Nanoscience and Nanotechnology Commons^™

Design And Development Of A Novel Glucose Biosensor Based On The Ferrocene-Functionalized Fe3O4 Nanoparticles/Carbon Nanotubes/Chitosan Nanocomposite Film Modified Electrode, Hua-Ping Peng, Dai-Jun Zha, Wei Chen, Ai-Lin Liu, Xin-Hua Lin

Journal of Electrochemistry

A novel platform for the fabrication of glucose biosensor was successfully constructed by entrapping glucose oxidase (GOD) in a ferrocene monocarboxylic acid-aminated Fe₃O₄ magnetic nanoparticles conjugate (FMC-AFNPs)/chitosan (CS)/multiwall carbon nanotubes (MWNTs) nanocomposite. The formation of FMC-AFNPs could effectively prevent the leakage of ferrocene and retain its electrochemical activity. This GOD/FMC-AFNPs/CS/MWNTs matrix provided a biocompatible microenvironment for retaining the native activity of the immobilized GOD. Moreover, the presence of MWNTs enhanced the charge-transport properties of the composite and facilitated electron transfer between the GOD and the electrode for the electrocatalysis of glucose. Under the optimal conditions the designed …

A New Nonenzymatic Glucose Sensor Based On The Cuo Nanoplatelets, Yan-Cai Li, Fu-Ying Huang, Shun-Xing Li, Jie Chen, Shu-Qing Feng, Fei Wang

Journal of Electrochemistry

The CuO nanoplatelets were synthesized by hydrothermal method. The structure and morphology of the CuO nanoplatelets were characterized by TEM and XRD. A new nonenzymatic glucose sensor was constructed by immobilizing the CuO nanoplatelets on glassy carbon electrode with Nafion. The electrochemical performance of the CuO/Nafion/GCE for the detection of glucose was investigated by cyclic voltammetry and current-time curve. The experiment results showed that the linear dependence of the sensor was 0.01 to 0.3 mmol·L^-1 for glucose with a sensitivity of 1783.58 μA·mmol^-1·L·cm^-2, and the detection limit of the sensor was 0.80 μmol·L^-1 (S/N …

Pulse Electrodeposition Of Pd-Ni Alloy Nanoparticles For Electrocatalytic Oxidation Of Formic Acid, Fang-Zu Yang, Jun-Pei Yue, Zhong-Qun Tian, Shao-Min Zhou

Journal of Electrochemistry

The Pd-Ni alloy nanoparticles with nickel atomic contents of 12.0%, 16.4% and 22.6% were successfully electrodeposited from a Pd-Ni alloy electrolyte by square wave pulse plating. The alloy nanoparticles were in the spherical shape with a diameter of 50 ~ 80 nm. As the growth potential of the alloy was negatively shifted, the nickel content of the alloy was increased, and the size of the nanoparticles was almost the same, whereas the number, the degree of crosslinking and the real active area of the nanoparticles were increased. As the nickel content of the alloy nanoparticles increased, the peak current for …

Surface Structure And Electrochemical Performance Of Zno Coated Lini1/3Co1/3Mn1/3O2, Chang-Wei Liu, Yu Wang, Yu-Zhong Guo, Lu-Lu Dan, Jian-Hua Wang

Journal of Electrochemistry

The surface of LiNi_1/3Co_1/3Mn_1/3O₂ particles were modified by ZnO. Surface structure and electrochemical properties of the coated materials were investigated by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and electrochemical tests. The results show that a ZnO coating affects the surface composition of LiNi_1/3Co_1/3Mn_1/3O₂ particles. The surface contents of nickel and manganese increase with the amount of ZnO coating. ZnO can react with LiNi_1/3Co_1/3Mn_1/3O₂ and a complex oxide is formed during the heat-treatment at above 400 ^oC. The …

Methods, Systems, And Devices For Surgical Access And Inserton, Tom Frederick, Shane Farritor, Jack Mondry, Eric Markvicka, Dmitry Oleynikov, Jacob Greenburg

Department of Mechanical and Materials Engineering: Faculty Publications

The various embodiments herein relate to systems, devices, and/or methods relating to Surgical procedures, and more specifically for accessing an insufflated cavity of a patient and/or positioning Surgical systems or devices into the cavity.

Systemand Method For Controlling Motion Of Spacecrafts, Piyush Grover, Christian Andersson

Department of Mechanical and Materials Engineering: Faculty Publications

A motion of an object is controlled from a geostationary transit orbit (GTO) of an earth to an orbit of a moon. A first trajectory of the motion of the object is determined from an intermediate orbit of an earth to a neighborhood of a stable manifold of a first Lagrange point (L1). A second trajectory of the motion of the object is determined from the GTO to the intermediate orbit. A third trajectory of the motion of the object is determined from the neighborhood to the stable manifold to an L1 orbit, and a fourth trajectory of the motion …

Use Of Graphene As Protection Film In Biological Environments, Weixia Zhang, Sudarat Lee, Kelly L. Mcnear, Ting Fung Chung, Seunghyun Lee, Kyunghoon Lee, Scott A. Crist, Timothy L. Ratliff, Zhaohui Zhong, Yong P. Chen, Chen Yang

Birck and NCN Publications

Corrosion of metal in biomedical devices could cause serious health problems to patients. Currently ceramics coating materials used in metal implants can reduce corrosion to some extent with limitations. Here we proposed graphene as a biocompatible protective film for metal potentially for biomedical application. We confirmed graphene effectively inhibits Cu surface from corrosion in different biological aqueous environments. Results from cell viability tests suggested that graphene greatly eliminates the toxicity of Cu by inhibiting corrosion and reducing the concentration of Cu2+ ions produced. We demonstrated that additional thiol derivatives assembled on graphene coated Cu surface can prominently enhance durability of …

Nanosensor Data Processor In Quantum-Dot Cellular Automata, Fenghui Yao, Mohamed Saleh Zein-Sabatto, Guifeng Shao, Mohammad Bodruzzaman, Mohan Malkani

Computer Science Faculty Research

Quantum-dot cellular automata (QCA) is an attractive nanotechnology with the potential alterative to CMOS technology. QCA provides an interesting paradigm for faster speed, smaller size, and lower power consumption in comparison to transistor-based technology, in both communication and computation. This paper describes the design of a 4-bit multifunction nanosensor data processor (NSDP). The functions of NSDP contain (i) sending the preprocessed raw data to high-level processor, (ii) counting the number of the active majority gates, and (iii) generating the approximate sigmoid function. The whole system is designed and simulated with several different input data.

Fabrication And Assembly Of Patchy Particles With Uniform Patches, Zhenping He

Dissertations, Theses, and Capstone Projects

Patchy colloidal particles have been widely studied as the self-assembly building blocks to illustrate their potential for forming complex structures. The parameters affecting the final assembly structures include (i) patch size, shape, and number per particle, (ii) their relative positions, and (iii) the surface properties of the patch material. Recent computational studies have highlighted the impact of patch shape on assembly structure; however, there are only a limited number of methods that can provide control over patch shape and size. In this thesis, a template is introduced to the Glancing Angle Vapor Deposition method (GLAD) to create surface anisotropy on …

Policy Makers’ Influence On The Emergence Of A New Scientific Discipline: The Case Of Nanotechnology In Ireland, Nicolas Battard

Doctoral

Science has undergone tremendous changes since World War II with the blurring of boundaries between science, government, and industry, as well as the so-called convergence of scientific disciplines. Nanotechnology is an illustrative example of this phenomenon. Boundaries between all these spheres are challenged, renegotiated, and reshaped under the influence of the multiple actors involved. I question here the extent to which nanoscience and nanotechnology (N&N) are emerging as a new scientific discipline under the influence of science and technology policies. With the study of N&N in Ireland from the late 1990s onwards, a focus is placed on both the macro-meso …

Property Enhancements Of Dielectric Nanoparticles Via Surface Functionalization, Andrew Byro

Dissertations, Theses, and Capstone Projects

This thesis describes the surface modification of barium strontium titanate nanoparticles for use in polymer/ceramic composite thin film capacitors with resultant improved dielectric and film-making properties. Phosphonic acid-type ligands proved to be most effective for surface conjugation to the surface of the barium strontium titanate nanoparticles. Amine-terminated ligands proved to be effective at removing surface adsorbed water before being almost entirely removed during the sample washing stage. Carboxylic acid terminated ligands proved to adhere less well to the nanoparticle than the phosphonic acid, but resulted in thin films with a higher dielectric constant, which was more stable in the measured …

2d & 3d Nanomaterial Fabrication With Biological Molecular Frameworks, Kristina Ivana Fabijanic

Dissertations, Theses, and Capstone Projects

Recently, there has been a heightened amount of work done in the field of biomineralization. By taking inspiration from natures' phenomenonal individualities as a means to develop new and interesting nanostructures of varying sizes and dimensions, there is a newly developed design, namely Biomimetic Crystallization Nanolithography (BCN). With this method, the simultaneous nano-patterning and crystallization has been achieved using urease as the nucleation point and the hydrolysis of urea to obtain patterns of oxide semiconductor material, namely zinc oxide, at room temperature and aqueous solvent. The new and interesting characteristic of BCN involves the construction of amorphous inks of ZnO …

Colloidal Quantum Dot Based Photonic Circuits And Devices, Nicky E. Okoye

Dissertations, Theses, and Capstone Projects

Colloidal quantum dots have desirable optical properties which can be exploited to realize a variety of photonic devices and functionalities. However, colloidal dots have not had a pervasive utility in photonic devices because of the absence of patterning methods. The electronic chip industry is highly successful due to the well-established lithographic procedures. In this thesis we borrow ideas from the semiconductor industry to develop lithographic techniques that can be used to pattern colloidal quantum dots while ensuring that the optical properties of the quantum dots are not affected by the process. In this thesis we have developed colloidal quantum dot …

Magnetic Janus Particles And Their Applications, Bin Ren

Dissertations, Theses, and Capstone Projects

Magnetic properties are important since they enable the manipulation of particle behavior remotely and therefore provide the means to direct a particle’s orientation and translation. Magnetic Janus particles combine magnetic properties with anisotropy and thus are potential building blocks for complex structures that can be assembled from a particle suspension and can be directed through external fields. In this thesis, a method for the fabrication of three types of magnetic Janus particles with distinct magnetic properties is introduced, the assembly behavior of magnetic Janus particles in external magnetic and electric fields is systematically studied, and two potential applications of magnetic …

Utilizing Fast Spin Echo Mri To Reduce Image Artifacts And Improve Implant/Tissue Interface Detection In Refractory Parkinson’S Patients With Deep Brain Stimulators, Subhendra N. Sarkar, Pooja R. Sarkar, Efstathios Papavassiliou, Rafael Rojas

Publications and Research

Introduction. In medically refractory Parkinson’s disease (PD) deep-brain stimulation (DBS) is an effective therapeutic tool. Postimplantation MRI is important in assessing tissue damage and DBS lead placement accuracy. We wanted to identify which MRI sequence can detectDBS leads with smallest artifactual signal void, allowing better tissue/electrode edge conspicuity.

Methods. Using an IRB approved protocol 8 advanced PDpatientswere imagedwithinMRconditional safety guidelines at lowRF power (SAR ≤ 0.1 W/kg) in coronal plane at 1.5T by various sequences.The image slices were subjectively evaluated for diagnostic quality and the lead contact diameters were compared to identify a sequence least affected by metallic leads.

Results …

Sub-Diffraction Laser Synthesis Of Silicon Nanowires, James I. Mitchell, Nan Zhou, Woongsik Nam, Luis M. Traverso, Xianfan Xu

Birck and NCN Publications

We demonstrate synthesis of silicon nanowires of tens of nanometers via laser induced chemical vapor deposition. These nanowires with diameters as small as 60 nm are produced by the interference between incident laser radiation and surface scattered radiation within a diffraction limited spot, which causes spatially confined, periodic heating needed for high resolution chemical vapor deposition. By controlling the intensity and polarization direction of the incident radiation, multiple parallel nanowires can be simultaneously synthesized. The nanowires are produced on a dielectric substrate with controlled diameter, length, orientation, and the possibility of in-situ doping, and therefore are ready for device fabrication. …

Project Nano: Will Allowing High School Students To Use Research Grade Scanning Electron Microscopes Increase Their Interest In Science?, Leslie Teneyck Smith

Dissertations and Theses

In this study, one AP Biology curriculum unit and one general Biology curriculum unit that included tabletop Scanning Electron Microscope (SEM) technology provided by Project NANO, a grant-funded, collaborative initiative designed to integrate cutting-edge nanotechnology into high school classrooms were implemented at a public high school in rural Oregon. Nine students participated in the AP unit and 52 students participated in the general Biology unit. Each student completed an opinion-based pre and post survey to determine if using the SEM as a part of the curriculum unit had an impact on his or her interest in science or in nanoscience. …

Integrating Non-Planar Metamaterials With Magnetic Absorbing Materials To Yield Ultra-Broadband Microwave Hybrid Absorbers, Wei Li, Tianlong Wu, Wei Wang, Jianguo Guan, Pengcheng Zhai

Birck and NCN Publications

Broadening the bandwidth of electromagnetic wave absorbers has greatly challenged material scientists. Here, we propose a two-layer hybrid absorber consisting of a non-planar metamaterial (MM) and a magnetic microwave absorbing material (MAM). The non-planar MM using magnetic MAMs instead of dielectric substrates shows good low frequency absorption and low reflection across a broad spectrum. Benefiting from this and the high frequency strong absorption of the MAM layer, the lightweight hybrid absorber exhibits 90% absorptivity over the whole 2-18 GHz range. Our result reveals a promising and flexible method to greatly extend or control the absorption bandwidth of absorbers. (C) 2014 …

Smart Polyacrylonitrile (Pan) Nanofibers With Thermal Energy Storage And Retrieval Functionality, De’Andre James Cherry

Theses

Phase change materials (PCMs) are generally substances with a high heat of fusion in the process of solid to liquid phase change. The nature of PCMs make them efficient materials to store and retrieve large amounts of thermal energy. Presently, high efficiency thermal energy storage/retrieval in applications where flexibility and space saving are required, such as smart textiles, still remains as a challenge. In this study, lauric acid (LA) and myristic acid (MA) were combined to prepare a specific binary fatty acid eutectic (LA-MA) with a melting point near the operating body temperature of a human being and then encapsulated …

Quality And Safety Of Minimally Invasive Surgery: Past, Present, And Future, Bernadette Mccrory, Chad A. Lagrange, M. S. Hallbeck

Department of Mechanical and Materials Engineering: Faculty Publications

Adverse events because of medical errors are a leading cause of death in the United States (US) exceeding the mortality rates of motor vehicle accidents, breast cancer, and AIDS. Improvements can and should be made to reduce the rates of preventable surgical errors because they account for nearly half of all adverse events within hospitals. Although minimally invasive surgery (MIS) has proven patient benefits such as reduced postoperative pain and hospital stay, its operative environment imposes substantial physical and cognitive strain on the surgeon increasing the risk of error. To mitigate errors and protect patients, a multidisciplinary approach is needed …