Materials Science and Engineering Commons^™

Photoluminescent Studies Of Metal-Organic Frameworks For Small Molecule Sensing, Julia T. Dematteo

USF Tampa Graduate Theses and Dissertations

Metal–organic frameworks (MOFs) are highly tunable nanoporous materials with broad applications in gas separation, drug delivery, light harvesting, and chemical sensing. The incorporation of photoactive components into MOFs enables the development of optical sensors capable of detecting a wide range of analytes. Porphyrins and metalloporphyrins are particularly attractive for such applications due to their high molar absorptivity, strong emission quantum yields, and versatile interactions with chemical species.

In this work, two porphyrinic MOFs, PCN-222 and MOF1(Cd), are investigated. Both frameworks utilize tetrakis(4-carboxyphenyl)porphyrin (TCPP) as the organic linker, imparting optical functionality to the materials. Integration of TCPP into the framework induces …

Chemical Design Strategies For Hybrid Metal Halide Semiconductors With Enhanced Stability And Optoelectronic Properties, Ali Azmy

USF Tampa Graduate Theses and Dissertations

Metal halide semiconductors have rejuvenated the attention of the scientific community for the last two decades owing to their photophysical and electronic properties. However, these materials have some limitations that hinder their commercialization and widespread application. One major limitation of these materials is their instability under ambient and operating conditions of moisture, head, light and radiation exposure. Here, we report multiple chemical design strategies to address the stability issues of these materials while simultaneously maintaining their exceptional optoelectronic properties. Such design strategies allowed the acquisition of the first members of the family of porous metal halide semiconductors which exhibit record …

Thermal Properties Of Novel Materials, Wilarachchige D.C. Bhagya Gunatilleke

USF Tampa Graduate Theses and Dissertations

Thermal properties play an important role in various aspects of applications of technology startingfrom the materials property determinations to device performance improvements and their safety and stability. Measurements of the thermal properties of such materials of interest pose challenges due to the demands of these measurements for determination of intrinsic materials properties. The research included in this dissertation involved both synthesis of novel materials and their measurement of thermal properties. Solid-state materials synthesis involves various synthesis and processing techniques, while specific technological applications demand synthesis of defect-free single crystals. Such synthesis techniques were explored for the research included in this …

Exploring Corona Discharge In Electrostatic Printing For Electronics And In Other Application, Zijian Weng

USF Tampa Graduate Theses and Dissertations

The field of printed electronics (PEs) is expanding rapidly, driven by increasing market demand. According to reports, the global market for PEs is expected to reach $23 billion by 2026, with a compound annual growth rate of 18.3% from 2023 to 2028. This growth necessitates the development of innovative printing technologies that can meet these demands efficiently, delivering high-quality, high-resolution PEs suitable for applications in health, environmental monitoring, sports, aerospace, and more.

Currently, PEs manufacturing relies on two main groups of printing technologies. Contact printing methods offer high-speed production but struggle with precision, while non-contact methods provide high resolution but …

Synthesis, Characterization And Electrical Properties Evaluation Of Zirconium Dioxide Capacitors, Thomas P. Chandy

USF Tampa Graduate Theses and Dissertations

This thesis focuses on the fabrication and comprehensive characterization of thin-film capacitors utilizing zirconium dioxide (ZrO2) as the dielectric material, placed between aluminum electrodes. The research primarily aims to examine the impact of varying ZrO2 film thickness and the effects of post-deposition annealing on the structural, morphological, and electrical properties of the capacitors. A controlled sputtering deposition technique was employed to ensure uniform film growth, maintaining consistency in thickness and material quality across all samples.

A comprehensive set of characterization techniques was employed to analyze the capacitors. Scanning electron microscope (SEM) was used to assess surface roughness, revealing fewer defects …

Synthesis, Characterization And Delamination Studies Of Metallic Thin Films Prepared Using Sputtering And Ebeam Evaporation Methods, Anoop Joseph

USF Tampa Graduate Theses and Dissertations

In many mechanical applications, including the manufacturing, automotive, and cutting tool sectors, metallic thin film coatings are crucial due to their tribological and protective properties. This research focuses on the development of metallic thin films of Aluminum (Al), Chromium (Cr) and Titanium (Ti) using deposition techniques like Sputtering and Electron Beam Evaporation. Metallic thin films were fabricated, with variations in thickness for each material, allowing for an in-depth study of the effects of Sputtering and Ebeam Evaporation deposition method on film characteristics. The thickness of these metallic thin films were evaluated using High-Resolution Scanning Electron Microscopy (HRSEM) and Profilometer while …

Ultrasound Based Dynamic Reference Reflection Technique For Simultaneous Specific Gravity And Temperature Estimation, Jose Paul

USF Tampa Graduate Theses and Dissertations

This work is driven by the need for a noninvasive density estimation device for pipeline infrastructure due to the increased risk of volatility in the high energy density fuels that are available in the market. Ultrasound based techniques have proved to be a viable alternative to traditional u tube resonance or nuclear techniques due to their robustness and safety offering. The major update that this work intends to make to the existing technology is development of a system wherein the transducer or the electronic components remain isolated from the flow field.As a result, this work dives headfirst into the fundamentals …

Photodegradation And Microencapsulation Of Organic Thermochromic Material For Application As Building Coating Envelope, Sushant Madhukar Nagare

USF Tampa Graduate Theses and Dissertations

Due to exponential urbanization, residential building electrical loads have increased over the past decades. Also, deforestation has led to increased urban heat island effects, due to which summer has been scorching and winter has become freezing. This further increases the load on generation due to the extensive use of heating and cooling systems. New techniques, such as cool building materials and green building concepts, compensate for the load. The building can be coated with a material that has heat reflectivity capability for summer and heat-trapping capability for winter. One such material is thermochromic, which turns white upon heating and black …

Investigation Of The Use Of Recycled Concrete Aggregates In Porous Asphalt Mixture, Asad Elmagarhe

USF Tampa Graduate Theses and Dissertations

This study aims to address the national need for using recycled concrete in road pavements. This is especially important in the governmental and corporate sectors, where reducing the cost and carbon footprint of construction projects is a priority. The long-term goal is to meet the public demand for environmentally friendly infrastructure and minimize the harmful effects of waste disposal on humans and the environment.

The project focuses on using recycled concrete aggregate (RCA) in porous asphalt pavement to reduce stormwater runoff, a popular environmentally friendly road design. However, compared to regular dense asphalt mixtures, porous asphalt mixtures (PAM) are more …

Electrospun Nanofiber Technology Based Energy Storage And Biosensor Devices For Wearable Electronics, Bianca Seufert

USF Tampa Graduate Theses and Dissertations

As progress in the field of nanotechnology continues to evolve, it is becoming more and more prevalent to apply this small but powerful technology to portable wearable electronics. The unique scale of such a technology lends its expertise to the investigation of enzymes for biometric related diagnostics or in the development of light weight flexible energy storage devices. Furthermore, as the need for highly precise and durable wearable electronics grows, the next generation of electronics must keep pace with this development in terms of shape, flexibility, functionality, and performance.

The presented research reviews the current state of art of nanofiber …

Interfacial Magnetism And Anisotropy In Dirac And Weyl Semimetals, Noah Schulz

USF Tampa Graduate Theses and Dissertations

Semimetals have gained intense interest recently due to their exotic magnetic and electronic properties. One of the most widely studied semimetals is graphene, a Dirac semimetal. The utilization of graphene in devices and sensors requires interfacing it with other materials, which may induce potentially strong interfacial effects. Furthermore, graphene alone does not possess magnetic order. Studying the interfacial effects between graphene and magnetic materials is therefore of great importance in the application of graphene to meet modern technological needs. Furthermore, by understanding the fundamental interfacial physics between graphene and magnetic materials, new properties can be unlocked, broadening the possible applications …

Surface Modification Of Poly(4,4'-Oxydiphenilene Pyromellitimide) With Low-Pressure Plasma Treatment, Cihan Aktas

USF Tampa Graduate Theses and Dissertations

This study explores the change of the wetting characteristics of commercially availablepolyimide (PI), Kapton® HN, films a type of poly(4,4′-oxydiphenylene-pyromellitimide), following treatment with low-pressure plasmas of carbon tetrafluoride (CF4), air, hydrogen (H2), carbon-dioxide (CO2) and oxygen (O2) gases as well as the surface texturing via laser-exposure procedure. The water contact angle (CA) and surface free energy (SFE) of untreated PI films were determined as 82.4°±0.8 and 45.0±0.3 mN/m, respectively. After CF4 plasma gas treatment, the CA value of PI films increased to 110.2°±1.0, while it decreased to 9.3°±2.3 after O2 plasma gas treatment. The surface free energy (SFE) of PI …

Syntheses, Photophysics, & Application Of Porphyrinic Metal-Organic Frameworks, Zachary L. Magnuson

USF Tampa Graduate Theses and Dissertations

Porphyrins are a group of heterocyclic macrocycles that play crucial roles in various biological processes such as electron transfer, catalysis, and sensing. Hemoglobin, which carries oxygen in the blood of mammals, and chlorophyll, which drives photosynthesis in plants and algae, are both porphyrins. The ability of porphyrins to bind metal ions and their unique electronic and photophysical properties make them an excellent platform for designing functional materials for various applications, often drawing inspiration from their function in nature. Metal-organic frameworks (MOFs) are a class of porous materials that have been extensively studied in recent years due to their high surface …

Durability Of Cfrp/Steel Bond In Natural Weather, Mastour Alsulami

USF Tampa Graduate Theses and Dissertations

Fiber reinforced polymers (FRP) are increasingly being used for infrastructurestrengthening and repair of steel structures. Though there have been several durability studies, exposures used are not representative of outdoor service conditions. Fewer studies have explored the effect of changing outdoor conditions typical in infrastructure use. The goal of the research is addressing this gap by evaluating the performance of commercially available CFRP systems under natural weather characteristic of hot, humid tropical conditions mainly and cold weather secondary in three different locations.

Thirty CFRP/steel joint specimens were prepared in laboratory conditions and exposed to ambient temperature on the Engineering building roofs …

Top-Down Nanomanufacturing Of Anisotropic Two-Dimensional Metals, Md Rubayat-E Tanjil

USF Tampa Graduate Theses and Dissertations

Two-dimensional (2D) materials have introduced a transformative era in materials science with extensive research being performed to gain a fundamental understanding of their diverse properties and applications. Amongst the broader 2D material family, 2D metals or 2D metallic nanosheets (2DMNSs) typically denotes the nanometer-scale thin elemental metals, compound, or alloys, which shows superlative chemical and physical properties compared to bulk counterparts due to the reduced dimensionality. 2D materials’ widespread direct physical or chemical isolation techniques have been facilitated due to their intrinsic van der Waals layered morphology, whereas 3D close-packed bulk metals with isotropic bonding hinder their facile isolation in …

Peak And Differential Temperature Determination Of Drilled Shafts, Amanda A. Lewis

USF Tampa Graduate Theses and Dissertations

The term “mass concrete” characterizes a specific concrete condition that typically requires unique considerations to mitigate extreme temperature effects on a structure. Mass concrete has historically been defined by the physical dimensions of a “mass”-ive concrete element with the intent of identifying when differential temperatures may induce early-onset cracking, leading to reduced service life. More recently, in addition to differential temperature considerations, extreme upper temperature limits have been imposed by the American Concrete Institute to prevent long-term concrete degradation. Studies dating back to 2007 show shafts as small as 48 inches in diameter can exceed both differential and peak temperature …

Restoration And Modification Of A Sputter Tool For The Deposition Of A Zno Guiding Layer Via Rf Sputtering, Matthew Watson

USF Tampa Graduate Theses and Dissertations

In this thesis, a novel sputter tool was restored and modified to deposit a ZnO film for future applications as a guiding layer on a surface acoustic wave (SAW) device. Some restorations and modifications included a water chiller being sized and added to the tool, leak checks to establish an ultra-high vacuum of 10-6 Torr, then finally heat lamps for temperature control were installed. Once modified, one of the preexisting magnetrons was utilized to deposit a ZnO via RF sputtering onto a quartz substrate. The layer was characterized via energy-dispersive X-ray spectroscopy which showed the existence of Zn on the …

The Influence Of Bipolar Electrochemical Cell Geometry On The Studies Of Pitting Corrosion, Amin Kazem Ghamsari

USF Tampa Graduate Theses and Dissertations

Bipolar electrochemistry (BPE) is a technique that provides a wireless alternative totraditional electrochemistry to elicit redox reactions. It has been utilized in different applications, including studying localized corrosion, gradient electrodeposition, propulsion of micromotors, and water treatment. The popularity of the method is not solely dependent on its wirelessness but more due to the simultaneous presence of cathodic and anodic poles on the same surface, which also begets its name as bipolar. The concept of the method is based on the polarization of conductive objects in an electric field in the presence of an electrolyte. In BPE, instead of controlling the …

Low-Pressure Plasma Surface Treatment Of Polycarbonate And Polyacrylic Plates With Different Plasmas And Their Characterization, Suleyman Gorkem Gizer

USF Tampa Graduate Theses and Dissertations

In this thesis, polycarbonate (PC) and acrylic (PMMA) surfaces were treated with carbon tetrafluoride (CF4), oxygen (O2), and air plasmas with a low-pressure plasma method in order to change their surface properties such as surface free energy and wettability. Moreover, different pattern sized, line, triangular and square shaped surface patterns were used to determine the shape and size-dependent changes. The characteristics of untreated and plasma treated surfaces were examined via contact angle (CA) measurements with distilled (DI) water, against plasma treatment number. Moreover, surface free energy (SFE) calculations of the PC and PMMA surfaces were carried out from sessile drop …

Plasma Treatment Of Polyethylene And Polydimethylsiloxane By Air, Oxygen, And Carbon Tetrafluoride And Their Characterization, Osman Polat

USF Tampa Graduate Theses and Dissertations

In this thesis, low density polyethylene (LDPE) and polydimethylsiloxane (silicone/PDMS) were treated with oxygen (O2) , air and carbon tetrafluoride (CF4) low pressure 13.56 MHz radiofrequency plasma. An experimental setup was used to determine process power and irradiation time for improved modification, the validation was done by measuring the contact angle of the treated samples immediately after treatment. The modification used commercially available sheets to imitate its use in the industry and various applications. The treatment aims to increase/decrease the surface free energy, making it possible to modify the intrinsic inert materials without affecting the bulk. Increased wettability, adhesion, and …

Development Of An Automated Platform For Sensing And Differentiating Vapor-Phase Btex Constituents, Jonathan Samuelson

USF Tampa Graduate Theses and Dissertations

Light aromatic hydrocarbons are an inevitable byproduct of fossil fuel extraction, refinement, distribution, and use. The four lightest and most prevalent of these are benzene, toluene, ethylbenzene, and xylene, which are known collectively as BTEX. In spite of their chemical similarity these species have markedly different effects on human health and substantially different concentrations are permitted by OSHA in workplaces and by the EPA in ambient air and groundwater. Real-time detection, identification, and quantification of these species is therefore of great importance wherever they see industrial use.This work represents the continuation and advancement of a line of research in which …

Magnetism In Doped And Hybrid Two – Dimensional Transition Metal Dichalcogenides, Nalaka Kapuruge

USF Tampa Graduate Theses and Dissertations

In recent years, spintronics has gained increasing interest due to the possibility of storing and processing information through the manipulation of both the charge and spin of an electron. Dilute magnetic semiconductors are ideal for the fabrication of such devices as they display carrier-mediated ferromagnetism which allows the electronic control of magnetism. Transferring these properties into the two-dimensional (2D) realm is very attractive for both fundamental research and novel applications. The recent discovery of long-range magnetic order in 2D materials has attracted a growing effort in the search for new functional 2D materials that can display ferromagnetic properties at room-temperature. …

Large Area Projection Sintering Of Semicrystalline Polymers And Part Analysis Of The Printed Specimens, Taranjot Kaur

USF Tampa Graduate Theses and Dissertations

As the requirements posed to products have increased in recent years. The trend towards individualized serial products steps up the need for respective manufacturing techniques to be more and more flexible. Conventional techniques of serial production, such as injection molding, are unable to fully meet the requirements of this trend. Additive manufacturing techniques generate components directly from a CAD data set while requiring no specific mold, producing minimal waste, and reaching satisfactory geometric accuracy. This is how, as opposed to conventional techniques, they comply with these increased demands to processing technology. Over the last two decades, the research community has …

Improved Performance Of Silica-Supported La0.5Ba0.5Feo3 In The Reverse Water Gas Shift - Chemical Looping Process For Carbon Dioxide Reduction – A Density Functional Theory Study, Jiawei Guo

USF Tampa Graduate Theses and Dissertations

Global warming is increasingly obvious, and the reduction of greenhouse gases is an effective way to heal. Increasing the efficiency of catalysts that is applied in the industry can significantly reduce the emission of greenhouse gases. Reverse water gas shift chemical looping (RWGS-CL) is a promising reaction to convert CO2 to CO. La0.5Ba0.5FeO3 (LBF) is a good candidate for RWGS-CL, which shows increased conversion yield when supported on silica. This research focuses on identifying the mechanism of RWGS-CL via silica-supported LBF by exploring the oxygen vacancy formation energy (EO-vac). Density Functional Theory (DFT) is a powerful computational method to solve …

Impedance Analysis Of Anodized Aluminum And Structural Bridge Tendons, Justin Silnutzer

USF Tampa Graduate Theses and Dissertations

This is a two-part thesis with the overall investigation technique being electrochemical impedance spectroscopy (EIS). In the first part, EIS is used to estimate the layer thickness of anodized aluminum oxide. This required the development of an appropriate electrical circuit model; that with parameters that correspond to physical properties of the oxide. In this work, it was found that for thicker oxides of which the outer porous layer is greater than 12 microns, impedance may be used to estimate the outer layer thickness. However, further research is required to understand the role of outer porous layer structure on the impedance …

Magnetic And Structural Effects In Interfacial Magnetism: Molecular Magnets And Ferrimagnetic Alloys, Jenae E. Shoup

USF Tampa Graduate Theses and Dissertations

Magnetic thin films are important for technological applications such as giant magnetoresistance,spin valves and magnetic tunnel junctions. A key feature for these applications to be possible is the interface between two materials. We will be studying two types of thin film magnetism; interfaces between molecular carbon, C60, and non-magnetic/ferromagnetic material and two layers of ferrimagnetic rare earth/ transition metal alloys (RE/TM) that have similar composition to engineer a magnetic tunable interface.

One of the most unexpected spin-related properties of C60 is the emergence of room-temperature ferromagnetism in multilayer films of C60 and non-ferromagnetic transition metals such as Cu or Mn …

Block Copolymer Directed Self-Assembly: Exploring The Efficacy Of Applications In Semiconductor Fabrication, Jakin Bryce Delony

USF Tampa Graduate Theses and Dissertations

Over the course of the past 80 years, semiconductor devices have become increasingly ubiquitous in everyday life.From constructing mainframes that encompassed entire rooms during the 1940s, to inventing personal computers in the 1980s, to developing progressively faster smartphones and wearable technology in the 2010s, the primary driving force behind the Digital Revolution has been increasing transistor counts, and thus computing power, via incremental improvements in optical lithography. In 1965, Intel co-founder Gordon Moore boldly predicted that the transistor density of semiconductor devices would double approximately every 18-24 months. While this prediction -- now colloquially referred to as Moore's Law -- …

Soft Magnetic Composite Substrates For Rf/Microwave Applications, Poonam Lathiya

USF Tampa Graduate Theses and Dissertations

Novel soft magnetic ferrite materials will play a crucial role in next-generation over one trillion sensors (also known as “trillion sensor economy) related to 5G communications and internet of things, as these materials can achieve improved wireless power and signal transfer efficiency with high operation frequency. In this work, Ni-Cu-Zn and Ni-Co-Zn ferrites with high permeability, high permittivity, and low magnetic and dielectric losses were prepared for RF and microwave device applications. Frequency dispersion of RF complex permeability of Ni-Cu-Zn ferrites prepared under different applied hydraulic pressures and durations have been thoroughly investigated. The Ni0.35Cu0.19Zn0.46Fe2O4 ferrites were prepared by conventional …

Crystal Structure Prediction Of Materials At Extreme Conditions, Ashley S. Williams

USF Tampa Graduate Theses and Dissertations

The prediction of the structure of a crystal given only the constituent elements is one of the greatest challenges in both materials science and computational science alike. If one were to try to predict a novel crystal by brute force, meaning by arranging the atoms in every possible position of the unit cell and optimizing the geometry to find the energy minima of the potential energy surface, the amount of computer resources required to complete the calculation on the timescale of a few years would vastly exceed the currently installed computational capacity of the entire world. Fortunately, several methods have …

The Photophysical Studies Of Transition Metal Polyimines Encapsulated In Metal Organic Frameworks (Mof’S), Jacob M. Mayers

USF Tampa Graduate Theses and Dissertations

Light harvesting systems provide a platform that converts solar energy into other forms of energy. One of the most common examples of photon capturing and conversion into chemical energy is observed in photosynthetic organisms in both Eurkaroyic and Prokaryotic domains. Nature provides a model for successful light harvesting platforms which includes the compartmentalization of antenna complexes that contain separated donor and acceptor pairs that participate in efficient electron transfer processes. In order to mimic such systems, crystalline porous materials that exhibits regular cavities and pore dimensions provides an excellent starting place. Metal organic frameworks (MOFs) are a class of porous …