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Full-Text Articles in Materials Science and Engineering

Effects Of Ball Milling Duration And Sintering Temperature On Mechanical Alloying Fe3si, Varistha Chobpattana, Chakansin Phoomkong, Peerawat Nutnual, Kritsada Thaengthong, Wanchai Pijitrojana Jan 2054

Effects Of Ball Milling Duration And Sintering Temperature On Mechanical Alloying Fe3si, Varistha Chobpattana, Chakansin Phoomkong, Peerawat Nutnual, Kritsada Thaengthong, Wanchai Pijitrojana

Journal of Metals, Materials and Minerals

Fe3Si is under interest as a ferromagnetic electrode of magnetic tunneling junctions (MTJs). Its crystalline structure is important for achieving high device efficiency. This work focuses on mechanical alloying of 3:1 ratio of 99% pure Fe and Si powder mixtures by ball milling and sintering. The mixtures were ball-milled for various durations up to 20 h. Then, they were sintered from 400°C  to 800°C for 4 h in Ar.  SEM images and particle size analysis show significant reduction in average particle size of the mixtures after ball milling for 20 h. The longer duration of ball milling process promotes powder …

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A Maximum Energy Release Rate Computational Framework For Fatigue Crack Trajectory And Life Prediction Under Mixed-Mode Proportional And Nonproportional Loading, Nahla Helmy Matar Jan 2027

A Maximum Energy Release Rate Computational Framework For Fatigue Crack Trajectory And Life Prediction Under Mixed-Mode Proportional And Nonproportional Loading, Nahla Helmy Matar

Theses and Dissertations

The problem of mixed-mode fatigue crack growth has been a persistent research challenge. The determination of fatigue crack propagation direction directly impacts the safety and integrity of components and structures, making it crucial in various industrial applications, including welded drilling pipes, aerospace, and automotive engineering. Unlike uniaxial loading, mixed-mode cracks tend to change direction frequently (kinking), and nonproportional loading adds to the complexity of the problem. This research aims to estimate the crack propagation direction and fatigue crack life in linear elastic materials subjected to mixed-mode (I+II) loading conditions under proportional or non-proportional cyclic loading. Numerical software was developed based …

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Engineering Sulfur Concrete Mixes: A Data-Driven Approach To Aggregate Packing And Binder Efficiency, Vasilia Al Khaldi, Abdel Hamid I. Mourad, Maisa El Gamal Dec 2026

Engineering Sulfur Concrete Mixes: A Data-Driven Approach To Aggregate Packing And Binder Efficiency, Vasilia Al Khaldi, Abdel Hamid I. Mourad, Maisa El Gamal

All Works

Processing window (mass loss < 3%). A first-order, order-of-magnitude carbon-footprint estimate—presented with explicit caveats rather than as a full life-cycle assessment—indicates that replacing Portland cement with by-product sulfur is the dominant contributor to a substantial reduction in embodied CO₂ per cubic metre relative to equivalent-strength Portland cement concrete. The valorization of steelmaking by-products aligns with circular economy principles, enabling high-performance, recyclable, and low-carbon construction materials without chemical binder modification.

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Structural And Electrochemical Characterization Of Na2co3/ Γ- Al2o3 Electrodes For Supercapacitor, Wiwin Dwiana, Jeniva Dinta Nanda Fahreza, Anissa Chairani Alfin Nadhira, Fatimatuz Zahra, Erma Surya Yuliana, Muhammad Safwan Abd Aziz, Nandang Mufti Nov 2026

Structural And Electrochemical Characterization Of Na2co3/ Γ- Al2o3 Electrodes For Supercapacitor, Wiwin Dwiana, Jeniva Dinta Nanda Fahreza, Anissa Chairani Alfin Nadhira, Fatimatuz Zahra, Erma Surya Yuliana, Muhammad Safwan Abd Aziz, Nandang Mufti

Journal of Mechanical Engineering Science and Technology (JMEST)

The development of electrode materials with suitable structural and surface properties is crucial for improving electrochemical energy storage systems. Gamma alumina (𝛾-Al2O3) has attracted considerable interest in electrochemical research due to its unique structural and surface properties. However, its charge-storage capacity is still limited, highlighting the need for structural and compositional modifications to improve its electrochemical performance. In this study, Na2CO3 was introduced into 𝛾-Al2O3 as a sodium precursor to induce phase modification and enhance the electrochemical activity. The systematic incorporation of Na2CO3 also provides an opportunity …

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A Systematic Review Of Alkali-Treated Polylactic Acid Biocomposites Relevant To Pineapple Leaf And Water Hyacinth Hybrid Design, Muhammad Rizky Adrianto Subandi, Tri Hartutuk Ningsih, Hanna Zakiyya Nov 2026

A Systematic Review Of Alkali-Treated Polylactic Acid Biocomposites Relevant To Pineapple Leaf And Water Hyacinth Hybrid Design, Muhammad Rizky Adrianto Subandi, Tri Hartutuk Ningsih, Hanna Zakiyya

Journal of Mechanical Engineering Science and Technology (JMEST)

The increasing demand for sustainable materials has accelerated the development of biodegradable polymer composites. Polylactic acid (PLA)-based natural fiber composites have attracted significant attention due to their renewable characteristics; however, their performance remains limited by weak fiber–matrix compatibility, moisture sensitivity, and inconsistent interfacial behavior. Alkali treatment has been widely applied to modify lignocellulosic fibers by removing non-cellulosic components and improving surface characteristics, although its effectiveness remains dependent on treatment conditions and fiber properties. This systematic review evaluates the influence of alkali treatment on PLA-based natural fiber composites and assesses the available evidence supporting future pineapple leaf fiber (PALF) and water …

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A Review Of Gallium And Germanium Recovery From Industrial Solid Residues, Ernest V. Oteng, Marthias Silwamba, Lana Alagha, Alex Luyima Nov 2026

A Review Of Gallium And Germanium Recovery From Industrial Solid Residues, Ernest V. Oteng, Marthias Silwamba, Lana Alagha, Alex Luyima

Mining Engineering Faculty Research & Creative Works

The global demand for critical elements such as gallium (Ga) and germanium (Ge), and the shift toward circular mining has accelerated the development of new extraction and recovery processing these metals from industrial solid residues. This transition is driven by a substantial surge in demand for advanced technologies and the depletion of primary ore. Consequently, industrial solid residues, particularly zinc processing residues, smelter slags, flue dusts, and coal fly ash, are emerging as viable alternative sources. These residues incorporate Ga and Ge through isomorphic substitution in phases such as ferrites, silicates, and glassy aluminosilicates, and are enriched by industrial processes, …

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A Performance-Based Indicator Framework For Assessing Innovative Materials In Modular Emergency Shelters, Riham Nady Faragallah, M. S. Refaey, Naglaa M. Yussuf, Riham S. Hassan Oct 2026

A Performance-Based Indicator Framework For Assessing Innovative Materials In Modular Emergency Shelters, Riham Nady Faragallah, M. S. Refaey, Naglaa M. Yussuf, Riham S. Hassan

HBRC Journal

In recent years, the increasing intensity of disasters, conflicts and mass displacement has amplified the need for emergency shelters that are rapidly deployable, structurally safe, and thermally comfortable, particularly when delivered through prefabricated modular systems. The recent development of innovative materials—including smart, recycled, bio-based, and 3D-printed composites—has demonstrated considerable potential for improving emergency shelter performance. However, existing studies primarily evaluate these materials individually, with limited efforts to integrate them into a comprehensive performance-based decision framework for modular emergency shelters. This research aims to develop a performance-based indicator framework for evaluating and selecting innovative materials to enhance the safety, comfort, durability, …

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Electrocatalytic Oxidation Of Ethylene Glycol To Glycolic Acid: From Mechanism And Catalyst Design To Emerging Neutral Electrolyte Systems, Man Zhang, Xue Li, Xin-Yu Peng, Lin Wang, Wen-Wen Chen, Yao-Yue Yang Oct 2026

Electrocatalytic Oxidation Of Ethylene Glycol To Glycolic Acid: From Mechanism And Catalyst Design To Emerging Neutral Electrolyte Systems, Man Zhang, Xue Li, Xin-Yu Peng, Lin Wang, Wen-Wen Chen, Yao-Yue Yang

Journal of Electrochemistry

Polyethylene terephthalate (PET) waste represents both an environmental burden and a loss of carbon resources. Alkaline depolymerization of PET yields terephthalic acid and ethylene glycol (EG). Electrocatalytic oxidation of EG to glycolic acid (GA), the monomer of biodegradable polyglycolic acid (PGA), offers a sustainable route driven by renewable electricity. However, the ethylene glycol oxidation reaction (EGOR) involves competing pathways toward C2 products (GA and oxalic acid) and C1 products (formic acid and CO2), making selective GA production a central challenge. This review provides a comprehensive overview of recent progress in selective EG-to-GA electrooxidation from catalyst design, mechanistic understanding, …

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Regularization-Based Crystallite Size Distribution Analysis Of Pt/C Catalysts From X-Ray Diffraction, Cheng-Long Ma, Wei-Yu Shi, Zhong-Jun Hou Oct 2026

Regularization-Based Crystallite Size Distribution Analysis Of Pt/C Catalysts From X-Ray Diffraction, Cheng-Long Ma, Wei-Yu Shi, Zhong-Jun Hou

Journal of Electrochemistry

Accurate determination of the platinum crystallite size distribution in carbon-supported platinum (Pt/C) catalysts is critical for evaluating both the initial performance and long-term durability of proton exchange membrane fuel cells (PEMFCs). Conventional characterization approaches—including transmission electron microscopy (TEM), small-angle X-ray scattering (SAXS), and the Scherrer equation—are limited by restricted statistical sampling, sensitivity to support interference, or the inability to resolve the full breadth of the size distribution. In this work, we present a regularization-based inversion framework that extracts the volume-weighted crystallite size distribution directly from X-ray diffraction (XRD) line profiles, without requiring any a priori assumption regarding the functional form …

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Metal Oxide Semiconductor Gas Sensors For Exhaled Breath Cancer Biomarker Detection, Guang-Lan Chen, Hui-Hui Luo, Wen-Wen Peng, Shi-Yu Xu, Yu-Ting Li, Hui-Jie Ke, Si-Hui Zhong, Jia-Ao Wei, Tong Chen, Xiao-Kun Li, You-Lin Zhang, Wei Chen Oct 2026

Metal Oxide Semiconductor Gas Sensors For Exhaled Breath Cancer Biomarker Detection, Guang-Lan Chen, Hui-Hui Luo, Wen-Wen Peng, Shi-Yu Xu, Yu-Ting Li, Hui-Jie Ke, Si-Hui Zhong, Jia-Ao Wei, Tong Chen, Xiao-Kun Li, You-Lin Zhang, Wei Chen

Journal of Electrochemistry

Early cancer screening can significantly improve therapeutic outcomes, volatile organic compounds (VOCs) and other related gases in exhaled breath, as cancer-specific biomarkers, offer a novel approach for non-invasive diagnosis. Metal oxide semiconductor (MOS)-based gas sensors are pivotal for exhaled breath VOCs detection, featuring compact size, cost-effectiveness, and rapid response. This review summarizes the most recent five-year research advances in cancer biomarker detection, and clarifies the core mechanisms of electrical property changes from sensing material-VOCs interactions and key performance metrics including sensitivity, selectivity, humidity tolerance, response/recovery time, stability, and operating temperature. This review also highlights the optimization strategies of sensing materials …

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Magnetic Cellulose Nanocrystal Composites Functionalized With Benzalkonium Chloride For Potential Pathogen Control, Kishore Chand, Sydney Herzog, Mohammad Jahid Hasan, Juganta Roy, Moses Ayitey-Adjin Jr., Corbon M. Moss, Sarah Khan, Sara Tester, Monishita Deb, Katherine Schlaak, Sarah Watzman, Yvonne Sun, Esteban Ureña-Benavides, Erick S. Vasquez-Guardado Oct 2026

Magnetic Cellulose Nanocrystal Composites Functionalized With Benzalkonium Chloride For Potential Pathogen Control, Kishore Chand, Sydney Herzog, Mohammad Jahid Hasan, Juganta Roy, Moses Ayitey-Adjin Jr., Corbon M. Moss, Sarah Khan, Sara Tester, Monishita Deb, Katherine Schlaak, Sarah Watzman, Yvonne Sun, Esteban Ureña-Benavides, Erick S. Vasquez-Guardado

Chemical and Materials Engineering Faculty Publications

This study presents the design and synthesis of multifunctional magnetic cellulose nanocrystal (CNC) composites engineered for targeted adsorption and broad-spectrum antimicrobial applications. The nanocomposites were fabricated by anchoring mixed-valence Fe3O4 magnetic nanoparticles on eco-friendly CNC frameworks, followed by surface functionalization with benzalkonium chloride (BC), a potent quaternary ammonium biocide. Both sulfated (S) and TEMPO-oxidized CNC (T) variants were investigated across Fe3O4:CNC mass ratios of 1:2 and 1:4. Comprehensive structural, magnetic, and morphological characterization confirmed successful surface modification, superparamagnetic responsiveness, and uniform component dispersion. Thermogravimetric analysis confirmed precise compositional tailoring, capturing up to 87 …

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Comparative Performance Evaluation Of Generative Ai-Assisted Acoustic Tiles From Recycled Educational Waste, Nada Ahmed Talaat, Ahmed Mahmoud Elfakarany, Nihal Atif Salim Oct 2026

Comparative Performance Evaluation Of Generative Ai-Assisted Acoustic Tiles From Recycled Educational Waste, Nada Ahmed Talaat, Ahmed Mahmoud Elfakarany, Nihal Atif Salim

HBRC Journal

Noise pollution is increasingly recognized as a critical environmental challenge with direct implications on public health and well-being. In Egypt, data from the Egyptian Environmental Affairs Agency (EEAA, 2019) identify noise as the second most reported environmental concern, affecting both indoor and outdoor spaces. At the same time, the growing volume of waste generated on university campuses represents an underexploited resource for sustainable design. This study addresses these challenges by investigating how generative AI can serve as a design collaborator in suggesting high-performance acoustic tiles from recycled campus waste. Two AI-driven prototypes were developed through prompts emphasizing acoustic absorption, aesthetic …

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Glutaraldehyde-Crosslinked Chitosan And Zinc Oxide Coating Reinforced With Polysulfone On Copper As A Platform For Electrochemical Formaldehyde Sensing, Anceu Murniati Anm, Rahmat Saputra Rs, Arie Hardian Ah, Manty Aldilani Ikaningsih Mai, Moh Haifan Haifan Oct 2026

Glutaraldehyde-Crosslinked Chitosan And Zinc Oxide Coating Reinforced With Polysulfone On Copper As A Platform For Electrochemical Formaldehyde Sensing, Anceu Murniati Anm, Rahmat Saputra Rs, Arie Hardian Ah, Manty Aldilani Ikaningsih Mai, Moh Haifan Haifan

Chimica et Natura Acta

Formaldehyde monitoring requires electrochemical platforms with stable structures and reliable interfacial responses. This study aimed to prepare and characterize a Cu|CS–GLA/ZnO–PSf composite film on a copper substrate as a platform for further formaldehyde-sensing development. The film was characterized using FTIR, SEM–EDX, XRD, and cyclic voltammetry. FTIR supported the presence of features associated with chitosan, imine, polysulfone, and Zn–O, while SEM–EDX revealed a heterogeneous polymer-rich coating with Zn- and O-containing domains distributed non-uniformly. XRD indicated a predominantly amorphous or poorly crystalline structure. Cyclic voltammetry showed scan-rate-dependent peak separations, with ΔEp increasing from 0.632 to 0.777 V in citrate buffer and from …

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Securing The Frontier: Environmental Adaptation Versus Urban Fortification In Strategic Border Gateways: The Case Of East Qantara, Ahmed M. Selim, Mohamed A. Shebl, Doha M. Saeed, Heba M. Gaber Oct 2026

Securing The Frontier: Environmental Adaptation Versus Urban Fortification In Strategic Border Gateways: The Case Of East Qantara, Ahmed M. Selim, Mohamed A. Shebl, Doha M. Saeed, Heba M. Gaber

HBRC Journal

Security-oriented urban design at strategic national gateways often restricts spatial openness, cultural identity, and social inclusion, all essential to functional public spaces. This study develops a multi-criteria framework for security-inclusive urban design at East Qantara, the primary vehicular gateway between continental Egypt and the Sinai Peninsula. This study employed a sequential quantitative–interpretive design approach. In the quantitative phase, 51 criteria were identified from Crime Prevention Through Environmental Design (CPTED) principles, Hostile Vehicle Mitigation (HVM) guidance, publicness theory, and context-specific desert and socio-cultural literature, and subsequently revised to 37 criteria through expert panel validation. A structured expert questionnaire with a five-point …

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Built To Fall: Ruin Value From Romanticist Ideal To Materials Design Philosophy, Vuk Uskoković Oct 2026

Built To Fall: Ruin Value From Romanticist Ideal To Materials Design Philosophy, Vuk Uskoković

Administration and Staff Articles and Research

Ruin value is an architectural principle endorsing the use of designs and materials that would allow buildings to age beautifully and retain their aesthetics even when transformed into ruins. Here, the principle is extracted from the political context in which its proponent, Albert Speer, proposed it and discussed as a continuation of a longer Romanticist tradition of appreciation of weathering and the melancholy beauty of things in decline. Noting its reach well beyond architecture and across other artistic genres, the principle is brought here into the context of natural sciences and the following question is analyzed: Is there room for …

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Developing A Digital Facility Management Framework For Enhancing Operation And Maintenance Of Public Parks In Egypt, Alaa Ezzat, Alia Amer, Yasser M. El Sayed Oct 2026

Developing A Digital Facility Management Framework For Enhancing Operation And Maintenance Of Public Parks In Egypt, Alaa Ezzat, Alia Amer, Yasser M. El Sayed

HBRC Journal

Public parks in Cairo represent important urban assets, however, their operation and maintenance (O&M) face many challenges due to fragmented information, reactive maintenance practices, organizational constraints, and limited digital integration. Digital Facility Management discipline still lacks the tailored framework that adequately addresses the operational needs of public parks in Egypt with all its specific details. This study develops an integrated digital FM framework for improving the efficiency of the management process of public parks. A four-phase methodology was adopted, comprising a literature review, framework development, technical system specification, and expert assessment. The proposed framework integrates BIM, COBie, CMMS, IoT technologies, …

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Direct Electrochemical Detection Of Carbaryl In Water Using Boron-Doped Diamond Electrodes, Natasha Fransisca, Chico Permana Putra, Salma Nur Zakiyyah, Muhammad Ihda Hamlu Liwaissunati Zein, Yeni Wahyuni Hartati, Irkham Irkham Oct 2026

Direct Electrochemical Detection Of Carbaryl In Water Using Boron-Doped Diamond Electrodes, Natasha Fransisca, Chico Permana Putra, Salma Nur Zakiyyah, Muhammad Ihda Hamlu Liwaissunati Zein, Yeni Wahyuni Hartati, Irkham Irkham

Chimica et Natura Acta

Carbaryl (1-naphthyl methylcarbamate) is a carbamate pesticide used to cause adverse environmental and health effects when misused through water contamination. Therefore, this research aimed to develop a direct electrochemical detection method for carbaryl in aqueous media using boron-doped diamond (BDD) electrodes. In this context, BDD electrodes exhibited superior electrochemical performance compared to conventional materials such as gold (Au), platinum (Pt), and glassy carbon electrodes (GCE) due to a wide potential window, low background current, and excellent chemical stability. Cyclic and differential pulse voltammetry reported a well-defined oxidation peak for carbaryl at 1.30 V, with significantly enhanced sensitivity. The results showed …

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The Vegetated-Canopy Roughness Sublayer Through A Tke-Budget Lens, Giulia Salmaso, Raul Bayoan Cal, Marc Calaf Oct 2026

The Vegetated-Canopy Roughness Sublayer Through A Tke-Budget Lens, Giulia Salmaso, Raul Bayoan Cal, Marc Calaf

Mechanical and Materials Engineering Faculty Publications and Presentations

It is well understood that vegetated canopies perturb the atmospheric flow within and immediately above the canopy, deviating from the inertial sublayer (ISL) regime characteristic of non-vegetated rough surfaces. Only above a certain height, denoted as the roughness sublayer height (RSL, 𝑧∗), do these flows return to ISL-like behavior. This distinction is critical, as parameterizations in Earth System Models (ESMs) are typically developed for ISL flows. Yet, most 𝑧∗ estimates stem from studies over flat, homogeneous canopies and may be biased. In contrast, little is known about 𝑧∗ in non-homogeneous or heterogeneous canopies that are not of agricultural interest, with …

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Thermo-Mechanical Behaviour Of Metal-Coated Optical Fibers For Distributed High-Temperature Sensing: From Laboratory Characterization To Industrial Case Validation, Koustav Dey, Rony Kumer Saha, Bohong Zhang, Laura Bartlett, Jeffrey D. Smith, Ronald J. O'Malley, Jie Huang Oct 2026

Thermo-Mechanical Behaviour Of Metal-Coated Optical Fibers For Distributed High-Temperature Sensing: From Laboratory Characterization To Industrial Case Validation, Koustav Dey, Rony Kumer Saha, Bohong Zhang, Laura Bartlett, Jeffrey D. Smith, Ronald J. O'Malley, Jie Huang

Electrical and Computer Engineering Faculty Research & Creative Works

Reliable distributed temperature sensing in high-temperature environments remains a significant challenge due to the thermal and mechanical limitations of conventional optical fibers. In particular, polymer-coated fibers degrade above ∼300 °C due to coating failure, mechanical fragility and hydrogen ingress. Metal-coated optical fibers offer a robust alternative for harsh environments such as Electric Arc Furnaces (EAFs), aerospace engines, nuclear systems, and oil and gas wells, owing to their superior mechanical strength and hermetic sealing. In this work, a first comprehensive experimental investigation of the thermo-mechanical behavior of metal-coated optical fibers for distributed high temperature sensing is presented over a wide temperature …

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Feasibility Of Acetylated Icacina Trichantha Oliv. Tuber Starch As Viscosity And Fluid Loss Control Agents In Water-Based Drilling Mud. A Comparative Assessment With Commercial Starch, Kennedy I. Ogunwa, Theresa O. Uchechukwu, Ozioma Achugasim, Leo C. Osuji, Onyewuchi Akaranta Sep 2026

Feasibility Of Acetylated Icacina Trichantha Oliv. Tuber Starch As Viscosity And Fluid Loss Control Agents In Water-Based Drilling Mud. A Comparative Assessment With Commercial Starch, Kennedy I. Ogunwa, Theresa O. Uchechukwu, Ozioma Achugasim, Leo C. Osuji, Onyewuchi Akaranta

Tanzania Journal of Science

The need for sustainable, non-food drilling fluid additives has prompted the feasibility assessment of acetylated Icacina trichantha tuber starch as a viscosity modifier and fluid loss control agent in water-based muds. Native starch was acetylated to obtain two derivatives (Degree of Substitution DS = 0.38 and 0.68) and characterized using FTIR, swelling power, and physicochemical analyses. Drilling mud performance was assessed through rheology, gel strength, filtration loss, sorptivity, and model fitting. Acetylation improved swelling and reduced gelatinization temperature. The optimal formulation, Mud-ITO-ACS2 (DS = 0.68), exhibited the most favorable performance, combining low plastic viscosity (6 cP vs 9 cP for …

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Settling Method For Decolorization Of Low Molecular Weight Polyethylene, Adham E. Norkobilov, Ravshan I. Adilov, Bobur B. Aykhodjaev, Saparboy B. Yuldoshev, Lobar Sh. Kholmirzayeva Sep 2026

Settling Method For Decolorization Of Low Molecular Weight Polyethylene, Adham E. Norkobilov, Ravshan I. Adilov, Bobur B. Aykhodjaev, Saparboy B. Yuldoshev, Lobar Sh. Kholmirzayeva

CHEMISTRY AND CHEMICAL ENGINEERING

This study investigates the bleaching of low molecular weight polyethylene (LMWPE) by the settling (sedimentation) method. LMWPE is a by-product of polyethylene production whose discoloration is associated with trace amounts of conjugated, oxidized, and polar micro-fractions. The research was conducted in three stages: selection of the appropriate sample grade, determination of the optimal settling time, and evaluation of the temperature effect on the settling process. Results showed that only Grade-1 LMWPE samples are suitable for the settling method; Grade-2 samples yielded insufficient results and are recommended for bentonite adsorption treatment instead. Optimal settling conditions were established as 150 °C for …

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Structural And Physico-Mechanical Properties Of Geomembranes Based On Recycled Polyolefins Modified With Argillite From The Sherabad Deposit, Munisa N. Davronova, Furqat B. Eshkurbonov, Azim P. Khamidov, Asal A. Ashurova, Raykhona I. Abdullayeva Sep 2026

Structural And Physico-Mechanical Properties Of Geomembranes Based On Recycled Polyolefins Modified With Argillite From The Sherabad Deposit, Munisa N. Davronova, Furqat B. Eshkurbonov, Azim P. Khamidov, Asal A. Ashurova, Raykhona I. Abdullayeva

CHEMISTRY AND CHEMICAL ENGINEERING

This study investigated the effect of argillite, sourced from the local Sherabad deposit and modified with maleic anhydride, on the physical and mechanical properties of geomembranes based on recycled high-density polyethylene (r-HDPE), recycled low-density polyethylene (r-LDPE), and recycled polypropylene (r-PP). Maleic anhydride was used as a compatibilizer to ensure interfacial adhesion between the polymer matrix in the hydrophilic filler and the layered aluminosilicates, and to promote the uniform distribution of mineral particles. The experimental results showed that hybrid modification makes it possible to elevate the strength properties of all types of recycled polymers to the level of their virgin (pure) …

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Physical-Chemical Properties Of Nmgca-Fertilizers Obtained On The Basis Of Ammonium Nitrate And Vermiculite, Madiyar J. Jabbarbergenov Sep 2026

Physical-Chemical Properties Of Nmgca-Fertilizers Obtained On The Basis Of Ammonium Nitrate And Vermiculite, Madiyar J. Jabbarbergenov

CHEMISTRY AND CHEMICAL ENGINEERING

Although ammonium nitrate (AN) ranks second after urea among nitrogen fertilizers in terms of production and application volume, it remains the leading agent regarding plant nutrient uptake efficiency. This is primarily because nearly the entire total nitrogen content is assimilated in both ammonium (NH4+) and nitrate (NO3-) forms. However, the widespread agricultural utilization of AN is significantly constrained by several disadvantageous factors, including its physiological acidity, high hygroscopicity, caking tendency, low granule strength, thermal instability, and high explosive hazards. In this study, to enhance the commercial and physical-chemical properties of AN, a vermiculite mineral modifier was incorporated. The chemical composition …

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Improved Electromechanical Response And Relaxor Ferroelectric Behavior In (76–X)Bi₁/₂Na₁/₂Tio₃–24srtio₃ Ceramics Modified With Bifeo₃ And Bialo₃, Muhammadali K. Nigmatjanov, Farrukh B. Erkinov, Shoira A. Kadirniyazova Sep 2026

Improved Electromechanical Response And Relaxor Ferroelectric Behavior In (76–X)Bi₁/₂Na₁/₂Tio₃–24srtio₃ Ceramics Modified With Bifeo₃ And Bialo₃, Muhammadali K. Nigmatjanov, Farrukh B. Erkinov, Shoira A. Kadirniyazova

CHEMISTRY AND CHEMICAL ENGINEERING

Piezoelectric ceramics are smart functional materials capable of converting mechanical energy into electrical energy and vice versa, making them indispensable for modern sensors, transducers, and precision actuators. Historically dominated by lead-containing materials like Pb(Zr,Ti)O₃ (PZT), strict environmental regulations and health concerns have driven an urgent global shift toward eco-friendly alternatives. Currently, bismuth sodium titanate (Bi₁/₂Na₁/₂TiO₃–BNT)-based solid solutions are at the forefront of lead-free piezoceramic trends due to their excellent polarization and electromechanical coupling properties. In this study, lead-free piezoelectric ceramics based on the (76–x)Bi₁/₂Na₁/₂TiO₃–24SrTiO₃ (BNST24) system were synthesized, and their structural, dielectric, and electromechanical properties were systematically investigated. This study …

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Research Of The Binary Content Of Transition Metal Oxides Of Cu, Mo And W On The Properties Of Semi-Frit Glazes, Mihail V. Dyadenko, Ivan A. Levitskiy, Mastura Kh. Aripova Sep 2026

Research Of The Binary Content Of Transition Metal Oxides Of Cu, Mo And W On The Properties Of Semi-Frit Glazes, Mihail V. Dyadenko, Ivan A. Levitskiy, Mastura Kh. Aripova

CHEMISTRY AND CHEMICAL ENGINEERING

The results of a study of the binary content of transition metal oxides CuO + MoO3; CuO + WO3 and a combination of MoO3 + WO3 on the physico-chemical properties of glaze coatings and their antibacterial activity are presented. A polycomponent raw material composition has been studied, including aluminum-sulfate high-calcium frit, the indicated antibacterial components, as well as feldspar, dolomite, and additives of alumina, quartz sand, kaolin, and refractory clay. Optimal technological modes of preparation of suspensions, their application to a ceramic base, followed by firing at a temperature of 1200 ± 5 ° C have been determined. Decorative, physico-chemical …

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Experimental Study On The Behavior Of High-Strength Reinforced Concrete Beams With A Longitudinal Void, With And Without Micro Steel Fibers, At Different Shear Spans, Farah M. Hussein, Saif Altai, Shatha Alasadi, Ayoob A. Ibrahim, Arshad Nadhom Shubber Sep 2026

Experimental Study On The Behavior Of High-Strength Reinforced Concrete Beams With A Longitudinal Void, With And Without Micro Steel Fibers, At Different Shear Spans, Farah M. Hussein, Saif Altai, Shatha Alasadi, Ayoob A. Ibrahim, Arshad Nadhom Shubber

Journal of Sustainable Construction Materials and Technologies

This study examines the impact of creating a longitudinal void in high-strength reinforced concrete (RC) beams to decrease concrete volume. Testing involved three groups: solid beams (SB), beams with a 75 mm void (VB), and beams with a void incorporating 1.2% micro-steel fibers (VBSF), across various shear spans (a/d) of 1.8, 2.7, and 3.6. Results indicated that increased a/d led to a 54.2% reduction in peak loads and a 119.2% increase in deflection for solid beams. The void negatively affected load-bearing at a/d = 1.8 with a 25% peak load reduction and brittle failure. At a/d = 2.7, effects were …

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Dense Platinum Nanoparticles Confined In Mn-N-C Nanocages For Robust Heavy-Duty Pemfcs, Lei Zhao, Zhen-Min Cao, Jia-Yu Zuo, Ming-Liang Yang, Hong-Yan Qiao, Jun-Song Chen, Rui Wu Sep 2026

Dense Platinum Nanoparticles Confined In Mn-N-C Nanocages For Robust Heavy-Duty Pemfcs, Lei Zhao, Zhen-Min Cao, Jia-Yu Zuo, Ming-Liang Yang, Hong-Yan Qiao, Jun-Song Chen, Rui Wu

Journal of Electrochemistry

High-loading Pt cathodes are essential for heavy-duty proton exchange membrane fuel cells but suffer from a critical tradeoff between ionomer sulfonate poisoning and nanoparticle instability. Herein, we report a spatial confinement strategy to encapsulate dense Pt nanoparticles (~51.8 wt%) within Mn/N-co-doped mesoporous carbon nanocages (denoted as Pt-MnNC). This architecture excludes bulky ionomers to create an ionomer-shielded environment against sulfonate poisoning, while Mn-Nx-mediated strong metal-support interactions anchor the Pt nanoparticles to prevent agglomeration and further boost durability. In the 5 × 5 cm2 membrane electrode assembly tests, the Pt-MnNC catalyst delivers an exceptional power density of 1.26 W·cm …

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Engineering Small-Sized Cations With Strong Solvation For High-Voltage Supercapacitors, Tong Huo, Pan Liu, Hao Chen, Peng Zhang, Zhen-Lei Chen, Guo-Fu Sun, Zhi-Qiang Shi, Jing Wang Sep 2026

Engineering Small-Sized Cations With Strong Solvation For High-Voltage Supercapacitors, Tong Huo, Pan Liu, Hao Chen, Peng Zhang, Zhen-Lei Chen, Guo-Fu Sun, Zhi-Qiang Shi, Jing Wang

Journal of Electrochemistry

Supercapacitors (SCs) have attracted much attention in the field of energy storage due to their high power density and long cycle life. However, their relatively low energy density limits their application in a wider range of fields. Methods to increase energy density include enhancing specific capacitance and extending operating voltage window. Herein, we report a novel electrolyte salt, tetramethylammonium bis(fluorosulfonyl)imide (TMA-FSI), the resulting electrolyte formed with propylene carbonate (PC), designated as TMF, exhibited a wide electrochemical stability window (ESW) of 5.09 V. On the one hand, we found that the small size of TMA+ enables it to enter the …

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Efficient Acidic H2O2 Electrosynthesis Over Co Atoms Anchored On Nitrogen-Doped Hierarchical Porous Carbon, Xiao Huang, Zi-Hao Zhan, Hao-Xu Niu, Guan-Yu Luo, Jin-Tao Huang, Bo-Xuan Jin, De-Li Wang Sep 2026

Efficient Acidic H2O2 Electrosynthesis Over Co Atoms Anchored On Nitrogen-Doped Hierarchical Porous Carbon, Xiao Huang, Zi-Hao Zhan, Hao-Xu Niu, Guan-Yu Luo, Jin-Tao Huang, Bo-Xuan Jin, De-Li Wang

Journal of Electrochemistry

The two-electron oxygen reduction reaction (2e− ORR) presents a promising route for the on-site production of hydrogen peroxide (H2O2), offering a green alternative to energy-consuming anthraquinone process. However, the high selectivity toward the competing 4e− ORR over the desired 2e− pathway leads to low Faradaic efficiency for H2O2, posing a critical challenge in catalyst design. In this work, a nitrogen-doped hollow hierarchical porous carbon with anchored Co atoms (CoN/HPC) was constructed for high-performance H2O2 production. The as-prepared Co-N/HPC catalyst showed excellent 2e− ORR performance, achieving …

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Complementary Thermodynamic Mechanisms Of Boron And Carbon Segregation At Grain Boundaries In Nickel Alloys, Tyler D. Dolezal, Rodrigo Freitas, Ju Li Sep 2026

Complementary Thermodynamic Mechanisms Of Boron And Carbon Segregation At Grain Boundaries In Nickel Alloys, Tyler D. Dolezal, Rodrigo Freitas, Ju Li

Faculty Publications

Grain boundary stabilization by light interstitials is central to the performance of Ni-based superalloys, yet the thermodynamic mechanisms governing their interactions with substitutional chemistry remain poorly resolved. Here, we use hybrid Monte Carlo molecular dynamics simulations to quantify how boron and carbon modify the thermodynamic, structural, and chemical ordering of grain boundaries in Ni-Cr alloys. By analyzing interfacial state variables, site-resolved segregation spectra, local chemical ordering, and structural evolution, we show that boron and carbon stabilize grain boundaries through complementary pathways. Carbon drives saturation-controlled stabilization by recruiting Cr and conditioning boundary chemistry, while suppressing temperature-driven structural transformations of the boundary. …

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