Chemical Engineering Commons^™

Influence Of Aerosols During Amine-Based Co2 Capture: Evolution And Control, David Immanuel Arthur Dhanraj

McKelvey School of Engineering Graduate Student Theses & Dissertations

Driven by escalating concerns on global warming and climate change, significant efforts have recently been initiated to reduce atmospheric CO2 concentration. Power generation from fossil fuels is the largest source of anthropogenic CO2. The US government has incentivized carbon capture through Section 45Q Tax code, which provides US$50/tCO2 (per metric ton) of qualified carbon dioxide captured and sequestered, as tax credits. The cost for carbon capture, transport and sequestration is US$75 – 150/t CO2, with the state-of-the-art capture technology costing between US$20 – 100/t CO2. Amine based post-combustion CO2 capture is the most economic technology suited for large power plants. …

Droplet And Particle Dynamics In Aerosol Reactors And Environmental System, Sukrant Dhawan

McKelvey School of Engineering Graduate Student Theses & Dissertations

Aerosol science and engineering is an enabler for continual advances in nanomaterial synthesis. The spray-based techniques have been used extensively for the large-scale production of nanoparticles. Synthesis of particles with a desired the size and morphology is of key importance for exploiting their properties for their use in several emerging technologies. In contrast to useful nanomaterials, the aerosols from industrial flue gas, dust, indoor cooking, pathogens, and wildfire etc. are harmful to human health. It is important to understand how these harmful aerosols travel through the environment and potentially impact the health. It is also very critical to improve the …

Direct Activation Of Light Alkanes To Value-Added Chemicals Using Supported Metal Oxide Catalysts, Md Ashraful Abedin

LSU Doctoral Dissertations

One of the most challenging aspects of modern-day catalysis is the conversion of methane. Direct conversion of methane via dehydroaromatization (MDHA) is a well-known process which can produce valuable hydrocarbons. Mo oxide supported on ZSM-5/MCM-22 has been studied extensively in recent years for MDHA. Mo carbides are responsible for activating methane by forming CHx species. These are dimerized into C2Hy and oligomerized on ZSM-5/MCM-22 Brønsted acid sites to form aromatics. Sulfated zirconia (SZ) supported Mo catalyst contains the acid sites necessary to produce benzene in MDHA. Here, sulfated hafnia (SH), a homologous oxide like SZ, has been proposed to provide …

Rapid Computation Of Effective Conductivity Of 2d Composites By Equivalent Circuit And Spectral Methods., Ben J. Ransom, Dean R. Wheeler

Faculty Publications

This work presents models for homogenizing or finding the effective transport or mechanical properties of microscale composites formed from highly contrasting phases described on a grid. The methods developed here are intended for engineering applications where speed and geometrical flexibility are a premium. A canonical case that is mathematically challenging and yet can be applied to many realistic materials is a 4-phase 2-dimensional periodic checkerboard or tiling. While analytic solutions for calculating effective properties exist for some cases, versatile methods are needed to handle anisotropic and non-square grids. A reinterpretation and extension of an existing analytic solution that utilizes equivalent …

Kinetic Modeling Study Of Laminar Burning Velocity Of Gasoline–Ethanol–Methanol Blends At Elevated Temperature And Pressure, Ahmad Syihan Auzani, Cahyo Setyo Wibowo, Riesta Anggarani, Yulianto Sulistyo Nugroho, Bambang Sugiarto

Makara Journal of Technology

Gasoline–ethanol–methanol (GEM) blends have been considered to replace pure gasoline as spark ignition engine fuel. Their physical and chemical properties and performance and emission measurements from real engines have been reported previously. However, a fundamental study that can explain the unique results of GEM compared with those of pure gasoline is lacking. This study aims to compare the laminar burning velocity of GEM blends at different mixtures, equivalence ratios, temperatures, and pressures with that of pure gasoline. A laminar flame propagation model and reaction mechanisms from the literature were were for a numerical simulation. In this study, the chemical components …

Music Information Retrieval Based On Active Frequency, Hardianto Wibowo, Wildan Suharso, Yufis Azhar, Galih Wasis Wicaksono, Agus Eko Minarno, Dani Harmanto

Makara Journal of Technology

Music is the art of combining frequencies. A balance of frequencies gives rise to a harmonious tone. Several features of music can be analyzed, and they include sociocultural background, lyrics, mood, tempo, rhythm, harmony, melody, timbre, and instrumentation. In this study, we use the frequency of instrumentation as a feature for classification because each instrument has a frequency range. To test this frequency range, we use five music genres and one music playing skill. The five genres are dangdut, electronic dance music (EDM), metal, pop/rock, and reggae. The music playing skill is acoustic. Active frequencies are tested using the k-nearest …

Predictive Delivery Man Assignment Problem Using Deep Learning, Rahmadini Payla Juarsa, Taufik Djatna

Makara Journal of Technology

Dispatching is a critical part in current online shopping. It relates to how the delivery man assignment should minimize cost along with the service from a source to an end customer with an appropriate scheduled time. The problem arises as neither enough products to deliver nor delivery men are available for dispatch, resulting in suboptimal service and a waste of money. The study aimed to formulate the cost of restaurant dispatching for inducing a deep learning-based solution with the gated recurrent unit recurrent neural network to receive hourly order data and to engage the result for near feature delivery man …

Effect Of Arc Plasma Sintering On The Structural And Microstructural Properties Of Fe-Cr-Ni Austenitic Stainless Steels, Parikin Parikin, M. Dani, A. Dimyati, N. D. Purnamasari, B. Sugeng, M. Panitra, A. Insani, T. H. Priyanto, S. Mustofa, Syahbuddin Syahbuddin, A. Huang

Makara Journal of Technology

X-ray diffraction techniques were performed to determine the actual crystal structure of A2 austenitic stainless steel (ASS) as-cast and A2 ASS after arc plasma sintering (APS) for 2 s. Computations were conducted on the basis of the Bragg arithmetic formula by comparing the S2 arithmetic with the interplanar spacing. The Bragg arithmetic formula is a simple series for the determination of the crystalline phase of materials based on the Miller indices of cubic shapes or other shapes. A2 ASS as-cast was identified to have a crystal structure of face-centered cubic with lattice parameter a = 3.58 Å. A similar crystal …

Comparison Of Concrete And Steel Jacket Methods For Reinforcing A Concrete Bridge Pier By Numerical And Experimental Studies, Hadi Faghihmaleki

Makara Journal of Technology

Various rehabilitation and strengthening procedures have been developed in recent decades. A study to determine which methods can be implemented to increase the useful life of the bridge before strengthening must be performed. In this study, the seismic behavior of a reinforced concrete bridge pier with dimension 3.5 × 3.5 m, which was reinforced by two steel and a concrete jacket, was investigated. Nonlinear geometric models and materials were analyzed to estimate the seismic parameters of the pier. Results show an increase in energy absorption, ultimate strength, and ductility for the steel jacket, as well as a greater increase in …

Trend Significance Levels Of Rain Onset And Cessation And Lengths Of The Wet And Dry Seasons In Epe, Lagos State, Nigeria, Adekunle Adedeji Alli, Olorunwa Eric Omofunmi

Makara Journal of Technology

This study aims to reduce crop failure resulting from a dry spell, which is the first occurrence of unsustainable rainfall that deceives farmers into planting. Thus, trends need to be tested using hypothesis, kurtosis, and other statistics to analyze the risks associated with unstable planting calendars and their possible mitigation strategies. The daily rainfall data from 1982 to 2018 were obtained from the archive of NASA/POWER SRB/FLASH, and the research location is Epe, Lagos State, Nigeria, which lies at latitude 6.585° N and longitude 3.962° E. Microsoft Excel was used to perform the tests. Results show that the null hypothesis …

Improvement Of Electrical Properties Of Cmc-Pva Doped With Various Contents Of Lino3 As An Application For Hybrid Polymer Electrolytes, Amalia Zulkifli, Norfatihah Mazuki, Ahmad Salihin Samsudin

Makara Journal of Technology

The present work was carried out with the development of hybrid polymer electrolytes (HPEs) by using carboxymethyl cellulose (CMC)–polyvinyl alcohol (PVA) doped with different contents of lithium nitrate (LiNO3) for the determination of their structural and conduction properties. The structural analysis was conducted by using Fourier transform infra-red spectroscopy and showed the interaction between the blend host polymer and ionic dopant, which formed via the coordinating site of CMC-PVA and Li+-NO3−. The complexes of CMC-PVA doped LiNO3 led to an increment in ionic conductivity, as observed by electrical impedance spectroscopy, and the sample containing 20 wt% LiNO3 obtained the highest …

Wetting And Drying Dynamics For Tio2 With Pbs Quantum Dots., Kelly M. Lee

Electronic Theses and Dissertations

Initial solar cells utilized silicon and alloys for their economic viability. Photoelectrochemical photovoltaic cells were discovered with technological advancement which increased solar efficiency and further improved economic feasibility leading to quantum dot sensitized solar cells. Lead sulfide quantum dots and titanium dioxide were studied for wetting and drying effects. Zeta potential, pH values, SEM, and optical microscopes quantified or observed the colloidal suspension and dried sample behavior. Combined mixtures of lead sulfide and titania were dried at 3.6 pH and 12.56 pH values. This due to the observed zeta potential isoelectric point of titania, and behavior showed increased stability occurring …

The Study Of Copper Corrosion Mechanisms Using Electrochemical Experimental Techniques., Evan Grimm

Electronic Theses and Dissertations

The purpose of this study was to discover and thoroughly explain the corrosion mechanisms of copper in saltwater, tap water and deionized water, and to apply these methods and findings when testing the corrosion mechanisms of other materials. The experimental procedure consisted of measuring the open circuit potential, electrochemical impedance spectroscopy, linear sweep voltammetry, and Tafel analysis.

The copper was found to corrode at a greater rate in saltwater, followed by tap water then deionized water, with a larger difference between saltwater and tap water than between tap water and deionized water. Each reaction was found to be both kinetically …

In Vitro Osteogenic Performance Of Two Novel Strontium And Zinc-Containing Glass Polyalkenoate Cements, Daniella Marx, Alireza Rahimnejad Yazdi, Marcello Papini, Mark R. Towler

Chemical and Biochemical Engineering Faculty Research & Creative Works

Glass polyalkenoate cements (GPCs) are under investigation as potential bone adhesives, as they may provide an alternative to polymethylmethacrylate-based cements. GPCs containing strontium (Sr) and zinc (Zn) in place of aluminum (Al) are of particular interest because these ions are known stimulators of osteoprogenitor differentiation. GPCs have been manufactured from a novel bioactive glass (SiO2:0.48, ZnO:0.36, CaO:0.12, SrO:0.04) in the past, but, while such materials have been assessed for their influence on viability, their influence on osteogenic function has not been investigated until now. For this study, two GPCs were formulated from the same glass precursor evaluated in previous studies. …

The Effects Of Ceria Loading On Three-Way Catalysts For Passive Scr Operation, Calvin R. Thomas, Josh A. Pihl, Vitaly Y. Prikhodko, Michelle K. Kidder, Jochen A. Lauterbach, Todd J. Toops

Faculty Publications

Passive SCR systems, which employ both a three-way catalyst and SCR catalyst, are effective for the reduction of nitrogen oxide (NOx) emissions from lean burn gasoline engines. However, questions remain regarding the effect of three-way catalyst formulations on their performance in these systems. Here, Pd/CeOx/Al2O3 catalysts with variable CeOx loading were synthesized, characterized, and evaluated to determine the effects of CeOx on catalyst performance. While a small amount of ceria was beneficial for promoting essential reactions, excess ceria was detrimental due to the increase in oxygen storage capacity. Additionally, insights into potential reaction pathways for NH3 production were determined.

Methane Emission Treatment And Potential Upcycling Using Methylomicrobium Alcaliphilum, Jace Parkinson

All Graduate Plan B and other Reports, Spring 1920 to Spring 2023

Anthropogenic methane emissions are harmful to the environment and can be difficult to treat. Use of M. alcaliphilum for bioremediation of methane looks to be one of the most promising methods of reducing the negative environmental impacts of methane emissions while simultaneously providing an economic incentive. Successful bioreactor design for M. alcaliphilum based methane treatment requires biokinetic constants and microbial growth information. Methods were established for determining biokinetic constants, including growth rate, biomass yield, specific methane consumption rate, and a correlation between methane oxidation and carbon dioxide production for M. alcaliphilum. Values determined for these constants were used to …

The Effects Of Ceria Loading On Three-Way Catalysts For Passive Scr Operation, Calvin R. Thomas, Josh A. Pihl, Vitaly Y. Prikhodko, Michelle K. Kidder, Jochen A. Lauterbach, Todd J. Toops

Faculty Publications

Passive SCR systems, which employ both a three-way catalyst and SCR catalyst, are effective for the reduction of nitrogen oxide (NOx) emissions from lean burn gasoline engines. However, questions remain regarding the effect of three-way catalyst formulations on their performance in these systems. Here, Pd/CeOx/Al2O3 catalysts with variable CeOx loading were synthesized, characterized, and evaluated to determine the effects of CeOx on catalyst performance. While a small amount of ceria was beneficial for promoting essential reactions, excess ceria was detrimental due to the increase in oxygen storage capacity. Additionally, insights into potential reaction pathways for NH3 production were determined.

Mixed Metal Oxide Nanowires Via Solid State Alloying., Veerendra Atla

Electronic Theses and Dissertations

Mixed metal oxide materials with composition control find applications in energy conversion and storage processes such as heterogenous catalysis, photoelectrochemical catalysis, electrocatalysis, thermal catalysis, and lithium-ion batteries. Mixed metal oxides and/or complex oxides with composition control and in one-dimensional form as nanowires could be interesting to various catalysis applications due to control on single crystal surfaces, active sites, acidity versus basicity site density, and oxygen vacancies. The major challenge is to synthesize mixed metal oxide nanowires beyond binary oxides with composition control. In this dissertation, solid state alloying of binary oxide nanowires with solid and liquid precursors is studied to …

Aggregation Dynamics Of Bulk Nanoparticle Haloing Systems And The Influence Of Non-Ambient Temperatures., Marzieh Moradi

Electronic Theses and Dissertations

One of the methods of assembling colloids into 3D crystal structures is through the use of nanoparticle haloing. Nanoparticle haloing is a stabilization mechanism in binary particle suspensions possessing both a size and charge asymmetry, with which the nanoparticles aid in the bulk suspension’s stability. By altering the volume fractions of nanoparticles, it is possible to control the effective repulsion between the microparticles. Understanding the colloidal interactions and aggregate crystallinity as a function of nanoparticle concentration, temperature, and time are key challenges in developing future materials and designing crystalized 3D colloidal systems. In this study, we investigated the effect of …

Exploring Meerwein-Ponndorf-Verley Reactions Using Metal Organic Framework Catalysts., Yuehan Zhou

Electronic Theses and Dissertations

The Meerwein–Ponndorf–Verley (MPV) reaction is a reaction that is used to reduce aldehydes and ketones to the corresponding alcohols with the added use of catalysts. The common metal triflate catalysts used in MPV reduction incur tremendous environmental hazards and high operational costs. The use of Metal-Organic Frameworks (MOFs) as catalysts can be an alternative due to MOFs’ extraordinarily high surface areas, ultrahigh porosities, tunable pore sizes, modifiable internal surfaces, and numerous framework structures. Moreover, using MOFs as catalysts for MPV hydrogenation is economically viable due to low operational and material costs. This study involves using MOF-808 (Hf) in the MPV …

Modified Electrode Surfaces With Hydrogen Evolution Reaction Catalysts Derived From Electropolymerized Complexes With Redox Active Ligands., Amanda Mae Arts

Electronic Theses and Dissertations

The demand for energy is growing exponentially, and to keep up with these demands new technologies for renewable energy have received increased attention. Hydrogen is one of the most promising energy sources for the future and plays a vital role in water electrolysis and fuel cells, as the hydrogen evolution reaction (HER) is the main step in the water splitting process. To increase the reaction rate and improve efficiency for the water electrolysis, catalysts are used to minimize the overpotential.

Most of the current electrocatalysts for HER are heterogeneous in nature and are dominated by platinum and other precious metals …

Room Temperature Alkali Treatment Of Rice Straw For Enhanced Enzymatic Hydrolysis., Seth Mains

Electronic Theses and Dissertations

Due to the pollution of fossil fuels due to greenhouse emissions, researchers continue to search for alternative methods that allow for the clean production of energy, fuels, and polymer fibers. A method currently under investigation is the use of lignocellulosic biomass as a solution to current problems with energy and polymer fiber production. Through the process of pretreatment, possibilities for lignocellulosic biomass expand due to improved accessibility of the cellulose and hemicellulose which can be broken down via enzymatic hydrolysis into C5 and C6 sugars such as xylose and glucose. This study investigated the fermentation of the rice straw into …

Life Cycle Impact Assessment Of Biofuels Derived From Sweet Sorghum In The U.S., Karla G. Morrissey, Greg Thoma, Dora E. Lopez

Chemical Engineering Faculty Publications and Presentations

Background

The objective of this study was to evaluate the environmental impact of the production of a range of liquid biofuels produced from the combination of fermenting sorghum stalk juice (bioethanol) and the pyrolysis/hydrotreatment of residual bagasse (renewable gasoline and diesel). Life cycle impact assessment (LCIA) was performed on a farm-to-wheels system that included: (i) sorghum farming, (ii) juice extraction, (iii) juice fermenting, (iv) bagasse pretreatment, (v) bagasse thermochemical treatment (pyrolysis, hydroprocessing, and steam reforming), and (vi) typical passenger vehicle operation. LCIA results were compared to those of petroleum fuels providing the equivalent functional unit—cumulative kilometers driven by spark ignition …

Mixing Optimization With Inward Flow Configuration Contra-Rotating Impeller, Baffle-Free Tank, P. Satjaritanun, J. R. Regalbuto, J. A. Regalbuto, N. Tippayawong, Sirivatch Shimpalee

Faculty Publications

In this study, pitched-blade, contra-rotating impeller, baffle-free tank with opposing inward flow is optimized using various designs of mixers derived from the Taguchi method. Mixing efficiency and torque are used to find the optimal design for the different specific gravities of solid particles employing in both experiments and CFD simulations. The analysis of signal-to-noise ratio shows that the impeller clearance and diameter are significant factors on the fluid flow and thus the mixing efficiency. In this study, 27 cases were studied to determine and report the optimal design parameters. A combination of CFD simulation with a strong design of experiment …

Rheological Properties Of Aged Crude Hard Wood Pyrolysis Oil, Divina D. Kaombe

Tanzania Journal of Engineering and Technology (TJET)

Upon storage of the pyrolysis oil, aging reactions may initiate phase separation and change of the rheological properties. These changes lead to unfavourable fuel characteristics in handling, transportation and applications. Efforts have been made for alleviation including methods on how to avoid these aging effects and development of equipment capable of handling aged pyrolysis liquids with unfavourable fuel characteristics. Therefore, the aim of this study was to explore the rheological properties of phase separated pyrolysis liquid fuel. Two batches of a well – stored poplar wood pyrolysis oils were used for the investigation; one batch was diluted with water to …

Production Of Pure Vanadium: Industry Review And Feasibility Study Of Electron Beam Melt Refining Of V–Al Alloys, Devin Rappleye, Rob Haun

Faculty Publications

The vanadium industry has experienced significant change over the last two decades with the emergence of vanadium redox flow batteries for grid-level energy storage, the growing demand for high-strength steel, and the selection of vanadium as a critical material in multiple countries. This review presents the status of the vanadium industry examining production processes and detailing facilities. The available information for each producer is presented including vanadium products and capacity. The production of pure vanadium is identified as a potential vulnerability for some nations where vanadium metal is needed in small, yet strategic, applications and globally only two producers of …

Finite Element Modelling And Exergy Analysis Of A Solar Thermal Hollow Fiber Vacuum Membrane Distillation System, Benjamin Shuldes

Department of Chemical and Biomolecular Engineering: Dissertations, Theses, and Student Research

A finite element model was developed to investigate the performance of a vacuum membrane distillation module under various operating conditions and membrane parameters. Porosity, tortuosity, pore diameter, membrane thickness, and fiber length were varied along with feed temperature, velocity, and flow configuration. In all cases, boundary layer polarization phenomena were seen to inhibit the performance of the module. At certain conditions, for a 7.5 cm fiber, the reduction in permeate flux from 65 LMH (Liter/m²/h) at the inlet to below 45 LMH at the outlet of the fibers was observed. In most cases, salt concentration polarization was the …

Fully Coupled Internal Radiative Heat Transfer For The 3d Material Response Of Heat Shield, Raghava S. C. Davuluri, Rui Fu, Kaveh A. Tagavi, Alexandre Martin

Mechanical Engineering Faculty Publications

The radiative transfer equation (RTE) is strongly coupled to the material response code KATS. A P-1 approximation model of RTE is used to account for radiation heat transfer within the material. First, the verification of the RTE model is performed by comparing the numerical and analytical solutions. Next, the coupling scheme is validated by comparing the temperature profiles of pure conduction and conduction coupled with radiative emission. The validation study is conducted on Marschall et al. cases (radiant heating, arc-jet heating, and space shuttle entry), 3D Block, 2D IsoQ sample, and Stardust Return Capsule. The validation results agree well for …

Exploiting The Role Of Nanoparticles For Use In Hydrogel-Based Bioprinting Applications: Concept, Design, And Recent Advances, Aishik Chakraborty, Avinava Roy, Shruthi Polla Ravi, Arghya Paul

Chemical and Biochemical Engineering Publications

Three-dimensional (3D) bioprinting is an emerging tissue engineering approach that aims to develop cell or biomolecule-laden, complex polymeric scaffolds with high precision, using hydrogel-based “bioinks”. Hydrogels are water-swollen, highly crosslinked polymer networks that are soft, quasi-solid, and can support and protect biological materials. However, traditional hydrogels have weak mechanical properties and cannot retain complex structures. They must be reinforced with physical and chemical manipulations to produce a mechanically resilient bioink. Over the past few years, we have witnessed an increased use of nanoparticles and biological moiety-functionalized nanoparticles to fabricate new bioinks. Nanoparticles of varied size, shape, and surface chemistries can …

Single-Particle Characterization Of Sars-Cov-2 Isoelectric Point And Comparison To Variants Of Interest, Oluwatoyin Areo, Pratik U. Joshi, Mark Obrenovich, Moncef Tayahi, Caryn L. Heldt

Michigan Tech Publications, Part 1

SARS-CoV-2, the cause of COVID-19, is a new, highly pathogenic coronavirus, which is the third coronavirus to emerge in the past 2 decades and the first to become a global pandemic. The virus has demonstrated itself to be extremely transmissible and deadly. Recent data suggest that a targeted approach is key to mitigating infectivity. Due to the proliferation of cataloged protein and nucleic acid sequences in databases, the function of the nucleic acid, and genetic encoded proteins, we make predictions by simply aligning sequences and exploring their homology. Thus, similar amino acid sequences in a protein usually confer similar biochemical …