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2012

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Articles 1 - 30 of 472

Full-Text Articles in Materials Science and Engineering

Advances And Challenges Of Intermediate Temperature Solid Oxide Fuel Cells: A Concise Review, Sanping Jiang Dec 2012

Advances And Challenges Of Intermediate Temperature Solid Oxide Fuel Cells: A Concise Review, Sanping Jiang

Journal of Electrochemistry

Fuel cell is an electrochemical energy conversion device to directly convert the chemical energy of fuels to electricity. Among all types of fuel cells, solid oxide fuel cells (SOFCs) operating at intermediate temperatures of 600~800 oC offer an attractive option that is much more fuel flexible than low temperature fuel cells such as proton exchange membrane fuel cells, and is suitable for a wide range of applications. However, two main challenges remain towards the commercial viability and acceptance of the SOFC technologies: the cost and durability. Both are critically dependent on the process, fabrication, performance, chemical and microstructural stability …

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Ternary Alloy Electrocatalysts For Oxygen Reduction Reaction, Jin Luo, Lefu Yang, Binghui Chen, Chuanjian Zhong Dec 2012

Ternary Alloy Electrocatalysts For Oxygen Reduction Reaction, Jin Luo, Lefu Yang, Binghui Chen, Chuanjian Zhong

Journal of Electrochemistry

Proton exchange membrane fuel cell represents an important electrochemical energy conversion device with many attractive features in terms of efficiency of energy conversion and minimization of environmental pollution. However, the large overpotential for oxygen reduction reaction at the cathode and the low activity, poor durability and high cost of platinum-based catalysts in the fuel cells constitute a focal point of major barriers to the commercialization of fuel cells. The development of nanostructured catalysts shows promises to addresses some of the challenging problems. The ability to engineer the composition and nanostructure of nanoalloy catalysts is important for developing active, robust and …

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Electrocatalytic Activity Of Palladium Nanocatalysts Supported On Carbon Nanoparticles In Formic Acid Oxidation, Jie Huang, Zhiyou Zhou, Yang Song, Xiongwu Kang, Ke Liu, Wancheng Zhou, Shaowei Chen Dec 2012

Electrocatalytic Activity Of Palladium Nanocatalysts Supported On Carbon Nanoparticles In Formic Acid Oxidation, Jie Huang, Zhiyou Zhou, Yang Song, Xiongwu Kang, Ke Liu, Wancheng Zhou, Shaowei Chen

Journal of Electrochemistry

Palladium nanostructures were deposited onto carbon nanoparticle surface by a chemical reduction method. Transmission electron microscopic studies showed that whereas the resulting metal-carbon (Pd-CNP) nanocomposites exhibited a diameter of 20 to 30 nm, the metal components actually showed a cauliflower-like surface morphology that consisted of numerous smaller Pd nanoparticles (3 to 8 nm). Electrochemical studies showed that the effective surface area of the Pd-CNP nanoparticles was about 40% less than that of Pd black, possibly because the Pd nanoparticles were coated with a layer of carbon nanoparticles; yet, the Pd-CNP nanocomposites exhibited marked enhancement of the electrocatalytic activity in formic …

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Electrocatalytic Oxidation Of Formic Acid On Pd/Ni Heterostructured Catalyst, Mingjun Ren, Liangliang Zou, Ju Chen, Ting Yuan, Qinghong Huang, Haifeng Zhang, Hui Yang, Songlin Feng Dec 2012

Electrocatalytic Oxidation Of Formic Acid On Pd/Ni Heterostructured Catalyst, Mingjun Ren, Liangliang Zou, Ju Chen, Ting Yuan, Qinghong Huang, Haifeng Zhang, Hui Yang, Songlin Feng

Journal of Electrochemistry

A Pd/Ni bimetallic nanostructured electrocatalyst was fabricated via a two-step reduction route. Owing to an epitaxial growth of Pd atoms on the surface of Ni nanoparticles, heterostructured Pd/Ni nanocomposites were formed and verified by high resolution transmission electron microscopy combined with energy-dispersion X-ray spectroscopy. X-ray diffraction confirmed that the as-prepared Pd/Ni nanocomposites possessed a single face-centered-cubic (fcc) Pd structure, probably due to a weaker diffraction intensity of metallic Ni and/or overlapping by that of Pd. The intrinsic catalytic activity on the Pd/Ni is higher than that on the Pd. Moreover, the durability of formic acid oxidation on the Pd/Ni was …

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Adsorption And Electrooxidation Of Carbon Monoxide On Platinum Surfaces Modified With Sulfur, A. Mattox Mathew, W. Henney Matthew, Johnson Adam, Zou Shouzhong Dec 2012

Adsorption And Electrooxidation Of Carbon Monoxide On Platinum Surfaces Modified With Sulfur, A. Mattox Mathew, W. Henney Matthew, Johnson Adam, Zou Shouzhong

Journal of Electrochemistry

Adsorbed sulfur is commonly considered as a reaction poison. However, small amounts of sulfur on platinum significantly increase the surface reactivity toward carbon monoxide (CO) electrooxidation. For the solution CO oxidation, the onset potential was shifted up to over 300 mV negative to that on S-free surface, and the extent of the negative potential shift increases with the sulfur coverage (Xs) up to about 0.6. The enhanced CO oxidation also depends on the solution pH. For the adsorbed CO, at low sulfur coverages (Xs < 0.3), the oxidation peak potential is about 40 mV negative to that of the corresponding clean Pt. However, at higher coverages, the peak potential is about 30 mV more positive. Surface-enhanced Raman spectra show that the adsorption of sulfur significantly redshifts the Pt-CO stretching frequency. These observations are explained by the weakening of the Pt-CO bond and the hindrance of CO diffusion by Sads.

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Kinetic Study Of Photoelectrochemical Oxidation Of Lignin Model Compounds On Tio2 Nanotubes, Min Tian, Daniel Liba, Aicheng Chen Dec 2012

Kinetic Study Of Photoelectrochemical Oxidation Of Lignin Model Compounds On Tio2 Nanotubes, Min Tian, Daniel Liba, Aicheng Chen

Journal of Electrochemistry

In this study, TiO2 nanotubes were prepared via the electrochemical oxidation of titanium substrates in a non-aqueous electrolyte and their morphology and microstructures were examined by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The photoelectrochemical oxidation of two lignin model compounds, 1-(3,4-dimethoxyphenoxy)-2-(2-methoxyphenoxy)-1,3-propanediol (DMP) and 3-hydroxy-1-(3,4-dimethoxyphenoxy)-2-(2-methoxyphenoxy)-1,3-propanone (HDM), was investigated. A new band appeared at ~304 nm during the photoelectrochemical oxidation of DMP. The rate of DMP intermediate formation was amplified with the increase of initial concentrations, while it was diminished with increased temperature. Despite the similarity in structure between HDM and DMP, there are only small increases in absorbance …

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Electrochemical Performance Of Screen-Printed Composite Coatings Of Conducting Polymers And Carbon Nanotubes On Titanium Bipolar Plates In Aqueous Asymmetrical Supercapacitors, Xiaohang Zhou, George Z. Chen Dec 2012

Electrochemical Performance Of Screen-Printed Composite Coatings Of Conducting Polymers And Carbon Nanotubes On Titanium Bipolar Plates In Aqueous Asymmetrical Supercapacitors, Xiaohang Zhou, George Z. Chen

Journal of Electrochemistry

Composites of conducting polymers (polypyrrole and polyaniline) with acid treated multi-walled carbon nanotubes were formulated into printable aqueous inks, with the aid of functional additives (benzethonium chloride as a surfactant with or without polyvinyl alcohol as a binder). The inks were screen-printed as fairly uniform coatings of various mass loading densities and areas (up to 75 mg cm-2 and 100 cm2) on thin titanium plates (0.1 mm in thickness). These screen-printed plates were used to fabricate both unit cell and multi-cell stack of asymmetrical supercapacitors with screen-printed negative electrodes of activated carbon (pigment black) in aqueous electrolytes …

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Grain Size And Texture Effects On Deformation Behavior Of Az31 Magnesium Alloy, W. Yuan, R. S. Mishra Dec 2012

Grain Size And Texture Effects On Deformation Behavior Of Az31 Magnesium Alloy, W. Yuan, R. S. Mishra

Materials Science and Engineering Faculty Research & Creative Works

Cold rolled AZ31 magnesium alloy sheet was subjected to friction stir processing to generate four average grain sizes ranging from 0.8 to 9.6 μm. the processed material exhibited a strong basal fiber texture with the c-axis tilted about 35-55° towards the processing direction. the grain size and texture dependence of mechanical behavior were evaluated by using tensile testing along two orthogonal directions. Remarkably high ductility of ~65% was achieved in relatively coarse-grained material that fractured without developing necking when tested in the processing direction. the ductility decreased significantly to ~10% for ultrafine grained material as the tensile yield strength increased …

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High Performance Low Temperature Solid Oxide Fuel Cells With Novel Electrode Architecture, Yu Chen, Qian Liu, Zhibin Yang, Fanglin Chen, Minfang Han Dec 2012

High Performance Low Temperature Solid Oxide Fuel Cells With Novel Electrode Architecture, Yu Chen, Qian Liu, Zhibin Yang, Fanglin Chen, Minfang Han

Faculty Publications

In this study, we have fabricated high performance low temperature solid oxide fuel cells (LT-SOFCs) with both acicular anodes and cathodes with thin Gd-doped ceria (GDC) electrolyte film. The acicular Ni-Gd0.1Ce0.9O2−δ (Ni-GDC) anode was prepared using freeze drying tape casting, while the hierarchically porous cathode with nano-size Sm0.5Sr0.5CoO3 (SSC) particles covering an acicular GDC skeleton was prepared by a combination of freeze drying tape casting and self-rising approaches. The acicular electrodes with 5–200 μm pores/channels enhance mass transport, while SSC particles of about 50 nm in the cathode promote …

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Effects Of Crossflow Velocity And Transmembrane Pressure On Microfiltration Of Oil-In-Water Emulsions, Nikolai V. Priezjev, Tohid Darvishzadeh Dec 2012

Effects Of Crossflow Velocity And Transmembrane Pressure On Microfiltration Of Oil-In-Water Emulsions, Nikolai V. Priezjev, Tohid Darvishzadeh

Mechanical and Materials Engineering Faculty Publications

This study addresses the issue of oil removal from water using hydrophilic porous membranes. The effective separation of oil-in-water dispersions involves high flux of water through the membrane and, at the same time, high rejection rate of the oil phase. The effects of transmembrane pressure and crossflow velocity on rejection of oil droplets and thin oil films by pores of different cross-section are investigated numerically by solving the Navier-Stokes equation. We found that in the absence of crossflow, the critical transmembrane pressure, which is required for the oil droplet entry into a circular pore of a given surface hydrophilicity, agrees …

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Recovery Of Metallic Materials From Printed Wiring Boards By Green Pyrolysis Process, Alex Luyima, Lifeng Zhang, Jaan Kers, Viktor Laurmaa Dec 2012

Recovery Of Metallic Materials From Printed Wiring Boards By Green Pyrolysis Process, Alex Luyima, Lifeng Zhang, Jaan Kers, Viktor Laurmaa

Materials Science and Engineering Faculty Research & Creative Works

Currently, the main options for the treatment of electronic waste are involved in reuse, remanufacturing, and recycling, as well as incineration and land filling. Recycling of e-waste can be broadly divided into three major steps: (a) disassembly: selectively disassembly, targeting on singling out hazardous or valuable components for special treatment, is an indispensable process in recycling of e-waste; (b) upgrading: using mechanical processing and/or metallurgical processing to up-grade desirable materials content, i. e. preparing materials for refining process; (c) refining: in the last step, recovered materials are retreated or purified by using chemical (metallurgical) processing so as to be acceptable …

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Analysis Of Solid Oxide Fuel Cell-Gas-Turbine Hybrid System Technology For Use In Aircraft, Jeremy Milliner, Rory Roberts Dec 2012

Analysis Of Solid Oxide Fuel Cell-Gas-Turbine Hybrid System Technology For Use In Aircraft, Jeremy Milliner, Rory Roberts

Explorations – The Journal of Undergraduate Research, Scholarship and Creativity at Wright State

Solid oxide fuel-cell-gas-turbine (SOFC/GT) hybrid systems are a technology that provides a more efficient source of energy for a variety of uses. One potential use is to provide more efficient energy to aircraft, which is the subject of this work. Potential applications to aircraft and results from a computer model of a SOFC/GT are presented here.

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Quantum Dot Deposition Into Pdms And Application Onto A Solar Cell, Christopher Marcus Botros, Richard N. Savage Dec 2012

Quantum Dot Deposition Into Pdms And Application Onto A Solar Cell, Christopher Marcus Botros, Richard N. Savage

Master's Theses

Research to increase the efficiency of conventional solar cells is constantly underway. The goal of this work is to increase the efficiency of conventional solar cells by incorporating quantum dot (QD) nanoparticles in the absorption mechanism. The strategy is to have the QDs absorb UV and fluoresce photons in the visible region that are more readily absorbed by the cells. The outcome is that the cells have more visible photons to absorb and have increased power output. The QDs, having a CdSe core and a ZnS shell, were applied to the solar cells as follows. First, the QDs were synthesized …

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Role Of Aluminum Monostearate On Heat Treated-Chitosan Sponges Properties, K. Yodkhum, T. Phaechamud Dec 2012

Role Of Aluminum Monostearate On Heat Treated-Chitosan Sponges Properties, K. Yodkhum, T. Phaechamud

Journal of Metals, Materials and Minerals

Heat treatment can be employed to modify properties such as biocompatibility and degradation rate of chitosan-based materials. However, heat treatment generally has effect on worsening of physical properties of the biomaterials. Our previous study indicated that fatty additive; aluminum monostearate (Alst), could improve thermal stability of chitosan sponges. Aim of this study is to investigate an effect of amount of Alst on physicochemical properties of chitosan sponges treated by different heat treatment methods. Two methods of heat treatment including moist heat (autoclave at 121°C, 15 psi for 5 minutes) and dry heat (vacuum heat at 110°C for 24 hours) were …

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An Experimental Investigation On The Trailing Edge Cooling Of Turbine Blades, Zifeng Yang, Hui Hu Dec 2012

An Experimental Investigation On The Trailing Edge Cooling Of Turbine Blades, Zifeng Yang, Hui Hu

Mechanical and Materials Engineering Faculty Publications

An experimental study was conducted to quantify the flow characteristics of the wall jets pertinent to trailing edge cooling of turbine blades. A high-resolution stereoscopic particle image velocimetry (PIV) system was used to conduct detailed flow field measurements to quantitatively visualize the evolution of the unsteady vortices and turbulent flow structures in the cooling wall jet streams and to quantify the dynamic mixing process between the cooling jet stream and the mainstream flows. The detailed flow field measurements were correlated with the adiabatic cooling effectiveness maps measured by using pressure sensitive paint (PSP) technique to elucidate underlying physics in order …

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Silica Nanoparticle-Based Coatings With Superhydrophilic And Superhydrophobic Properties, Robert Andrew Fleming Dec 2012

Silica Nanoparticle-Based Coatings With Superhydrophilic And Superhydrophobic Properties, Robert Andrew Fleming

Graduate Theses and Dissertations

Superhydrophilic and superhydrophobic surfaces have potential for implementation into a variety of fields, including self-cleaning surfaces, anti-fogging transparent materials, and biomedical applications. In this study, sandblasting, oxygen plasma treatments, silica nanoparticle films, and a low surface energy fluorocarbon film were employed to change the natural surface wettability of titanium, glass, and polyethylene terephthalate (PET) substrates, with an aim to produce superhydrophilic and superhydrophobic behavior. The effects of these surface modifications are characterized by water contact angles (WCAs), surface wetting stability, surface morphology and roughness, surface elemental composition, and optical transmittance measurements. The results show that stable superhydrophilic and superhydrophobic surfaces …

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Design, Fabrication, Testing Of Cnt Based Isfet And Characterization Of Nano/Bio Materials Using Afm, Zhuxin Dong Dec 2012

Design, Fabrication, Testing Of Cnt Based Isfet And Characterization Of Nano/Bio Materials Using Afm, Zhuxin Dong

Graduate Theses and Dissertations

A combination of Carbon Nanotubes (CNTs) and Ion Selective Field Effect Transistor (ISFET) is designed and experimentally verified in order to develop the next generation ion concentration sensing system. Micro Electro-Mechanical System (MEMS) fabrication techniques, such as photolithography, diffusion, evaporation, lift-off, packaging, etc., are required in the fabrication of the CNT-ISFET structure on p-type silicon wafers. In addition, Atomic Force Microscopy (AFM) based surface nanomachining is investigated and used for creating nanochannels on silicon surfaces. Since AFM based nanomanipulation and nanomachining is highly controllable, nanochannels are precisely scratched in the area between the source and drain of the FET where …

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Investigation On Thermo-Mechanical Instability Of Porous Low Dielectric Constant Materials, Emil Hyunbae Zin Dec 2012

Investigation On Thermo-Mechanical Instability Of Porous Low Dielectric Constant Materials, Emil Hyunbae Zin

Material Science and Engineering Dissertations - Archive

This study investigates the structural stability of porous low dielectric constant materials (PLK) under thermal and mechanical load and the influence of contributing factors including porosity as intrinsic factor and plasma damage and moisture absorption as extrinsic factors on thermo-mechanical instability of PLK in advanced Cu/PLK interconnects. For this purpose, a ball indentation creep test technique was developed to examine the thermal and mechanical instability of PLK at relevant load and temperature conditions in the interconnect structure. Our exploration with the ball indentation creep test found that PLK films plastically deforms with time, indicating that viscoplastic deformation does occur under …

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First-Principles Studies On N-Type And P-Type Doping In Cuprous Oxide, Qiong Bai Dec 2012

First-Principles Studies On N-Type And P-Type Doping In Cuprous Oxide, Qiong Bai

Material Science and Engineering Dissertations - Archive

We have performed studies on n-type and p-type cuprous oxide with and without doping by first principles methods. Generalized Gradient Approximation (GGA) is used for the geometry optimization. The total energy and the final electronic structure calculations are conducted using the nonlocal screened Heyd-Scuseria-Ernzerhof (HSE) hybrid density functionals approach for cuprous oxide. The HSE hybrid density functionals overcome the shortcoming of GGA, which gives a much reliable value of the band gap. The formation energies of native point defects in undoped cuprous oxide have been studied by HSE hybrid functional theory in two conditions, which are vacuum based condition and …

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Properties Of Concrete With Tire Derived Aggregate And Crumb Rubber As A Ligthweight Substitute For Mineral Aggregates In The Concrete Mix, Gideon Momanyi Siringi Dec 2012

Properties Of Concrete With Tire Derived Aggregate And Crumb Rubber As A Ligthweight Substitute For Mineral Aggregates In The Concrete Mix, Gideon Momanyi Siringi

Material Science and Engineering Dissertations - Archive

Scrap tires continue to be a nuisance to the environment and this research proposes one way of recycling them as a lightweight aggregate which can substitute for mineral aggregates in concrete. Aggregates derived from scrap tires are often referred to as Tire Derived Aggregate (TDA). First, the focus is how much mineral aggregate can be replaced by these waste tires and how the properties of concrete are affected with the introduction of rubber. This is being mindful of the fact that for a new material to be acceptable as an engineering material, its properties and behavior has to be well …

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Growth Mechanism And Interface Effects On Microstructure Of Perovskite-Type Barium Titanate-Based Epitaxial Films, Jie He Dec 2012

Growth Mechanism And Interface Effects On Microstructure Of Perovskite-Type Barium Titanate-Based Epitaxial Films, Jie He

Material Science and Engineering Dissertations - Archive

This work was motivated and focused on the growth mechanism, microstructures and interfaces of barium titanate, BaTiO3 (BTO), based epitaxial thin films. Transimission electron microscopy (TEM), high resolution TEM (HRTEM), electron diffraction (ED) have been mainly employed in this study for microstructure investigations of BTO-based epitaxial thin films with the assistance of other materials characterization methods, such as X-ray diffraction (XRD), atomic force microscopy (AFM), Nanoindentation testing, etc. As a basic studying model, epitaxial BTO films were first deposited on the (001) MgO substrate using RF magnetron sputtering to provide fundamental knowledge of the film growth for BTO based thin …

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Syntheses, Characterization, And Applications Of Injectable Citrate-Based Mussel-Inspired Biodegradable Adhesive (Icmba) Polymers And Hydrogels, Mohammadreza Mehdizadeh Dec 2012

Syntheses, Characterization, And Applications Of Injectable Citrate-Based Mussel-Inspired Biodegradable Adhesive (Icmba) Polymers And Hydrogels, Mohammadreza Mehdizadeh

Material Science and Engineering Dissertations - Archive

Tissue adhesives are increasingly gaining more popularity in various areas of biomedical applications. They are utilized as surgical adhesives, as a replacement or adjunct to conventional wound closure and bleeding control techniques such as suturing, as well as in other applications such as tissue engineering and drug delivery.Unfortunately, the existing surgical adhesives are not ideal for wet tissue adhesion required in many surgeries such as those for internal organs. Developing surgical adhesives with strong wet tissue adhesion, controlled degradability and mechanical properties, and excellent biocompatibility has been a significant challenge. Herein, learning from nature, we report a one-step synthesis of …

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Prediction Of Compressive Creep Bhaviour In Flexible Polyurethane Foam Over Long Time Scales And At Elevated Temperatures, Conor Briody, Barry Duignan, Stephen Jerrams, Stephen Ronan Dec 2012

Prediction Of Compressive Creep Bhaviour In Flexible Polyurethane Foam Over Long Time Scales And At Elevated Temperatures, Conor Briody, Barry Duignan, Stephen Jerrams, Stephen Ronan

Articles

Compressive creep gradually affects the structural performance of flexible polymeric foam material over extended time periods. When designing components, it is often difficult to account for long-term creep, as accurate creep data over long time periods or at high temperatures is often unavailable. This is mainly due to the lengthy testing times and/or inadequate high temperature testing facilities. This issue can be resolved by conducting a range of short-term creep tests and applying accurate prediction methods to the results. Short-term creep testing was conducted on viscoelastic polyurethane foam, a material commonly used in seating and bedding systems. Tests were conducted …

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Influence Of Casting Techniques On Hardness, Tarnish Behavior And Microstructure Of Ag-Cu-Zn-Si Sterling Silver Jewelry Alloys, C. Chanmuang, W. Kongmuang, J.T.H. Pearce, T. Chairuangsri Dec 2012

Influence Of Casting Techniques On Hardness, Tarnish Behavior And Microstructure Of Ag-Cu-Zn-Si Sterling Silver Jewelry Alloys, C. Chanmuang, W. Kongmuang, J.T.H. Pearce, T. Chairuangsri

Journal of Metals, Materials and Minerals

The effects of Zn and Si on the hardness, tarnish resistance and microstructures of experimental Ag-Cu-Zn-Si alloy were investigated by means of vickers hardness, tarnish testing, optical and scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). The various compositions of 935 sterling silver alloys produced by different casting techniques, investment (lost wax) process and metal mould casting, were compared. An induction casting machine with a vacuum system was used for investment casting at 1,025C with the mould temperature at 600C whereas a LPG/oxygen single flame tip torch was used for the metal mould process. Vickers hardness of the samples …

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Bismuth Vanadate (Bivo4) Powder Prepared By The Sol-Gel Method, P. Pookmanee, S. Kojinok, S. Phanichphant Dec 2012

Bismuth Vanadate (Bivo4) Powder Prepared By The Sol-Gel Method, P. Pookmanee, S. Kojinok, S. Phanichphant

Journal of Metals, Materials and Minerals

Bismuth vanadate (BiVO4) powder was prepared by the sol-gel method. Bismuth nitrate and ammonium vanadate were used as the starting precursors with mole ratio of 1:1 in ethanol at 70C for 1 hour. The obtained sol was changed to the yellow gel after addition of deionized water and acetic acid. The yellow gel was dried at 100C for 48 h and calcined at 400-600C for 2 hours. The phase of BiVO4 powder was studied by X-ray diffraction (XRD). The morphology of BiVO4 powder was investigated by scanning electron microscopy (SEM). The element composition of BiVO4 powder was indicated by energy …

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Preparation And Characterization Of Highly Filled Graphite-Based Polybenzoxazine Composites, A. Pengdam, S. Rimdusit Dec 2012

Preparation And Characterization Of Highly Filled Graphite-Based Polybenzoxazine Composites, A. Pengdam, S. Rimdusit

Journal of Metals, Materials and Minerals

This research aims to study suitable preparation methods and to characterize highly filled graphite composites using polybenzoxazine as a matrix. The high loading of graphite filler was attained in the range of 40 to 80% by wt. due to the very low a-stage viscosity of the benzoxazine resin (BA-a) used. The suitable condition for the compression molding of the highly filled graphite-polybenzoxazine (PBA-a) composites was at temperature of 200°C, and pressure of 15 MPa in the hydraulic hot-press machine for 3 hours to assure a fully cured specimen. The densities of the obtained composites were found to be in a …

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Study Of Dynamic Vulcanized Pla/Enr Tpv Filled With Various Organic Modified Mmt (Ommt), C. Thongpin, N. Kuttanate, K. Kampuang, N. Suwanwanit Dec 2012

Study Of Dynamic Vulcanized Pla/Enr Tpv Filled With Various Organic Modified Mmt (Ommt), C. Thongpin, N. Kuttanate, K. Kampuang, N. Suwanwanit

Journal of Metals, Materials and Minerals

In this research, we investigated the crystallization behavior of PLA and properties of PLA/ENR thermoplastic vulcanizates (TPVs). ENR was compounded with phenolic resin and with PLA at the blend ratio of 40/60 by using an internal mixer at 170°C and rotor speed of 70 rpm. Three types of organic modified montmorillonite (OMMT) which are Cloisite® 15A, Cloisite® 20 A and Cloisite® 30B were also added at various contents during mixing. The TPVs were pressed to form thin film in a compression molding machine and cooled down under pressure for 10 minutes. Crystallization behavior, thermal properties and morphology of TPVs were …

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Dynamic And Static Effects In Wetting Of Capillaries And Fibers, Taras Andrukh Dec 2012

Dynamic And Static Effects In Wetting Of Capillaries And Fibers, Taras Andrukh

All Dissertations

This research is centered on the analysis of static and dynamic effects of wetting of single capillaries and fibers. We discuss specifics of the capillary rise and drop-on-fiber techniques and develop new methods of characterization of surface energy of single fibers when its contact angle varies between zero and ninety degrees. The contact angles were evaluated and compared for different substrates. We study the dynamics of the meniscus formation inside and outside of capillaries and fibers. We develop a mathematical model of liquid uptake by capillaries and analyze the factors affecting liquid uptake. The derived fundamental equation describes the dynamics …

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Double Paddle Oscillators For The Mechanical Spectroscopy Of Ion-Solid Interactions, Jason Puls Dec 2012

Double Paddle Oscillators For The Mechanical Spectroscopy Of Ion-Solid Interactions, Jason Puls

All Theses

We demonstrated using a double paddle oscillator to measure subsurface defect formation at room temperatures caused by ion implantation. This sensor has a low amount of noise based because of its high quality factors in certain modes. The double paddle oscillator was bombarded with Ar ions under ultra-high vacuum conditions while it was oscillating. The resultant resonant frequency changes were discussed as a method to determine defect formation inside the bulk substrate.

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Implementation And Validation Of Fault-Rupture Response Spectrum Analysis Procedure In Csibridge For Bridges Crossing Earthquake Fault Ruptures, Jennifer Evelyn Tures Dec 2012

Implementation And Validation Of Fault-Rupture Response Spectrum Analysis Procedure In Csibridge For Bridges Crossing Earthquake Fault Ruptures, Jennifer Evelyn Tures

Master's Theses

This thesis evaluates the application of a simplified analysis procedure as implemented in version 16 of CSiBridgeTM for design of bridges crossing earthquake fault ruptures. The fault-rupture response spectrum analysis (FR-RSA) approximation method has been proved adequate for both straight and curved ordinary bridges, but lacked a comfortable interface to accommodate the method users. Computers and Structure, Inc. has implemented the FR-RSA procedure into CSiBridgeTM, a user-friendly integrated 3-D bridge design software, as an added seismic design feature. By combining the response of the bridge due to the quasi-static displacement from the fault strike-slip rupture and the …

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