Open Access. Powered by Scholars. Published by Universities.®
- Discipline
-
- Biochemical and Biomolecular Engineering (689)
- Petroleum Engineering (605)
- Biomedical Engineering and Bioengineering (233)
- Physical Sciences and Mathematics (233)
- Geological Engineering (183)
-
- Social and Behavioral Sciences (146)
- Energy Policy (142)
- Public Affairs, Public Policy and Public Administration (142)
- Biomedical Devices and Instrumentation (131)
- Chemistry (115)
- Earth Sciences (90)
- Geology (89)
- Mining Engineering (85)
- Electrical and Computer Engineering (83)
- Mechanical Engineering (80)
- Nuclear Engineering (62)
- Materials Science and Engineering (56)
- Civil and Environmental Engineering (49)
- Medicine and Health Sciences (33)
- Life Sciences (32)
- Business (31)
- Health Information Technology (31)
- Technology and Innovation (31)
- Materials Chemistry (27)
- Geophysics and Seismology (25)
- Aerospace Engineering (23)
- Biology (19)
- Architecture (18)
- Keyword
-
- Adsorption (24)
- Hydrodynamics (22)
- Nanoparticles (17)
- Conformance control (16)
- Drug delivery (15)
-
- Rheology (14)
- Catalysis (13)
- Enhanced oil recovery (13)
- Machine learning (13)
- Electrospun fibers (12)
- Bubble column (11)
- CARPT (11)
- Hydrogel (10)
- CFD (9)
- Conformance Control (9)
- Multiphase flow (9)
- Carbon nanotubes (8)
- Chemistry (8)
- Kinetics (8)
- Polymers (8)
- Preformed particle gel (8)
- Sustainability (8)
- Atomic layer deposition (7)
- Atomic layer deposition (ALD) (7)
- Computed tomography (7)
- Diffusion (7)
- EOR (7)
- Graphene (7)
- Human (7)
- Humans (7)
- Publication Year
- Publication
-
- Chemical and Biochemical Engineering Faculty Research & Creative Works (821)
- Masters Theses (443)
- Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works (251)
- Doctoral Dissertations (249)
- UMR-MEC Conference on Energy / UMR-DNR Conference on Energy (237)
-
- Symposia on Turbulence in Liquids (126)
- Business and Information Technology Faculty Research & Creative Works (31)
- Professional Degree Theses (20)
- UMR Journal -- V. H. McNutt Colloquium Series (20)
- Chemistry Faculty Research & Creative Works (19)
- Opportunities for Undergraduate Research Experience Program (OURE) (18)
- Civil, Architectural and Environmental Engineering Faculty Research & Creative Works (16)
- Biological Sciences Faculty Research & Creative Works (15)
- Electrical and Computer Engineering Faculty Research & Creative Works (14)
- Materials Science and Engineering Faculty Research & Creative Works (12)
- Undergraduate Research Conference at Missouri S&T (9)
- Mechanical and Aerospace Engineering Faculty Research & Creative Works (7)
- Miners Solving for Tomorrow Research Conference (5)
- Nuclear Engineering and Radiation Science Faculty Research & Creative Works (5)
- Computer Science Faculty Research & Creative Works (4)
- Mathematics and Statistics Faculty Research & Creative Works (4)
- Missouri School of Mines and Metallurgy Bulletins (3)
- School of Mines and Metallurgy Bulletins (3)
- UMR-DNR Conference on Energy (2)
- Economics Faculty Research & Creative Works (1)
- Mining Engineering Faculty Research & Creative Works (1)
- Missouri S&T’s Peer to Peer (1)
- NASA-Missouri Space Grant Consortium (1)
- Physics Faculty Research & Creative Works (1)
- Publication Type
- File Type
Articles 1 - 30 of 2339
Full-Text Articles in Chemical Engineering
Rheology Modifiers For Water-Based Slurry Pipeline Transportation: Overview, Efficiency, And Intensification, Ahmed Alalou, Mohammed El Asri, Ahmed Boulahna, Muthanna H. Al-Dahhan
Rheology Modifiers For Water-Based Slurry Pipeline Transportation: Overview, Efficiency, And Intensification, Ahmed Alalou, Mohammed El Asri, Ahmed Boulahna, Muthanna H. Al-Dahhan
Chemical and Biochemical Engineering Faculty Research & Creative Works
Owing to their cost-efficiency and eco-friendliness, water-based slurry pipelines are the state-of-the-art technology for the transportation of several types of solids such as coal, fly ash, petcoke, iron ore, phosphate rock and other minerals. This review comprehensively examines the effect of numerous commercial dispersants and novel chemical additives that are used as rheology modifiers to enhance the slurryability and fluidity of solid-water slurries at high solids loading. Several key performance parameters such as the rheological characteristics (shear stress, apparent viscosity, yields stress, and flow behavior), the potential stability, surface tension and contact angle that highlight the efficiency of the rheology …
Graphene Oxide–Driven In Situ Bismuth Reduction Enables Highly Efficient Electroreduction Of Co2 To Formic Acid, Hao Feng, Bohong Zhang, Jie Huang, Xinhua Liang
Graphene Oxide–Driven In Situ Bismuth Reduction Enables Highly Efficient Electroreduction Of Co2 To Formic Acid, Hao Feng, Bohong Zhang, Jie Huang, Xinhua Liang
Electrical and Computer Engineering Faculty Research & Creative Works
To enable large scale efficient electrochemical CO2 reduction reaction (CO2RR) to formic acid (HCOOH), it is important to develop catalysts that can be operated in a wide potential window with good stability. Herein, we successfully synthesized Bi2O3 catalyst supported on graphene oxide (GO) and graphene (G) and found that Bi2O3/GO catalyst had a better overall performance than Bi2O3/G. The Bi2O3/GO catalyst demonstrated an outstanding CO2RR performance with a greater than 90% faradaic efficiency (FE) across a wide applied potential window …
Percolation-Induced Thermo-Rheological Transitions In Biobased Graphene Nanoplatelet Nanofluids, Abiodun A. Saka, Tobechukwu K. Abor, Anthony C. Okafor, Monday U. Okoronkwo
Percolation-Induced Thermo-Rheological Transitions In Biobased Graphene Nanoplatelet Nanofluids, Abiodun A. Saka, Tobechukwu K. Abor, Anthony C. Okafor, Monday U. Okoronkwo
Mechanical and Aerospace Engineering Faculty Research & Creative Works
Biobased lubricants with thermally responsive rheology are increasingly needed for high-efficiency mechanical systems. Graphene nanoplatelet (GnP) nanofluids in vegetable oils are promising candidates, yet their percolation-driven thermo-rheological transitions remain insufficiently understood. In particular, the coupled concentration–temperature landscape controlling network-mediated flow transitions has not previously been established. Here, surfactant-free GnP nanofluids were prepared in high-oleic soybean oil (HOSO) at concentrations of 0.025–2.15% v/v (ϕ), and their rheological response was mapped between 25°C and 80 °C under steady-shear and oscillatory conditions. Below the percolation threshold (ɸ ≤ 0.1% v/v), the nanofluids exhibit near-Newtonian behavior, moderate reversible viscosity enhancement, and classical Arrhenius-type temperature …
Upar-Guided Dendrimer Gel Nanoparticles Reprogram Inflammation To Stabilize Atherosclerotic Plaques, Hsin Yin Chuang, Huari Kou, Yue-Wern Huang, Hu Yang
Upar-Guided Dendrimer Gel Nanoparticles Reprogram Inflammation To Stabilize Atherosclerotic Plaques, Hsin Yin Chuang, Huari Kou, Yue-Wern Huang, Hu Yang
Biological Sciences Faculty Research & Creative Works
Atherosclerosis is characterized by lipid deposition, chronic inflammation, and apoptosis within the arterial wall, leading to plaque progression and instability. Current lipid-lowering therapies fail to fully address residual cardiovascular risk driven by local inflammation and cell death. Here, we report the development of uPA-functionalized, rapamycin-encapsulated dendrimer nanoparticles (G5PM-uPA/RA) that preferentially accumulate in urokinase plasminogen activator receptor (uPAR)-enriched atherosclerotic plaque, including macrophage- and apoptosis-rich lesion microenvironments. G5PM-uPA/RA was constructed by cross-linking reaction-enabled flash nanoprecipitation in a custom-made multi-inlet vortex mixer, followed by thiol-maleimide conjugation of uPA for uPAR-guided targeting. The nanoparticles demonstrated uniform morphology, favorable stability, and efficient rapamycin loading. In …
Comparative Catalytic Pyrolysis Of Wheat Straw For Enhanced Bio-Oil Production, Nourhan H. Khashaba, Noura F. Abdelsalam, Hany A. Elazab, Mamdouh A. Gadalla, Thokozani Majozi, Fatma H. Ashour
Comparative Catalytic Pyrolysis Of Wheat Straw For Enhanced Bio-Oil Production, Nourhan H. Khashaba, Noura F. Abdelsalam, Hany A. Elazab, Mamdouh A. Gadalla, Thokozani Majozi, Fatma H. Ashour
Chemical and Biochemical Engineering Faculty Research & Creative Works
Catalytic fast pyrolysis of lignocellulosic biomass is a promising thermochemical route for producing renewable biofuels and value-added chemicals. Many African countries have abundant underutilized agricultural residues whose reuse can improve waste management while reducing reliance on fossil fuels. This study used wheat straw as a representative residue to examine how two catalysts—zinc oxide (ZnO) and cement kiln dust (CKD)—affect bio-oil yield and quality. Bench-scale experiments were performed in a fixed-bed reactor under an inert nitrogen atmosphere at 500–600 °C. Each catalyst was tested separately at loadings from 0 to 7 g per 500 g of biomass to evaluate impacts on …
Rheological Protocol To Assess And Optimize Latex Coagulation Dynamics For The Thin Glove Coagulant Dipping Process, Monday U. Okoronkwo, Kok Kong Ng, Wolfram Franke, Gaurav Sant
Rheological Protocol To Assess And Optimize Latex Coagulation Dynamics For The Thin Glove Coagulant Dipping Process, Monday U. Okoronkwo, Kok Kong Ng, Wolfram Franke, Gaurav Sant
Chemical and Biochemical Engineering Faculty Research & Creative Works
Many products that directly impact the quality of human life today — gloves, catheters, condoms, and baby bottle teats — are made through the latex-dipping technology. While a variety of methods have been developed – e.g., particle counting, turbidimetry, microscopy, and light scattering – which are suitable for studying the coagulation of latex at very low concentrations, much less work has focused on methods suitable for in-situ characterization of latex coagulation in concentrated solutions (e.g., as relevant to the dipping process). This paper presents a process-relevant rheological protocol for assessing and optimizing latex coagulation dynamics for the thin glove coagulant …
Converting Co2 Into Carbon Nanotubes Via Sequential Co2 Methanation And Methane Pyrolysis, Kaiying Wang, Hao Feng, Ahmad Helaley, Xiaoqing He, Bohong Zhang, Jie Huang, Xinhua Liang
Converting Co2 Into Carbon Nanotubes Via Sequential Co2 Methanation And Methane Pyrolysis, Kaiying Wang, Hao Feng, Ahmad Helaley, Xiaoqing He, Bohong Zhang, Jie Huang, Xinhua Liang
Electrical and Computer Engineering Faculty Research & Creative Works
This study presents a sequential thermochemical catalytic process for converting CO2 into carbon nanotubes (CNTs), achieving nearly 99% overall CO2 conversion and solid carbon yields of up to 49% in a single pass. The overall transformation is divided into two thermodynamically favorable steps: (1) low-temperature CO2 methanation to CH4 over a sol-gel-prepared Ni87Ce6.5Zr6.5-SG catalyst, which achieved >95% CO2 conversion at 250 °C in a single pass, and (2) subsequent methane pyrolysis to CNTs and H2 over a Ni@Al2O3-IE core-shell catalyst, which showed improved stability and carbon …
Oriented Electrospun Fibers Of Poly(Pro-Curcumin/Peg) Sequester Reactive Oxygen Species And Promote The Growth Of Schwann Cells, Jack W. Devlin, Payton R. O'Connor, Conrad H. Cheung, John T. Leman, Martin Oudega, Edmund F. Palermo, Ryan J. Gilbert
Oriented Electrospun Fibers Of Poly(Pro-Curcumin/Peg) Sequester Reactive Oxygen Species And Promote The Growth Of Schwann Cells, Jack W. Devlin, Payton R. O'Connor, Conrad H. Cheung, John T. Leman, Martin Oudega, Edmund F. Palermo, Ryan J. Gilbert
Chemical and Biochemical Engineering Faculty Research & Creative Works
In the biological injury microenvironment, pathologically elevated oxidative stress hinders healthy cell migration. Aligned electrospun fibers are used as tissue engineering scaffolds to support and guide the directionality of cell migration. The ability of cells in the central nervous system to sequester and quench reactive oxygen species is limited, and most electrospun fibers do not exert any antioxidant activity on contact. Thus, the challenge remains in designing a scaffold that can both guide cells to the injury site as well as sequester and quench excess free radicals, allowing cells to thrive and potentially regenerate. Curcumin is a well-known, potent antioxidant, …
Investigation Of Portland Limestone Cement Blended With Biochar From Downdraft Gasification: Hydration Kinetics, Microstructure, Rheology, And Performance Mechanisms, Ugochukwu Ewuzie, Paul C. Ani, Abdulkareem O. Yusuf, Joseph D. Smith, Monday Uchenna Okoronkwo
Investigation Of Portland Limestone Cement Blended With Biochar From Downdraft Gasification: Hydration Kinetics, Microstructure, Rheology, And Performance Mechanisms, Ugochukwu Ewuzie, Paul C. Ani, Abdulkareem O. Yusuf, Joseph D. Smith, Monday Uchenna Okoronkwo
Chemical and Biochemical Engineering Faculty Research & Creative Works
The widespread adoption of Portland Limestone Cement (PLC) in U.S. concrete production has necessitated research into commercially available supplementary cementitious materials (SCMs) for formulating high-performance, low-carbon blended binders with PLC. This study investigated the influence of biochar (BC) in biochar-PLC composites (CBCs), focusing on hydration kinetics, microstructure, rheology, pore-solution chemistry, compressive strength, and the underlying mechanisms. Biochar was produced via downdraft gasification at 850 °C and incorporated into PLC at 5, 7, and 10% substitution by mass. Isothermal calorimetry and hydration data modeled using the Knudsen equation revealed that BC retarded early hydration but improved hydration degree and later-age heat …
Mechanism Of Improved Miscibility Of Co2–Oil Systems By Multiester-Headgroup Surfactants, Ning Xu, Yanling Wang, Baojun Bai, Yu Zhang, Wenjing Shi, Zhaonian Zhang, Wenhui Ding, Peixu Ma, Zan Gao
Mechanism Of Improved Miscibility Of Co2–Oil Systems By Multiester-Headgroup Surfactants, Ning Xu, Yanling Wang, Baojun Bai, Yu Zhang, Wenjing Shi, Zhaonian Zhang, Wenhui Ding, Peixu Ma, Zan Gao
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
In the pursuit of carbon neutrality, the CO2-enhanced oil recovery provides dual benefits by enabling both carbon sequestration and incremental oil production. However, its application is limited by high minimum miscibility pressure. CO2-philic and oil-affinitive surfactants have emerged as an effective, low-dosage, and cost-efficient strategy to reduce the minimum miscibility pressure. In this study, macroscopic phase behavior experiments combined with molecular dynamics simulations were employed to systematically elucidate the influence of multiester-head surfactants on CO2–oil miscibility. Using a modified pressure–volume–temperature apparatus equipped with optical power monitoring, we determined that multiester-head surfactants reduced the first-contact …
Uptake And Fate Of Silver And Zinc Engineered Nanoparticles In Maize Under Single And Binary Dosing Soil Ecosystems, Lei Xu, Qingbo Yang, Xingmao Ma, Honglan Shi, John Yang, Hu Yang, Samira Mahdi, Ying Wang, Young Shin Jun
Uptake And Fate Of Silver And Zinc Engineered Nanoparticles In Maize Under Single And Binary Dosing Soil Ecosystems, Lei Xu, Qingbo Yang, Xingmao Ma, Honglan Shi, John Yang, Hu Yang, Samira Mahdi, Ying Wang, Young Shin Jun
Chemistry Faculty Research & Creative Works
Recent agricultural applications of engineered metallic nanoparticles (ENPs) have raised concerns about their uptake and fate in plants. To understand this critical issue, this study investigated the fate and uptake of silver (Ag) and zinc oxide (ZnO) ENPs in maize (Zea mays L.) after single or binary ENP exposure in soil. Results indicated that both Zn and Ag elemental concentrations in roots increased with increasing ENP dosage. Ag NPs in the tissues were detected, but not Zn NPs. Ag NP concentration was 3 times higher in the roots than in the shoots at low Ag NP dosing, while Ag NP …
Controlled Gelation Of Co₂-Resistant Polymer Systems For Improved Conformance In Co₂-Eor, Maryam Sharifi Paroushi
Controlled Gelation Of Co₂-Resistant Polymer Systems For Improved Conformance In Co₂-Eor, Maryam Sharifi Paroushi
Miners Solving for Tomorrow Research Conference
This presentation introduces a CO₂-resistant hydrogel developed to control fluid movement and improve CO₂ injection performance in subsurface reservoirs for Enhanced Oil Recovery (EOR) and Carbon Capture and Storage (CCS). Conventional polymer gels often lose strength in CO₂-rich environments, resulting in weak plugging, early breakdown, and ineffective flow control. To address this limitation, a sulfonated HPAM-based gel system crosslinked with chromium was developed. The effects of polymer concentration, molecular weight, crosslinker ratio, ionic strength, and pH were investigated to better understand gelation behavior and performance. The formulation exhibited controlled gelation, strong resistance to temperature and CO₂, and minimal shrinkage over …
Biosensors For Biomedicine, Drake O'Leary
Biosensors For Biomedicine, Drake O'Leary
Miners Solving for Tomorrow Research Conference
This project investigated the use of engineered bacterial reporter systems to detect cellular stress responses associated with antibiotic activity. While constructs were successfully introduced and tested against known antibiotics, the reporter consistently produced a blue signal across conditions, limiting the ability to distinguish specific stress responses. This suggests issues such as leaky expression, insufficient regulatory control, or lack of specificity in the reporter design. Although results were inconclusive, this work highlights key challenges in developing reliable biosensors and provides a foundation for future optimization. Improving signal specificity and reducing background expression will be critical for enabling accurate characterization of antibiotic …
Dendrimer Nanogels With Built-In Free Radical Scavenging Enable Efficient Topical Delivery Of A Hydrophilic Antioxidant To Restore Lens Redox Balance For Cataract Treatment, Lin Qi, Huari Kou, Anna Chernatynskaya, Da Huang, Vimalin Jeyalatha Mani, Humeyra Karacal, Nuran Ercal, Hu Yang
Dendrimer Nanogels With Built-In Free Radical Scavenging Enable Efficient Topical Delivery Of A Hydrophilic Antioxidant To Restore Lens Redox Balance For Cataract Treatment, Lin Qi, Huari Kou, Anna Chernatynskaya, Da Huang, Vimalin Jeyalatha Mani, Humeyra Karacal, Nuran Ercal, Hu Yang
Chemistry Faculty Research & Creative Works
Cataract is a leading cause of vision impairment worldwide and are primarily caused by oxidative stress that damages and aggregates lens proteins, leading to lens opacification. However, the eye's anatomical barriers limit the penetration and bioavailability of antioxidant therapies. To address this challenge, a dendrimer-based nanogel with a built-in reactive oxygen species (ROS)-scavenging capability developed by us was employed to deliver the antioxidant N-acetylcysteine (NAC) to the lens. NAC was loaded into a generation-5 PEGylated poly(amidoamine) dendrimer (G5-PEG-TK, termed the GPT) nanogel. The resulting NAC-GPT was characterized for its ROS-scavenging activity, bioavailability, and corneal permeability. The efficacy of NAC-GPT was …
Graphene Synthesis: A Reactor-Oriented Review Of Conventional And Emerging Production Methods, Paul C. Ani, Zeyad Zeitoun, Hasan J. Al-Abedi, Joseph D. Smith
Graphene Synthesis: A Reactor-Oriented Review Of Conventional And Emerging Production Methods, Paul C. Ani, Zeyad Zeitoun, Hasan J. Al-Abedi, Joseph D. Smith
Chemical and Biochemical Engineering Faculty Research & Creative Works
Graphene's unparalleled electrical, mechanical, and thermal properties have positioned it as a transformative material across diverse sectors, including electronics, energy storage, biomedicine, and environmental remediation. However, scalable, cost-effective, and high-quality production remains a critical challenge. This review presents a comprehensive, reactor-oriented analysis of both conventional and emerging graphene synthesis methods, categorized into top-down and bottom-up approaches. Special emphasis is placed on the role of reactor configurations in determining product quality, layer control, scalability, and economic viability. Key synthesis techniques explored include chemical vapor deposition (CVD), epitaxial growth, electrochemical exfoliation, ultrasonic-assisted methods, microwave reactors, combustion synthesis, and plasma-enhanced processes. By evaluating …
Near-Wall Void Distribution Characterization In Pebble Bed Reactor Using Gamma-Ray Ct And Dem Simulation, Ahmed Jasim, Mauricio Maestri, Abdullah Al Zubaidi, Omar Farid, Muthanna Al-Dahhan
Near-Wall Void Distribution Characterization In Pebble Bed Reactor Using Gamma-Ray Ct And Dem Simulation, Ahmed Jasim, Mauricio Maestri, Abdullah Al Zubaidi, Omar Farid, Muthanna Al-Dahhan
Chemical and Biochemical Engineering Faculty Research & Creative Works
Accurate characterization of void-fraction distributions in pebble-bed reactors (PBRs) is essential for predicting flow, heat transfer, and neutronic behavior. High-fidelity experimental benchmark data for validating such predictions remain scarce, largely due to the challenges of non-invasive measurements. In this study, gamma-ray computed tomography (CT) was employed to measure radial and cross-sectional porosity in a laboratory-scale pebble bed containing 6cm graphite pebbles. A Discrete Element Method (DEM) simulation was implemented and validated against these measurements, then applied to the full-scale geometry of the Xe-100 high-temperature gas-cooled pebble-bed reactor. Analyses included radial and axial void-fraction profiles in the cylindrical section and conical …
Ionic Liquid Pilocarpine Serves As Therapeutic Cosolvent And Permeation Enhancer For Glaucoma Medication, Ashish Trital, Lei Xu, Burhan Ates, Tzu Chen Wang, Vimalin Mani, Hu Yang
Ionic Liquid Pilocarpine Serves As Therapeutic Cosolvent And Permeation Enhancer For Glaucoma Medication, Ashish Trital, Lei Xu, Burhan Ates, Tzu Chen Wang, Vimalin Mani, Hu Yang
Chemical and Biochemical Engineering Faculty Research & Creative Works
The efficacy of hydrophobic ocular drugs is significantly hindered by their low bioavailability, for which poor water solubility is a major contributing factor. In this work, we synthesized pilocarpine-derived ionic liquid [Pilo-OEG] Cl (PO) and evaluated its cosolvent properties for the codelivery of the hydrophobic antiglaucoma drug brimonidine (BM) for glaucoma therapy. Pilocarpine was quaternized with 2-[2-(2-chloroethoxy) ethoxy] ethanol in a one-pot reaction to yield PO, and its structure was confirmed using 1H NMR and FT-IR spectroscopy methods and further characterized for its rheological property and thermal stability. The HET-CAM assay and cell viability study showed that PO was …
Advancing Activated Carbon Production: Utilizing Pine Pruning Biochar Via Induction Heating With Co2and Iron-Based Catalysts, Ahmet Erdem, Muthanna H. Al-Dahhan, Ahmed Jasim
Advancing Activated Carbon Production: Utilizing Pine Pruning Biochar Via Induction Heating With Co2and Iron-Based Catalysts, Ahmet Erdem, Muthanna H. Al-Dahhan, Ahmed Jasim
Chemical and Biochemical Engineering Faculty Research & Creative Works
This study introduces an induction heating approach for producing activated carbon from biochar obtained by thermal degradation of pine pruning waste from timber-related industries, using CO2 and iron-based catalysts as activation agents. Activation experiments were performed using a 10 kW high-frequency induction system (28–40 kHz) under continuous CO₂ flow (15 mL min−1), with electric current intensities of 200, 300, 400, and 500 A (corresponding to 700–1100°C) and durations of 30, 60, and 90 min, employing 45 g of iron-based catalysts (Fe–Ni–Ti–C, 85:6:3:6 wt.%) per 3 g biochar (15:1 w/w). Mass loss increased from 13.7 % (200 A, …
The Effect Of Reduction Of Input-Parameters On Data-Driven Prediction Of Critical Heat Flux In Rod Bundles Using Extended Parameters For Reactor Thermal–Hydraulic Safety, Rehan Zubair Khalid, Atif Khan, Farooq Ahmad, Muthanna H. Al-Dahhan, Atta Ullah
The Effect Of Reduction Of Input-Parameters On Data-Driven Prediction Of Critical Heat Flux In Rod Bundles Using Extended Parameters For Reactor Thermal–Hydraulic Safety, Rehan Zubair Khalid, Atif Khan, Farooq Ahmad, Muthanna H. Al-Dahhan, Atta Ullah
Chemical and Biochemical Engineering Faculty Research & Creative Works
Accurate prediction of the critical heat flux (CHF) is a key pillar for ensuring both the safety and economic performance of nuclear reactors. While machine learning (ML)-based methodologies have demonstrated considerable success in predicting CHF, most existing studies have been confined to simplified geometries, such as single tubes. Conversely, limited attention has been devoted to CHF prediction in realistic reactor environments, particularly within rod bundle configurations, where complex multiphase flow and heat transfer phenomena prevail. In this work we develop different AI models based on large dataset operating conditions as well as the complex geometric features of rod bundles. The …
Sustainable Pathways For Fish Waste Oil Valorization Into Biofuel: Process Synthesis And Case Study, Hany A. Elazab, Radhi H. Alazmi, Abdelrahman El-Bagalaty, Hossam Tammam, Mahmoud El-Sayed, Mohamed Omar, Fathi Shokry, Mamdouh A. Gadalla, Fatma H. Ashour, Thokozani Majozi
Sustainable Pathways For Fish Waste Oil Valorization Into Biofuel: Process Synthesis And Case Study, Hany A. Elazab, Radhi H. Alazmi, Abdelrahman El-Bagalaty, Hossam Tammam, Mahmoud El-Sayed, Mohamed Omar, Fathi Shokry, Mamdouh A. Gadalla, Fatma H. Ashour, Thokozani Majozi
Chemical and Biochemical Engineering Faculty Research & Creative Works
Biodiesel is a promising, sustainable alternative to fossil fuels such as petrol and diesel. Currently, biodiesel can be produced from edible plant oils and non-edible sources and wastes. Notably, fish waste oil is a sustainable resource for transesterification reactions to produce biodiesel. This research proposes a general process design methodology to investigate the potential of biodiesel production from fish waste oil as a pathway for waste-to-energy. The methodology integrates Pinch Analysis principles and process simulation to optimize the energy efficiency of a process design. Real data are collected on fish waste from fish industries in Egypt, focusing on three regions …
Neuproio: A Dual-Action Solid Drug Nanoparticle Topical Formulation For Simultaneous Intraocular Pressure Reduction And Neuroprotection For Glaucoma, Lei Xu, Mu Li, Lin Qi, Tzu Chen Wang, Dong Liu, Vimalin Jeyalatha Mani, Hsin Yin Chuang, Qingbo Yang, Ruipu Mu, Samira Mahdi, Da Huang, Honglan Shi, Yang Hu, Hu Yang
Neuproio: A Dual-Action Solid Drug Nanoparticle Topical Formulation For Simultaneous Intraocular Pressure Reduction And Neuroprotection For Glaucoma, Lei Xu, Mu Li, Lin Qi, Tzu Chen Wang, Dong Liu, Vimalin Jeyalatha Mani, Hsin Yin Chuang, Qingbo Yang, Ruipu Mu, Samira Mahdi, Da Huang, Honglan Shi, Yang Hu, Hu Yang
Chemical and Biochemical Engineering Faculty Research & Creative Works
Glaucoma is a leading cause of irreversible blindness, primarily due to elevated intraocular pressure (IOP) that damages the retina and optic nerve. Most topical glaucoma treatments focus solely on IOP-lowering without direct neuroprotection, as drug delivery to the posterior eye is challenging. Here, we developed NeuProIO, a dual-action solid drug nanoparticle (NP) eye drop for simultaneous IOP reduction and neuroprotection. Using flash nanoprecipitation in a multi-inlet vortex mixer, we fabricated the first NeuProIO solid drug NPs incorporating the repurposed neuroprotective agent maprotiline (MAP) and the IOP-lowering agent betaxolol (BX), forming MAP/BX NPs for synergistic glaucoma treatment. The NeuProIO improved stability …
Cationic Poly(Glucosamine)-Based Polymers Bind To Glycans With Varying Affinity Facilitating Transport Across The Glycocalyx Of Endothelial Cells, Claire Bridges, Lu Fu, Dan Wang, James D. Sterling, Susanna Liang, Shenda M. Baker, Jonathan Yeow, Megan S. Lord
Cationic Poly(Glucosamine)-Based Polymers Bind To Glycans With Varying Affinity Facilitating Transport Across The Glycocalyx Of Endothelial Cells, Claire Bridges, Lu Fu, Dan Wang, James D. Sterling, Susanna Liang, Shenda M. Baker, Jonathan Yeow, Megan S. Lord
Business and Information Technology Faculty Research & Creative Works
Natural polysaccharides, such as chitosan, offer promising avenues for drug delivery due to their cytocompatibility and ability to interact with cell surfaces. However, the endothelial glycocalyx, a glycan-rich extracellular matrix, presents a barrier that must be navigated for effective intracellular delivery. This study investigates how cationic poly(glucosamine)-based polymers, functionalized with guanidinium or ammonium groups, interact with key glycocalyx components including hyaluronan (HA) and heparan sulfate (HS). We demonstrate that these cationic polymers form tunable biomolecular condensates with glycans, with stronger binding observed for sulfated glycans, HS and heparin, than unsulfated HA. Derivatized chitosan polymers with varied cationic side chains exhibit …
Hybrid Data-Driven Cement-Stabilized Soil Design: An Integration Of Machine Learning, Multi-Objective Optimization, And Life Cycle Assessment, Chikezie Chimere Onyekwena, Yunli Li, Ikenna J. Okeke, Ubani Obinna Uzodimma, Monday Uchenna Okoronkwo, Wenping Wu
Hybrid Data-Driven Cement-Stabilized Soil Design: An Integration Of Machine Learning, Multi-Objective Optimization, And Life Cycle Assessment, Chikezie Chimere Onyekwena, Yunli Li, Ikenna J. Okeke, Ubani Obinna Uzodimma, Monday Uchenna Okoronkwo, Wenping Wu
Chemical and Biochemical Engineering Faculty Research & Creative Works
Soil stabilization is crucial in geotechnical engineering, yet conventional methods are often time-consuming, resource-intensive, and environmentally unsustainable. Despite growing interest in Machine Learning (ML) and optimization tools for mix design, few studies integrate these methods with decision-making techniques and environmental assessment to support practical implementation. This study proposes a hybrid data-driven framework for predicting strength, optimizing mix compositions, and evaluating environmental impacts via life cycle assessment of cement-stabilized soft soils. Six ML models were evaluated, and the top-performing eXtreme Gradient Boosting (XGB) model was further improved using the Grey Wolf Optimizer (GWO). The optimized XGB-GWO model, integrated with a polynomial …
Performance And Mechanistic Insights Into Cement Systems Modified With Wastewater-Recovered Struvite, Ugochukwu Ewuzie, Rupack R. Halder, Abdulkareem O. Yusuf, Abiodun A. Saka, Godwin I. Ogbuehi, Titus C. Egbosiuba, Damilola A. Daramola, Monday Uchenna Okoronkwo
Performance And Mechanistic Insights Into Cement Systems Modified With Wastewater-Recovered Struvite, Ugochukwu Ewuzie, Rupack R. Halder, Abdulkareem O. Yusuf, Abiodun A. Saka, Godwin I. Ogbuehi, Titus C. Egbosiuba, Damilola A. Daramola, Monday Uchenna Okoronkwo
Chemical and Biochemical Engineering Faculty Research & Creative Works
Struvite, the stable hydration product and primary strength phase in magnesium ammonium phosphate cement (MAPC), derived from wastewater treatment, has recently been utilized as a sustainable additive to Portland cement (PC). However, its impacts on cement hydration kinetics, pore refinement, rheology, and the mechanisms underlying these processes have not been comprehensively studied. This study developed Portland cement-struvite (PCS) systems by replacing PC with 3–20 % struvite (ST wt.%: PCS3–PCS20) and evaluated these processes using isothermal calorimetry, 3D micro-computed tomography (μXCT), time-dependent rheometry, X-ray diffraction (XRD), and Fourier-transform infrared spectroscopy (FTIR), and the Krstulović-Dabić (K-D) model. The FTIR/XRD confirmed the coexistence …
Nanocatalytic Enhancement Of Local Heat Transfer In Continuous-Flow Thermal Reactors, Nasser Zouli, Nujud Maslamani, Ayman Yousef, Muthanna H. Al-Dahhan
Nanocatalytic Enhancement Of Local Heat Transfer In Continuous-Flow Thermal Reactors, Nasser Zouli, Nujud Maslamani, Ayman Yousef, Muthanna H. Al-Dahhan
Chemical and Biochemical Engineering Faculty Research & Creative Works
An experimental investigation was conducted to evaluate the thermal conductivity (TC) and local heat-transfer coefficients (LHTCs) of nanofluids containing alumina (Al2O3), hematite (Fe2O3), and copper oxide (CuO) nanoparticles dispersed in deionized water. A newly developed non-invasive LHTC probe was integrated into the inner wall of the test section to enable direct quantification of interfacial heat-transfer performance. The measurements were conducted under laminar and turbulent flow conditons across Reynolds numbers ranging from 1000 to 10,000. The selected nanoparticles were chosen based on their high intrinsic thermal conductivity, cost effectiveness, and, in the case …
Effect Of Ionic Strength On Gelation Time And Strength Of Amps-Based Polymer Gels, Maryam Sharifi Paroushi, Xuyang Tian, Baojun Bai, Thomas P. Schuman, Yin Zhang, Mingzhen Wei
Effect Of Ionic Strength On Gelation Time And Strength Of Amps-Based Polymer Gels, Maryam Sharifi Paroushi, Xuyang Tian, Baojun Bai, Thomas P. Schuman, Yin Zhang, Mingzhen Wei
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
Polymer gel treatment has been widely applied for improving sweep efficiency and controlling excessive water and gas production. Their performance depends on gelation time and final gel strength. In most studies, brine salinity is used to describe the effect of formation water on gel behavior. However, changing salinity also changes ionic strength and ion composition at the same time. Because of this coupling, it is difficult to identify the mechanisms controlling gelation, which has led to inconsistent trends in the literature. Increasing salinity has been reported to either slow or accelerate gelation and to weaken or strengthen gels depending on …
Evaluation Of A Novel Re-Crosslinkable Preformed Particle Gel For Conformance Control In Ultra-High Temperature Reservoirs, Yanbo Liu, Tao Song, Caleb Kwasi Darko, Thomas P. Schuman, Mingzhen Wei, Baojun Bai
Evaluation Of A Novel Re-Crosslinkable Preformed Particle Gel For Conformance Control In Ultra-High Temperature Reservoirs, Yanbo Liu, Tao Song, Caleb Kwasi Darko, Thomas P. Schuman, Mingzhen Wei, Baojun Bai
Chemistry Faculty Research & Creative Works
Preferential fluid flow remains a major challenge in subsurface energy production and gas storage operations, resulting in excessive water production in mature oil fields, reduced heat extraction in geothermal reservoirs, and low sweep and storage efficiency in CO2-EOR projects. Polymer gels are widely used to mitigate high-permeability channels; however, conventional systems exhibit limited plugging efficiency and short lifetimes in ultra-high-temperature reservoirs due to poor thermal stability. This study presents a novel ultra-high-temperature-resistant preformed particle gel (UHT-PPG) developed for conformance control in reservoirs with temperatures of 150–275 °C and severe super-K or channeling problems. The material was evaluated in …
A Four-Step Thermocatalytic Route For Converting Co2 Into High-Purity Oxalic Acid, Hao Feng, Muhammad Kashif Khan, Lei Li, Hongyan Ma, Xinhua Liang
A Four-Step Thermocatalytic Route For Converting Co2 Into High-Purity Oxalic Acid, Hao Feng, Muhammad Kashif Khan, Lei Li, Hongyan Ma, Xinhua Liang
Civil, Architectural and Environmental Engineering Faculty Research & Creative Works
This research outlines a four-step methodology for transforming CO2 into high-purity oxalic acid. CO2 was first sequestered as KHCO3 through its reaction with aqueous KOH, followed by hydrogenation using a supported AgPd/CNT catalyst in a batch reactor at an initial H2 pressure of 60 bar and a temperature of 150°C. The formate yield reached 91.8% at optimum conditions. Potassium formate in the solid state was thermally coupled in the presence of KOH at 400°C under N2 flow, yielding potassium oxalate of up to 76% yield. The final step was the selective precipitation of potassium oxalate with ferrous …
Evaluation Of Chromium-Crosslinked Amps-Hpam Copolymer Gels: Effects Of Key Parameters On Gelation Time And Strength, Maryam Sharifi Paroushi, Baojun Bai, Thomas P. Schuman, Yin Zhang, Mingzhen Wei
Evaluation Of Chromium-Crosslinked Amps-Hpam Copolymer Gels: Effects Of Key Parameters On Gelation Time And Strength, Maryam Sharifi Paroushi, Baojun Bai, Thomas P. Schuman, Yin Zhang, Mingzhen Wei
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
Controlling CO2 channeling in heterogeneous reservoirs remains a major challenge for both enhanced oil recovery (EOR) and secure geological storage. AMPS-HPAM copolymers exhibit high-temperature resistance and brine tolerance compared with conventional HPAM gels, making them well suited for the harsh environments associated with CO2 injection. Chromium-based crosslinkers (CrAc and CrCl3) were investigated because sulfonic acid groups in AMPS can coordinate with trivalent chromium ions, enabling dual ionic crosslinking and the formation of a robust gel network. While organic crosslinked AMPS-HPAM gels have been widely studied, the behavior of chromium-crosslinked AMPS-containing systems, particularly their gelation kinetics under …
Solubility And Dissolution Mechanism Of Novel Multi-Ester Headgroup Surfactants In Supercritical Co2, Ning Xu, Yan Ling Wang, Baojun Bai, Shi Zhang Cui, Yu Zhang, Wen Jing Shi, Zhao Nian Zhang, Wen Hui Ding, Pei Xu Ma, Zan Gao
Solubility And Dissolution Mechanism Of Novel Multi-Ester Headgroup Surfactants In Supercritical Co2, Ning Xu, Yan Ling Wang, Baojun Bai, Shi Zhang Cui, Yu Zhang, Wen Jing Shi, Zhao Nian Zhang, Wen Hui Ding, Pei Xu Ma, Zan Gao
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
To address the limited solubility and applicability of conventional hydrocarbon surfactants in supercritical CO2, a series of multi-ester headgroup surfactants were designed and synthesized by leveraging the CO2-philic properties of ester groups. The molecular structures were characterized using Fourier transform infrared (FT-IR) spectroscopy and 1H NMR. A custom-designed laser-based apparatus was developed to quantify surfactant solubility and systematically investigate phase behavior in CO2. Molecular dynamics (MD) simulations were employed to elucidate structure–solubility relationships across multiple scales, including solubility parameters, interaction energies, radial distribution functions (RDFs), and free volume fractions. Results indicate that, at 323.15 K, …