Polymer Science Commons^™

Phase-Separation Dynamics Of Polycarbonate Polymethyl Methacrylate Blends. Ii. Temperature Jumps Above An Immiscibility Loop, Thein Kyu, Ds Lim

College of Polymer Science and Polymer Engineering

No abstract provided.

The Effects Of Low Doses (1 To 500 Kilograys) Of 100-Kev Electrons On Four Polymers, Cynthia Anne Bradbury

Physics Theses & Dissertations

Commercial films of polyetherimide (PEI), polyetheretherimide (PEEI), polyethylene terephthalate (PET), and polycarbonate (PC) were exposed in vacuum to l 00-keV electron radiation to total absorbed doses of l, l 0, l 00, 300, and 500 kilograys. The concentration of radiation-generated radicals, as measured by electron paramagnetic resonance (EPR), increased by over an order of magnitude in all four polymers. Correspondingly, the intensity of the infrared absorption peaks increased uniformly for all doses. Solubility tests resulted in decreased solubility in all polymers. IR, EPR, and solubility suggest dehydrogenation of the aliphatic C-H and phenyl C-H sites. The data indicated that cross …

Sodium-Initiated Polymerization Of Alpha-Methylstyrene In The Vicinity Of Its Reported Ceiling Temperature, Shuenn-Long Ou

Dissertations

No abstract provided.

The Synthesis Of New Maleimide Addition Polymer Precursors, Richard B. Brown

Chemistry & Biochemistry Theses & Dissertations

1H-2,3-dimethylpyrrolo(1,2-a) benzimidazol-l-one (27) and 1H,9H- 2,3,7,8-tetramethyl-bispyrrolo(1,2-a:6,7-a')benzodiimidazo1-1,9-dione (32) have been synthesized from dimethylmaleic anhydride and o-phenylenediamine and 1,2,4,5-tetraaminobenzene, respectively. The presence of reactive olefinic double bonds in the synthesized compounds was of interest as a site for possible addition polymerization.

The synthetic route involved, in both cases, a simple nucleophilic substitution reaction between the diamine(or tetraamine) and the anhydride to form an intermediate amide-acid-amine which rapidly cyclized to the imide amine. The final ring closure required more rigorous conditions and occurred at melt reaction temperatures.

Inhibitors And Retarders For The Free Radical Polymerization Of Alpha-Methylstyrene, Alexander Accetta

Masters Theses

No abstract provided.