC-MLLE rarely appears in literature because it requires a delicate balance between capillary and hydrodynamic forces for deterministic flow.

This dissertation showcases a patented screen mesh-based CC-MLLE invention that performs stable, long-duration (> 36 hr.), countercurrent liquid-liquid extraction and achieves 37 equilibrium stages within a 38.5 μl internal volume. The device is fabricated from chemically resistant polyetheretherketone plastic, using standard machine shop equipment, a plotting cutter, screen …