Materials Science and Engineering Commons^™

Responsive Economic Model Predictive Control For Next-Generation Manufacturing, Helen Durand

Chemical Engineering and Materials Science Faculty Research Publications

There is an increasing push to make automated systems capable of carrying out tasks which humans perform, such as driving, speech recognition, and anomaly detection. Automated systems, therefore, are increasingly required to respond to unexpected conditions. Two types of unexpected conditions of relevance in the chemical process industries are anomalous conditions and the responses of operators and engineers to controller behavior. Enhancing responsiveness of an advanced control design known as economic model predictive control (EMPC) (which uses predictions of future process behavior to determine an economically optimal manner in which to operate a process) to unexpected conditions of these types …

Impact Of Team Formation Approach On Teamwork Effectiveness And Performance In An Upper-Level Undergraduate Chemical Engineering Laboratory Course, Erick S. Vasquez, Matthew J. Dewitt, Zachary J. West, Michael J. Elsass

Chemical and Materials Engineering Faculty Publications

This study focuses on the impact of team formation approach on teamwork effectiveness and performance spanning three years of instruction of the chemical engineering unit operations laboratory, which is an upper-level undergraduate laboratory course. Team formation approaches changed each year, and assessment tools, including peer-assessment, academic performance, and course evaluations, were employed to evaluate team performance. Approaches included three cases: instructor-selected teams based on GPA with the objective of a similar cumulative average GPA for each team, student self-selected teams, and a combination of self-selected teams with instructor-selected teams for a final experiment. For the third case, new teams were …

Defect-Free Plastic Deformation Through Dimensionality Reduction And Self-Annihilation Of Topological Defects In Crystalline Solids, Yipeng Gao, Yongfeng Zhang, Larry K. Aagesen, Jianguo Yu, Min Long, Yunzhi Wang

Computer Science Faculty Publications and Presentations

As a signature of symmetry-breaking processes, the generation and annihilation of topological defects (domain walls, strings, etc.) are of great interest in condensed matter physics and cosmology. Here we propose a distinctive self-organization process through phase transitions, in which all the generated topological defects are dimensionality reduced and self-annihilated. In crystalline solids, such a unique mechanism allows a perfect single crystal after plastic deformation, which originates from the coupling of different types of broken symmetries.

Ii-Vi Type-Ii Quantum Dot Superlattices For Novel Applications, Vasilios Deligiannakis

Dissertations, Theses, and Capstone Projects

In this thesis, we discuss the growth procedure and the characterization results obtained for epitaxially grown submonolayer type-II quantum dot superlattices made of II-VI semiconductors. We have investigated the spin dynamics of ZnSe layers with embedded type-II ZnTe quantum dots and the use of (Zn)CdTe/ZnCdSe QDs for intermediate band solar cell (IBSC). Samples with a higher quantum dot density exhibit longer electron spin lifetimes, up to ~1 ns at low temperatures. Tellurium isoelectronic centers, which form in the ZnSe spacer regions as a result of the growth conditions, were also probed. A new growth sequence for type-II (Zn)CdTe/ZnCdSe (QDs) was …

Development Of Integrated Zinc Oxide Nanorods Coated Glass Substrate Sensing Device, Mohd Yusof Haziezol Helmi

Student Works (2020-2029)

A simple and practical cost-effective integrated zinc oxide (ZnO) nanorods coated glass substrate sensing device for humidity and formaldehyde vapor sensing applications is reported. The developed sensor device is composed of a commercial light-emitting diode (LED) and photodiode that correspondingly served as light source and detector which precisely positioned on a 3D printed sensor platform. A receiver circuit and Arduino platform were employed for signal amplification and processing. A uniform ZnO nanorods coating were grown on the surface of glass substrate via hydrothermal method by controlling the growth durations and coating length. A standard reference for the optimum working condition …

Dry And Wet Torrefaction Of Microalgal Biomass For Biochar Production As Bioenergy Sources, Yong Yang Gan

Student Works (2020-2029)

Increasing population in global and living standards have risen the consumption of global energy. Thermochemical conversion approaches hold great potential for the biomass conversion into energy applications. Among these approaches, torrefaction is a promising technique to enhance the biomass properties, making it more practical and suitable in biofuel applications. In this study, two different species of microalgae (third generation biofuel feedstock) including Chlorella vulgaris ESP-31 and FSP-E were used as feedstocks for dry and wet torrefaction. Dry torrefaction of microalgae was performed at temperatures of 200, 250 and 300 ºC, and holding times of 15, 30, 45 and 60 min, …

Performance Evaluation Of Lightweight Normal And Geopolymer Foamed Concrete Using Palm Oil Fuel Ash As Partial Replacement Of Binder, M .E. Alnahhal Ahmed

Student Works (2020-2029)

Carbon dioxide (CO2) emissions from Ordinary Portland Cement (OPC) have a detrimental effect on the environment and this had led many researchers to search for other alternatives in the form of sustainable cementitious materials. The depletion of natural resources and dumping the industrial by-products and waste materials are serious concern to our environment. This research focusses on the performance of using a palm oil industrial by-product, namely, palm oil fuel ash (POFA), as a partial replacement for OPC and fly ash (FA) in lightweight normal foamed concrete and lightweight geopolymer foamed concrete, respectively. Thus, using 10, 20, and 30% POFA …

Noble-Transition Alloy Absorbers For Near-Infrared Hot-Carrier Optoelectronics, Sara Karoline Figueiredo Stofela

LSU Doctoral Dissertations

Optoelectronics is the field of technology concerned with the study and application of electronic devices that source, detect and control light. Here we focus on the optical communications field which relies on optical fiber systems to carry signals to their destinations operating in the near-infrared range. To improve the performance of current optical fiber systems, one of the paths is to develop better near-infrared photodetectors.

The current group of materials used for near-infrared photodetection relies in the III-V semiconductor family. Although their spectral photosensitivity correlates well with the near-infrared, response time performance and electronic circuit integration remain limited for this …

Mechanical And Structural Behavior Of As-Built And Post Treated Ti6al4v Lattice Structures Fabricated By Selective Laser Melting (Slm), Hala Ahmed Salem

Theses and Dissertations

Lattice structure is a type of cellular structures that is composed of repeatable unit cells, each of which is formed of interconnect network of struts. Lattices with different structures are gaining attention for their good mechanical properties for light weight applications. Selective laser melting (SLM), is one of the AM powder-bed fusion fabrication techniques. SLM is widely known for its capability for fabricating complex metallic structures such as lattice structures with high resolution. SLM process influence the microstructure and mechanical properties of fabricated parts. The used processing parameters influence the level of internal porosity within the fabricated parts which directly …

Plasmonic-Active Nanostructured Thin Films, Jay Bhattarai, Helal Maruf, Keith Stine

Chemistry & Biochemistry Faculty Works

Plasmonic-active nanomaterials are of high interest to scientists because of their expanding applications in the field for medicine and energy. Chemical and biological sensors based on plasmonic nanomaterials are well-established and commercially available, but the role of plasmonic nanomaterials on photothermal therapeutics, solar cells, super-resolution imaging, organic synthesis, etc. is still emerging. The effectiveness of the plasmonic materials on these technologies depends on their stability and sensitivity. Preparing plasmonics-active nanostructured thin films (PANTFs) on a solid substrate improves their physical stability. More importantly, the surface plasmons of thin film and that of nanostructures can couple in PANTFs enhancing the sensitivity. …

A Validation Study For A New Erosion Model To Predict Erosive Airfoil Defouling, Arthur Rudek, David Muckenhaupt, Thomas Zitzmann, Gerald Russ, Barry Duignan

Articles

A new defouling erosion model for Lagrangian particle tracking is used to predict defouling of amor-phous, heterogeneous coatings such as those typically found in aircraft compressors. The main problem description, the mathematical formulation and the underpinning experiment of the model are presented in a previous communication by the authors. In this work, the Ansys CFX implementation of the model is described and an experiment is presented for the validation of the model. Air flows laden with a number of dry-ice particles are observed in an optically accessible stream channel containing a flat plate target. The defouling process of these particles …

Fabrication Of Dielectric Elastomers With Improved Electromechanical Properties Using Silicone Rubber And Walnut Polyphenols Modified Dielectric Particles, Liang Jiang, Yuhao Wang, Shipeng Wen, Yanfen Zhou, Qingdao University, Stephen Jerrams

Articles

In this work, polyphenolic extract from walnut green husks (denoted as walnut polyphenols), which is an abun-dant agroindustrial residue/waste, was used to modify barium titanate (BT) particles in the preparation of sili-cone rubber (SR) based dielectric elastomer (DE) composites with enhanced electromechanical performance.By employing walnut polyphenols modification, the dispersibility of BT particles in the SR matrix and the com-patibility between BT and SR were greatly improved, which resulted in enhanced mechanical performance ofthe DE composites. Dielectric property measurement showed that DE composites containing walnut polyphenolsmodified BT particles (WNBT) had higher dielectric constants and lower dielectric losses than that of DEs …

Rc Mini Baja Car - Suspension And Chassis, Collin Mckenzie

All Undergraduate Projects

Two students have developed a unique design of the RC Baja Car to optimize functionality and performance. A Baja car is a remote controlled 1/10 scale car that is used for recreation or competition, usually meant for competing in the ASME Baja car competition versus various schools. The competition focuses on the best time achieved in different courses that utilize speed, turns, and jumps. The objective for the project was to create a unique suspension from previous individual’s projects by creating a four-link suspension in which allows more travel in the suspension of the car and maintains functionality with the …

Graphene/Oxide Interactions With Polymer Networks Modeled Using Molecular Dynamics, Matthew Alan Reil

Electronic Theses and Dissertations

Due to its unique physical properties, graphene has shown great promise as an additive to Polymer Matrix Composites (PMCs) for material property enhancement. Achieving homogeneous dispersion of the graphene platelets within a polymeric network is critical to realizing these enhancements. Research has shown that achieving homogeneous dispersion of graphene platelets within PMCs is challenging as graphene is immiscible with most polymeric networks. This work used Molecular Dynamics (MD) simulations to demonstrate dispersion of graphene platelets within PMCs is inhibited by molecular surface charge potentials. Further simulations were conducted to demonstrate functionalized forms of graphene, specifically graphene oxide, have altered surface …

Thermally Driven Spin Transport In Ferromagnetic Metals, Wafa Saud Aljuaid

Electronic Theses and Dissertations

Since the discovery in 2008, the spin Seebeck effect has become one of the most active topics in the spin caloritronics research field. It opened a new way to create spin current by a combination of magnetic fields and heat. A temperature gradient in ferromagnetic (FM) metals generates a ow of spin current due to split of spin chemical potential between spin up and spin down electrons. This thermal spin current has been detected using an attached nonmagnetic heavy metal with large spin Hall angle via the inverse spin hall effect (ISHE). A voltage signal is generated since the nonmagnetic …

Concrete Beam Design: Pouring The Foundation To Engineering In T&E Classrooms, Andrew J. Hughes, Chris Merrill

Educational Leadership & Technology Faculty Publications

Ask a middle or high school student if they could design a concrete beam that weighs only 20 pounds and is 36” long but must hold 600 pounds without failing. What is the student likely to say? What if the student was told that, with some optimized decision making based on relatively straightforward mathematics, their beam could hold 2400 pounds or more? The focus of this article is not on concrete beam design, it is rather an introduction to engineering principles in beam design using a lab activity. The concepts and skills learned in this article will lead students into …

Investigation Of Physiochemical Properties And Biocompatibility Of Amourphos Calcium Polyphosphate Hydrogel Doped With Antibiotics And Injectable Polymeric Dicalcium Phosphate Dihydrate Bone Cement, Yasaman Chehreghanianzabi

Wayne State University Dissertations

Amorphous calcium polyphosphate (ACPP) is an inorganic polymer ceramic. Here we use a simple method of preparing ACPP hydrogel in the presence of excess volume of water. Essentially, water availability to polyphosphate chains accelerates water molecule ingress and microstructural transformation of ACPP hydrogels. Antibiotic delivery capacity of ACPP hydrogel increases by the specific mixing and molding method, where the VCM has higher antibiotic encapsulation efficiency with the small burst release for the compressed discs. In part of this study, we investigate impact of ACPP hydrogel replacement by monomeric calcium phosphate on the quality of final product (dicalcium phosphate dihydrates (DCPD) …

The Fabrication And Properties Of Magnetorheological Elastomers Employing Bio-Inspired Dopamine Modified Carbonyl Iron Particles, Yanfen Zhou, Lele Li, Wenyue Li, Shipeng Wen, Liang Jiang, Stephen Jerrams, Jianwei Ma, Shaojuan Chen

Articles

To obtain magnetorheological elastomers (MREs) with improved mechanical properties and exhibiting an enhanced magnetorheological (MR) effect, bio-inspired dopamine modification has been used to improve the functionality at the surface of carbonyl iron (CI) particles. Various techniques including x-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) and transmission electron microscopy (TEM) were used to confirm that a polydopamine (PDA) layer of about 27.5 nm had been successfully deposited on the surface of the carbonyl iron particles prior to their inclusion in the MRE composites. The magnetic properties of PDA modified CI particles were shown to be almost the same as those …

Influence Of Graphene Oxide And Carbon Nanotubes On The Fatigue Properties Of Silica/Styrene-Butadiene Rubber Composites Under Uniaxial And Multiaxial Cyclic Loading, Zongchao Xu, Stephen Jerrams, Hao Guo, Yanfen Zhou, Liang Jiang, Yangyang Gao, Liqun Zhang, Li Liu, Shipeng Wen

Articles

The influence of equivalent replacement of silica (SiO2) by carbon nanotubes (CNT) or graphene oxide (GO) on the microstructure, mechanical and fatigue behaviors of SiO2/styrene-butadiene rubber (SBR) composites was investigated. Results showed that the synergistic effect between CNT (or GO) and SiO2 was beneficial for the filler network and improved the mechanical properties of SBR composites. Furthermore, the introduction of CNT (or GO) led to low crack growth rates and the crack propagation tips were easy to deflection. Under multiaxial fatigue conditions, the maximum engineering stress was determined to be a reliable fatigue life predictor for SBR composites.

Enhanced Fatigue And Durability Of Carbon Black/Natural Rubber Composites Reinforced With Graphene Oxide And Carbon Nanotubes, Hao Guo, Stephen Jerrams, Zongchao Xu, Yanfen Shou, Liang Jiang, Liqun Zhang, Li Liu, Shipeng Wen

Articles

Graphene oxide (GO) sheets and carbon nanotubes (CNTs) are of nanometer size and offer large shape factors which are beneficial in reducing crack propagation rates of composites when used in carbon black (CB) reinforced natural rubber (NR), thereby prolonging the service lives of rubber composites. In this research, CNT-CB/NR and GO-CB/NR composites were prepared by partially replacing CB with one-dimensional CNTs and two-dimensional flaky graphene oxide GO, respectively. The results showed that the complex filler dispersion in NR matrices was improved due to the isolation effect between the different fillers. The strain-induced crystallization (SIC) ability of CB/NR was effectively enhanced …

Exact Solutions To The Three-Dimensional Navier-Stokes Equations Using The Extended Beltrami Method, Nolan J. Dyck, Anthony G. Straatman

Mechanical and Materials Engineering Publications

No abstract provided.

Nanoengineered Core-Shell Structures Using Tubile Halloysite Clay, Yusuf A. Darrat

Doctoral Dissertations

Halloysite nanotubes are a versatile nanomaterial that can be used in a wide variety of applications. They have a unique structure which could be described as a flat material that consists of silica on one side and alumina on the other; this structure is rolled up in a way naturally forming an internal 10-15 nm lumen and interlayer spacing. This could lead to many potential applications for example incorporating halloysite as a template material or as a support structure. They are an inexpensive clay material that is available in large quantities (thousands of tons), so they may be practically used …

Thei Student Applied Research Presentations Sarp 2020, Research Office, Technological And Higher Education Institute Of Hong Kong

THEi Student Applied Research Presentations (SARP)

No abstract provided.

Parametric Investigation And Optimization For Inconel 718 Nickel-Based Superalloy In Laser Powder Bed Fusion, Thinh Huynh

Electronic Theses and Dissertations, 2020-2023

Excellent weldability and high temperature stability make Inconel 718 (IN718) one of the most desired alloys to be produced by additive manufacturing (AM). Within the flourishing field of AM technology, laser powder bed fusion (LPBF) is a popular prospective candidate capable of fabricating complex and near net-shape engineering components that traditional manufacturing methods cannot accomplish. In this study, the effects of processing parameters on the relative density and microstructure was investigated. Gas atomized IN718 powders were used to fabricate cuboidal specimens via LPBF for metallographic characterization. The specimens were printed with independently varied laser power (125 - 350 W), laser …

Ac Conductivity Studies Of Polyethylene-Oxide-Garnet Type Li7la3zr2o12 Hybrid Composite Solid Polymer Electrolyte For Li-Ion Battery, Parisa Bashiri

Wayne State University Dissertations

Solid electrolytes including ceramics and polymers are considered to be the ultimate substitute for organic liquid electrolytes currently used in commercialized lithium ion batteries to address the safety concerns due to Li dendrite growth and internal short circuiting. However, low ionic conductivity due to high grain boundary resistance in ceramics and semi-crystalline nature of polymers has held back the solid electrolytes from being used in Li-ion batteries. Polyethylene oxide (PEO), complexed with a Li-salt, is a well-studied polymer electrolyte showing ionic conductivity properties at room temperature. However, the coexistence of amorphous and crystalline regions at room temperature (< Tm, the melting temperature) has

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Optimization Studies For The Gas Atomization And Selective Laser Melting Processes Of Al10simg Alloy, Sharon Park

Electronic Theses and Dissertations, 2020-2023

Selective laser melting (SLM) is an additive manufacturing technology that can fabricate complex engineering components using a scanning laser beam to melt consecutive layers of powders with characteristics that significantly influence material properties. Present work investigates both the gas atomization and SLM processes for the Al10SiMg alloy with a focus on establishing the relationships among atomization parameters, powder characteristics, SLM parameters and materials properties. Al10SiMg alloy powders (Al-10wt.%Si-0.5wt.%Mg) were batch-produced through gas atomization by systematically varying the melt flow rate (0.012 - 0.037 kg/s), gas pressure (1.4 - 3.1 MPa), and melt temperature (850C -1000C). The highest yield of 80 …

Designing Metal Nanocatalysts And Tuning Their Microenvironment For Gas-Involving Electrocatalysis, Lin Hu

Electronic Theses and Dissertations, 2020-2023

In the development of renewable energy technologies, electrocatalysis plays a central role in energy conversion processes, such as fuel cells and electrochemical fuel synthesis. Development of such technologies relies on the rational design of electrocatalysts as well as understanding their interaction with the working environment. Here we focus on gas-involving electrocatalytic reactions, particularly nitrogen electroreduction to ammonia and formic acid electrooxidation to carbon dioxide. First, to understand the structure-activity relationships for nitrogen electroreduction on Ru, we prepared a series of size-controlled Ru nanoparticles using atomic layer deposition. Both catalytic activity and selectivity for ammonia production on Ru catalysts strongly depend …

The Reliability Of Through Glass Vias And Solder Joints For Three Dimensional Multi Functional Integrated Systems, Omar Ahmed

Electronic Theses and Dissertations, 2020-2023

Three-dimensional (3D) integration technologies, including interposer-based integration, are among the most promising solutions to meet the increased demand for high performance computing, high chip density, and small form factor. Key technologies that enable 3D integration include through-substrate vias and solder joints. Glass is considered as a promising substrate material for interposer-based 3D integration technology especially in radio frequency applications because of glass's high resistivity, low dielectric constant, low electrical loss, and the adjustable coefficient of thermal expansion (CTE). However, during fabrication or service, through-glass vias can suffer from interface delamination and substrate cracking. The problem of copper protrusion is also …

Investigation Of Via Extrusion And The Effect Of Cap Layer For 3d Integrated Circuits, Golareh Jalilvand

Electronic Theses and Dissertations, 2020-2023

Copper (Cu) through-silicon via (TSV) is an essential structural and functional element in three-dimensional integration circuits (3D ICs), which offers substantial improvements in integration density, form factor, device performance, and power efficiency. However, Cu-filled TSVs are exposed to multiple thermal cycles during fabrication, test and operation, which lead to the development of considerable thermal stresses, in and around the vias, due to the large mismatch of the coefficient of thermal expansion (CTE) between Cu and silicon (Si). The stress subsequently raises reliability concerns, among which, via extrusion is an important one. Via extrusion can damage the adjacent components, in particular …

Understanding The Deformation Mechanisms In Ni-Based Superalloys With Using Crystal Plasticity Finite Element Method, Tianju Chen

Doctoral Dissertations

“Ni-based superalloy is considered as a good candidate due to its excellent resistance to elevated temperature deformation for long term period application. Understanding the deformation and failure mechanisms of Ni-Based superalloys is very helpful for providing design guidelines for processing Ni-based superalloys. Experimental characterization indicates that the deformation mechanisms of Ni based superalloy is strongly microstructure dependent. Besides, damage transform from the void nucleation to the macro cracks by voids growth leading to the failure of the Ni-based superalloys are also showing strong microstructure sensitivity. Therefore, this work focuses on the prediction and comprehension of the deformation and void growth …