Materials Science and Engineering Commons^™

Inhibited Surface Diffusion In Nanoporous Multi-Principal Element Alloy Thin Films Prepared By Vacuum Thermal Dealloying, Tibra Das Gupta, Thomas John Balk

Chemical and Materials Engineering Faculty Publications

Nanoporous structures with 3D interconnected networks are traditionally made by dealloy- ing a binary precursor. Certain approaches for fabricating these materials have been applied to refrac- tory multi-principal element alloys (RMPEAs), which can be suitable candidates for high-temperature applications. In this study, nanoporous refractory multi-principal element alloys (np-RMPEAs) were fabricated from magnesium-based thin films (VMoNbTaMg) that had been prepared by magnetron sputtering. Vacuum thermal dealloying (VTD), which involves sublimation of a higher vapor pres- sure element, is a novel technique for synthesizing nanoporous refractory elements that are prone to oxidation. When VMoNbTaMg was heated under vacuum, a nanoporous structure was …

The Roles Of Carbonaceous Wastes For Catalysis, Energy, And Environmental Remediation, Chi Huey Ng, Mohd Aizzan Mistoh, Siow Hwa Teo, Andrea Galassi, Hin Taufiq-Yap, Nancy Julius Siambun, Jurry Foo, Coswald Stephen Sipaut, Jeffrey Seay, Jidon Janaun

Chemical and Materials Engineering Faculty Publications

This article reviews recent studies about various generations of the carbon materials for their applications in energy and environmental remediation. The synthesis routes of the carbon materials including the condition parameters, interaction of precursors, dopants and carbon materials, as well as their physical/chemical properties are explicated first. Then, the application and mechanism of metal-free/metal-doped/non-metal-doped carbon materials are discussed in detail. Lastly, this review is ended with a summary and invigorating perspectives on the challenges and future directions at the forefront of the catalysis platform to take a step further for real application.

Investigating The Structure And Performance Of Electrodes Made By Dry And Wet Slurry Processes, Kubra Uzun, Bhamiti Sharma, Bradley R. Frieberg, Ming Wang, Jiazhi Hu, Anita Li, Xiaosong Huang, Yang-Tse Cheng

Chemical and Materials Engineering Faculty Publications

Performance, cost, and safety are vital factors in producing and handling lithium-ion batteries. Using a dry process reduces the cost and environmental impact of producing large-scale lithium-ion battery electrodes significantly as solvents are eliminated. Thus, in this study, solvent-free dry electrostatic spray deposition (ESD) and conventional slurry processes were compared to uncover the influence of the manufacturing process on thick LiNi 0.8Mn0.1Co 0.1O 2 (NMC 811) positive electrodes. More pressure during calendering was found necessary for the dry-made (dry) electrodes to have the same porosity, leading to more cracks within the NMC particles and better adhesion. At slower discharge rates, …

Automating Selective Area Electron Diffraction Phase Identification Using Machine Learning, Nathaniel Tomczak, Jennifer Carter

Faculty Scholarship

Selective area electron diffraction (SAED) patterns can provide valuable insight into the structure of a material. However, the manual identification of collected patterns can be a significant bottleneck in the overall phase classification workflow. In this work, we utilize the recent advances in computer vision and machine learning (ML) to automate the indexing of SAED patterns. The performance of six different ML algorithms is demonstrated using metallic plutonium-zirconium alloys. The most successful approach trained a neural network (NN) to make a classification of the phase and zone axis, and then utilized a second NN to synthesize multiple independent predictions of …

Nanoparticles For Applications In Specific Diagnostics And Precision Medicine, Naxhije Berisha

Dissertations, Theses, and Capstone Projects

Heterogeneity is common in the expression of cancer and treatment response. Precision medicine enables healthcare providers to tailor medical care to an individual's distinct genetic and environmental makeup. This customization has the potential to result in more efficient treatments while minimizing side effects. We believe that by studying the interface of nanotechnology and cancer medicine we can elucidate innovative solutions that address the challenges of disease heterogeneity. This includes advancements in drug delivery, formulations development, and diagnostic sensing. We highlight three studies that use nanotechnology for applications in precision medicine. In Chapter 2, we highlight design optimization of drug formulations …

Rational Design Of Peptide-Based Materials Informed By Multiscale Molecular Dynamics Simulations, Dhwanit Rahul Dave

Dissertations, Theses, and Capstone Projects

The challenge of establishing a sustainable and circular economy for materials in medicine and technology necessitates bioinspired design. Nature's intricate machinery, forged through evolution, relies on a finite set of biomolecular building blocks with through-bond and through-space interactions. Repurposing these molecular building blocks requires a seamless integration of computational modeling, design, and experimental validation. The tools and concepts developed in this thesis pioneer new directions in peptide-materials design, grounded in fundamental principles of physical chemistry. We present a synergistic approach that integrates experimental designs and computational methods, specifically molecular dynamics simulations, to gain in-depth molecular insights crucial for advancing the …

A 3d Imaging-Based Critique Of Wire Arc Additive Manufacturing (Waam) Simulations, Omar Oraby

Theses and Dissertations

Residual stresses play a critical role in the mechanical behavior and structural integrity of engineered components. Understanding and quantifying these stresses are essential for ensuring the reliable performance and durability of materials and structures. Traditionally destructive methods are used that involve sample sectioning and material removal. However, non-destructive methods have gained popularity due to their advantages in preserving the specimen's integrity for further testing and material waste reduction. Among these techniques, Digital Image Correlation (DIC) stands out as a powerful non-contact and full-field measurement approach. DIC captures displacements and strain distributions by analyzing the deformation of speckle patterns on the …

The Effect Of Mechanical Strain On The Electronic Conductivity Of Α- Fe2o3: A Density Functional Theory Study, Sheriff Naziru Abdulmutalib

Theses and Dissertations

Hydrogen has emerged as a promising future energy carrier due to its ability to produce zero carbon dioxide (CO2) emissions when burned. However, the limited natural abundance of hydrogen necessitates the development of cost-effective and environmentally friendly methods for large-scale hydrogen production. Among the different hydrogen production approaches, photoelectrochemical water splitting, which employs a photoanode material in a cell using solar energy to split water into hydrogen and oxygen, is the focus of this work. α-Fe2O3 (hematite) is a photoanode material that shows a promising future for hydrogen generation in a photoelectrochemical cells due to its cheapness, availability, and its …

Mechanical And Electromagnetic Properties Of Incorporating Graphene Oxide In Cementitious Mixtures, Cherif Khalil

Theses and Dissertations

This multidisciplinary study aimed at investigating the impact of incorporating graphene oxide (GO) on the mechanical properties and electromagnetic (EM) shielding effectiveness of cementitious mixtures, as well as critically examining the mechanism with which GO affects their microstructure properties. Analysis of the literature review showed that there are discrepancies in reporting the impact of GO on the mortar mix. Consequently, this study focuses on exploring the cause for such discrepancies and identifies three main factors which are thoroughly investigated. The factors were the different sonication energies applied to the GO (Shear Mixing, 1.5 kJ/ml, 3 kJ/ml and 6 kJ/ml), the …

Preparation Of 2d Tungsten Diselenide (Wse2) Thin Films By Selenization Of Dc-Sputtered W Precursors, Lwitiko P. Mwakyusa

Tanzania Journal of Science

Two-dimensional layered transition metal dichalcogenides based on WSe2 films demonstrated promising properties for nano-electronics and photovoltaic applications. In this work, WSe2 films were prepared by selenization of DC-sputtered W precursors. The influence of the selenization temperature on the structural, morphology, and optical properties of the WSe2 films was investigated. The selenization temperature was varied from 350 °C to 450 °C at the interval of 50 °C. Structural, morphology and optical properties of the WSe2 were investigated using X-ray diffractometry (XRD), Atomic Force Microscope (AFM), and UV-VIS-NIR spectrophotometer, respectively. XRD analysis revealed that all WSe2 were polycrystalline and exhibited the co-existence …

Self-Terminating, Heterogeneous Solid–Electrolyte Interphase Enables Reversible Li–Ether Cointercalation In Graphite Anodes, Dawei Xia, Heonjae Jeong, Dewen Hou, Lei Tao, Tianyi Li, Kristin Knight, Anyang Hu, Ethan P. Kamphaus, Dennis Nordlund, Sami Sainio, Yuzi Liu, John R. Morris, Wenqian Xu, Haibo Huang, Luxi Li, Hui Xiong, Lei Cheng, Feng Lin

Materials Science and Engineering Faculty Publications and Presentations

Ether solvents are suitable for formulating solid-electrolyte interphase (SEI)-less ion-solvent cointercalation electrolytes in graphite for Na-ion and K-ion batteries. However, ether-based electrolytes have been historically perceived to cause exfoliation of graphite and cell failure in Li-ion batteries. In this study, we develop strategies to achieve reversible Li–solvent cointercalation in graphite through combining appropriate Li salts and ether solvents. Specifically, we design 1M LiBF₄ 1,2-dimethoxyethane (G1), which enables natural graphite to deliver ~91% initial Coulombic efficiency and >88% capacity retention after 400 cycles. We captured the spatial distribution of LiF at various length scales and quantified its heterogeneity. The electrolyte …

Dielectric Properties Of Polycrystalline And Single Crystal (100) Strontium Titanate From 4 To 295 K, Hung Trinh, Alan Devoe, Fatih Dogan

Materials Science and Engineering Faculty Research & Creative Works

The dielectric properties of single crystal and polycrystalline SrTiO₃ (ST) were investigated from 295 to 4 K. Relative permittivity (εr) and loss tangent (tan(δ)) were measured systematically as a function of direct current (DC) voltage (0 V/cm to 800 V/cm), frequency (100 Hz to 1 MHz), and temperature (295 K to 4 K) for type (100) single crystal SrTiO₃ (SC-ST) and for polycrystalline SrTiO₃ (PC-ST). Calculated equivalent series resistance (ESR) data are also reported. Overall, the permittivity of ST showed a dependence on temperature, DC voltage, and frequency. Dependences on voltage and frequency were only observed at …

Rational Design Of Heterostructured Nanomaterials For Accelerating Electrocatalytic Hydrogen Evolution Reaction Kinetics In Alkaline Media, Hai-Bin Ma, Xiao-Yan Zhou, Jia-Yi Li, Hong-Fei Cheng, Ji-Wei Ma

Journal of Electrochemistry

Owing to the merits of high energy density, as well as clean and sustainable properties, hydrogen has been deemed to be a prominent alternative energy to traditional fossil fuels. Electrocatalytic hydrogen evolution reaction (HER) has been considered to be mostly promising for achieving green hydrogen production, and has been widely studied in acidic and alkaline solutions. In particular, HER in alkaline media has high potential to achieve large-scale hydrogen production because of the increased durability of electrode materials. However, for the currently most prominent catalyst Pt, its HER kinetics in an alkaline solution is generally 2–3 orders lower than that …

Stability Of A Solid Oxide Cell Stack Under Direct Internal-Reforming Of Hydrogen-Blended Methane, Ya-Fei Tang, An-Qi Wu, Bei-Bei Han, Hua Liu, Shan-Jun Bao, Wang-Lin Lin, Ming Chen, Wan-Bing Guan, Subhash C. Singhal

Journal of Electrochemistry

In this work, the long-term stability and degradation mechanism of a direct internal-reforming solid oxide fuel cell stack (IR-SOFC stack) using hydrogen-blended methane steam reforming were investigated. An overall degradation rate of 2.3%·kh^–1 was found after the stack was operated for 3000 hours, indicating a good long-term stability. However, the voltages of the two cells in the stack were increased at the rates of 3.38 mV·kh^–1 and 3.78 mV·kh^–1, while the area specific resistances of the three metal interconnects in the stack were increased to 0.276 Ω·cm², 0.254 Ω·cm² and 0.249 Ω·cm^{2 …}

Surface Modification Of Poly(4,4'-Oxydiphenilene Pyromellitimide) With Low-Pressure Plasma Treatment, Cihan Aktas

USF Tampa Graduate Theses and Dissertations

This study explores the change of the wetting characteristics of commercially availablepolyimide (PI), Kapton® HN, films a type of poly(4,4′-oxydiphenylene-pyromellitimide), following treatment with low-pressure plasmas of carbon tetrafluoride (CF4), air, hydrogen (H2), carbon-dioxide (CO2) and oxygen (O2) gases as well as the surface texturing via laser-exposure procedure. The water contact angle (CA) and surface free energy (SFE) of untreated PI films were determined as 82.4°±0.8 and 45.0±0.3 mN/m, respectively. After CF4 plasma gas treatment, the CA value of PI films increased to 110.2°±1.0, while it decreased to 9.3°±2.3 after O2 plasma gas treatment. The surface free energy (SFE) of PI …

Synthesis And Characterization Of Cellulose Microfibril-Reinforced Polyvinyl Alcohol Biodegradable Composites, Fatemeh Mahdiyeh-Boroujeni, Gabriella Fioravanti, Ronald Kander

School of Design and Engineering Papers

The pursuit of an environmentally sustainable manufacturing process requires the substitution of less damaging and recyclable solutions for harmful reagents. This study aims to assess the effectiveness of using cellulose microfibrils synthesized via different hydrolysis reactions as reinforcing agents in polyvinyl alcohol (PVA) at varying concentrations. The investigation explores the morphology, thermal properties, and chemical behavior of the cellulose particles. The cellulose microfibrils (CMFs) produced using citric acid exhibited the highest yield and aspect ratio. Notably, particles from organic acids demonstrated greater thermal stability, with oxalic acid-derived particles displaying the maximum thermal degradation temperature. Subsequently, cast films of PVA reinforced …

Research On Orthogonal Test Of Mgo-Fiber Cement Soil′S Deformation Modulus, Hu Qizhi, Yu Yang, Ma Qiang, Zhuang Xinshan

Journal of China & Foreign Highway

Appropriate amounts of MgO and fiber can improve the compressive strength of cement soil. In order to further study the mechanical properties of MGO-fiber cement soil, Minitab software was used to design an orthogonal test method, and sensitivity analysis and influence analysis were carried out. The change rules of deformation modulus of MgO content, fiber content, and fiber length were studied at three different levels. The regression equations of MgO content, fiber content, and fiber length with cement soil deformation modulus were obtained by using Matlab software to process the test data. The sample was tested by scanning electron microscope …

Experimental Study On Performance Of Cast Asphalt Mixture Basedon Dry Modification, Wang Ming, Li Bo, Bao Guangzhi, Hu Deyong

Journal of China & Foreign Highway

Cast asphalt mixture is the most widely used material for the pavement of long-span steel bridge decks, and the special asphalt binder cannot be produced and used in small batches. The wet modification process is obviously not suitable for the production of the cast asphalt mixture during the operation and maintenance period. In this paper, according to the requirements of cast asphalt mixture and its binder, combined with the requirements of the dry modification process, the developed direct injection modifier was employed to conduct the mix design of cast asphalt mixture and tests of the fluidity, penetration and increment, low-temperature …

Kinetic Applications Of Smart Materials In Architecture: A Descriptive Analysis, Youssef Elkhayat

Journal of Engineering Research

In recent years, many smart materials for architectural applications have been invented. Some smart materials can adapt and interact with the surrounding environment and its variants, whether temperature, humidity, daylight or electric current. Smart material changes its shape without any need for assistance, and it can return to its original state without any significant deformation in shape with the end of the external influence. The invention of smart materials stimulated several architects and facade designers to consider using them in various architectural applications such as sun shading, sun breakers, and windows, significantly impacting the concept and technology of movement in …

Hanford Low-Activity Waste Vitrification: A Review, José Marcial, Brian J. Riley, Albert A. Kruger, Charmayne E. Lonergan, John D. Vienna

Materials Science and Engineering Faculty Research & Creative Works

This Paper Summarizes the Vast Body of Literature (Over 200 Documents) Related to Vitrification of the Low-Activity Waste (LAW) Fraction of the Hanford Tank Wastes. Details Are Provided on the Origins of the Hanford Tank Wastes that Resulted from Nuclear Operations Conducted between 1944 and 1989 to Support Nuclear Weapons Production. Waste Treatment Processes Are Described, Including the Baseline Process to Separate the Tank Waste into LAW and High-Level Waste Fractions, and the LAW Vitrification Facility Being Started at Hanford. Significant Focus is Placed on the Glass Composition Development and the Property-Composition Relationships for Hanford LAW Glasses. Glass Disposal Plans …

Thermo-Photo Catalytic Anode Process For Carbonate-Superstructured Solid Fuel Cells, Hanrui Su, Yun Hang Hu

Michigan Tech Publications

Converting hydrocarbons and greenhouse gases (i.e., carbon dioxide, CO2) directly into electricity through fuel cells at intermediate temperatures (450 to 550 °C) remains a significant challenge, primarily due to the sluggish activation of C-H and C=O bonds. Here, we demonstrated a unique strategy to address this issue, in which light illumination was introduced into the thermal catalytic CO2reforming of ethane in the anode as a unique thermo-photo anode process for carbonate-superstructured solid fuel cells. The light-enhanced fuel activation led to excellent cell performance with a record-high peak power density of 168 mW cm-2at an intermediate temperature of 550 °C. Furthermore, …

Balsa Bridge, Caleb T. Lovett

All Undergraduate Projects

The problem presented throughout this report was to create a small-scale bridge made entirely out of balsa wood and glue, that could withstand substantial force, as well as perform a lifting/lowering cycle. Other requirements associated with the bridge were properties of weight, deflection, size, and shape. This problem presented a challenge that tested the mathematical side of engineering, being strongly reliant on statics, mechanics of materials, and mechanical design analyses.

To approach this problem, the first step was to complete in depth calculations of the chosen design. With this done, manufacturing and assembly was able to be completed. With a …

Hempcrete Curtain Walls, Anh Bui

2024 Awards for Excellence in Student Research and Creative Activity - Documents

This research aims to scrutinize the performance, durability, and viability of hempcrete in curtain wall applications—an exploration critical to advancing sustainable construction practices. Comprising hemp hurds and lime binders, hempcrete stands as an emerging sustainable building material with promising ecological benefits. Despite its potential, there exists a notable research gap concerning its application in curtain walls, which demand rigorous structural and weatherproofing standards. The primary objective is to subject full-scale hempcrete curtain wall assemblies to ASTM standard test methods, comparing their performance with conventional materials like stone and glass. The research hypothesis posits that hempcrete will exhibit satisfactory strength, fire …

Electrochromic Polymers: From Electrodeposition To Hybrid Solid Devices, Haradou Sare, Dongmei Dong

College of Science & Mathematics Departmental Research

This paper reports on the linear colorimetric and electrochromic (EC) characteristics of electrodeposited polyaniline (PANI) films. This paper also investigates the infrared EC properties of acid-doped PANI films. The electrochemical polymerization method was employed to create a porous and thin PANI film layer onto PET-ITO substrates. This layer was capped with WO3 film to create a gel electrolyte sandwich structure that demonstrates the compatibility of PANI films with cathodic WO3 films in full devices. The electrodeposition of the film was fabricated by applying different voltages and time, with the optimal film quality achieved with the 1.7 V voltage and a …

Research Trends And Impact Report On Aggregation-Induced Emission (Aie), 2001-2021, Elsevier Analytical Services

Public Reports

Since the concept of AIE was first proposed in China in 2001, it has gradually grown to a field of science that attracts dedicated researchers from around the world. Elsevier's data analytics team used AIE experts' interpretation of current theoretical, technological, and industrial development trends in the field for reference to collect AIE-related global scientific publications (from the Scopus database) to serve as a publication set in the field of AIE. This was undertaken to present, accurately and objectively, the development of AIE research over the past two decades and the latest scientific advancements in the field; to facilitate the …

Predicting Compressive Strength Of Concrete Incorporating Fly Ash, Blast Furnace Slag, And Superplasticizer Using Machine Learning Techniques, Muhammad Faisal Yaqub

2024 REYES Proceedings

Concrete is the second most essential element in the construction industry, and its strength requirements vary based on the specific conditions of each project. However, determining the compressive strength of concrete involves laboratory tests, which wastes a lot of time and money. Researchers have developed machine learning models that predict the compressive strength of cement-based concrete having various mixes. In this research, the compressive strength of concrete incorporating fly ash, blast furnace slag, and superplasticizer is predicted using different machine learning models, namely, Linear Regression, Random Forest Regression, Decision Tree Regression, Extreme Gradient Boosting, Light Gradient Boosting, AdaBoost, and CatBoost …

Deep Learning Based Optical Flow Analysis Of High-Speed Flows, Daniel H. Zhang, Zifeng Yang

Mechanical and Materials Engineering Faculty Publications

Two-dimensional Rayleigh scattering imaging is utilized to quantify the high-speed flow velocity by employing deep learning based optical flow analysis, along with density fields from Rayleigh scattering intensity profiles.

Amplification-Free Rapid Detection Of Specific Oligonucleotides Through Formation Of Core-Satellite Nanostructures On Solid Substrates, Vineet Kumar Jayakrishnan

Material Science and Engineering Theses - Archive

A rapid, portable, and highly sensitive method for detecting specific pathogens like Covid-19 would be invaluable for public health and emergency responses. The current standards like PCR and RT-PCR, are incredibly sensitive but also time-consuming, require skilled personnel, and demand substantial lab space. Here, we propose an alternative method capable of detecting specific oligonucleotide sequences within just 3 minutes, using a portable silicon or glass substrate (6 mm x 9 mm). We demonstrated this using 67-mer oligonucleotides with a Covid-19 sequence as a model system, achieving a detection sensitivity down to 1 nM. Our approach involves sandwiching target COVID-19 oligonucleotides …

Investigation Of Bone Structure And Composition Differences In Osteofibrous Dysplasia And Neurofibromatosis Type 1, Farzaneh Fereidouni

Material Science and Engineering Dissertations - Archive

Abstract

Investigation of Bone Structure and Composition Differences in Osteofibrous Dysplasia and Neurofibromatosis Type 1

Farzaneh Fereidouni, Ph.D.

The University of Texas at Arlington, 2024

Supervising Professor: Harry F. Tibbals

Bone genetic diseases such as Osteofibrous Dysplasia (OFD) and Neurofibromatosis type 1 (NF1) present significant challenges, particularly in children, due to their effects on skeletal homeostasis. This study aims to apply advanced material analysis to elucidate the biological disparities associated with OFD and NF1 bone dysplasia and contribute to developing diagnostic protocols and remediation approaches for these and similar bone disorders.

By employing various analytical methods, including analysis of mineral-to-matrix …

Sub-1k Cold Electron Transport At Room Temperature, Anthony Martinez

Material Science and Engineering Dissertations - Archive

Thermally excited electrons at the high-energy tail of the Fermi-Dirac distribution impose fundamental limitations on the performance of solid-state electronic and spintronic devices. For example, the thermally excited electrons obscure the Coulomb blockade essential for single-electron transport. The hot electrons can also overcome the energy barrier of Metal-Oxide-Semiconductor Field-Effect transistors (MOSFETs), causing unwanted leakage currents that lead to excessive power consumption in the integrated circuits. This study investigates an approach in which quantum states are used to manipulate electron tunneling, blocking the transport of thermally excited hot electrons, thereby enabling cold-electron transport at room temperature. Here two heterogeneous quantum wells …